The present invention relates to the field of metrology in semiconductor devices, and more particularly, to target design and measurement concepts applicable, among others, to overlay metrology.
Periodic scatterometry targets are used to obtain accurate measurements of target features. Such targets include massive arrays of uniformly constructed and uniformly spaced periodic features arranged to provide the best possible targeting information. For example, periodic gratings may be used as targets as may other periodically configured higher dimensional target arrays having uniformly spaced and sized metrology features.
Current scatterometry overlay (SCOL) targets are non-design-rule targets, which include features or spaces as large as 400 nm. A typical SCOL target consists of several cells, each consisting of two gratings (one in each of the layers between which the overlay needs to be measured). An example of a grating in one of these layers is seen in
Another aspect of current 1st order SCOL technologies is that they have TIS (tool induced shift) and TIS3s (tool induced shift 3-sigma—a variability value relating to the TIS) that result from non-zero illumination asymmetry. To reduce TIS and TIS3s one needs a variety of error-prone calibration techniques which lead to a residual TIS and TIS3s. Another disadvantage of current 1st order SCOL technologies is that there is no direct per-pupil-coordinate weight that is strongly correlated to accuracy.
Another aspect of current 1st order SCOL technologies is that they are based on comparing signals performed at different times (signals that correspond to pupil images of different target cells). These signals experience different system noise which needs to be removed. The sensitivity of the overlay to miss-handling the system noise is significant, and leads to very tight tolerances on this parameter.
Periodic targeting structures typically feature two layers of similarly oriented periodic gratings formed one over the other. Typically, the layers are designed with a specified predetermined offset with respect to each other. This enables scattering signals to be generated when illuminated by a light beam. A comparison of the actual signal produced with the expected scattering signal enables highly accurate overlay metrology measurements to be made. Optical metrology targets can also comprise of single gratings and/or gratings in a single layer, for example in optical metrology of critical dimension or in overlay optical metrology having targets positioned side by side.
Current SCOL target designs comprise of finite size cells 90 which include gratings 80, 85 of a defined pitch. The number of gratings and their position depends on the specific SCOL technology. For example, in 0th or 1st order SCOL, a target comprises of several cells, each cell comprising of two gratings in two different layers. In the single patterning case, for instance, the two layers are positioned on top of each other, with, possibly, several film layers in between. Relative offset 75 of the grating position includes a programmed offset (pof) and the overlay (ovl). The main SCOL paradigm is that the asymmetry in the cell is solely due to the total offset and so that rotating the target by 180° is equivalent to negating the sign of the total offset. This basic assumption leads to a variety of algorithms that take as input the asymmetry signals of various cells with different values for pof, and use it to extract the overlay.
Scatterometry overlay (SCOL) technology, as illustrated e.g., in WIPO publication no. WO 2004076963, measures an overlay error between congruent targets in different layers by measuring the interferences of reflected diffraction orders from the targets.
One aspect of the present invention provides a method of estimating an overlay error between at least two layers, the method comprising: illuminating a metrology target that comprises at least two periodic structures which are at different layers, are along a common measurement direction and have a same pitch, wherein the metrology target is symmetric with respect to a 180° rotation about an axis that is perpendicular to the target, and wherein the illumination is carried out simultaneously with respect to the at least two periodic structures; measuring interference of at least one diffraction order from the at least two periodic structures; and extracting the overlay error from the measured interference.
These, additional, and/or other aspects and/or advantages of the present invention are set forth in the detailed description which follows; possibly inferable from the detailed description; and/or learnable by practice of the present invention.
For a better understanding of embodiments of the invention and to show how the same may be carried into effect, reference will now be made, purely by way of example, to the accompanying drawings in which like numerals designate corresponding elements or sections throughout.
In the accompanying drawings:
Prior to the detailed description being set forth, it may be helpful to set forth definitions of certain terms that will be used hereinafter.
The terms “target” or “metrology target” as used in this application refer to a region from which metrology information is extracted. Metrology targets may be positioned on dedicated areas on the chip, on device edges or within the device area.
The term “periodic structure” as used in this application refers to any kind of designed or produced structure in at least one layer which exhibits some periodicity. The periodicity is characterized by its pitch, namely its spatial frequency. In the present application, periodic structures are occasionally referred to in a non-limiting manner as “grating” as these are simple and common periodic structures that are used for metrology. Such use however is not to be understood as limiting the term “periodic structure” in any way.
The terms “cell” or “grating cell” as used in this application refer to an area which includes at least one periodical structure for metrology measurements. Metrology targets may comprise one or more cell, which comprises periodic structures on one or more layers. Different cells may comprise distinct structures or different areas or parts of a single structure.
The terms “boundaries” or “cell boundaries” as used in this application refer to a circumference of a target cell, determined with respect to characteristics of the target cells. For example, for a single layer target, the boundary may be defined from the properties of that single layer and the target. For example, for grating-on-grating targets the boundary may be defined per layer (per grating) and the symmetric target design dictates that at least one of the boundaries obeys symmetry. The cell boundaries may be a frame that separates the cell from its surrounding, in case such a frame is present. If a frame is not present, the cell boundary may be defined in a non-limiting manner as the perimeter of the smallest area containing the printed structure which can be un-ambiguously associated with the relevant grating or periodic structure. For example, in case of a grating, the boundary may be defined as the perimeter of the smallest area which contains the resist bars in a resist grating.
The term “scatterometry overlay (SCOL)” as used in this application refers to a metrology method that derives metrology information from the phases of diffraction orders (e.g. the +1 and −1 diffraction orders) that reflect off targets which contain periodic structures such as gratings or grating cells.
The term “side by side” as used in this application refers to areas in a metrology targets which are positioned at least partly adjacent to each other and not one beneath the other.
The terms “symmetry” or “rotational symmetry” in relation to targets, as used in this application, refer to a rotational symmetry upon rotating the target 180° about an axis through the center of the target and which is perpendicular to the target.
The term “overlay” as used in this application refers to a non-programmed shift between two layers in a chip. The terms “programmed offset” or “offset” as used in this application refers to a specified intentionally-introduced shift between layers.
With specific reference now to the drawings in detail, it is stressed that the particulars shown are by way of example and for purposes of illustrative discussion of the preferred embodiments of the present invention only, and are presented in the case of providing what is believed to be the most useful and readily understood description of the principles and conceptual aspects of the invention. In this regard, no attempt is made to show structural details of the invention in more detail than is necessary for a fundamental understanding of the invention, the description taken with the drawings making apparent to those skilled in the art how the several forms of the invention may be embodied in practice.
Before at least one embodiment of the invention is explained in detail, it is to be understood that the invention is not limited in its application to the details of construction and the arrangement of the components set forth in the following description or illustrated in the drawings. The invention is applicable to other embodiments or of being practiced or carried out in various ways. Also, it is to be understood that the phraseology and terminology employed herein is for the purpose of description and should not be regarded as limiting.
Certain embodiments comprise metrology targets 100 having at least two periodic structures 85 which are at different layers 60. Periodic structures 85 (e.g. gratings 85) are along a common measurement direction 102 and have a same pitch 103 and metrology target 100 is symmetric with respect to a 180° rotation 74 about an axis 73 that is perpendicular to target 100. A metrology system 110 is arranged to measure an overlay shift or error in direction 102 between layers 60.
Scatterometry overlay (SCOL) derives metrology information from the phases of diffraction orders (e.g. the +1 and −1) that reflect off targets 100 which contain periodic structures 85 such as gratings 85 or grating cells 101. In certain embodiments, periodic structures 85 are located side by side (e.g., at different layers) as illustrated in
or along any other axis in the wafer plane). To measure the overlay in the y-direction, additional cells 101 may be used, with periodic structures 85 such as gratings 85 along the y-direction. In a non-limiting example, a two dimensional overlay metrology may be implemented by four side-by-side cells 101 two for the measurement of the x-overlay and two for the measurement of the overlay in the y-direction. In such embodiments, the measurement time may be shortened by using four measurement beams, two falling on the grating cells for the x direction and two falling on the grating cells for the y direction. The beams may be all simultaneous or pairwise simultaneous with respect to measurement directions 102. Each pair of two beams that fall on a pair of cells 101 that are in the same direction 102 are coherent among themselves. All the four beams may or may not be coherent among themselves. The signal from each pair of cells with grating lines in the same direction appears at different portions of the collection pupil, as it happens in the case of targets of the form presented in
Certain embodiments of the invention comprise methods for designing and/or producing any of targets 100 illustrated above and below, as well as variations of such targets according to the measurement principles presented below. Certain embodiments comprise sets of design rules as well as wafers that comprise such targets 100.
In certain embodiments, the target's zeroth order reflectivity is reduced with respect to its first order reflectivities, to improve measurement accuracy. The ideal signal in SCOL measurements is coming only from the ±1st orders of the two gratings, without any inaccuracy contributed by leakage of 0th order light into the ±1st orders regions due to diffractions from objects in field planes. However, current 1st order SCOL technologies do not allow reducing the zeroth order reflectivity because, as the signals originate in a grating-over-grating stack, the zeroth and ±1st order signals actually results from all possible combinations of nth order light from the first grating and the mth order light from the second, with n+m=0,±1, respectively. Therefore, the relative reflectivities are not separable by diffraction order. In contrast, the side by side paradigm and targets enable such separation, as the periodic structures do not overlap. Hence, it is possible to design side by side targets and periodic structures are designed to have a lower reflectivity of a zeroth diffraction order than a reflectivity of ±1st diffraction orders.
Rotational Symmetry of Targets
The current invention overcomes the following disadvantage of prior art targets, which is illustrated in
Since the total induced offset is zero, the assumption mentioned above means that this cell should be symmetric to 180° rotations and so that its signal asymmetry should be zero. But this expectation ignores the symmetry breakdown induced by the finite size effects of the cell's edge. As is clear from
In embodiments, the symmetry operation that is referred to in the disclosure is the 180° rotation with respect to an axis that is perpendicular to the target. This symmetry operation is commonly used with respect to SCOL signals. However, certain embodiments of the invention are not limited to this case, and in cases of other targets and other symmetry operations, embodiments of the invention may comprise designing target cells that are invariant with respect to the cell edges under any specified transform.
The current invention overcomes this neglect of edge-induced asymmetry effects which lead to significant inaccuracy in the overlay measurement that can range from a few to tens of nanometers, depending on the stack, wave length, polarization, and cell size.
As metrology target cells become smaller, the error introduced by edge effects increases. In particular, edge effects may produce an additional offset between gratings at different layers, beyond the designed offset (which is known) and the uncontrollable offset (which is to be measured). Certain embodiments of the invention introduce cells having gratings which are symmetrical with respect to the cell edges defining the cell frame. The symmetry cancels out edge effects. Target cells may be either fully symmetrical by design, or targets may include complementary cells having opposite designed offsets.
Certain embodiments of the current invention introduce target 100 designs that produce (i) zero signal asymmetries for cells 101 with zero total offset and (ii) in cases where there exists a total offset 107A for cell 101A and a total offset 107B=−offset 107A for cell 101B, the target design leads to signal asymmetry in two cells 107A, 107B that is opposite in sign.
Without being bound by theory, the design of target 100 leads, even in the presence of significant diffractions from cell edges 70, to the following relation:
Signal(180° rotation(cell with offset))=Signal(cell with −offset) (Equation 1);
which also means that:
Signal asymmetry(offset)=−Signal asymmetry(−offset) (Equation 2); and
Signal asymmetry(0 offset)=0 (Equation 3).
Specifically, instead of target design 90 (
In certain embodiments, metrology target 100 comprises at least one cell 101 having at least one periodic structure (e.g., 80, 85 such as a grating) that is invariant with respect to a specified transform with respect to edges 70 of at least one cell 101. In certain embodiments, the specified transform is a 180° rotation 74 about axis 73 perpendicular to at least one cell 101.
In certain embodiments, metrology target 100 comprises at least one cell having at least one grating that is rotationally symmetrical within edges of the at least one cell with respect to a 180° rotation about an axis perpendicular to the at least one cell. In embodiments with more than one grating, the second grating may also rotationally symmetric but it may suffice that it be rotationally symmetric in the absence of the cell edges. In certain embodiments, both cells 101 may be invariant under a 180° rotation about respective axes (e.g., as in
In certain embodiments, metrology target 100 may comprise at least one cell 101 having two parallel gratings 80, 85, each at a different layer of target 100, wherein at least one of gratings 80, 85 is rotationally symmetric with respect to axis 73 which is perpendicular to gratings 80, 85 and central with respect to edges 70 of at least one cell 101. Metrology target 100 may comprise one cell 101 with two parallel gratings 80, 85 which are both rotationally symmetric with respect to axis 73 which is central with respect to edges 70 of cell 101.
For the case in which target 100 is a grating-over-grating type of target, SCOL targets 100 may generally comprise N cells 101. For example in technologies that are based on a first order diffraction signal, N is larger or equal to two, while technologies that are based on the zeroth order diffraction signal require that N must be larger or equal to four. All SCOL technologies require that the 180° flip of the cell be equivalent to negating the sign of the offset between the top and bottom grating, and this requirement is broken if the cell is designed such that neither of the gratings, together with its frame is symmetric to 180° rotation. Therefore, to fulfill this requirement, the current invention dictates that in all such SCOL technologies at least one of the gratings is printed in a way that makes it rotationally symmetric to a 180° rotation together with the cell edges.
As illustrated in
Metrology target 100 may comprise two cells 101A, 101B, each comprising a first and a second parallel gratings 80, 85 respectively, in a first and a second layer of target 100, wherein the first gratings (e.g. lower gratings 80) of both cells 101 are rotationally symmetric with respect to axis 73 which is perpendicular to gratings 80, 85 (in each cell 101) and central with respect to edges 70 of the respective cell. The second gratings (e.g. upper gratings 85) may be offset from the respective first gratings at an equal and opposite offset 107.
The pictorial representations above are for the case where edge 70 (and/or frame, if present) of cell 101 is not shifted with upper grating 85. Another option for the target design is to shift edge 70 (and/or frame) with the upper offset, and in that case the new target design still leaves Equations 1-3 valid.
In embodiments, metrology targets 100 may be designed as e.g. scatterometry overlay (SCOL) or optical critical dimension (OCD) targets. SCOL targets 100 may comprise four cell or eight cell targets or any number N of cells where N depends on the technology. Targets 100 may comprise cells 101 in a single layer, in two layers or in more than two layers. Targets 100 may have their top views comprised of one dimensional gratings or of two dimensional gratings. In particular, targets 100 may comprise at least four cells 101 arranged in two dimensions of target 100. Targets 100 may comprise no offset between cell elements (e.g. gratings 80, 85), a single offset between cell elements, or multiple offsets. Targets 100 may comprise at least n gratings 80, 85 and be designed to have at least k offsets among the gratings (with k<n).
Advantageously, the inventors have found out that targets 100 having their design following the disclosed rules produce more accurate results for the overlay measurement. The causes for inaccuracy, which are left to be corrected, merely comprise e.g. de-centering of the illumination around the cell center, light contamination from the surrounding of the cell (which is not expected to be symmetric to 180° rotation), and grating asymmetries (such as differences in the left and right side wall angles of each bar).
In embodiments, method 200 comprises producing at least one metrology target cell having at least one grating that is symmetrically positioned within edges of the at least one cell with respect to both a reflection and a 180° rotation around an axis perpendicular to the at least one cell.
In embodiments, method 200 may comprise designing and/or producing a rotationally symmetric metrology target cell with reference to the cell edges (stage 210); designing and/or producing a metrology target cell to be rotationally symmetric with respect to one grating and have another grating offset therefrom (stage 212); designing and/or producing a metrology target cell having some of its features rotationally symmetric with respect to the cell edges (stage 214); designing and/or producing metrology targets having multiple cells with elements that are invariant under a specific transform with respect to the corresponding cell boundaries (stage 215) and designing and/or producing metrology target cells which are symmetric to a 180° rotation with respect to at least some of their features (e.g. one grating) (stage 218), and as a non-limiting example for such a transform.
Method 200 uses rotationally symmetric or partially rotationally symmetric target cells for overlay measurements (stage 220), to reduce an error in overlay measurements (stage 225).
Embodiments of the invention comprise metrology systems arranged to measure at least one metrology target 100 as described above, and metrology target design and production system operating according to method 200, as well as software tools used to design and produce targets 100 or implement method 200.
Side by Side Paradigm
Without being bound by theory, the following derivation provides a basis for various measurement techniques which are described below. In the side-by-side SCOL paradigm the overlay information is contained in the interference terms between the electromagnetic fields reflected off the two side-by-side cells in the collection pupil. Specifically, the electric field of the nth diffraction order reflected by layer ‘a’, in the collection pupil, is denoted by
Here |En(a)({right arrow over (k)})| is the amplitude of the field and ψn(a)({right arrow over (k)}) is its phase, both with respect to the position in the pupil plane denoted by k. The total intensity present at the collection pupil point {right arrow over (k)} and diffraction order n, is then given by the following expression (here and below the collection pupil coordinates are denoted in terms of illumination pupil coordinates, and so, for example, the intensity at the center of the +1st order is denoted by In=+1 ({right arrow over (k)}=0)).
where OVL is the relative overlay between gratings 85, Offset is the programmed offset between gratings 85 in direction 102 of the overlay, {right arrow over (X)} is the relative distance between the centers of the symmetric parts of the spots (which is taken to be equal to the distance between the centers of the cells, see
Clearly, the overlay information is present in the argument of the cosine, or more precisely, in the difference of the argument of the cosine at diffraction order +1 and −1. In particular, the side-by-side technology uses the fact that for targets whose symmetry is non-damaged (rotationally symmetric gratings) the phases obey the following symmetry relation:
ψn(a)({right arrow over (k)})=ψ−n(a)(−{right arrow over (k)}). (Equation 5)
Relying on this fact, a multitude of techniques is described below, for extracting the overlay from the intensity in the pupil. It is noted in passing that for targets having non-damaged symmetry (rotationally symmetric gratings), the amplitude of fields also obeys symmetry of the following form.
|En(a)({right arrow over (k)})|=|E−n(a)(−{right arrow over (k)})|. (Equation 6)
In certain embodiments, method 500 may further comprise introducing a controlled variable that effects the illumination and/or collection beams from at least one of the periodic structures (stage 460) and extracting the overlay error from the measured interference with respect to the introduced controlled variable (stage 485). Finally, method 500 may comprise estimating an overlay error between at least two layers with the periodic structures (stage 490).
Introducing a controlled variable is to be understood in a broad sense. In certain embodiments, the controlled variable may be a phase φ introduced by phase modulator 43 (see e.g., Example 5 below). In certain embodiments, the controlled variable may be an image shift in any plane (see e.g., Example 2 below for image shifts in the field plane). In certain embodiments, the controlled variable may be additional measurements and/or additional targets that allow extracting the overlay from multiple measurement results (see e.g., Example 1 below).
The controlled variable, such as phase φ, may be used to calibrate metrology system 110 on the fly with respect to the measured targets. In certain embodiments, the distance X between the periodic structures may also be designed to calibrate metrology system 110.
In certain embodiments, side by side targets 100 may be different parts of a single periodic structure, e.g., two regions of a single grating 85.
In metrology system 110, a light beam from a light source 40 enters a spot splitting apparatus 42 which has all required optics and apertures to generate at its exit a number of beams with designed spatial and angular content (e.g. beam diameter, shape, phase, divergence and polarization). As noted above, multiple beams may be generated either from multiple coherent sources or via spot splitting apparatus 42. Illumination arm 45 includes all components or systems (optical, mechanical, electrical or other) required to enable the operation of system 110 according to any implementation as exemplified below for non-limiting possible variations. The light then goes through a beam splitter 54 into an objective 51 (e.g. a high NA objective). Then, the light is reflected (diffracted) off side by side SCOL target 100, through objective 51, beam splitter 54 and collection arm 55, which includes all required components and systems required for signal detection according to the relevant operational option. After passing collection arm 55 the light falls onto a detector 59 (e.g. a camera). Detector 59 may be either in a pupil conjugate plane or in a field conjugate plane. In certain embodiments, illumination arm 45 and/or collection arm 55 may comprise a scanning mechanism in wither the field or pupil planes.
Spot Splitting
There are a few ways of splitting the illumination spot from source 40, which are illustrated in the following for splitting the illumination beam into two beams as a non-limiting example (clearly splitting to more beams is straightforward). All subsystems also include the required optics and apertures to generate spots on target 100 that have the required illumination NA (numerical aperture), size and distribution and polarization.
In certain embodiments, beam splitter 42 may be arranged to yield multiple illumination beams 169 and/or to allow splitting the illumination beam (i.e. electromagnetic radiation from at least one source 40) into two (or more) out of a range of N possible illumination beams. Beam splitter 42 and/or illumination arm 45 may be arranged to controllably yield and direct illumination beams 169 at selected periodic structures 85. For example (see
The following are non-limiting examples for metrology method stages, techniques and apparatus configurations for measuring side by side targets 100 according to the side by side paradigm, referring to Equation 4 presented above. These examples illustrate different ways to extract the overlay OVL from the intensity measurements, and more particularly from the argument of the cosine in Equation 4, namely:
Illumination arm 45, collection arm 55 and processor 111 may be arranged to implement the principles presented below, as well as any combination or variation of these principles.
In certain embodiments, method 500 comprises setting the illumination beams to exhibit no phase differences (stage 510) i.e. setting φ1,2=0; illuminating separately each periodic structure to measure the respective diffracted intensity (stage 512), i.e. illuminating grating (1) alone to provide a measurement of |En(1)({right arrow over (k)})| and illuminating grating (2) alone to provide a measurement of |En(2)({right arrow over (k)}) (e.g. by turning off the beams illuminating the other grating respectively); illuminating simultaneously the periodic structures to measure the interference term (stage 514) of Equation 4 and extracting the overlay from interference measurements for ±1 diffraction orders and opposite locations ±k (stage 516).
For example, stage 516 may be carried out as follows: Extracting the cosine
for each order n=+1, n=−1. From the cosines, extracting the two mathematically consistent arguments of the cosine, βn({right arrow over (k)})=±a cos(Cn({right arrow over (k)})). From the two mathematically consistent candidates for β+1({right arrow over (k)}) and the two candidates for β−1(−{right arrow over (k)}), producing four candidates for
In certain embodiments, these measurements may be carried out with polarized or un-polarized light. If polarized, the polarization of beams (1) and (2) can be identical or different, and if the two polarizations are orthogonal, a polarizer may be used at collection arm 55. The polarization of the beams may be linear or polar (radial/azimuthal).
Extracting the overlay may be carried out by symmetrizing all the candidate functions
and using the statistical distribution of Δβ({right arrow over (k)}) across the pupil coordinate {right arrow over (k)} to find the correct solution which gives the constant function
This choice may be simplified by choosing a programmed offset judicially to simplify the extraction (stage 518). Finally, the collection pupil may be calibrated to remove from each of the four candidates for Δβ({right arrow over (k)}) the function 2 {right arrow over (k)}·{right arrow over (X)}.
Extracting the overlay may be carried out by using three periodic structures, one in one layer and two in another layer with different programmed offsets (stage 520) and extracting the overlay from interference measurements for ±1 diffraction orders and the two structures in the same layer with different programmed offsets (stage 522). Denoting the target in layer no. 1 as cell I and the two cells in layer no. 2 as cell II and cell III, each of cells II and III has a different programmed offset with respect to cell I. Performing the measurements of stages 512 and 514 for both cell pairs (I-III) and (II-III), two cosines are obtained for the two relative offsets OF(I-III) and OF(II-III) in both the plus and minus first orders. These four cosines have only one solution for the overlay that is mathematically consistent.
Extracting the overlay may be carried out by taking multiple measurements with different illumination intensities (stage 524) and extracting the overlay from interference measurements for ±1 diffraction orders and the different illumination intensities (stage 526). The multiple measurements with different relative intensities between the two spots provides sufficient information to extract the cosines Cn({right arrow over (k)}).
In certain embodiments, method 500 comprises setting the illumination beams to exhibit no phase differences (stage 510) i.e. setting φ1,2=0; imaging the wafer to a field conjugate plane (stage 530) and performing image shifting at the field conjugate plane (stage 532), e.g. by modifying the image to shift the image part containing one of the gratings in the direction of the grating by N different shifts, with N≥3, compensating for the image shifting in the illumination (stage 534) and extracting the overlay algorithmically from the compensated image shifts (stage 536).
The following non-limiting example illustrates the method with N=4 and
with a=0,1,2, and 3. As the generalization to N=3 and N≥5 is straightforward the following calculated can be easily adjusted.
Image shifting 532 may be compensated by shifting the illuminating beam in an opposite direction, to maintain the overall position of the image unchanged (stage 534). For example, the laser beam falling on the cell, whose image is shifted, may be shifted back in illumination branch 45, so that its position in the field conjugate plane after the image shifting stage is unchanged.
The algorithmic extracting of the overlay may be carried out using the N different collection pupil images in any of the following non-limiting ways. Other algorithms and algorithm combinations may be optimized with respect to performance requirements of the system.
Algorithm (I): For each diffraction order n=±1, and each illumination pixel {right arrow over (k)}, use linear combinations of the N signals to extract two differential signals, D1,2 which are proportional to the cosine and the sine of the phase
respectively. The amplitude of these differential signals is proportional to the amplitude of the fields, |En(1,2))({right arrow over (k)})|, but is independent of the phases ψn(1,2)({right arrow over (k)}). Next, for each order, construct the per-pixel complex number D1+iD2, whose phase is equal to βn({right arrow over (k)}). Finally, using the difference Δβ({right arrow over (k)})=β+1({right arrow over (k)})−β−1(−{right arrow over (k)}), and assuming the symmetry properties of the phases ψn(1,2))({right arrow over (k)}), extract the overlay by either writing
or by calibrating the pupil, and subtracting 2 {right arrow over (k)}·{right arrow over (X)} from each βn({right arrow over (k)}).
Algorithm (II): For each illumination pixel {right arrow over (k)}, use the 2N signals obtained from the +1st and −1st orders of the N field offsets, to form four linear combinations; two that are proportional to the sine of
and two that are proportional to the cosine of γ({right arrow over (k)}). For example, if N=4, these four combinations are proportional to the amplitudes |En(1,2))({right arrow over (k)})|; also two of the combinations (denoted as σ1,2({right arrow over (k)})) are proportional to the cosine of Δψ=ψ+1(1)({right arrow over (k)})−ψ+1(2)({right arrow over (k)}) and the other two (denoted as δ1,2({right arrow over (k)})) to the sine of Δψ. From these four differential signals produce two complex numbers, whose phase is γ({right arrow over (k)}) and obtain two independent determinations of the OVL (both can be obtained by either symmetrizing γ({right arrow over (k)})→γ({right arrow over (k)})+γ(−{right arrow over (k)}) or by performing a pupil calibration and subtracting from γ({right arrow over (k)}) the function {right arrow over (k)}·{right arrow over (X)}). Use these two overlay determinations to form a weighted average overlay determination.
Algorithm (III): Form two combinations from the squares of σ1,2({right arrow over (k)}) and δ1,2({right arrow over (k)}) defined above such that their size is independent of Δψ. These two combinations are proportional to the cosine of γ({right arrow over (k)}) and to its sine, respectively, and this allows one to extract the phase γ({right arrow over (k)}) itself. To determine the overlay proceed as described in Algorithm (II).
Algorithm (IV): For each diffraction order and each pupil coordinate, form two linear combinations with pre-determined coefficients that are optimized to reduce system noise and that follow any of the well-known phase shifting algorithms in the analysis of interferometric signals. These two combinations are proportional to the sine and the cosine of βn({right arrow over (k)}) from Algorithm (I). Use these linear combinations in the same way as Algorithm (I) uses them.
In certain embodiments, compensated field shifts may be combined with multiple measurements (see Example 1 above), for example in the following ways. One or more of the measurements in the multiple measurements example may be taken with a nonzero compensated field shift (stage 528) to remove ambiguities in the overlay measurements and improve sensitivity, or one or more additional measurements may be taken with a nonzero phase shift (stage 529) to remove ambiguities and improve sensitivity.
In certain embodiments, these measurements may be carried out with polarized or un-polarized light. If polarized, the polarization of beams (1) and (2) can be identical or different, and if the two polarizations are orthogonal, a polarizer may be used at collection arm 55. The polarization of the beams may be linear or polar (radial/azimuthal).
In certain embodiments, method 500 comprises performing image shifts physically (stage 538) and extracting the overlay algorithmically along principles similar to the ones described in Example 2. Generally, physical image shift, carried out by moving the wafer, may replace all or some of the N signals described above. In certain embodiments, images of each side-by-side cell couple may be taken once, without any spot compensation procedure.
In certain embodiments, method 500 comprises processing uncompensated shifted images with respect to phases which are dependent on the pupil coordinates (stage 540) and calibrating the pupil to calculate the phase and extract the overlay therefrom (stage 542). Instead of shifting the image in the conjugate field plane by N≥3 amounts Δa=1,2 . . . ,N and shifting the spot back on the wafer by minus these amounts as described in Example 2, the image shifting may be performed without the compensated spot shifting. Such shifting provides each pupil point with a pupil-coordinate dependent phase. Performing a pupil calibration enables one to know these phases. With that knowledge, both βn({right arrow over (k)}) and γ({right arrow over (k)}) may be extracted using the algorithms described above, and consequently the overlay may be extracted by any of the methods described above in Example 2.
In certain embodiments, method 500 comprises measuring pupil images corresponding to several values of illumination phase (stage 544), by setting φ2=0, Offset=0 and the illumination phases to a predetermined set of N values φa=1=φ1,2, . . . ,N. The measured corresponding N pupil images are used to extract the overlay in any of the algorithms described in the sections of Example 2 presented above.
In certain embodiments, these measurements may be carried out with polarized or un-polarized light. If polarized, the polarization of beams (1) and (2) can be identical or different, and if the two polarizations are orthogonal, a polarizer may be used at collection arm 55. The polarization of the beams may be linear or polar (radial/azimuthal).
In certain embodiments, method 500 comprises using mutually orthogonal polarized illumination beams and (stage 550) and configuring the collection field stop to have respective polarizers to separate the illumination beams (stage 552) to improve the accuracy of overlay measurements by reducing the leakage of light from the tail of one beam falling onto the other cell and vice-versa.
At the collection field stop plane (CFS 155C) plane, CFS 155C may be divided into two parts 187A, 187B, namely CFS part 187A that is aligned with target cell 101A, on which respective illumination beam 169A is incident, and CFS part 187B that is aligned with target cell 101B, on which respective illumination beam 169B is incident. Collection field stop 155C may have a polarizer 155G with a polarization angle that is parallel to the polarization axis in CFS part 187A and a polarizer 155H with a polarization angle that is parallel to the polarization axis in CFS part 187B. This “polarized CFS” reduces the leakage of light from the tail of illumination beam 169A falling onto cell 101B and vice-versa. In addition, a polarizer 155I may be set before the pupil detection plane. The polarization angle of polarizer 155I may be optimized in accordance to sensitivity, to achieve optimal contrast of the cross polarized incident beams. It is noted that the input polarization need not be linear, and one can use, for example, radial polarization in beam 169A and azimuthal polarization in beam 169B, with respective polarizers in the CFS parts 187A and 187B. For example, parts 187A, 187B may be two halves of CFS 155B with orthogonal polarizations. In certain embodiments, a complete control of the polarization distribution may be achieved in illumination arm 45 and/or in collection arm 55, e.g., by use of a polarization sensitive SLM such as a liquid crystal device. In certain embodiments, CFS 155C may be apodized. In certain embodiments, the polarization control may be carried out in a single plane as the aperture limit or in a different plane (e.g., either another field conjugate plane or an intermediate plane).
In certain embodiments, multiple polarizers may be used in the collection path, e.g., collection arm 55 may be duplicated after collection field stop 155C into two collection arms (i.e. two polarizers 155H and two pupil cameras 59 may be placed at the end of the two collection arms). Importantly, one needs to tune polarizer no. 1 to have angle α and polarizer no. 2 to have angle −α (with α chosen to optimize overlay sensitivity). To understand why, consider the interference of light coming from beam no. 1 (which is, for example, X-polarized in illumination) and reflecting off cell no. 1, with the tail of beam no. 2 (which, in this example, is Y-polarized in illumination), that is also reflected off cell no. 1, and that was rotated into an X-polarized light. Because this interference term does not contain overlay information it causes overlay inaccuracy. Interestingly, however, this interference term does not flip sign under the transformation α→−α. In contrast, the interference terms which do contain overlay information switch their sign when α does. Therefore, if the signals are subtracted from the two cameras 59, a portion of the signal inaccuracy is removed and the overlay accuracy is improved.
In certain embodiments, method 500 comprises shifting phases of the reflected beams in the collection arm (stage 555) by placing a phase modulator, which induces the phase onto one of the beams, into collection arm 55 (instead of in illumination arm 45 as described in Example 5). Extraction of the overlay is equivalent to that explained above in the “compensated field shifts” and the “phase shifts” Examples 2 and 5. As in former examples, the beams may be polarized to improve the accuracy of the measurements accuracy and the collection filed stop may comprise respective polarizers as explained in Example 6. The input polarization need not be linear polarizations, and one can use, for example, radial polarization in beam (1) and azimuthal polarization in the other.
In certain embodiments, method 500 comprises shifting phases of the reflected beams in the pupil plane (stage 560). A phase inducer (for example, a rotating plate with N wedges, each corresponding to a specific phase shifts) is placed in a pupil plane on collection arm 55. In certain embodiments, phase shifts may be applied with respect to the polarization of the beam (stage 562). The phase inducer may be controlled to induce phase-shifts only to one polarization (for example, only to an X-polarized light), and in a known way that depends on the plate's properties and the light's wavelength. In certain embodiments, different phases may be induced for the ±1 diffraction orders and/or for different diffraction orders (stage 564). The phase inducer may be controlled to induce a different phase onto the +1st diffracted light and the −1st diffracted light, with relative phases φ1,2, . . . ,N. To extract the overlay from the corresponding N pupil images, any one of the steps and algorithms described above in Example 2 (compensated field shifts) may be used.
With respect to phase shifts disclosed in any of the above examples, in certain embodiments, continuous phase shifts may be induced and the shifts may be made discrete by the pixel light integration procedure at detector 59 (stage 566).
With respect to phase shifts disclosed in any of the above examples, in certain embodiments, method 500 comprises applying a per-pixel weight during the extraction of the overlay (stage 570). In certain embodiments, the pixel weights may be chosen to optimize the signal to noise ratio of the overlay measurement on each pixel (stage 572) and in certain embodiments, the pixel weights may be used to perform a weighted average of the overlay across the pupil (stage 574).
In certain embodiments, the per-pixel weights may be used to provide direct and on-the-fly accuracy metrics. Since side-by-side SCOL involves two beams falling on two different gratings, the beam on one of the gratings may be turned off to measure the pupil image and conclude whether there is a per-pixel asymmetry. If such asymmetry exists, it is cause for an overlay inaccuracy, which may thus be identified, evaluated and reported. In all Side-by-side SCOL technologies, excluding the multiple measurement technology (Example 1) and algorithms II and III (in Example 2), the overlay information is found in the phase of the complex differential signal Z=D1+iD2. In particular, the overlay is extracted from the difference in the phases that correspond to Z(p) and Z(p′) that are located at pupil point p and p′, where p′ is the 180° rotation of p (see
In any of the disclosed examples, method 500 may comprise in certain embodiments, calibrating the pupil using the overlay measurements (stage 580). Several of the algorithms presented above involve the averaging of a function ƒ({right arrow over (k)}) across the plus and minus 1st order circles in a symmetric way (ƒ({right arrow over (k)})+ƒ(−{right arrow over (k)})). This requires that the points A± on the plus and minus 1st order circles on the detector, in which {right arrow over (k)}=0, are known. Assuming that the center of the whole collection pupil A0 is known, (which is imperative in all 1st order SCOL technologies), the points A± can be obtained if an angle θ between the detector's coordinate system and the grating-cell's coordinate system is known. The following options exemplify methods of estimating θ.
A first option is to apply a mathematical alignment in which the angle θ is measured using a field camera in the normal procedure, by measuring the tilt between two grating cells that are very far apart on the wafer. In addition, a lens may be inserted before the field camera, so to make it into a pupil camera, on which the overlay measurement in done. This makes sure that the measured θ is between the grating cell coordinate system in the field plane and the coordinate system of the pupil plane on the detector.
A second option is to apply a pupil TIS (tool induced shift) calibration, namely by measuring a TIS map from the measurement of the overlay of a single grating and subtracting the TIS map from the actual overlay pupil map. As the angle θ introduced a purely TIS error which is only a function of θ and the distance between the spots and is a purely geometrical contributor, the proposed TIS calibration removes the error introduced by the angle θ.
In any of the disclosed examples, method 500 may comprise in certain embodiments, modulating the beam amplitudes by apodizer(s) in pupil plane and/or in field plane (stage 590). These apodizers may, for example, take the form of the Blackman apodizers, or any other type of modulation of the light amplitude in the corresponding plane.
In certain embodiments, the phase modulation may be polarization sensitive. Such feature could be achieved for example by using a birefringent electro-optic material (e.g. LiNbO3) to apply the phase shift only for one of the polarizations that pass through the material. The geometrical arrangement of the component could be used to facilitate a different phase shift for different orders in the pupil (e.g. +1 and −1 diffraction orders).
Combinations of Technologies
This section illustrates some non-limiting examples for implementing system 110 according to the principles disclosed above and in combination with systems disclosed elsewhere in order to achieve reciprocal enhancement of their features.
In certain embodiments, metrology system 110 with side by side targets may also be used for imaging (instead of scatterometry overlay measurements) or may be integrated with current SCOL systems and targets. Also, any combination of the above examples may be used to enhance measurements, as illustrated in
Multiple Side by Side Targets
Current overlay measurement technologies that rely on scatterometry require the manufacture of “grating-over-grating” targets that comprise two gratings in the same direction and of the same pitch in the respective layers between which one wishes to measure the overlay error. Current SCOL technologies use two such targets to measure the positive and negative first diffraction, so that measuring overlays among N layers generally require ca. N2 targets (e.g., N(N−1)/2).
In the side by side paradigm, targets 100 use the wafer area in a much more efficient way to yield measurement results. In the illustrated example, cells 101 may be designated by an arbitrary relative position vector {right arrow over (r)} and the spot splitting may be dependent on r to allow measuring the overlay error using any pair of cells 101. For example,
Taking a non-limiting example of using the side by side paradigm as implementing a phase shift interferometer (see e.g., Example 5), a given spatial distribution of N single gratings 85 at N layers on the wafer (e.g., all with the same grating pitch 103, and the same grating direction 102), any pair of cells 101 may be used to measure the relative overlay. The real-estate (used wafer area) of target 100 for measuring overlays among N layers is thus proportional to N, in contrast to current SCOL technologies which require a real estate that is proportional to N2.
Advantages of the Proposed Side by Side Technology with Respect to SCOL
The following are some of the advantages of certain embodiments of the invention with respect to using the proposed side by side technology in scatterometry overlay (SCOL) measurements.
Zero algorithmic inaccuracy. Current SCOL technologies are fundamentally based on the assumption that the way the SCOL signal depends on the programmed offset and the induced offset is a simple series in cos (2πm(programmed offset+overlay)/Pitch) and sin (2πm(programmed offset+overlay)/Pitch) with m any integer number. Depending on details, current SCOL technologies measure only a limited number of SCOL signals (those that correspond to a limited number of values for the total offset). This fact necessarily means that the overlay measurement involves a generic inaccuracy. This inaccuracy depends on many things (like the specific stack, the programmed offset, the overlay, the target design, and the algorithm), and can reach a few nanometers in problematic stacks and a few angstroms in others. In addition, finite target size effects cause deviations of the signal form from a sum of sines and cosines. This causes additional algorithmic inaccuracy which increases as the target size decreases. As explained in the previous sections pertaining to the specifics of the different side-by-side SCOL technology, the algorithmic inaccuracy of all side-by-side technologies is zero.
Low sensitivity to illumination asymmetry. Current first order SCOL technologies extract the overlay from the difference in intensity at pupil pixel p and the 180 deg rotated pupil pixel p′. In the presence of illumination asymmetry, this intensity difference reflects both the overlay and the illumination asymmetry itself. This causes TIS and TIS3S, which is directly proportional to the per-pixel illumination asymmetry. To overcome this and decrease TIS and TIS3S, current first order SCOL technologies use a variety of prescriptions to cancel out the TIS and TIS3S due the illumination asymmetry that involve a variety of error-prone calibrations to correct for illumination asymmetry. All these prescriptions involve errors that are best avoided. In most side by side SCOL technologies (Algorithms II and III excluded), two differential signals are initially extracted from the 1st and −1st order, and then, two phases which contain the overlay are extracted from these two signals. The overlay is contained in the difference between these two phases. Importantly, because the overlay is contained in phase information which is probed directly by the technology and for each order separately, there is no dependence on illumination asymmetry and the resulting TIS and TIS3S is zero.
Good overlay sensitivity. The overlay sensitivity of current SCOL technologies is partly determined by the number N of the signals collected from the target, which is equal to the number of cells that are printed on the target. It also depends on the value of the programmed offsets printed by the scanner. The number N in current SCOL technologies (like 1st order and 0th order SCOL) is limited by cost of ownership considerations, and for example at 1st order SCOL one usually sets N=2 and in 0th order SCOL one sets N=4. The value of the programmed offsets is determined by optimizing a balance between sensitivity and algorithmic accuracy. Because Side-by-side technologies have zero algorithmic inaccuracy, and because the N signals obtained in the side by side paradigm all come from the same two cells (excluding Example 3—wafer shifts), but have differing illumination/collection configurations, then for the same number of physical printed cells, the sensitivity is much optimized compared to current SCOL technologies.
Low sensitivity to target asymmetry. Current first order SCOL technologies are very sensitive to grating asymmetry. In particular, while a grating asymmetry of a few percentages (in, for example, the side-wall-angles) can cause a few nanometers of an ambiguity in the definition of the overlay, current 1st order SCOL technologies tend to amplify these few nanometers to much larger inaccuracy, reaching tens of nanometers on occasions. The basic reason for this amplification is that the overlay signal in current first order SCOL technologies is extracted from differences of intensities and so it is sensitive to the asymmetry of the amplitude of the electromagnetic fields induced by the grating asymmetry.
In contrast to that, most side-by-side SCOL technologies (excluding Algorithm II and III), are only sensitive to the phase asymmetry generated by the grating asymmetry, and this phase asymmetry is nothing but the overlay ambiguity. Thus, excluding Algorithm II and III, side by side SCOL technologies have a minimal sensitivity to global target asymmetry.
Low sensitivity to target noise. Current SCOL technologies can be very sensitive to random target noise (for example, to random induced topography). Such target imperfection is caused by the incompatibility of the process to the target pitch, especially when a grating over grating SCOL stack is printed. Also, in current SCOL technologies, if one wishes to increase overlay sensitivity in current SCOL technologies, and/or reduce the algorithmic inaccuracy, one is led to printing more grating-over-grating cells with additional programmed offsets, which lead to an increased level of target noise, and so to degraded accuracy. Since side-by-side SCOL technologies are not grating-over-grating targets, they are expected to be much more process compatible. In addition, an increase of the number of signals N (so to improve sensitivity or reduce effects of slowly oscillating system noise, for example) does not increase target-noise related inaccuracy because all N signals are taken from the same physical cells (here we exclude the “wafer shifts” technology).
Zero sensitivity to intra-target process variation. Current SCOL technologies assume that the only difference between the cells contained in one target are the programmed offsets. Even in the absence of random target noise this assumption may be broken by intra-target process variations. These process variations cause a cell-to-cell variability in the reflectivity which is additional to the variation due to the programmed offset. In side by side SCOL, there is only one cell on each layer and so intra-target process variations are a non-issue (excluding the Example 3—wafer shifts).
Low real-estate area for given sensitivity: For the same reasons explained above, increasing the number of signals N by a factor f in current SCOL technologies increases target size by roughly f. In contrast, the target size in all side-by-side technologies is independent on N. In addition, and as explained above, there is a possibility to simultaneously measure overlays along the X and Y directions, with only two cells, while the minimal number of cells that are required in current SCOL technologies is four. Finally, to measure the overlay between multitudes of layers in current SCOL technologies requires a grating over grating SCOL target for each of the layers' pairs. In contrast, in side by side SCOL, a single grating for each layer is required.
Low sensitivity to fully correlated noise. Current SCOL technologies are very sensitive to fully correlated noise, and, to avoid inferior TMU and accuracy, the tolerance on fully correlated system noise is quite tight. In contrast, in side by side SCOL, the fully correlated noise contribution to precision is minimal because, as a result of the inter-beam distance, the signal on the pupil is strongly oscillating with the pupil coordinate. This causes the influence of the fully correlated noise to be much reduced from its “naive” value.
The side by side paradigm also allows for performance optimizations which arise from the fact that side by side SCOL involves two coherent beams and so there is a larger space of system parameters to be optimized over. These kinds of performance optimizations are thus not possible in current SCOL technologies. (1) Per-beam light intensity tuning. In stacks where the contrast is sub-optimal (because one grating is more reflective than the other), the light level of one beam may be tuned relative to the other beam, to shed less light on the more reflective layer. This was shown in simulations to enable the measurements of certain challenging stacks. (2) Using cross-polarized beams and optimizing the analyzer angle. For the same stacks where the contrast is sub-optimal, and if one uses one of the side by side technologies that involve cross-polarized beams, the angle of the final polarizer which enables the interference between the cross-polarized beams, can be tuned to enable optimal contrast. In addition, the choice of the polarization axes along which the incident beams are polarized can be used as a knob to optimize the performance of the side by side technology.
In the above description, an embodiment is an example or implementation of the invention. The various appearances of “one embodiment”, “an embodiment”, “certain embodiments” or “some embodiments” do not necessarily all refer to the same embodiments.
Although various features of the invention may be described in the context of a single embodiment, the features may also be provided separately or in any suitable combination. Conversely, although the invention may be described herein in the context of separate embodiments for clarity, the invention may also be implemented in a single embodiment.
Certain embodiments of the invention may include features from different embodiments disclosed above, and certain embodiments may incorporate elements from other embodiments disclosed above. The disclosure of elements of the invention in the context of a specific embodiment is not to be taken as limiting their use in the specific embodiment alone.
Furthermore, it is to be understood that the invention can be carried out or practiced in various ways and that the invention can be implemented in certain embodiments other than the ones outlined in the description above.
The invention is not limited to those diagrams or to the corresponding descriptions. For example, flow need not move through each illustrated box or state, or in exactly the same order as illustrated and described.
Meanings of technical and scientific terms used herein are to be commonly understood as by one of ordinary skill in the art to which the invention belongs, unless otherwise defined.
While the invention has been described with respect to a limited number of embodiments, these should not be construed as limitations on the scope of the invention, but rather as exemplifications of some of the preferred embodiments. Other possible variations, modifications, and applications are also within the scope of the invention. Accordingly, the scope of the invention should not be limited by what has thus far been described, but by the appended claims and their legal equivalents.
This application is a divisional patent application filed under 35 USC §§ 120 and 121 based on U.S. patent application Ser. No. 14/161,398, filed on Jan. 22, 2014, which application is a Continuation of International Patent Application Serial No. PCT/US2013/065527, filed on Oct. 17, 2013, which application claims priority of U.S. Provisional Patent Application No. 61/715,603, filed on Oct. 18, 2012 and U.S. Provisional Patent Application No. 61/745,981, filed on Dec. 26, 2012, all of which applications are incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
5298939 | Swanson | Mar 1994 | A |
5333050 | Nose et al. | Jul 1994 | A |
5340992 | Matsugu | Aug 1994 | A |
5465148 | Matsumoto | Nov 1995 | A |
6013355 | Chen | Jan 2000 | A |
6628390 | Johnson | Sep 2003 | B1 |
6982793 | Yang | Jan 2006 | B1 |
6992764 | Yang | Jan 2006 | B1 |
7046361 | Yang | May 2006 | B1 |
7242477 | Mieher | Jul 2007 | B2 |
7289214 | Li | Oct 2007 | B1 |
7561282 | Widmann | Jul 2009 | B1 |
7671990 | Adel | Mar 2010 | B1 |
7834997 | Nakayama | Nov 2010 | B2 |
8189202 | Liesener et al. | May 2012 | B2 |
8250497 | Hsu et al. | Aug 2012 | B2 |
8582114 | Manassen et al. | Nov 2013 | B2 |
8854632 | Shibazaki | Oct 2014 | B2 |
8908145 | Shibazaki | Dec 2014 | B2 |
9046792 | Hetzler et al. | Jun 2015 | B2 |
9134256 | Smilde | Sep 2015 | B2 |
9257351 | Ausschnitt | Feb 2016 | B2 |
9442393 | Hetzler et al. | Sep 2016 | B2 |
9784690 | Sapiens | Oct 2017 | B2 |
9811003 | Jak | Nov 2017 | B2 |
9835956 | Liu | Dec 2017 | B2 |
9885961 | Amir | Feb 2018 | B1 |
9903823 | Lu | Feb 2018 | B2 |
9910366 | Middlebrooks | Mar 2018 | B2 |
10061212 | Van Der Schaar | Aug 2018 | B2 |
10078268 | Den Boef | Sep 2018 | B2 |
10162271 | Smilde | Dec 2018 | B2 |
10162272 | Jak | Dec 2018 | B2 |
10222709 | Quintanilha | Mar 2019 | B2 |
20030021465 | Adel | Jan 2003 | A1 |
20040264903 | Dridi | Dec 2004 | A1 |
20050012928 | Sezginer et al. | Jan 2005 | A1 |
20050122506 | Wegmann et al. | Jun 2005 | A1 |
20050189502 | Van Bilsen | Sep 2005 | A1 |
20050195398 | Adel | Sep 2005 | A1 |
20050208685 | Abdulhalim | Sep 2005 | A1 |
20080062432 | Sandig et al. | Mar 2008 | A1 |
20090262362 | de Groot et al. | Oct 2009 | A1 |
20090296075 | Hu et al. | Dec 2009 | A1 |
20090313589 | Hsu et al. | Dec 2009 | A1 |
20100214550 | Hulsebos | Aug 2010 | A1 |
20100244333 | Bedal | Sep 2010 | A1 |
20110032535 | Liesener | Feb 2011 | A1 |
20110080585 | Rabello | Apr 2011 | A1 |
20120033215 | Kandel et al. | Feb 2012 | A1 |
20120044470 | Smilde | Feb 2012 | A1 |
20120212749 | Den Boef | Aug 2012 | A1 |
20120243004 | El Gawhary et al. | Sep 2012 | A1 |
20130010306 | Coene et al. | Jan 2013 | A1 |
20130066597 | Van Beurden | Mar 2013 | A1 |
20130278942 | Jeong et al. | Oct 2013 | A1 |
20130293890 | Amir | Nov 2013 | A1 |
20150177135 | Amit | Jun 2015 | A1 |
20160291481 | Smilde et al. | Oct 2016 | A1 |
Number | Date | Country |
---|---|---|
1601931 | Dec 2005 | EP |
2004076963 | Sep 2004 | WO |
Number | Date | Country | |
---|---|---|---|
20160216197 A1 | Jul 2016 | US |
Number | Date | Country | |
---|---|---|---|
61745981 | Dec 2012 | US | |
61715603 | Oct 2012 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 14161398 | Jan 2014 | US |
Child | 15092329 | US |
Number | Date | Country | |
---|---|---|---|
Parent | PCT/US2013/065527 | Oct 2013 | US |
Child | 14161398 | US |