Shaping polishing pad for small head chemical mechanical planarization

Information

  • Patent Grant
  • 6517419
  • Patent Number
    6,517,419
  • Date Filed
    Thursday, October 26, 2000
    23 years ago
  • Date Issued
    Tuesday, February 11, 2003
    21 years ago
Abstract
Specific embodiments of the present invention are directed to a method of forming a polishing pad having a smaller diameter than an object to be planarized and to be used for planarizing the object by chemical-mechanical planarization. The method comprises placing a polishing surface of the polishing pad in contact with an abrasive surface of a conditioning object having a shape identical to the object to be planarized. The polishing surface of the polishing pad is engaged with the abrasive surface of the conditioning object under conditions substantially equal to the conditions to be applied for planarizing the object. The polishing surface is observed, and is disengaged from the abrasive surface of the conditioning object when abrasion of a center region of the polishing surface of the polishing pad by the abrasive surface of the conditioning object is initially detected. In a specific embodiment, another polishing pad is preformed to have the shape of the polishing surface of the polishing pad after disengaging the polishing pad from the conditioning object. That polishing pad may be preformed by molding.
Description




BACKGROUND OF THE INVENTION




The present invention relates to the manufacture of electronic devices. More particularly, the invention provides a device for planarizing a film of material of an article such as a semiconductor wafer. In an exemplary embodiment, the present invention provides an improved substrate support for the manufacture of semiconductor integrated circuits. However, it will be recognized that the invention has a wider range of applicability; it can also be applied to flat panel displays, hard disks, raw wafers, MEMS wafers, and other objects that require a high degree of planarity.




The fabrication of integrated circuit devices often begins by producing semiconductor wafers cut from an ingot of single crystal silicon which is formed by pulling a seed from a silicon melt rotating in a crucible. The ingot is then sliced into individual wafers using a diamond cutting blade. Following the cutting operation, at least one surface (process surface) of the wafer is polished to a relatively flat, scratch-free surface. The polished surface area of the wafer is first subdivided into a plurality of die locations at which integrated circuits (IC) are subsequently formed. A series of wafer masking and processing steps are used to fabricate each IC. Thereafter, the individual dice are cut or scribed from the wafer and individually packaged and tested to complete the device manufacture process.




During IC manufacturing, the various masking and processing steps typically result in the formation of topographical irregularities on the wafer surface. For example, topographical surface irregularities are created after metallization, which includes a sequence of blanketing the wafer surface with a conductive metal layer and then etching away unwanted portions of the blanket metal layer to form a metallization interconnect pattern on each IC. This problem is exacerbated by the use of multilevel interconnects.




A common surface irregularity in a semiconductor wafer is known as a step. A step is the resulting height differential between the metal interconnect and the wafer surface where the metal has been removed. A typical VLSI chip on which a first metallization layer has been defined may contain several million steps, and the whole wafer may contain several hundred ICs.




Consequently, maintaining wafer surface planarity during fabrication is important. Photolithographic processes are typically pushed close to the limit of resolution in order to create maximum circuit density. Typical device geometries call for line widths on the order of 0.5 μm. Since these geometries are photolithographically produced, it is important that the wafer surface be highly planar in order to accurately focus the illumination radiation at a single plane of focus to achieve precise imaging over the entire surface of the wafer. A wafer surface that is not sufficiently planar, will result in structures that are poorly defined, with the circuits either being nonfunctional or, at best, exhibiting less than optimum performance. To alleviate these problems, the wafer is “planarized” at various points in the process to minimize non-planar topography and its adverse effects. As additional levels are added to multilevel-interconnection schemes and circuit features are scaled to submicron dimensions, the required degree of planarization increases. As circuit dimensions are reduced, interconnect levels must be globally planarized to produce a reliable, high density device. Planarization can be implemented in either the conductor or the dielectric layers.




In order to achieve the degree of planarity required to produce high density integrated circuits, chemical-mechanical planarization processes (“CMP”) are being employed with increasing frequency. A conventional rotational CMP apparatus includes a wafer carrier for holding a semiconductor wafer. A soft, resilient pad is typically placed between the wafer carrier and the wafer, and the wafer is generally held against the resilient pad by a partial vacuum. The wafer carrier is designed to be continuously rotated by a drive motor. In addition, the wafer carrier typically is also designed for transverse movement. The rotational and transverse movement is intended to reduce variability in material removal rates over the surface of the wafer. The apparatus further includes a rotating platen on which is mounted a polishing pad. The platen is relatively large in comparison to the wafer, so that during the CMP process, the wafer may be moved across the surface of the polishing pad by the wafer carrier. A polishing slurry containing chemically-reactive solution, in which are suspended abrasive particles, is deposited through a supply tube onto the surface of the polishing pad.




CMP is advantageous because it can be performed in one step, in contrast to past planarization techniques which are complex, involving multiple steps. Moreover, CMP has been demonstrated to maintain high material removal rates of high surface features and low removal rates of low surface features, thus allowing for uniform planarization. CMP can also be used to remove different layers of material and various surface defects. CMP thus can improve the quality and reliability of the ICs formed on the wafer.




Chemical-mechanical planarization is a well developed planarization technique. The underlying chemistry and physics of the method is understood. However, it is commonly accepted that it still remains very difficult to obtain smooth results near the center of the wafer. The result is a planarized wafer whose center region may or may not be suitable for subsequent processing. Sometimes, therefore, it is not possible to fully utilize the entire surface of the wafer. This reduces yield and subsequently increases the per-chip manufacturing cost. Ultimately, the consumer suffers from higher prices.




It is therefore desirable to improve the useful surface of a semiconductor wafer to increase chip yield. What is needed is an improvement of the CMP technique to improve the degree of global planarity that can be achieved using CMP.




SUMMARY OF THE INVENTION




The present invention achieves these benefits in the context of known process technology and known techniques in the art. The present invention provides an improved planarization apparatus for chemical mechanical planarization (CMP). Specifically, the present invention provides an improved planarization apparatus that provides multi-action CMP, such as orbital and spin action, to achieve uniformity during planarization. The present invention further provides a way to shape and form a polishing pad to improve planarization uniformity during CMP.




An aspect of the present invention is directed to a method of forming a polishing pad having a smaller diameter than an object to be planarized and to be used for planarizing the object by chemical-mechanical planarization. The method comprises placing a polishing surface of the polishing pad in contact with an abrasive surface of a conditioning object having a shape identical to the object to be planarized. The polishing surface of the polishing pad is engaged with the abrasive surface of the conditioning object under conditions substantially equal to the conditions to be applied for planarizing the object. The polishing surface is observed, and is disengaged from the abrasive surface of the conditioning object when abrasion of a center region of the polishing surface of the polishing pad by the abrasive surface of the conditioning object is initially detected.




In some embodiments, the polishing surface of the polishing pad is pushed against the abrasive surface of the conditioning object by a force substantially equal to a force to be applied to the polishing pad against the object to be planarized. The polishing pad is moved relative to the conditioning object in a manner similar to a movement for planarizing the object. The polishing pad is rotated relative to the conditioning object at a rate which is lower than a rate of rotation for planarizing the object. In a specific embodiment, another polishing pad is preformed to have the shape of the polishing surface of the polishing pad after disengaging the polishing pad from the conditioning object. That polishing pad may be preformed by molding.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a simplified diagram of a planarization apparatus according to an embodiment of the present invention;





FIG. 1A

is a simplified top-view diagram of a carousel for supporting multiple guide and spin assemblies according to an embodiment of the present invention;





FIG. 2

is a detailed diagram of a guide and spin roller according to an embodiment of the present invention;





FIG. 2A

is a diagram of a guide and spin roller according to another embodiment of the present invention;





FIG. 3

is a detailed diagram of a polish pad back support according to an embodiment of the present invention;





FIG. 3A

is a simplified diagram of a support mechanism for supporting the wafer with projected gimbal points according to an embodiment of the present invention;





FIG. 3B

is a top plan view of a gimbal drive support for the polishing pad with project gimbal point;





FIG. 3C

is a cross-sectional view of the gimbal drive support of

FIG. 3B

along


1





1


;





FIG. 3D

is a cross-sectional view of the gimbal drive support of

FIG. 3B

along


2





2


;





FIG. 3E

is an exploded perspective view of the gimbal drive support of FIG.


3


B.





FIG. 4

is a simplified top-view diagram of a planarization apparatus according to an embodiment of the present invention;





FIG. 4A

is a simplified top-view diagram of the polishing pad and spindle illustrating spin and orbit rotations;





FIG. 4B

is a sectional view diagram of the orbit and spin mechanism for the polishing head in accordance with an embodiment of the present invention;





FIG. 5

is a simplified diagram of a polishing apparatus according to an alternative embodiment of the present invention;





FIG. 6A

is a simplified diagram schematically illustrating nonuniform polishing using a polishing pad;





FIG. 6B

is a simplified diagram schematically illustrating the conditioning and shaping of a polishing pad using a dummy wafer;





FIG. 6C

is a simplified diagram schematically illustrating the profile of a conditioned polishing pad;





FIG. 7

is an alternative diagram of a planarization apparatus according to another embodiment of the present invention;





FIG. 8

is a simplified diagram of a planarization apparatus according to another embodiment of the present invention;





FIG. 9

is a simplified diagram illustrating a fluid delivery system in the planarization apparatus of

FIG. 8

; and





FIG. 10

is a simplified block diagram of a planarization calibration system of the present invention.











DESCRIPTION OF THE SPECIFIC EMBODIMENTS





FIG. 1

is a simplified diagram of a planarization apparatus


100


according to an embodiment of the present invention. This diagram is merely an example, which should not limit the scope of the claims herein. One of ordinary skill in the art would recognize many other variations, modifications, and alternatives. In a specific embodiment, planarization apparatus


100


is a chemical-mechanical planarization apparatus.




Wafer Guide and Spin Assembly




The apparatus


100


includes an edge support, or a guide and spin assembly


110


, that couples to the edge of an object, or a wafer


115


. While the object in this specific embodiment is a wafer, the object can be other items such as a in-process wafer, a coated wafer, a wafer comprising a film, a disk, a panel, etc. Guide assembly


110


supports and positions wafer


115


during a planarization process.

FIG. 1

also shows a polishing pad assembly


116


having a polishing pad


117


, and a back-support


118


attached to a dual arm


119


. Pad assembly


116


, back support


117


, dual arm


118


is described in detail below.




In a specific embodiment, guide assembly


110


includes rollers


120


, each of which couples to the edge of wafer


115


to secure it in position during planarization. The embodiment of

FIG. 1

shows three rollers. The actual number of rollers, however, will depend on various factors such as the shape and size of each roller, the shape and size of the wafer, and nature of the roller-wafer contact, etc. Also, at least one of the rollers


120


drives the wafer


115


, that is, cause the wafer to rotate, or spin. The rest can serve as guides, providing support as the wafer is polished. The rollers


120


are positioned at various points along the wafer perimeter. As shown in

FIG. 1

, the rollers


120


attach to the wafer


115


at equidistant points along the wafer perimeter. The rollers


120


can be placed anywhere along the wafer perimeter. The distance between each roller will depend on the number of rollers, and on other factors related to the specific application.




The embodiment of

FIG. 1

shows one guide and spin assembly


110


. The actual number of such assemblies will depend on the specific application. For example,

FIG. 1A

shows a simplified top-view diagram of a carousel


121


for supporting multiple guide and spin assemblies


110


for processing multiple wafers


115


according to an embodiment of the present invention. In this specific embodiment, the carousel (

FIG. 1A

) can be used with multiple guide assemblies for planarizing many wafers. The actual size, shape, and configuration of the carousel will depend on the specific application. Also, when multiple guide assemblies are used, all guide assemblies need not be configured identically. The configuration of each guide assembly will depend on the specific application. For higher throughput, wafers are mounted onto the guide assemblies that are in cue during the planarization of one or more of the other wafers. For even higher throughput, such wafer carousels are configured to operatively couple to multiple planarization apparatus.





FIG. 2

is a detailed diagram of a roller


120


of

FIG. 1

according to an embodiment of the present invention. This diagram is merely an example, which should not limit the scope of the claims herein. One of ordinary skill in the art would recognize many other variations, modifications, and alternatives. As shown, each roller


120


has a base portion


125


, a top portion


130


, and an annular notch


131


extending completely around the roller, and positioned between the base and top portions. The depth and shape of notch


131


will vary depending on the purpose of the specific roller. A roller designated to drive the rotation of the wafer might have a deeper notch to provide for more surface area contact with the wafer


115


. Alternatively, a roller designated to merely guide the wafer might have a shallower notch, having enough depth to provide adequate support.





FIG. 2A

shows another roller


120




a


having a base portion


125




a


similar to the base portion


125


of FIG.


2


. The top portion


130




a


has a smaller cross-section that the top portion


130


of

FIG. 2

, and desirably includes a tapered or inclined surface


132




a


tapering down to an annular notch


131




a


which is more shallow than the notch


131


of FIG.


2


. The shallow notch


131




a


is sufficient to connect the roller


120




a


to the edge of the wafer


115


. The top portion


130




a


and the shallow notch


131




a


make the engagement of the roller


120




a


with the edge of the wafer


115


easier. The replacement of the wafer


115


can also be performed more readily and quickly since the roller


120




a


with the smaller to portion


130




a


need not be retracted as far as the roller


120


of FIG.


2


. The surface


133




a


of the bottom portion


125




a


may also be inclined by a small degree (e.g., about 1-5°) as indicated by the broken line


133




b


to further facilitate wafer engagement.




The edge of wafer


115


is positioned in the notch of each roller such that the process side of wafer


115


faces polishing pad


117


. To secure wafer


115


, the base portion of each roller provides an upward force


140


against the back side


150


of the wafer while the top portion provides a downward force


160


against the process surface


170


(side to be polished) of the wafer. For additional support, the inner wall


171


of the notch provides an inward force


190


against the wafer edge. The top and base portions


130


,


125


constitute one piece. Alternatively, the top and base portions


130


,


125


can include multiple pieces. For example, the top portion


130


can be a separate piece, such as a screw cap or other fastening device or the equivalent. Each roller


120


has a center axis


201


and each can rotate about its axis. Rotation can be clockwise or counterclockwise. Rotation can also accelerate or decelerate.




Guide and spin assembly


110


also has a roller base (not shown) for supporting the rollers. The size, shape, and configuration of the base will depend on the actual configuration of the planarization apparatus. For example, the base can be a simple flat surface that is attached to or integral to the planarization apparatus. The base can support some of the rollers, while at least one roller need to be retractable sufficiently to permit insertion and removal of the wafer


115


, and need to be adjustable relative to the edge of the wafer


115


to control the force applied to the edge of the wafer


115


.




In operation, during planarization, guide assembly


110


can move wafer


115


in various ways relative to polishing pad


117


. For example, the guide assembly can move the wafer laterally, or provide translational displacement, in a fixed plane, the fixed plane being substantially parallel to a treatment surface of polishing pad


117


and back support


118


. The guide assembly can also rotate, or spin, the wafer in the fixed plane about the wafer's axis. As a result, the guide assembly


110


translates the wafer


115


in the x-, y-, and z-directions, or a combination thereof. During actual planarization, that is when a polishing pad contacts the wafer, the guide assembly can move the wafer laterally in a fixed plane. The guide assembly can translate the wafer in any number of predetermined patterns relative to the polishing pad. Such a predetermined pattern will vary and will depend on the specific application. For example, the pattern can be substantially radial, linear, etc. Also, at least when the polishing pad contacts the object during planarization, such a pattern can be continuous or discontinuous or a combination thereof.




Conventional translation mechanisms for x-, y-, z-translation can control and traverse the guide assembly. For example, alternative mechanisms include pulley-driven devices and pneumatically operated mechanisms. The guide assembly and the wafer can traverse relative to the polishing pad in a variety of patterns. For example, the traverse path can be radial, linear, orbital, stepped, etc. or any combination depending on the specific application. The rotation direction of the wafer can be clockwise or counter clockwise. The rotation speed can also accelerate or decelerate.




Still referring to

FIG. 2

, as indicated above, in addition to lateral movement, the guide assembly can also rotate, or spin, wafer


115


in the fixed plane about the wafer center axis


202


. The fixed plane is substantially parallel to a treatment surface of polishing pad


117


. One way to provide rotational movement is by using rollers


120


described above. As mentioned above, at least one roller rotates about its center axis to drive the wafer to rotate about its center axis. The other rollers can also drive the wafer to rotate. They can also rotate freely. As said, each roller can rotate about its center axis


201


in either a clockwise or counterclockwise direction. The wafer will rotate in the opposite direction of the driving roller.




Specifically, as one or more of the driving rollers spin along their rotational axis


201


during operation, the friction between the inner walls of notch


131


and the wafer edge cause wafer


115


to rotate along its own axis


202


. The roller itself can provide the friction. For example, the notch can include ribs, ridges, grooves, etc. Alternatively, a layer of any known material having a sufficient friction coefficient, such as a rubber or polyamide material, can also provide friction. One of ordinary skill in the art would recognize many other variations, modifications, and alternatives. For example, each roller can be movably or immovably fixed to a base (not shown) and a wheel within the notch of each roller can spin, causing the wafer to spin.




To rotate, or spin, the wafer, one or more conventional drive motors (not shown) or the equivalent can be operatively coupled to the wafer, rollers, or roller base. The drive can be coupled to one or more of the rollers via a conventional drive belt (not shown) to spin the wafer. Alternatively, the drive can also couple to the guide assembly such that the entire guide assembly rotates about its center axis thereby causing the wafer to rotate about the guide assembly center axis. With all embodiments, the motor can be reversible such that the rotation direction


275


(

FIG. 1

) of the polishing pad


117


about its axis


270


can be clockwise or counter clockwise. Drive motor can also be a variable-speed device to control the rotational speed of the pad. Also, the rotational speed of the pad can also accelerate or decelerate depending on the specific application.




Alternatively, the edge support can also be stationary during planarization while a polishing pad rotates or moves laterally relative to the wafer. This variation is described in more detail below. During planarization, such movement occurs in the fixed plane at least when the polishing pad


117


contacts the wafer. During any part of or during the entire planarization process, any combination of the movements described above is possible.




Referring to

FIG. 1

, planarization apparatus


100


also includes a polishing head, or polishing pad assembly


116


, for polishing wafer


115


. Pad assembly


116


includes polishing pad


117


, a polishing pad chuck


250


for securing and supporting polishing pad


117


, and a polishing pad spindle


260


coupled to chuck


250


for rotation of pad


117


about its axis


270


. According to a specific embodiment, the pad diameter is substantially less than the wafer diameter, typically 20% of the wafer diameter.




To rotate, or spin, the wafer, one or more conventional drive motors (not shown) or the equivalent can be operatively coupled to polishing pad spindle


260


via a conventional drive belt (not shown). The motor can be reversible such that the rotation direction


275


of polishing pad


117


can be clockwise or counter clockwise. Drive motor can also be a variable-speed device to control the rotational speed of the polishing pad.




Also, the rotational speed of the polishing pad can also accelerate or decelerate depending on the specific application.




Polishing and Back Support Assembly




The planarization apparatus also includes a base, or dual arm


119


. While the base can have any number of configurations, the specific embodiment shown is a dual arm. Pad assembly


116


couples to back support


118


via dual arm


119


. Dual arm


119


has a first arm


310


for supporting pad assembly


116


and a second arm


320


for supporting back support


118


. The arms


310


,


320


may be configured to move together or, more desirably, can move independently. The arms


310


,


320


can be moved separately to different stations for changing pad or puck and facilitate ease of assembling the components for the polishing operation.




According to a specific embodiment of the invention, back support


118


tracks polishing pad


117


to provide support to wafer


115


during planarization. This can be accomplished with the dual arm. In a specific embodiment, the pad assembly


116


attaches to first arm


310


and back support


118


attaches to second arm


320


. Dual arm


119


is configured to position the pad assembly


116


and back support


118


such that a support surface of back support


118


faces the polishing pad


117


and such that the support surface of back support


118


and polishing pad


117


are substantially planar to one another. Also, according to the present invention, the centers of the polishing pad and surface of the back support are precisely aligned. This precision alignment allows for predicable and precise planarization. Precision alignment is ensured when the first and second arms constitute one piece. Alternatively, both arms can include multiple components and may be movable independently. As such, the components are substantially stable such that the precision alignment is maintained.




Specifically, according to one embodiment, dual arm


119


supports pad assembly


116


such that spindle


260


passes rotatably through first arm


310


towards back support


118


which is supported by second arm


320


. The rotational axis


270


of the pad


117


is equivalent to that of the spindle


260


. Rotational axis


270


is positioned to pass through back support


118


, preferably through the center of the back support


118


. Pad assembly


116


is configured for motion in the direction of wafer


115


.

FIG. 1

shows the process surface of the wafer positioned substantially horizontally and facing upwardly.




According to a specific embodiment of the present invention, the entire planarization system can be configured to polish the wafer in a variety of positions. During planarization, for example, the dual arm


119


can be positioned such that the wafer


115


is controllably polished in a horizontal position or a vertical position, or in any angle. These variations are possible because the wafer


115


is supported by rollers


120


rather than by gravity. Such flexibility is useful in, for example, a slurry-less polish system.




In operation, dual arm


119


can translate pad assembly


116


relative to wafer


115


in a variety of ways. For example, the dual arm


119


can pivot about the pivot shaft to traverse the pad


117


radially across the wafer


115


. In another embodiment, both arms


310


and


320


can extend telescopically (not shown) to traverse the pad laterally linearly across the wafer


115


. Both radial and linear movements can also be combined to create a variety of traversal paths, or patterns, relative to the wafer


115


. Such patterns can be, for example, radial, linear, orbital, stepped, continuous, discontinuous, or any combination thereof. The actual traverse path will of course depend on the specific application.





FIG. 3

is a detailed diagram of back support


118


of

FIG. 1

according to an embodiment of the present invention. This diagram is merely an example, which should not limit the scope of the claims herein. One of ordinary skill in the art would recognize many other variations, modifications, and alternatives. Back support


118


supports wafer


115


during planarization. Specifically, back support


118


dynamically tracks polishing pad


117


to provide local support to wafer


115


during planarization. Such local support eliminates wafer deformation due to the force of the polishing pad against the wafer during planarization. This also results in uniform polishing and thus planarity. In a specific embodiment, the back support


118


operatively couples to the pad assembly


116


via the dual arm


19


. In a specific embodiment, the back support


118


is removably embedded in second arm


320


of the dual arm. Referring to

FIG. 1

, rotational axis


270


of polishing pad


117


and spindle


260


pass through back support


118


.




Referring back to

FIG. 3

, back support


118


can be configured in any number of ways for supporting wafer


115


during planarization. In a specific embodiment, back support


118


has a flat portion, or support surface


350


, that contacts the back side


150


of the wafer during planarization. The support surface


350


desirably provides a substantially friction free interface between surface


350


and back side


150


of the wafer by using a low-friction solid material such as Teflon. Alternatively, the support surface


350


may support a fluid bearing as the frictionless interface with the back side


150


. The fluid may be a gas such as air or a liquid such as water, which may be beneficial for serving the additional function of cleaning the back side


150


of the wafer. This friction free interface allows the wafer to move across the surface of the back support.




Support surface


350


is substantially planar with the wafer


115


and pad


117


. The diameter of the surface should be large enough to provide adequate support to the object during planarization. In a specific embodiment, the back support surface has a diameter that is substantially the same size as the polishing pad diameter. In

FIG. 3

, the back support


118


shown is a spherical air bearing and has a spherical portion


340


allowing it to be easily inserted into second arm


320


. The rotation of the spherical portion


340


relative to the second arm allows the back support


118


to track the polishing pad


117


and support the wafer


115


with the support surface


350


. The back support


118


in

FIG. 3

has a protrusion


341


into a cavity of the second arm. The protrusion


341


may serve to limit the rotation of the back support


118


relative to the second arm


320


during tracking of the polishing pad


117


. In an alternate embodiment, the back support


118


may be generally hemispherical without the protrusion.




The process surface


170


of the wafer


115


faces the pad


117


and the back side


150


of the wafer


115


faces the back support


118


. Also, the wafer


115


is substantially planar with both the pad


117


and back support


118


. In another embodiment, the back support


118


can be replaced with a second polishing pad assembly for double-sided polishing. In such an embodiment, the second pad assembly can be configured similarly to the first pad assembly on the first arm. The polishing pads of each are substantially planar to one another and to the wafer


115


.




In a specific embodiment, the back support is a bearing. In this specific embodiment, the bearing can be a low-friction solid material (e.g., Teflon), an air bearing, a liquid bearing, or the equivalent. The type of bearing will depend on the specific application and types of bearing available.




In the specific embodiment as shown in

FIG. 1

, the dual arm


119


is a C-shaped clamp having projected gimbal points that allow for flexing of the dual arm


119


and still keep the face of the wafer in good contact with the polishing pad


117


. The projected gimbal points are more clearly illustrated in FIG.


3


A. The polishing pad chuck


250


is supported by the first arm


310


, and the back support


118


is supported by the second arm


320


. The polishing pad chuck


250


has a hemispherical surface


251


centered about a pivot point or gimbal point


252


which preferably is disposed at or near the upper surface of the wafer


115


. Positioning the gimbal point


252


at or near the surface of the wafer


115


allows gimbal motion or pivoting of the chuck


250


relative to the first arm


310


without the problem of cocking. Cocking occurs when the projected gimbal point is above the wafer surface, and causes the forward end of the polishing pad


117


to dig into the wafer surface at the forward edge and lift up at the rear edge. The cocking is inherently unstable. Positioning the project gimbal point on the wafer surface avoids cocking. If the gimbal point is projected below the surface of the wafer, friction between the polishing pad


117


and the wafer surface produces a skiing effect which lifts the forward edge of the polishing pad


117


and causes the rear edge to dig into the wafer surface as the polishing pad moves relative to the wafer surface. This is more stable than cocking. The desirable maximum distance between the projected gimbal point and the wafer surface depends on the size of the polishing pad


117


. For example, the distance may be less than about 0.1 inch for a polishing pad having a diameter of about 1.5 inch. The distance is desirably less than about 0.1 times, more desirably less than about 0.02 times, the diameter of the polishing pad. Likewise, the spherical surface


340


of the back support


118


desirably has a projected pivot point


254


disposed at or near the lower surface of the wafer


115


.





FIGS. 3B-3E

show the gimbal mechanism coupling the polishing pad chuck


250


with the first arm


310


. The chuck


250


is connected to an inner cup


256


which is connected to an outer cup


258


that is supported by the first arm


310


of the dual arm


119


. A torsional drive motor may be coupled with the outer cup


258


to rotate the polishing pad


117


via the gimbal mechanism around the z-axis. A pair of inner drive pins


262


extend from the chuck


250


into radial slots


264


provided in the inner cup


256


and extending generally in the direction of the y-axis. The radial slots


264


constrain the inner drive pins


262


in the circumferential direction so that the chuck


250


moves with the inner cup


256


in the circumferential direction around the z-axis. The inner drive pins


262


may move along the radial slots


264


to permit rotation of the chuck


250


relative to the inner cup


256


around the x-axis.




A pair of outer drive pins


266


extend from the inner cup


256


into radial slots


268


provided in the outer cup


258


and extending generally in the direction of the x-axis. The radial slots


268


constrain the outer drive pins


266


in the circumferential direction so that the inner cup


256


moves with the outer cup


258


in the circumferential direction around the z-axis. The outer drive pins


266


may move along the radial slots


268


to permit rotation of the inner cup


256


relative to the outer cup


258


around the y-axis.




The hemispherical drive cups


256


,


258


isolate two axes of motion to allow full gimbal of the gimbal mechanism about the gimbal point or pivot point


252


. The gimbal mechanism allows transmission of the torsional drive of the polishing pad


117


about the z-axis without inducing a torque moment on the polishing pad


117


at the interface with the wafer surface to produce a skiing effect. The polishing pad


117


becomes self-aligning with respect to the surface of the wafer


115


which may be offset from the x-y plane.




The gimbal mechanism shown in

FIGS. 3B-3E

is merely illustrative. In different embodiments, the drive pins may be replaced by machined protrusions. Balls or rollers that fit into mating, crossing grooves may be used to provide rolling contact with low friction between the movable members of the mechanism. Although the embodiment shown includes a single track in the x-direction and a single track in the y-direction, additional tracks may be provided. The members of the assembly may have other shapes different from the spherical members and still provide gimbal movements or spherical drive motions. It is understood that other ways of supporting the wafer and of tracking the polishing pad may be employed to provide the projected gimbal point at the desired location.




Planarization apparatus


100


operates as follows. Referring back to

FIG. 1

, assembly


110


positions wafer


115


between polishing pad


117


and back support


118


. The polishing pad is lowered onto the process surface


170


of the wafer


115


. Pad assembly


116


is driven by a conventional actuator (not shown), a piston-driven mechanism, for example, having variable-force control to control the downward pressure of the pad


117


upon the process surface


170


. The actuator is typically equipped with a force transducer to provide a downforce measurement that can be readily converted to a pad pressure reading. Numerous pressure-sensing actuator designs, known in the relevant engineering arts, can be used.





FIG. 4

is a simplified top-view diagram of planarization apparatus


100


according to an embodiment of the present invention. This diagram is merely an example, which should not limit the scope of the claims herein. One of ordinary skill in the art would recognize many other variations, modifications, and alternatives. In a specific embodiment, dual arm


119


is configured to pivot about a pivot shaft


360


to provide translational displacement of pad assembly


116


, and polishing pad


117


, relative to guide and spin assembly


110


, and wafer


115


. Pivot shaft


360


is fixed to a planarization apparatus system (not shown).




The polishing pad spindle


260


may also rotate to rotate the polishing pad


117


, as illustrated in FIG.


4


A. In addition to the spin rotation


276


about its own axis


270


, the spindle


260


may also orbit about an orbital axis


277


in directions


278


to produce orbiting of the polishing pad


117


as shown in broken lines. The orbital axis


277


is offset from the spin axis


270


by a distance which may be selected based on the size of the wafer


115


and the size of the polishing pad


117


. For instance, the offset distance may range from about 0.01 inch to several inches. In a specific example, the distance is about 0.25 inch. The orbital rotation is more clearly illustrated in FIG.


4


A. Different motors may be used to drive the spindle


260


in spin and to drive the spindle


260


in orbital rotation.





FIG. 4B

shows an apparatus


600


that allows both orbital and pure spin motion of a polishing head


602


that holds a polishing pad


604


which is smaller in size than the wafer


606


for planarizing the wafer. An orbit housing


610


is held in place with respect to the arm frame


612


by bearings


614


and driven directly by a direct orbit motor or through an orbit belt or an orbit gear.

FIG. 4B

shows an orbit drive belt


616


coupled to an orbit motor


618


. The orbit housing


610


has an eccentric or offset hole


620


which supports a shaft


622


with bearings


624


. The shaft


622


is offset from the centerline of the orbit housing


610


by an offset


625


which may be set to any desired amount (e.g., about 0.5 inch). The shaft


622


is connected to the polishing head


602


. An external tooth gear


626


(or friction drive or the like) is attached to the shaft


622


and mates with an internal tooth gear


628


(or friction drive). The internal tooth gear is a ring gear


628


supported by another bearing


630


concentric with the outer orbit housing bearings


614


, and is driven by a direct spin motor, or through a spin gear or a shaft drive belt.

FIG. 4B

shows a spin drive belt


632


coupled to a spin motor


634


. By controlling the relative speeds of the orbit motor


618


and the spin motor


634


, the polishing head


602


can be made to spin only (while holding the orbit motor


634


stationary), to spin and orbit (i.e., to precess), or to orbit only (by controlling the relative motions of the two motors


618


,


634


so that the polishing pad


604


does not spin relative to the wafer


606


).

FIG. 4B

also shows a chemical/fluid/slurry supply


640


supplying the chemical/fluid/slurry through a feed passage


642


to the polishing pad


604


.




The inventors have discovered that improved uniformity of planarization can be achieved by polishing the center of the wafer by predominately orbital motion and polishing the edge of the wafer by predominately spin motion. Predominate orbital motion at the center of the wafer produces relatively uniform surface velocity motion to the entire polish pad surface where the center of the wafer is at a theoretical zero velocity. This results in good uniformity at the center of the wafer while maintaining superior planarity. Pure spin motion allows a very precise balance position at the edge of the wafer to give superior edge exclusion polish results where the orbital motion causes the pad to tend to drop off the edge too far before the center of action can be close enough to the edge to achieve good removal. This produces good uniformity results at the edge of the wafer while maintaining superior planarity results. In some embodiments, the orbiting speed is greater than the spinning speed when the polishing pad is contacted with the center region of the wafer. In a specific embodiment, the spinning speed is approximately zero at the center region. In some embodiments, the spinning speed is greater than the orbiting speed when the polishing pad is contacted with an edge region of the wafer. In a specific embodiment, the orbiting speed is approximately zero at the edge region.




The inventors have also found that uniformity can be affected by the relative wafer rotational speed and orbiting speed of the polishing pad. For instance, during combined orbital motion and rotation of the wafer, if the ratio of the greater of the orbiting speed and the wafer rotational speed to the lesser of the two is an integer, then the polishing pattern will repeat in a Rosette pattern and produces nonuniformity polishing. Typically, the orbiting speed is larger than the wafer rotational speed. Thus, it is desirable to have the ratio of the two speeds be a non-integer to achieve improved uniformity during planarization. For example, if the orbiting speed is 1000 rpm, the wafer rotational speed may be 63 rpm.





FIG. 5

is a simplified top view diagram


500


of a multi-pad CMP apparatus according to an embodiment of the present invention. This diagram is merely example, which should not limit the scope of the claims herein. One of ordinary skill in the art would recognizes many other variations, modifications, and alternatives. As shown, the diagram


500


illustrates a top-view of a base panel


501


, which houses a variety of systems and sub-systems. The base panel


501


is a frame support structure, which has doors for enclosing the frame support structure.




The panel includes a polishing head


515


(or arm), which pivots about member


517


. The polishing head extends from member


517


to a region overlying the object


507


to be polished. The object can be a variety of work pieces, such as a semiconductor wafer, a glass plate, a flat panel, a blank wafer, a disk, and other objects with surfaces that need polishing or planarization. The object often rests on and is attached to a base plate or platen


505


. The base plate can often rotate the object in either direction. Additionally, the base plate can ramp up in speed, or step up in speed, or perform other functions.




The polishing head includes a polishing pad


19


, which is coupled to the polishing head. The polishing pad rotates in a circular or orbital manner and traverses across the surface of the object. The polishing pad can also move in the vertical direction to a selected height. Other functions of the polishing pad have been previously noted and also apply here, but should not unduly limit this embodiment.




The polishing pad can move from the object to one of a plurality of sites. These sites include a disposal site


502


, where the polishing pad can be removed. The disposal site can also include a device, such as the handling arms, which are used to remove the polishing pad and cap from the polishing head. Here, the polishing arm completes a polishing process, is elevated, and traverse to the disposal site


502


, where the handling arms clamp the cap, the drive motor turns the drive shaft to free the cap, and the polishing head lifts up to free itself from the cap. Next, the arms release the cap, including the pad, into the disposal site. In a specific embodiment, the disposal site can be covered, when it is not in use to prevent particulate contamination from being released from the disposal site to the object.




Shaping Polishing Pad




Another aspect of the invention is directed to modifying the shape of the polishing pad to eliminate or reduce nonuniformity of the wafer during CMP. As shown in

FIG. 6A

, the relatively high downforce applied on the polishing pad


520


by the pad holder


522


tends to deform the wafer


524


into a dish shape during CMP. If the pad


520


is relatively hard, it will remain substantially planar and the edge region of the pad


520


will be more likely to make contact with the wafer surface than the center region of the pad


520


. This contact creates rings on the wafer surface during CMP and causes planarization non-uniformity. One way to reduce the ring effect is to use a softer polishing pad material. Alternatively, the polishing pad can be rotated at a higher spinning or grinding speed. These solutions may be undesirable.




One aspect of the invention is to modify a polishing pad (typically made of a very hard material) by conditioning it in situ using a wafer and sheet abrasive to generate a profile on the surface of the pad. The pad profile so formed is more suitable or optimized for polishing a wafer under the same forces during CMP to achieve superior planarity and maintain uniformity.




In one embodiment, a layer of fine sand paper


526


(e.g., 600 G) is bonded to the surface of a dummy wafer or conditioning wafer


528


for use in conditioning a polishing pad


520


prior to the actual planarization process, as seen in FIG.


6


B. The polishing pad


520


is placed in contact with the sand paper


526


using a downforce and under conditions similar to the actual planarization process, while the polishing speeds may be reduced from the speeds during actual planarization. The sand paper


526


will wear down the polishing pad


520


at the edge region. The polishing pad is checked periodically, typically at short time intervals (e.g., about 5-10 seconds), until the beginning of a polish pattern is detected in the center region of the pad. This signals that the desired polishing pad shape is achieved for use in the actual planarization process. In general, the desired shape of the polishing pad


520


′ has a substantially flat center region and a rounded edge region, as shown in FIG.


6


C. This can be observed by holding a precision rule


530


against the surface and observing the flatness of the center region. Over-conditioning the pad is undesirable by eliminating the flat center region and destroying planarity. Of course, other abrasive material can be used instead of the sand paper.




After conditioning the polishing pad


520


′, the sand paper is flushed to remove particles thereon. The polishing pad


520


′ is cleaned and the dummy wafer


528


is removed. The same apparatus may be cleaned and used for actual planarization, or a different apparatus may be employed to planarize a wafer using the conditioned polishing pad


520


′.




In another embodiment, the shape of the conditioned polishing pad


520


′ can be used to preform polishing pads having the same profile to be used for CMP under the same conditions. The pads may be preformed by molding. In this way, the shaping of the polishing pad


520


′ only needs to be performed once for the particular CMP application.




Polishing Chemical Delivery





FIG. 7

is an alternative diagram of planarization apparatus


100


according to another embodiment of the present invention. This diagram is merely an example, which should not limit the scope of the claims herein. One of ordinary skill in the art would recognize many other variations, modifications, and alternatives. In a specific embodiment, a slurry delivery mechanism


400


is provided to dispense a polishing slurry (not shown) onto the process surface of wafer


115


during planarization. Although

FIG. 7

shows a single mechanism


400


or dispenser


400


, additional dispensers may be provided depending on the polishing requirements of the wafer. Polishing slurries are known in the art. For example, typical slurries include a mixture of colloidal silica or dispersed alumina in an alkaline solution such as KOH, NH


4


OH or CeO


2


. Alternatively, slurry-less pad systems can be used.




A splash shield


410


is provided to catch the polishing fluids and to protect the surrounding equipment from the caustic properties of any slurry that might be used during planarization. The shield material can be polypropylene or stainless steel, or some other stable compound that is resistant to the corrosive nature of polishing fluids. The slurry can be dispose via a drain


420


.




A controller


430


in communication with a data store


440


issues various control signals


450


to the foregoing-described components of the planarization apparatus. The controller provides the sequencing control and manipulation signals to the mechanics to effectuate a planarization operation. The data store


440


can be externally accessible. This permits user-supplied data to be loaded into the data store


440


to provide the planarization apparatus with the parameters for planarization. This aspect of the invention will be further discussed below.




Any of a variety of controller configurations is contemplated for the present invention. The particular configuration will depend on considerations such as throughput requirements, available footprint for the apparatus, system features other than those specific to the invention, implementation costs, and the like. In a specific embodiment, controller


430


is a personal computer loaded with control software. The personal computer includes various interface circuits to each component of apparatus


100


. The control software communicates with these components via the interface circuits to control apparatus


100


during planarization. In this embodiment, data store


440


can be an internal hard drive containing desired planarization parameters. User-supplied parameters can be keyed in manually via a keyboard (not shown). Alternatively, the data store


440


is a floppy drive in which case the parameters can be determined elsewhere, stored on a floppy disk, and carried over to the personal computer. In yet another alternative, the data store


440


is a remote disk server accessed over a local area network. In still yet another alternative, the data store


440


is a remote computer accessed over the Internet; for example, by way of the world wide web, via an FTP (file transfer protocol) site, and so on.




In another embodiment, controller


430


includes one or more microcontrollers that cooperate to perform a planarization sequence in accordance with the invention. Data store


440


serves as a source of externally provided data to the microcontrollers so they can perform the polish in accordance with user-supplied planarization parameters. It should be apparent that numerous configurations for providing user-supplied planarization parameters are possible. Similarly, it should be clear that numerous approaches for controlling the constituent components of the planarization apparatus are possible.





FIG. 8

shows a CMP apparatus


700


disposed in a process cavity


702


. A wafer


704


is transported into the process cavity


702


using a robot end effector (edge grip)


706


and supported on a wafer platen


708


which may be a vacuum chuck made of a porous material. A splash shield


710


is desirably placed around the wafer and platen


708


. The wafer platen


708


is supported on a rotary shaft


712


which is coupled with a vacuum rotary union


714


. A wafer drive motor


716


is connected to the rotary shaft


712


to spin the shaft


712


, platen


708


, and wafer


704


.




A polishing chuck


720


is disposed above the wafer


704


and supported on an arm


722


. The arm


722


is housed in an arm cover


724


and supported on an arm support pivot tube


726


which has a hollow center through which a slurry chemical supply tube


730


extends for supplying a slurry chemical to the polishing chuck


720


. A spindle drive motor


734


drives a spindle coupled to the polishing chuck


720


to rotate around its axis to spin the polishing pad over the wafer surface. The pivot tube


726


is rotatable relative to the frame


736


and is mounted to the frame by a bearing assembly


738


. An arm rotation drive assembly and motor unit


740


rotates the arm


722


through the arm support tube


726


around the axis of the tube


726


. An arm lift assembly and drive unit


742


is provided to move the arm


722


up and down through the arm support tube


726


. An auto change pad magazine


750


may be provided for supplying polishing pads which are detachably connected to the polishing chuck


720


for polishing the wafer


704


. A cavity spray rinse/wash


756


is disposed on top of the apparatus


700


with a splash containment cover


758


surrounding the upper portion to reduce splashing.





FIG. 9

shows additional details of the delivery of the slurry chemical. A pump


760


pumps the slurry chemical from a source


762


through the supply tube


730


to a hollow spindle shaft


764


connected to the polishing chuck


720


. The chemical flows through the channel


766


in the spindle shaft


764


and the polishing chuck


720


under gravity, and into the region between the annular polishing pad


770


and the surface of the wafer


704


. The center application of the chemical through a removed center portion of the polishing pad


770


advantageously produces uniform chemical distribution even at high spindle speeds, thereby minimizing chemical consumption. The use of a slurry-less pad


770


eliminates the problem of slurry build-up in the spindle


764


. A non-contact level sensor


774


is desirably provided to monitor the chemical level in the channel


766


of the shaft


764


to ensure proper chemical flow. The sensor information can be used to control the pump


760


via a pump controller


776


to adjust the pumping to achieve the desired chemical flow rate and level and avoid flow interruption.

FIG. 9

further shows a belt and pulley coupling


780


between the spindle drive motor


734


and the spindle shaft


764


. The wafer holding vacuum for the vacuum chuck


708


is generated by using a high velocity air (or water or other fluids) flow away from the opening


784


at the bottom of the wafer chuck shaft


712


. This may employ a non-contact vacuum venturi


786


with compressed air flow


788


for increased reliability.




Planarization Calibration System





FIG. 10

is a simplified block diagram of a planarization calibration system of the present invention. It is noted that the figure is merely a simplified block diagram representation highlighting the components of the planarization apparatus of the present invention. The system shown is exemplary and should not unduly limit the scope of the claims herein. A person of ordinary skill in the relevant arts will recognize many variations, alternatives and modifications without departing from the scope and spirit of the invention. Planarization system


800


includes a planarization station


804


for performing planarization operations. Planarization station


804


can use a network interface card (not shown) to interface with other system components, such as a wafer supply, measurement station, transport device, etc. There is a wafer supply


802


for providing blank test wafers and for providing production wafers. A measurement station


806


is provided for making surface measurements from which the removal profiles are generated. The planarization station


804


, wafer supply


802


and measurement station


806


are operatively coupled together by a robotic transport device


808


. A controller


810


includes control lines and data input lines


814


that cooperatively couple together the constituent components of system


800


. Controller


810


includes a data store


812


for storing at least certain user-supplied planarization parameters. Alternatively, data store


812


can be a remotely accessed data server available over a network in a local area network.




Controller


810


can be a self-contained controller having a user interface to allow a technician to interact with and control the components of system


800


. For example, controller


810


can be a PC-type computer having contained therein one or more software modules for communicating with and controlling the elements of system


800


. Data store


812


can be a hard drive coupled over a communication path


820


, such as a data bus, for data exchange with controller


810


.




In another configuration, a central controller (not shown) accesses controller


810


over communication path


820


. Such a configuration might be found in a fabrication facility where a centralized controller is responsible for a variety of such controllers. Communication path


820


might be the physical layer of a local area network.




As can be seen, any of a number of controller configurations is contemplated in practicing the invention. The specific embodiment will depend on considerations such as the needs of the end-user, system requirements, system costs, and the like.




The system diagrammed in

FIG. 10

can be operated in production mode or in calibration mode. During a production run, wafer supply


802


contains production wafers. During a calibration run, wafer supply


802


is loaded with test wafers. Measurement station


806


is used primarily during a calibration run to perform measurements on polished test wafers to produce removal profiles. However, measurement station


806


can also be used to monitor the quality of the polish operation during production runs to monitor process changes over time.




In another embodiment, measurement system


806


can be integrated into planarization station


804


. This arrangement provides in situ measurement of the planarization process. As the planarization progresses, measurements can be taken. These real time measurements allow for fine-tuning of the planarization parameters to provide higher degrees of uniform removal of the film material.




The program code constituting the control software can be expressed in any of a number of ways. The C programming language is a commonly used language because many compilers exist for translating the high-level instructions of a C program to the corresponding machine language of the specific hardware being used. For example, some of the software may reside in a PC based processor. Other software may be resident in the underlying controlling hardware of the individual stations, e.g., planarization station


804


and measurement station


806


. In such cases, the C programs would be compiled down to the machine language of the microcontrollers used in those stations. In one specific embodiment, the system employs a PC-based local or distributed control scheme with soft logic programming control.




As an alternative to the C programming language, object-oriented programming languages can be used. For example, C++ is a common object-oriented programming language. The selection of a specific programming language can be made without departing from the scope and spirit of the present invention. Rather, the selection of a particular programming language is typically dependent on the availability of a compiler for the target hardware, the availability of related software development tools, and on the preferences of the software development team.




While the above is a full description of the specific embodiments, various modifications, alternative constructions and equivalents known to those of ordinary skill in the relevant arts may be used. For example, while the description above is in terms of a semiconductor wafer, it would be possible to implement the present invention with almost any type of article having a surface or the like. Moreover, instead of performing a conditioning procedure using a dummy wafer, numerical or computer simulation and modeling may be used to obtain the desired shape of the polishing pad. Therefore, the above description and illustrations should not be taken as limiting the scope of the present invention which is defined by the appended claims.



Claims
  • 1. A method of forming a polishing pad having a smaller diameter than an object to be planarized and to be used for planarizing the object by chemical-mechanical planarization, the method comprising:placing a polishing surface of the polishing pad in contact with an abrasive surface of a conditioning object having a shape identical to the object to be planarized; engaging the polishing surface of the polishing pad with the abrasive surface of the conditioning object under conditions substantially equal to the conditions to be applied for planarizing the object; observing the polishing surface; and disengaging the polishing surface of the polishing pad from the abrasive surface of the conditioning object when abrasion of a center region of the polishing surface of the polishing pad by the abrasive surface of the conditioning object is initially detected.
  • 2. The method of claim 1 wherein the polishing surface of the polishing pad is pushed against the abrasive surface of the conditioning object by a force substantially equal to a force to be applied to the polishing pad against the object to be planarized.
  • 3. The method of claim 1 wherein the polishing pad is moved relative to the conditioning object in a manner similar to a movement for planarizing the object.
  • 4. The method of claim 1 wherein the polishing pad is rotated relative to the conditioning object at a rate which is lower than a rate of rotation for planarizing the object.
  • 5. The method of claim 1 further comprising shaping another polishing pad to have a profile similar to a profile of the polishing surface of the polishing pad after disengaging the polishing pad from the conditioning object.
  • 6. The method of claim 5 wherein said another polishing pad is shoved by molding.
  • 7. The method of claim 5 wherein the steps of placing the polishing surface of the polishing pad in contact with the abrasive surface of the conditioning object and engaging the polishing surface of the polishing pad with the abrasive surface of the conditioning object are performed with a polishing apparatus; and further comprising polishing a wafer using said another polishing pad with the same polishing apparatus.
  • 8. The method of claim 7 further comprising cleaning the polishing apparatus before polishing the wafer.
  • 9. The method of claim 1 wherein the conditioning object comprises a layer of fine sand paper having the abrasive surface.
  • 10. The method of claim 1 wherein the polishing surface of the polishing pad has a substantially flat center region and a rounded edge region after being disengaged from the abrasive surface of the conditioning object.
Parent Case Info

The present application is based on and claims the benefit of U.S. Provisional Patent Application Nos. 60/161,705, 60/161,830, and 60/161,778 filed Oct. 27, 1999, the entire disclosures of which are incorporated herein by reference.

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5792709 Robinson et al. Aug 1998 A
5938504 Talieh Aug 1999 A
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6022807 Lindsey, Jr. et al. Feb 2000 A
6093280 Kirchner et al. Jul 2000 A
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Provisional Applications (3)
Number Date Country
60/161705 Oct 1999 US
60/161830 Oct 1999 US
60/161778 Oct 1999 US