The present disclosure relates to processing chambers, and more particularly to systems and methods for reducing parasitic plasma in plasma-enhanced semiconductor processing chambers.
The background description provided herein is for the purpose of generally presenting the context of the disclosure. Work of the presently named inventors, to the extent it is described in this background section, as well as aspects of the description that may not otherwise qualify as prior art at the time of filing, are neither expressly nor impliedly admitted as prior art against the present disclosure.
Some semiconductor processing systems may employ plasma when depositing thin films on a substrate in a processing chamber. Generally, the substrate is arranged on a pedestal in the processing chamber. To create the thin film using chemical vapor deposition, one or more precursors are supplied by a showerhead to the processing chamber.
During processing, radio frequency (RF) power may be supplied to the showerhead or to an electrode to create plasma. For example, RF power may be supplied to the electrode embedded in a pedestal platen, which may be made of a non-conducting material such as ceramic. Another conducting portion of the pedestal may be connected to RF ground or another substantially different electrical potential.
When the electrode is excited by the RF power, RF fields are generated between the substrate and the showerhead to create plasma between the wafer and the showerhead. When the pedestal platen is made of ceramic, the RF fields will also appear under and beside the pedestal platen and give rise to parasitic plasma. Parasitic plasma may be reduced or eliminated in certain regions if the electric fields penetrating these regions can be reduced. One way to reduce or eliminate the electric fields is to use a grounded RF shield. However, if the RF shield is not designed properly, it can give rise to a low RF impedance path to ground.
One way to prevent excessive RF coupling to ground is to use a solid dielectric layer between ground and the electrode. However, the thickness of the solid dielectric layer that is required to achieve low coupling capacitance to ground is generally not practical.
A plasma reducing system for reducing parasitic plasma in a semiconductor process comprises a first surface and a plurality of dielectric layers that are arranged between an electrode and the first surface. The first surface and the electrode have substantially different electrical potentials. The plurality of dielectric layers defines a first gap between the electrode and one of the plurality of dielectric layers, a second gap between adjacent ones of the plurality of dielectric layers, and a third gap between a last one of the plurality of dielectric layers and the first surface. A number of the plurality of dielectric layers and sizes of the first gap, the second gap and the third gap are selected to prevent parasitic plasma between the first surface and the electrode during the semiconductor process.
In other features, the first surface comprises a grounded conducting structure. Barriers are arranged between radially outer ends of the plurality of dielectric layers to prevent incursion of deposition precursor species between the plurality of dielectric layers. Diameters of each of the plurality of dielectric layers decrease as a distance increases between the electrode and a respective one of the plurality of dielectric layers. Each of the plurality of dielectric layers comprises a radially inner portion having a first thickness in an axial direction and a protruding portion that extends radially outwardly and has a second thickness in the axial direction. A difference between the first thickness and the second thickness is equal to the second gap. The semiconductor process comprises plasma-enhanced chemical vapor deposition (PECVD).
In other features, a pedestal comprises the plasma reducing system, a pedestal including a pedestal platen that supports a substrate and that is made of a non-conducting material, and the electrode. The electrode is embedded in the pedestal platen. During the semiconductor process, the grounded conducting structure is connected to RF ground and the electrode is connected to an RF bias.
In other features, a collar is connected to the first surface and an adapter is connected to the collar. The first surface, the collar and the adapter are made of aluminum. The pedestal platen comprises ceramic, the first surface comprises a conducting disk, the electrode comprises wire mesh and each of the plurality of dielectric layers comprises a disk.
In other features, a showerhead system comprises the plasma reducing system. The electrode includes a showerhead including a first stem portion and a head portion. The plurality of dielectric layers comprise M dielectric layers arranged adjacent to the head portion and P dielectric portions arranged around the first stem portion, wherein M and P are integers greater than one.
In other features, the grounded conducting structure comprises a second stem portion arranged around the first stem portion and the P dielectric portions and a disk portion that projects radially outwardly from the second stem portion. During the semiconductor process, the showerhead is connected to an RF bias and the grounded conducting structure is connected to RF ground.
A pedestal system for a semiconductor process comprises a pedestal platen that supports a substrate, that is made of a non-conducting material and that includes an electrode embedded therein. A first surface has a substantially different electrical potential than the electrode. N dielectric layers are arranged between the pedestal platen and the first surface, where N is an integer that is greater than one. The N dielectric layers define a first gap between the pedestal platen and the N dielectric layers, a second gap between adjacent ones of the N dielectric layers, and a third gap between the N dielectric layers and the first surface. N and sizes of the first gap, the second gap and the third gap are selected to prevent parasitic plasma between the first surface and the electrode during the semiconductor process.
A showerhead system for a semiconductor process comprises a showerhead. A first surface has a substantially different electrical potential than the showerhead. A dielectric structure includes a plurality of spaced dielectric layers and is arranged between the first surface and the showerhead. A number of the plurality of spaced dielectric layers and spacing between the plurality of spaced dielectric layers are selected to prevent parasitic plasma between the first surface and the showerhead during the semiconductor process.
Further areas of applicability of the present disclosure will become apparent from the detailed description provided hereinafter. It should be understood that the detailed description and specific examples are intended for purposes of illustration only and are not intended to limit the scope of the disclosure.
The present disclosure will become more fully understood from the detailed description and the accompanying drawings, wherein:
Referring now to
Another portion 135 of the pedestal system 134 has a substantially different electrical potential than the electrode 128. For example the portion 135 may be connected to a ground reference potential. Alternately, the HF RF generator 120, the LF RF generator 124 and the matching network 126 can be connected to the showerhead system 110.
The RF signal supplied by the matching network 126 has a power and a frequency sufficient to generate plasma from the process gas. In a typical process, the HF RF generator 120 may operate in a frequency range of 2-60 MHz, although other frequencies may be used. The LF RF generator 124 may operate in a frequency range of 100 kHz-2 MHz, although other frequencies may be used. Suitable power levels may include LF power at about 200-600 W and HF power at about 100-1500 W, although other power levels may be used. The process chamber may be operated at approximately 500 mT-12 Torr.
The pedestal system 134 typically includes a chuck, a fork, or lift pins (all not shown) to hold and transfer a substrate 136 during and between deposition and/or plasma treatment reactions. The chuck may be an electrostatic chuck, a mechanical chuck or various other types of chuck.
The process gases are introduced via inlet 142. Multiple process gas lines 142-1, 142-2, 143-3, are connected to a manifold 150. The process gases may be premixed or not. Appropriate valving and mass flow control mechanisms (generally identified at 144-1, 144-2, 144-3, . . . ) are employed to ensure that the correct gases are delivered during the deposition and plasma treatment phases of the process. In some examples, the chemical precursor(s) are initially delivered in the liquid form. For example only, the liquid may be vaporized and mixed with other process gases in a manifold that is heated above a vaporization temperature. Process gases exit the process chamber 102 via an outlet 160. A vacuum pump 164 typically draws process gases out of the process chamber 102 and maintains a suitably low pressure within the reactor by a flow restriction device, such as a valve 166.
The system for reducing parasitic plasma according to the present disclosure can be retro-fit to existing systems and/or implemented when the semiconductor processing system is initially installed. The system suppresses unwanted (parasitic) plasma near RF powered surfaces (e.g. an electrode in a pedestal or showerhead) while providing a high impedance path to ground from those surfaces. The high impedance path is created using a plurality of spaced dielectric layers, which have a lower dielectric constant than can be achieved using a solid dielectric layer. Alternating gaps and dielectric layers may be terminated by a surface having a substantially different electrical potential such as a grounded conducting structure.
Referring now to
In some examples, a gap “g” is provided between the conducting structure 240 and a first one of the N dielectric layers 250, between adjacent ones of the N dielectric layers 250 and between a last one of the N dielectric layers 250 and the pedestal platen 252. The pedestal platen 252 may be made of a non-conducting material such as ceramic or other suitable material. In some examples, N=2, although additional or fewer dielectric disks may be used.
An additional surface 254 or “mesa” may be provided on a top surface of the pedestal platen 252. The substrate 136 may be arranged on an upper surface of the pedestal platen 252 or on the additional surface 254 or mesa. The pedestal platen 252 may include an inner cylindrical portion 256 that extends downwardly through an inner cylindrical portion 258 of the collar 230. The pedestal platen 252 may include a flanged portion 260 that extends radially outwardly from a bottom end of the inner cylindrical portion 258. The flanged portion 260 may mate with a recess 262 formed in the adapter 220. A seal 266 such as an “O”-ring may be arranged between the recess 262 and the flanged portion 260.
The electrode 128 may be embedded in the pedestal platen 252. In some examples, the electrode 128 may include a wire mesh or spaced conductors. In other examples, the conducting structure 240 may have a diameter that is greater than the adapter 220, greater than the substrate 136 and/or less than the diameter of the pedestal platen 252. In some examples, the adapter 220, the collar 230 and the conducting structure 240 may be made of metal such as aluminum or another suitable conducting material.
In some examples, the metal adapter 220, the collar 230 and the conducting structure 240 are connected to RF ground or another electrical potential that is substantially different than the electrode 128. The combination of the N dielectric layers 250, the adapter 220, the collar 230 and the conducting structure 240 provide RF shielding, which attenuates the RF fields below the pedestal platen 252. This, in turn, significantly attenuates plasma density formed below the pedestal platen 252. This design has been shown to reduce parasitic plasma density by a factor of about 5.
The presence of conducting grounded surfaces (such as the adapter 220, the collar 230 and/or the conducting structure 240) near RF “hot” surfaces (such as the conducting structure 240) presents a problem if the capacitive coupling of the RF “hot” surfaces to ground is too high. In some examples, coupling capacitance to ground may be limited to values less than 100 picoFarads (pF). Insertion of a dielectric sufficiently thick to provide low capacitive coupling (i.e. values less than 100 pF) typically results in very thick layers (many cm in size) that are either not practical or expensive to implement. In some examples, the present disclosure resolves this problem using the N dielectric layers or disks with a gap between them, where N is an integer greater than one.
An equivalent circuit corresponding to the spaced N dielectric layers includes multiple capacitors that are connected in series. The net capacitance of the series connection of the equivalent capacitors is lower than the lowest capacitor value. For the dielectric stack shown in
Since the RF fields in the dielectric stack are still very high, plasma formation (plasma light-up) may occur between the N dielectric layers 250. In some examples, the gap g is selected such that it is sufficiently small to prevent formation of “bulk” plasma. For example only, the gap g that is less than or equal to 3 mm tends to prevent plasma formation when N=2 for pressures and power levels that are typically used. However, the size of the gap g may be set to other values when N=2, when N>2, or when different pressures or RF power levels are used. The size of the gap and the number of dielectric layers may be selected to prevent plasma formation between the dielectric layers during the semiconductor process for the selected species and selected process conditions such as temperature, pressure and RF power and frequency.
In some examples, the N dielectric layers 250 include a radially inner portion 300 having a first thickness in an axial direction and a protruding portion 302 that extends radially outwardly and has a second thickness in the axial direction. A difference between the first thickness and the second thickness is equal to the gap g.
In some examples, one or more barriers 320 may be arranged between radially outer ends of the N dielectric layers 250 to prevent incursion of deposition precursor species between the N dielectric layers 250. While only one barrier is shown, additional barriers may be arranged in other locations to prevent incursion of deposition precursor into the gaps. For example only, the barriers 320 may be made from any suitable dielectric material that does not shed particles. The barriers 320 tend to reduce the risk for creating a difficult to clean site that can lead to accumulation of film between the N dielectric layers 250 that could radiate particles into the process chamber 102.
Referring now to
Referring now to
Referring now to
P dielectric portions 520-1, . . . , and 520-P (collectively referred to as the P dielectric portions 520) are arranged vertically adjacent to the stem portion 506. A conducting portion 530 is arranged adjacent to the M dielectric layers 510 and the P dielectric layers 520. The conducting portion 530 may include a cylindrical stem portion 534 and a disk portion 538 that projects radially outwardly from one end of the cylindrical stem portion 534.
In some examples, the P dielectric layers 520 may have a cylindrical cross section and the M dielectric layers 510 have a disk shape similar to that shown in
Referring now to
A first supporting portion 644 is connected to a top portion 646 of the processing chamber. The first supporting portion 644 is arranged adjacent to the stem portion 606 of the showerhead 600. The top portion 646 of the processing chamber or any other surface at a different electrical potential is arranged adjacent to the head portion 604 of the showerhead 600. A plurality of dielectric layers or disks 650 are arranged between the head portion 604 and the top portion 646. A first gap 652 is defined between the head portion 604 and a first one of the plurality dielectric layers 650. A second gap 654 is defined between adjacent ones of the plurality dielectric layers 650. A third gap 656 is defined between a last one of the plurality dielectric layers 650 and the supporting portion 648.
In some examples, the head portion 604 and the stem portion 606 of the showerhead 600 may be made of a conducting material and may be connected to an RF bias source. The first supporting portion 644 may be made of an insulating material. The pedestal 620 may be made of a conducting material and may be connected to a ground reference potential. As can be appreciated, the top portion 646 of the processing chamber has a substantially different electrical potential than the showerhead 600. As a result, parasitic plasma may be formed in a gap between the showerhead and the top portion of the processing chamber.
According to the present disclosure, the plurality of dielectric layers are separated by gaps and are arranged between the showerhead and the top portion of the processing chamber to eliminate the parasitic plasma that would otherwise be created. As with the preceding examples, the size of the gaps 652, 654 and 656 and the number of dielectric layers 650 are selected to prevent plasma formation in the area between the showerhead 600 and the top portion 646 of the processing chamber during the semiconductor process for the selected species and selected process conditions such as temperature, pressure and RF power and frequency.
The foregoing description is merely illustrative in nature and is in no way intended to limit the disclosure, its application, or uses. The broad teachings of the disclosure can be implemented in a variety of forms. Therefore, while this disclosure includes particular examples, the true scope of the disclosure should not be so limited since other modifications will become apparent upon a study of the drawings, the specification, and the following claims. For purposes of clarity, the same reference numbers will be used in the drawings to identify similar elements. As used herein, the phrase at least one of A, B, and C should be construed to mean a logical (A or B or C), using a non-exclusive logical OR. It should be understood that one or more steps within a method may be executed in different order (or concurrently) without altering the principles of the present disclosure.
The present disclosure is a divisional of U.S. patent application Ser. No. 13/303,386, filed on Nov. 23, 2011, which claims the benefit of U.S. Provisional Application No. 61/547,962, filed on Oct. 17, 2011. The entire disclosures of the applications referenced above are incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
4580522 | Fujioka et al. | Apr 1986 | A |
5290381 | Nozawa et al. | Mar 1994 | A |
5366585 | Robertson et al. | Nov 1994 | A |
5382311 | Ishikawa et al. | Jan 1995 | A |
5443648 | Ohkase | Aug 1995 | A |
5539179 | Nozawa et al. | Jul 1996 | A |
5567243 | Foster et al. | Oct 1996 | A |
5628829 | Foster et al. | May 1997 | A |
5637146 | Chyi | Jun 1997 | A |
5680013 | Dornfest et al. | Oct 1997 | A |
5772770 | Suda et al. | Jun 1998 | A |
5772773 | Wytman | Jun 1998 | A |
5800618 | Niori | Sep 1998 | A |
5846883 | Moslehi | Dec 1998 | A |
5959409 | Dornfest et al. | Sep 1999 | A |
5996528 | Berrian et al. | Dec 1999 | A |
6001183 | Gurary | Dec 1999 | A |
6036782 | Tanaka et al. | Mar 2000 | A |
6051100 | Walko, II | Apr 2000 | A |
6095085 | Agarwal | Aug 2000 | A |
6120640 | Shih et al. | Sep 2000 | A |
6120661 | Hirano et al. | Sep 2000 | A |
6235146 | Kadotani et al. | May 2001 | B1 |
6349670 | Nakano | Feb 2002 | B1 |
6415736 | Hao et al. | Jul 2002 | B1 |
6453992 | Kim | Sep 2002 | B1 |
6494958 | Shamouilian et al. | Dec 2002 | B1 |
6506254 | Bosch et al. | Jan 2003 | B1 |
6533867 | Doppelhammer | Mar 2003 | B2 |
6634314 | Hwang et al. | Oct 2003 | B2 |
6783627 | Mahawili | Aug 2004 | B1 |
6863018 | Koizumi | Mar 2005 | B2 |
6902620 | Omstead et al. | Jun 2005 | B1 |
7147760 | Woodruff et al. | Dec 2006 | B2 |
7153542 | Nguyen et al. | Dec 2006 | B2 |
7337745 | Komino et al. | Mar 2008 | B1 |
7438765 | Park | Oct 2008 | B2 |
7661386 | Kasai et al. | Feb 2010 | B2 |
7712434 | Dhindsa et al. | May 2010 | B2 |
7749353 | Rusu et al. | Jul 2010 | B2 |
7802539 | Bosch | Sep 2010 | B2 |
8043842 | Blattner et al. | Oct 2011 | B2 |
8083855 | Dhindsa et al. | Dec 2011 | B2 |
8137467 | Meinhold et al. | Mar 2012 | B2 |
8216486 | Dhindsa et al. | Jul 2012 | B2 |
8443756 | Fischer et al. | May 2013 | B2 |
8733279 | White et al. | May 2014 | B2 |
9388494 | Xia | Jul 2016 | B2 |
20010047760 | Moslehi | Dec 2001 | A1 |
20020000198 | Ishikawa | Jan 2002 | A1 |
20020017243 | Pyo | Feb 2002 | A1 |
20020048311 | Norrbakhsh et al. | Apr 2002 | A1 |
20020158060 | Uchiyama et al. | Oct 2002 | A1 |
20030196760 | Tyler et al. | Oct 2003 | A1 |
20030205202 | Funaki et al. | Nov 2003 | A1 |
20040000378 | Lee et al. | Jan 2004 | A1 |
20040065255 | Yang et al. | Apr 2004 | A1 |
20040074609 | Fischer et al. | Apr 2004 | A1 |
20040149212 | Cho et al. | Aug 2004 | A1 |
20040187779 | Park et al. | Sep 2004 | A1 |
20050173569 | Noorbakhsh et al. | Aug 2005 | A1 |
20050241765 | Dhindsa et al. | Nov 2005 | A1 |
20060057303 | Agarwal et al. | Mar 2006 | A1 |
20070031236 | Chen | Feb 2007 | A1 |
20070137573 | Kholodenko et al. | Jun 2007 | A1 |
20070256785 | Pamarthy et al. | Nov 2007 | A1 |
20070266945 | Shuto et al. | Nov 2007 | A1 |
20080017111 | Ishisaka et al. | Jan 2008 | A1 |
20080066682 | Yamashita | Mar 2008 | A1 |
20080075858 | Koh | Mar 2008 | A1 |
20080196666 | Toshima | Aug 2008 | A1 |
20080241517 | Kenworthy et al. | Oct 2008 | A1 |
20090000743 | Iizuka | Jan 2009 | A1 |
20090078694 | Hayashi | Mar 2009 | A1 |
20090095219 | Meinhold et al. | Apr 2009 | A1 |
20090101283 | Iwata | Apr 2009 | A1 |
20090159587 | Shimanuki | Jun 2009 | A1 |
20090190908 | Shibagaki | Jul 2009 | A1 |
20100000684 | Choi | Jan 2010 | A1 |
20100059182 | Lee et al. | Mar 2010 | A1 |
20100083902 | Kim et al. | Apr 2010 | A1 |
20100103584 | Nam | Apr 2010 | A1 |
20110198417 | Detmar et al. | Aug 2011 | A1 |
20120097330 | Iyengar et al. | Apr 2012 | A1 |
20120220109 | Komori et al. | Aug 2012 | A1 |
20120222815 | Sabri et al. | Sep 2012 | A1 |
20120225193 | Yudovsky | Sep 2012 | A1 |
20120225195 | Yudovsky | Sep 2012 | A1 |
20130092086 | Keil et al. | Apr 2013 | A1 |
20130233491 | Choi | Sep 2013 | A1 |
20130269609 | Leeser | Oct 2013 | A1 |
20130344245 | Xia et al. | Dec 2013 | A1 |
20140116338 | He et al. | May 2014 | A1 |
20140165911 | Kao et al. | Jun 2014 | A1 |
20140238608 | Sabri et al. | Aug 2014 | A1 |
Number | Date | Country |
---|---|---|
101620989 | Jan 2010 | CN |
H0892746 | Apr 1996 | JP |
H10237657 | Sep 1998 | JP |
H1126192 | Jan 1999 | JP |
H11-111626 | Apr 1999 | JP |
11214195 | Aug 1999 | JP |
2002302772 | Oct 2002 | JP |
2004296553 | Oct 2004 | JP |
2006060073 | Mar 2006 | JP |
2010086958 | Apr 2010 | JP |
2010258404 | Nov 2010 | JP |
2010282970 | Dec 2010 | JP |
10-0388530 | Jun 2003 | KR |
100565131 | Mar 2006 | KR |
2007-0111881 | Nov 2007 | KR |
20080001336 | Jan 2008 | KR |
10-0845896 | Jul 2008 | KR |
20100004857 | Jan 2010 | KR |
200403136 | Mar 2004 | TW |
WO-9943018 | Aug 1999 | WO |
Entry |
---|
IEEE Recommended Practice for Powering and Grounding Sensitive Electronic Equipment “Std 1100-1992”, p. 22 (Year: 1992). |
Notification Concerning Transmittal of International Preliminary Report on Patentability for PCT/US2012/052789 filed Aug. 29, 2012; 9 pages. |
International Search Report and Written Opinion for PCT/US2012/052789 filed Aug. 28, 2012; 13 pages. |
First Office Action dated Nov. 17, 2015 corresponding to Chinese Patent Application No. 201280062473.3, 8 pages. |
Translation of Notification of Examination Opinions dated Feb. 17, 2016 corresponding to Taiwan Patent Application No. 101138269, 3 pages. |
Notification of Reasons for Rejection corresponding to Japanese Patent Application No. 2014-537061, dated Jul. 8, 2016, 13 pages. |
Translation of Office Action dated Jun. 12, 2020 corresponding to Korean Patent Application No. 10-2014-0024538, 2 pages. |
Number | Date | Country | |
---|---|---|---|
20190172684 A1 | Jun 2019 | US |
Number | Date | Country | |
---|---|---|---|
61547962 | Oct 2011 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 13303386 | Nov 2011 | US |
Child | 16267932 | US |