With advances in semiconductor technology, there has been increasing demand for higher storage capacity, faster processing systems, higher performance, and lower costs. To meet these demands, the semiconductor industry continues to scale down the dimensions of semiconductor devices, such as metal oxide semiconductor field effect transistors (MOSFETs), including planar MOSFETs and fin field effect transistors (finFETs). Such scaling down has increased the complexity of semiconductor manufacturing processes and increased the difficulty of defects control in the semiconductor devices.
Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures.
Illustrative embodiments will now be described with reference to the accompanying drawings. In the drawings, like reference numerals generally indicate identical, functionally similar, and/or structurally similar elements.
The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. As used herein, the formation of a first feature on a second feature means the first feature is formed in direct contact with the second feature. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper,” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
It is noted that references in the specification to “one embodiment,” “an embodiment,” “an example embodiment,” “exemplary,” etc., indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases do not necessarily refer to the same embodiment. Further, when a particular feature, structure or characteristic is described in connection with an embodiment, it would be within the knowledge of one skilled in the art to effect such feature, structure or characteristic in connection with other embodiments whether or not explicitly described.
It is to be understood that the phraseology or terminology herein is for the purpose of description and not of limitation, such that the terminology or phraseology of the present specification is to be interpreted by those skilled in relevant art(s) in light of the teachings herein.
In some embodiments, the terms “about” and “substantially” can indicate a value of a given quantity that varies within 20% of the value (e.g., ±1%, ±2%, ±3%, ±4%, ±5%, ±10%, ±20% of the value). These values are merely examples and are not intended to be limiting. The terms “about” and “substantially” can refer to a percentage of the values as interpreted by those skilled in relevant art(s) in light of the teachings herein.
With advances in semiconductor technology, multi-gate devices have been introduced to improve gate control by increasing gate-channel coupling, reducing off-state current, and reducing short-channel effects (SCEs). One such multi-gate device is the nanostructure transistor, which includes the gate-all-around field effect transistor (GAA FET), the nanosheet transistor, the nanowire transistor, the multi bridge channel transistor, the nano-ribbon transistor, and other similar structured transistors. The nanostructure transistor provides a channel in a stacked nanosheet/nanowire configuration. The GAA FET device derives its name from the gate structure that can extend around the channel and provide gate control of the channel on multiple sides of the channel. Nanostructure transistor devices are compatible with MOSFET manufacturing processes and their structure allows them to be scaled while maintaining gate control and mitigating SCEs.
With increasing demand for lower power consumption, higher performance, and smaller area (collectively referred to as “PPA”) of semiconductor devices, nanostructure transistor devices can have their challenges. For example, nanostructure transistor devices can have inner spacer structures between the gate structure and the source/drain (S/D) structures to reduce parasitic capacitance. In p-type nanostructure transistor devices, embedded silicon germanium (SiGe) stressors (e.g., S/D structures) can be used to increase the device current and improve device performance. However, dislocation defects can form in the S/D structures of nanostructure transistor devices having inner spacer structures. The S/D defects can relax the strain imparted on the channels, lower the device current, and degrade the device performance of nanostructure transistor devices. At the same time, without the inner spacer structures, the dislocation defects in the S/D structures can be reduced while the parasitic capacitance between the S/D structures and the gate structure can increase. The increase of parasitic capacitance can decrease the device performance.
Various embodiments in the present disclosure provide example methods for forming an asymmetric source/drain (S/D) design for a nanostructure transistor device (e.g., a GAA FET) and/or other semiconductor devices in an integrated circuit (IC). The nanostructure transistor device can have multiple nanostructure channels and a gate structure wrapped around the nanostructure channels. An inner spacer structure can be in contact with a first side of the gate structure and can be disposed between the gate structure and a first S/D structure. An epitaxial layer can be in contact with a second side of the gate structure and can be disposed between the gate structure and a second S/D structure. The second side can be opposite to the first side. In some embodiments, the first side can be a drain side of the nanostructure transistor device and the second side can be a source side of the nanostructure transistor device.
With the epitaxial layer on the source side, the dislocation defects in the second S/D structure can be reduced by about 50% to about 80%, the resistance of the second S/D structure can be significantly reduced, the proximity between the second S/D structure and the gate structure can be reduced, the strain imparted on the nanostructure channels can be improved, and the device current can be increased. The inner spacer structure on the drain side can reduce the parasitic capacitance between the gate structure and the first S/D structure. As the channel current of the nanostructure transistor device is dominated by the resistance of the second S/D structure on the source side, the asymmetric design of the nanostructure transistor device can improve the device performance, for example, by about 5% to about 20% for a p-type nanostructure transistor device and by about 0.5% to about 5% for an n-type nanostructure transistor device.
In some embodiments, nanostructure transistors 102-1 and 102-2 can be both n-type nanostructure transistors (NFETs). In some embodiments, nanostructure transistor 102-1 can be an NFET and have n-type S/D structures 114. Nanostructure transistor 102-2 can be a p-type nanostructure transistor (PFET) and have p-type S/D structures 114. In some embodiments, nanostructure transistors 102-1 and 102-2 can be both PFETs. Though
Referring to
STI regions 106 can provide electrical isolation between nanostructure transistors 102-1 and 102-2 from each other and from neighboring nanostructure transistors (not shown) on substrate 104 and/or neighboring active and passive elements (not shown) integrated with or deposited on substrate 104. STI regions 106 can be made of a dielectric material. In some embodiments, STI regions 106 can include silicon oxide, silicon nitride, silicon oxynitride, fluorine-doped silicate glass (FSG), a low-k dielectric material, and/or other suitable insulating materials. In some embodiments, STI regions 106 can include a multi-layered structure.
Referring to
As shown in
Referring to
As shown in
In some embodiments, metal gate structure 124 can include a work-function layer and a gate electrode. The work-function layer can wrap around nanostructures 108 and can include work-function metals to tune the threshold voltage (Vt) of nanostructure transistors 102-1 and 102-2. In some embodiments, the work-function layer can include titanium nitride, ruthenium, titanium aluminum, titanium aluminum carbon, tantalum aluminum, tantalum aluminum carbon, or other suitable work-function metals. In some embodiments, the work-function layer can include a single metal layer or a stack of metal layers. The stack of metal layers can include work-function metals having work-function values equal to or different from each other. The gate electrode can include titanium, tantalum, aluminum, cobalt, tungsten, nickel, ruthenium, and other suitable conductive materials. Depending on the spaces between adjacent nanostructures 108 and the thicknesses of the layers of gate structures 110, nanostructures 108 can be wrapped around by one or more layers of gate structures 110 filling the spaces between adjacent nanostructures 108.
Referring to
S/D structures 114 can be disposed on substrate 104 and on opposing sides of nanostructures 108. In some embodiments, semiconductor device 100 can have a first S/D structure 114A on a first side (e.g., drain side) and a second S/D structure 114B on a second side (e.g., source side) of nanostructure transistors 102-1 or 102-2. S/D structures 114 can function as S/D regions of nanostructure transistors 102-1 or 102-2. In some embodiments, S/D structures 114 can have any geometric shape, such as a polygon, an ellipsis, and a circle. In some embodiments, S/D structures 114 can include an epitaxially-grown semiconductor material, such as silicon, the same material as substrate 104. In some embodiments, the epitaxially-grown semiconductor material can include an epitaxially-grown semiconductor material different from the material of substrate 104, such as silicon germanium, and imparts a strain on the channel regions under gate structures 110. Since the lattice constant of such epitaxially-grown semiconductor material is different from the material of substrate 104, the channel regions are strained to increase carrier mobility in the channel regions of semiconductor device 100. The epitaxially-grown semiconductor material can include: (i) a semiconductor material, such as germanium and silicon; (ii) a compound semiconductor material, such as gallium arsenide and aluminum gallium arsenide; or (iii) a semiconductor alloy, such as silicon germanium and gallium arsenide phosphide.
In some embodiments, S/D structures 114 can include silicon and can be in-situ doped during an epitaxial growth process using n-type dopants, such as phosphorus and arsenic. In some embodiments, S/D structures 114 can include silicon, silicon germanium, germanium, or III-V materials (e.g., indium antimonide, gallium antimonide, or indium gallium antimonide) and can be in-situ doped during an epitaxial growth process using p-type dopants, such as boron, indium, and gallium. In some embodiments, S/D structures 114 can include one or more epitaxial layers, where each epitaxial layer can have different compositions.
As shown in
In some embodiments, first S/D epitaxial layers 116 can have a thickness 116t ranging from about 2 nm to about 10 nm. If thickness 116t is less than about 2 nm, first epitaxial layers 116 may not grow. If thickness 116t is greater than about 10 nm, the proximity between S/D structure 114 and gate structures 110 may increase and the device on-current of nanostructure transistors 102-1 and 102-2 may decrease. In some embodiments, sidewalls of first S/D epitaxial layers 116A and inner spacer structures 111 can be aligned. In some embodiments, sidewalls of first S/D epitaxial layers 116A and inner spacer structures 111 may not be aligned.
As shown in
In some embodiments, epitaxial layers 112 can include an epitaxially-grown semiconductor material, such as silicon. Epitaxial layers 112 can be un-doped or doped. In some embodiments, epitaxial layers 112 can include un-doped silicon. In some embodiments, epitaxial layers 112 can include silicon and can be in-situ doped during an epitaxial growth process using n-type dopants, such as phosphorus and arsenic. The n-type dopants can have a concentration from about 1×1019 atoms/cm3 to about 1×1021 atoms/cm3. In some embodiments, epitaxial layers 112 can include silicon and can be in-situ doped during an epitaxial growth process using p-type dopants, such as boron. The p-type dopants can have a concentration from about 1×1019 atoms/cm3 to about 1×1021 atoms/cm3. If the concentration of the n-type dopant or the p-type dopant is greater than about 1×1021 atoms/cm3, the hot carrier leakage current of nanostructure transistors 102-1 and 102-2 may increase. If the concentration of the n-type dopant or the p-type dopant is less than about 1×1019 atoms/cm3, the device on-current of nanostructure transistors 102-1 and 102-2 may decrease.
In some embodiments, epitaxial layers 112 can act as an etch stop layer to protect S/D structures 114 during the formation of gate structures 110. In some embodiments, epitaxial layers 112 can reduce the dislocation defects in S/D structure 114B by about 50% to about 80%, reduce the resistance of S/D structure 114B, reduce the proximity between S/D structure 114B and gate structures 110, increase the strain imparted on nanostructures 108, and increase the device on-current of nanostructure transistors 102-1 and 102-2.
In some embodiments, epitaxial layers 112 can have a thickness 112t ranging from about 1 nm to about 10 nm. A ratio of thickness 112t to thickness 108t can range from about 0.1 to about 2. If thickness 112t is less than about 1 nm or the ratio is less than about 0.1, first epitaxial layers 116B may not grow and S/D structure 114B may be damaged during the formation of gate structures 110. If thickness 112t is greater than about 10 nm or the ratio is greater than about 2, the proximity between S/D structure 114B and gate structures 110 may increase and the device on-current of nanostructure transistors 102-1 and 102-2 may decrease.
In some embodiments, epitaxial layers 112 can improve the device performance for a p-type nanostructure transistor device by about 5% to about 20%. In some embodiments, epitaxial layers 112 can improve the device performance for an n-type nanostructure transistor device by about 0.5% to about 5%.
Referring to
ILD layer 136 can be disposed on ESL 126 over S/D structures 114 and STI regions 106. ILD layer 136 can include a dielectric material deposited using a deposition method suitable for flowable dielectric materials. For example, flowable silicon oxide can be deposited using flowable chemical vapor deposition (FCVD). In some embodiments, the dielectric material can include silicon oxide.
S/D contact structures 128 can be disposed on S/D structures 114 and can be configured to electrically connect S/D regions (e.g., S/D structures 114) of nanostructure transistors 102-1 and 102-2 to other elements of semiconductor device 100 and/or other semiconductor devices in the IC of semiconductor device 100. S/D contact structures 128 can be formed within ILD layer 136. According to some embodiments, S/D contact structures 128 can include metal silicide layers 130 and metal contacts 132 disposed on metal silicide layers 130. Examples of metal used for forming metal silicide layers 130 can include cobalt, titanium, and nickel. In some embodiments, metal contacts 132 can include, for example, tungsten, cobalt, aluminum, copper, titanium, tantalum, silver, ruthenium, metal alloys, or combinations thereof.
For illustrative purposes, the operations illustrated in
In referring to
In some embodiments, first and second sets of semiconductor layers 438* and 108* can be epitaxially grown on substrate 104. In some embodiments, first set of semiconductor layers 438* can include a semiconductor material different from substrate 104. Second set of semiconductor layers 108 can include a semiconductor material the same as substrate 104. In some embodiments, substrate 104 and second set of semiconductor layers 108* can include silicon. First set of semiconductor layers 438* can include silicon germanium. In some embodiments, a germanium concentration in the silicon germanium can range from about 10% to about 50% to increase etch selectivity between first and second sets of semiconductor layers 438* and 108*. In some embodiments, first set of semiconductor layers 438* can have a thickness 438t along a Z-axis ranging from about 3 nm to about 10 nm. Second set of semiconductor layers 108* can have a thickness 108t along a Z-axis ranging from about 5 nm to about 15 nm.
Referring to
In some embodiments, as shown in
In some embodiments, as shown in
Referring to
Referring to
In some embodiments, as shown in
The lateral recess of first set of semiconductor layers 438 can be followed by the formation of inner spacer structures 111. The formation of inner spacer structures 111 can include deposition of spacer layer 111* and trimming spacer layer 111* to form inner spacer structures 111. As shown in
The blanket deposition of spacer layer 111* can be followed by trimming spacer layer 111*. For example, as shown in
In some embodiments, the formation of inner spacer structures 111 can be followed by laterally etching semiconductor layers 438 and 108, as shown in
Referring to
In some embodiments, epitaxial layers 112 can include an epitaxially-grown semiconductor material, such as silicon. Epitaxial layers 112 can be un-doped or doped. In some embodiments, epitaxial layers 112 can include un-doped silicon. In some embodiments, epitaxial layers 112 can include silicon and can be in-situ doped during an epitaxial growth process using n-type dopants, such as phosphorus and arsenic. The n-type dopants can have a concentration from about 1×1019 atoms/cm3 to about 1×1021 atoms/cm3. In some embodiments, epitaxial layers 112 can include silicon and can be in-situ doped during an epitaxial growth process using p-type dopants, such as boron. The p-type dopants can have a concentration from about 1×1019 atoms/cm3 to about 1×1021 atoms/cm3.
In some embodiments, epitaxial layers 112 can have a thickness 112t ranging from about 1 nm to about 10 nm. A ratio of thickness 112t to thickness 108t can range from about 0.1 to about 2. If thickness 112t is less than about 1 nm or the ratio is less than about 0.1, first epitaxial layers 116B may not grow and subsequently-grown S/D structure 114B may be damaged during the formation of gate structures 110. If thickness 112t is greater than about 10 nm or the ratio is greater than about 2, the proximity between subsequently-formed S/D structure 114B and gate structures 110 may increase and the device on-current of nanostructure transistors 102-1 and 102-2 may decrease.
Referring to
In some embodiments, first and second S/D epitaxial layers 116 and 118 can be epitaxially grown by (i) CVD, such as LPCVD and other suitable CVD; (ii) MBE; (iii) any suitable epitaxial process; or (iv) a combination thereof. In some embodiments, first and second S/D epitaxial layers 116 and 118 can be grown by an epitaxial deposition/partial etch process, which can repeat the epitaxial deposition/partial etch process multiple times. Such repeated deposition/partial etch process can be referred to as a cyclic deposition-etch (CDE) process. The CDE process can reduce epitaxial defects formed during the growth and can control the profiles of S/D structures 114. In some embodiments, first and second S/D epitaxial layers 116 and 118 can be in-situ doped with n-type or p-type dopants during the epitaxial growth process.
In some embodiments, S/D structures 114 can include silicon and can be in-situ doped during an epitaxial growth process using n-type dopants, such as phosphorus and arsenic. For n-type in-situ doping, n-type doping precursors, such as phosphine, arsine, and other n-type doping precursors, can be used. In some embodiments, each of the multiple epitaxial layers of S/D structures 114 can have different dopant concentrations. For example, first S/D epitaxial layers 116 can include silicon doped with arsenide or phosphide at a concentration from about 1×1019 atoms/cm3 to about 1×1021 atoms/cm3. Second S/D epitaxial layers 118 can include silicon doped with phosphide at a concentration from about 1×1021 atoms/cm3 to about 1×1022 atoms/cm3.
In some embodiments, S/D structures 114 can include silicon, silicon germanium, germanium, or III-V materials (e.g., indium antimonide, or indium gallium antimonide) and can be in-situ doped during an epitaxial growth process using p-type dopants, such as boron, indium, and gallium. For p-type in-situ doping, p-type doping precursors, such as diborane, boron trifluoride, and other p-type doping precursors, can be used. In some embodiments, each of the multiple epitaxial layers of S/D structures 114 can have different compositions, for example, different dopant concentrations and/or different germanium concentrations. In some embodiments, first S/D epitaxial layers 116 can have a lower Ge concentration than second S/D epitaxial layers 118 to prevent lattice mismatch and dislocation defects. For example, first S/D epitaxial layers 116 can include silicon germanium having a germanium concentration from about 0% to about 30% and doped with boron at a concentration from about 1×1020 atoms/cm3 to about 1×1021 atoms/cm3. Second S/D epitaxial layers 118 can include silicon germanium having a germanium concentration from about 20% to about 100% and doped with boron at a concentration from about 1×1021 atoms/cm3 to about 2×1021 atoms/cm3.
With epitaxial layer 112B on substrate 104 and the second end of semiconductor layers 438 and 108, S/D structure 114B can be epitaxially grown with reduced dislocation defects. S/D structure 114B can include first S/D epitaxial layers 116B and second S/D epitaxial layers 118B. In some embodiments, first and second S/D epitaxial layers 116B and 118B can include silicon and can be in-situ doped with n-type dopants having different concentrations. In some embodiments, first and second S/D epitaxial layers 116B and 118B can include silicon germanium with different germanium concentration and can be in-situ doped with p-type dopants having different concentrations. In some embodiments, epitaxial layer 112B can reduce the dislocation defects in S/D structure 114B by about 50% to about 80%. The decrease of the dislocation defects in S/D structure 114B can reduce the resistance of S/D structure 114B, increase the strain imparted on nanostructures 108, and increase the device on-current of nanostructure transistors 102-1 and 102-2.
The formation of S/D structures 114 can be followed by the formation of ILD layer 136, as shown in
The formation of ILD layer 136 can be followed by formation of gate structures 110. For example, as shown in
In some embodiments, gate capping structure 542 and sacrificial gate structures 510 can be removed in one or more etch processes. In some embodiments, the etch processes can include a dry etch process, a wet etch process, or other suitable etch processes to remove gate capping structure 542 and sacrificial gate structures 510 but not gate spacers 120. After the removal of gate capping structure 542 and sacrificial gate structures 510, first set of semiconductor layers 438 can be exposed for subsequent etching processes.
In some embodiments, first set of semiconductor layers 438 can be removed by a selective etching process. In some embodiments, first set of semiconductor layers 438 can have a higher etch selectivity than second set of semiconductor layers 108, gate spacers 120, epitaxial layers 112, and inner spacer structures 111. In some embodiments, due to the high etch selectivity, the selective etch process may not remove epitaxial layers 112, inner spacer structures 111, or second set of semiconductor layers 108 after removal of first set of semiconductor layers 438. Therefore, epitaxial layers 112B can protect S/D structure 114B and prevent damage to S/D structure 114B. Inner spacer structures 111 can protect S/D structure 114A and prevent damage to S/D structure 114A. After the selective etching process, first set of semiconductor layers 438 can be removed and openings 1610 can be formed above and around second set of semiconductor layers 108.
Referring to
In some embodiments, the formation of gate dielectric layer 122 can include formation of an interfacial layer on semiconductor layers 108 and formation of a high-k dielectric layer on the interfacial layer. The interfacial layer and high-k dielectric layer can wrap around each of semiconductor layers 108, as shown in
The formation of gate structures 110 can be followed by formation of S/D contact structures 128, as shown in
In some embodiments,
In some embodiments,
Various embodiments in the present disclosure provide example methods for forming an asymmetric S/D design for semiconductor device 100. Semiconductor device 100 can have nanostructures 108 acting as channels and gate structures 110 wrapped around nanostructures 108. Inner spacer structures 111 can be in contact with a first side (e.g., drain side) of gate structure 110 and can be disposed between gate structures 110 and S/D structure 114A. Epitaxial layer 112B can be in contact with a second side (e.g., source side) of gate structures 110 and can be disposed between gate structures 110 and S/D structure 114B. The second side can be opposite to the first side. With epitaxial layer 112B on the source side, the dislocation defects in S/D structure 114B can be reduced by about 50% to about 80%, the resistance of S/D structure 114B can be significantly reduced, the proximity between S/D structure 114B and gate structures 110 can be reduced, the strain imparted on nanostructure 108 can be improved, and the device current of semiconductor device 100 can be increased. Additionally, inner spacer structures 111 on the drain side can reduce the parasitic capacitance between gate structures 110 and S/D structure 114A. The asymmetric S/D design can improve the device performance of semiconductor device 100, for example, by about 5% to about 20% for a p-type nanostructure transistor device and by about 0.5% to about 5% for an n-type nanostructure transistor device.
In some embodiments, a semiconductor structure includes multiple semiconductor layers on a substrate, a gate structure wrapped around the multiple semiconductor layers, an inner spacer structure between the multiple semiconductor layers and in contact with a first side of the gate structure, and an epitaxial layer in contact with a second side of the gate structure. The second side is opposite to the first side.
In some embodiments, a semiconductor device includes multiple channel structures on a substrate, a gate structure wrapped around the multiple channel structures, an inner spacer structure in contact with the gate structure and adjacent to a first end of the multiple channel structures, a gate spacer on a sidewall of the gate structure and above the multiple channel structures, and an epitaxial layer in contact with the gate structure and a second end of the multiple semiconductor layers. The second end is opposite to the first end.
In some embodiments, a method includes forming multiple semiconductor layers on a substrate. The multiple semiconductor layers include a first set of semiconductor layers and a second set of semiconductor layers stacked in an alternate configuration. The method further includes replacing a portion of the first set of semiconductor layers with an inner spacer structure at a first end of the multiple semiconductor layers, forming an epitaxial layer in contact with the substrate and a second end of the multiple semiconductor layers, and forming a first S/D structure in contact with the inner spacer structure and a second S/D structure on the epitaxial layer. The second end is opposite to the first end.
It is to be appreciated that the Detailed Description section, and not the Abstract of the Disclosure section, is intended to be used to interpret the claims. The Abstract of the Disclosure section may set forth one or more but not all possible embodiments of the present disclosure as contemplated by the inventor(s), and thus, are not intended to limit the subjoined claims in any way.
The foregoing disclosure outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art will appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art will also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
This application claims the benefit of U.S. Provisional Patent Application No. 63/374,782, titled “Semiconductor Devices with Asymmetric Source/Drain Design,” filed Sep. 7, 2022, and U.S. Provisional Patent Application No. 63/340,274, titled “Strategic Asymmetric SD Design for GAA Performance Enhancement,” filed May 10, 2022, the disclosures of which are incorporated by reference in their entireties.
Number | Date | Country | |
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63374782 | Sep 2022 | US | |
63340274 | May 2022 | US |