A claim of priority under 35 U.S.C. §119 is made to Korean Patent Application No. 10-2011-0016637, filed on Feb. 24, 2011, the entire contents of which are hereby incorporated by reference.
The inventive concept relates to variable resistance memory devices and to methods of manufacturing the same.
Semiconductor devices may be classified into memory devices and logic devices. The memory devices store data. In general, the memory devices may be largely divided into volatile memory devices and nonvolatile memory devices. Volatile memory devices, e.g., Dynamic Random Access Memory (DRAM) devices and Static Random Access Memory (SRAM) devices, lose their stored data once power is no longer supplied to the devices. Nonvolatile memory devices, e.g., Programmable ROMs (PROMs), Erasable PROMs (EPROMs), Electrically EPROMs (EEPROMs) and flash memory devices, retain their stored data even once the power being supplied to the devices has been turned off.
Additionally, next generation semiconductor memory devices such as Ferroelectric Random Access Memory (FRAM), Magnetic Random Access Memory (MRAM), and Phase-Change Random Access Memory (PRAM) devices are in development to meet the demand for high performance semiconductor memory devices which have relatively low power consumptions. These next generation semiconductor memory devices employ materials whose resistances vary according to the amount of current or voltage supplied/applied and maintain their resistance even the current or voltage supplied/applied thereto has been interrupted or cutoff.
According to an aspect of the inventive concept, there is provided a method of manufacturing a variable resistance memory device, comprising: providing a substrate having a cell array region and a peripheral circuit region, using an epitaxial process in forming a semiconductor layer on the cell array region and the peripheral circuit region such that the semiconductor layer is an epitaxial semiconductor layer, and forming a peripheral transistor constituted by part of the epitaxial semiconductor layer on the peripheral circuit region.
According to another aspect of the inventive concept, there is provided a method of manufacturing a variable resistance memory device, comprising: providing a substrate having a cell array region and a peripheral circuit region, forming structures of semiconductor material on the cell array region and forming an active region of semiconductor material on the peripheral circuit region including by epitaxially growing crystalline material simultaneously on the cell array region and the peripheral circuit region, forming variable resistor elements on the structures of semiconductor material on the cell array region, and forming a peripheral transistor at the active region.
According to still another aspect of the inventive concept, there is provided a variable resistance memory device comprising: a substrate having a cell array region and a peripheral circuit region, selecting devices in the form of diodes, Metal Oxide Semiconductor (MOS) transistors, or bipolar transistors on the cell array region, first conductive lines extending below the selecting devices and electrically connected to the selecting devices, variable resistance memory elements on the selecting devices, and a peripheral transistor on the peripheral circuit region, wherein the peripheral transistor comprises an epitaxial pattern of semiconductor material on the peripheral circuit region, and the top surface of the epitaxial pattern on the peripheral circuit region is located at a level above the level of the top surfaces of the first conductive lines.
In the drawings:
Various embodiments and examples of embodiments of the inventive concept will be described more fully hereinafter with reference to the accompanying drawings. In the drawings, the sizes and relative sizes and shapes of elements, layers and regions, such as implanted regions, shown in section may be exaggerated for clarity. In particular, the cross-sectional illustrations of the semiconductor devices and intermediate structures fabricated during the course of their manufacture are schematic. Also, like numerals are used to designate like elements throughout the drawings.
Furthermore, spatially relative terms, such as “upper,” and “lower” are used to describe an element's and/or feature's relationship to another element(s) and/or feature(s) as illustrated in the figures. Thus, the spatially relative terms may apply to orientations in use which differ from the orientation depicted in the figures. Obviously, though, all such spatially relative terms refer to the orientation shown in the drawings for ease of description and are not necessarily limiting as embodiments according to the inventive concept can assume orientations different than those illustrated in the drawings when in use. In addition, the terms “top” or “bottom” as used to describe a surface or region generally refer not only to the orientation depicted in the drawings but to the fact that the surface or boundary is the uppermost or bottommost surface or boundary in the orientation depicted, as would be clear from the drawings and context of the written description.
Other terminology used herein for the purpose of describing particular examples or embodiments of the inventive concept is to be taken in context. For example, the terms “comprises” or “comprising” when used in this specification specifies the presence of stated features or processes but does not preclude the presence or additional features or processes. The term “substrate” will generally refer to that portion of the device that is non-active and forms the base of the device and may thus exclude regions that are doped, for example, again as the context makes clear. The term “pattern” will generally refer to an element or feature that has been formed as the result of a patterning process (e.g., an etching or damascene process), i.e., an element or feature formed as the result of the patterning of some particular layer.
A circuit of a memory cell array of a variable resistance memory device according to the inventive concept will now be described with reference to the diagram of
The memory cell array has a plurality of memory cells MC arranged in a matrix. Each memory cell MC includes a variable resistance element 11 and a selecting element 12. The variable resistance element 11 and the selecting element 12 are interposed between a bit line BL and a word line WL.
In an example of this embodiment, the state of the variable resistance element 11 depends on the amount of current supplied through the bit line BL. The selecting element 12 is connected between the variable resistance element 11 and the word line WL to control the current supplied to the variable resistance element 11 based on the voltage of the word line WL. To this end, the selecting element 12 may be a diode, a Metal Oxide Semiconductor (MOS) transistor, or a bipolar transistor.
Also, an example of the variable resistance element 11 that will be used in the following description is a phase change memory device. A phase change memory device is made of phase change material that can be converted between an amorphous state (in which its resistance is relatively high) and a crystalline state (in which its resistance is relatively low) by being heated to a certain temperature or by being allowed to cool for a certain amount of time. The amorphous state may be a SET state and the crystalline state may be a RESET state. In this respect, the phase change memory device also has a lower electrode for heating the phase change material. Specifically, the lower electrode generates Joule's heat according to the amount of current supplied through the lower electrode, to thereby heat the phase change material.
However, the inventive concept is not limited to the use of phase change memory devices as the variable resistance elements 11. Rather, other known types of variable resistance elements may be used instead.
A layout of a cell array that may be adopted by variable resistance memory devices according to the inventive concept will now be described with reference to
Referring to
A first impurity region 110 is formed in the cell array region CR. The conductivity type of the first impurity region 110 is different from that of the substrate 100. In the example of the present embodiment, the first impurity region 110 is formed by forming an ion implantation mask (not shown) on the substrate 100 to cover the peripheral circuit region PR, and then doping the substrate 100 with n-type impurity ions (at a high concentration). However, the first impurity region 110 may be formed in the peripheral circuit region PR. In either case, a thermal treatment may be subsequently performed to cure defects caused by the ion implantation process.
Next, an etch stop layer 121 is provided on the first impurity region 110. The etch stop layer 121 is formed of a material different than that of the substrate 100. For example, the etch stop layer 121 may comprise silicon nitride or silicon oxynitride.
Referring to
At this time, a lower impurity region 131 having a conductivity type different than that of the substrate 100 is formed at the lower part of the first epitaxial semiconductor layer 130. For example, the lower impurity region 131 may be formed as the result of the diffusion of impurity ions from the first impurity region 110 into the lower part of the epitaxial semiconductor layer 130 as the epitaxial semiconductor layer 130 is being formed. Alternatively, the lower impurity region 131 may be formed by an in-situ doping process or an ion implantation process.
Also, at this time, an upper impurity region 132 having the same conductivity type as the substrate 100 may be formed at the upper port of the first epitaxial semiconductor layer 130. Thus, in the example of the present embodiment, the upper impurity region 132 is a p-type impurity region. The upper impurity region 132 may be formed through an ion implantation process or an in-situ doping process.
The first epitaxial semiconductor layer 130 does not form on the etch stop layer 121. Thus, in the illustrated embodiment, a first opening 141 is defined on the etch stop layer 121 as the first epitaxial semiconductor layer 130 grows. In another example of this embodiment, an insulation pattern (not shown) is provided on the etch stop layer 121 before the epitaxial semiconductor layer 130 is formed (in which case no opening in the first epitaxial semiconductor layer is formed on the etch stop layer 121).
The second epitaxial semiconductor layer 133 may be formed by epitaxially growing a layer of material on the peripheral circuit region PR, and implanting impurity ions into the upper part only of the expitaxially grown layer (i.e., while leaving the lower part of the epitaxially grown layer as it is).
In any case, the conductivity type of the second epitaxial semiconductor layer 133 depends on the type of transistors to be provided for the finalized device. For example, in the case in which a Complementary Metal Oxide Semiconductor (CMOS) transistor is provided in the peripheral circuit region PR, the second epitaxial semiconductor layer 133 may be used as an active region of an NMOS transistor and/or a PMOS transistor. Therefore, the second epitaxial semiconductor layer 133 may be of the same or different conductivity type as the substrate 100. In this example, as applied to the present embodiment, the second epitaxial semiconductor layer 133 has a p-type of conductivity.
Referring to
Also, first trenches 142 are formed in the cell array region CR and second trenches 143 are formed in the peripheral circuit region PR by patterning the first and second epitaxial semiconductor layers 130 and 133. For example, the first and second epitaxial semiconductor layers 130 and 133 are dry etched to form the trenches 142 and 143. In this respect, the first and second trenches 142 and 143 may be formed simultaneously, i.e., by the same etching process. Depending on the depths of the trenches and the characteristics of the etching process, the trenches may have inclined sides as shown in the figures. However, the first trenches 142 and the second trenches 143 may have shapes different from those shown in the drawings.
Moreover, the trenches 142 and 143 are formed so as to be elongated, i.e., so as to extend longitudinally, in a first direction (the Y-direction in
The first trenches 142 are formed at least to the level of the substrate such that the first impurity region 110 is divided into first conductive lines 111. The first conductive lines 111 may be word lines in the finalized device. In any case, the first conductive lines 111 thus extend in the Y-direction and are spaced from each other in a second direction orthogonal to the first direction (the X-direction in
On the other hand, the second trenches 143 extend through the second epitaxial semiconductor layer 133 and into the substrate 100. Thus, the second trenches 143 define an active region in the second epitaxial semiconductor layer 133.
Next, the first trenches 142 are filled with a first insulating layer 124 and the second trenches 143 are filled with second insulating layer 125. The first and second insulating layers 124 and 125 may be formed simultaneously. In this respect, these features may be formed by a Shallow Trench Isolation (STI) technique. For example, insulating material (not shown), such as silicon oxide, may be deposited on the substrate 100 to such a thickness as to overfill the first and second trenches 142 and 143, and then the resulting layer of insulating material may be planarized until the epitaxial semiconductor layers 130 and 133 are exposed. In this example, the deposition process is preferably a high-density plasma chemical vapor deposition process having an excellent gap-fill characteristic.
Referring to
The peripheral transistor PT includes a gate insulation layer 152 contacting the second epitaxial semiconductor layer 133, a gate electrode 151 on the gate insulation layer 152, and a source/drain region 154 adjacent to the gate electrode 151. A spacer 153 may be formed on sidewalls of the gate electrode 151. The gate insulation layer 152 is a thermal oxide layer, for example. The gate electrode 151 comprises conductive material such as a doped semiconductor, a metal, or a conductive metal nitride. The spacer 153 may include at least one of a silicon oxide layer, a silicon nitride layer, and a silicon oxynitride layer.
The source/drain region 154 may be formed in the second epitaxial semiconductor layer 133. Preferably, the bottom F2 of the source/drain region 154 is disposed at a level higher than that of the top surface F1 of the first conductive lines 111. If the peripheral transistor PT is an NMOS, the source/drain region 154 is an n-type impurity region formed in the second epitaxial semiconductor layer 133.
Referring to
The first mask layer 127 is removed. Third trenches 144 are then formed by patterning (etching) the first epitaxial semiconductor layer 130. The third trenches 144 are elongated in a second direction (the X-direction in
As another result, a two-dimensional array of diodes D is formed on the cell array region CR. That is, columns of the diodes D in the X-direction and rows of the diodes D in the Y-direction are formed. In this embodiment, the top surfaces of the diodes D are substantially coplanar with the top surface of the second epitaxial semiconductor layer 133.
Furthermore, upper portions of the first conductive lines 111 are etched by the process of forming the third trenches 144. That is, the first conductive lines 111 are not divided in the Y-direction by the process of patterning the first epitaxial semiconductor layer 130.
Referring to
Referring to
The variable resistance patterns 181 may be formed by first forming, on the substrate 100, a patterned third interlayer insulation layer 164 having openings that expose the lower electrode patterns 172. The third interlayer insulation layer 164 may comprise silicon oxide or silicon oxynitride. Then the openings in the patterned third interlayer insulation layer 164 are filled with a layer of phase change material. In this example, the phase change material is a layer of material comprising at least one of chalcogenide-based elements such as Te and Se, and a compound including at least one of Ge, Sb, Bi, Pb, Sn, Ag, As, S, Si, P, O, and C.
Next, second conductive lines 116 are formed on the variable resistance patterns 181, respectively. In particular, the second conductive lines 116 are formed so as to extend longitudinally in a direction that crosses the first conductive lines 111 and so as to be electrically connected to the diodes D via the variable resistance patterns 181 and lower electrode structures. For example, a patterned fourth interlayer insulation layer 165 comprising silicon oxide or silicon oxynitride, for example, is formed on the substrate 100. Then openings in the patterned fourth interlayer insulation layer 165 are filled with at least one of a transition metal, a conductive transition metal nitride, and a conductive ternary nitride to form the second conductive lines 116. The second conductive lines 116 may serve as bit lines in the finalized device. Also note, an upper electrode (not shown) may be provided between the second conductive lines 116 and the variable resistance pattern 181. The third and fourth interlayer insulation layers 164 and 165 may include a silicon oxide or a silicon oxynitride.
In addition, a contact plug CP is formed as electrically connected to each first conductive line 111. More specifically, a contact hole 145 is formed through the first insulation layer 123 and the second to fourth interlayer insulation layers 162, 164, and 165, and through the etch stop layer 121 to expose the conductive line 111. Then the contact hole 145 is filled with conductive material such as a doped semiconductor, a metal, or a conductive metal nitride.
As shown in
Furthermore, components of the peripheral transistor PT are formed after the high temperature epitaxial process for forming the diodes D is performed. Therefore, the characteristics of the peripheral transistor PT are not degraded by the process of forming the diodes D.
Accordingly, the peripheral transistor PT has improved electrical characteristics.
Still further, the second epitaxial semiconductor layer 133 may be formed together with the diodes D of the cell array region CR. That is, the second epitaxial semiconductor layer 133 may be formed by the same epitaxial process used to form the diodes D. Additionally, the second insulating layer 125 for defining an active region on the second epitaxial semiconductor layer 133 and the first insulating layer 124 for forming the diodes D can be formed simultaneously. Therefore, the process of manufacturing a variable resistance memory device according to the inventive concept is relatively simple.
A second embodiment of a variable resistance memory device and a method of manufacturing the same according to the inventive concept will now be described with reference to
Referring to
An interlayer insulation layer 166 including a two-dimensional array of second openings 146 is formed on the resulting structure by deposition and etching, e.g., dry-etching, processes. The second openings 146 expose the first conductive lines 111. Upper portions of the first conductive lines 111 may be etched during the forming of the second openings 146. Depending on the depths of the second openings 146 and the characteristics of the etching process used to form the second openings 146, the second openings 146 may have inclined sides as shown in the figure.
Furthermore, in this process, the first conductive lines 111 and the interlayer insulation layer 166 are not formed on the peripheral circuit region PR. In this respect, a mask (not shown) may be formed on the peripheral circuit region PR before the first conductive lines 111 and the fifth interlayer insulation layer 166 are formed.
Referring to
The diodes D are formed by forming a first lower impurity region 136 and a first upper impurity region 135 of different conductivity types in the second openings 146, with the first lower impurity region 136 having a different type of conductivity than the substrate 100 and the first upper impurity region 135 having the same type of conductivity as the substrate 100. The first upper and lower impurity regions 135 and 136 may be formed using an ion implantation process or an in-situ doping process.
The ion implantation process or in-situ doping process for forming the first upper and lower impurity regions 135 and 136 may be simultaneously performed on the peripheral circuit region PR. For example, p-type impurities may be simultaneously implanted into an epitaxial layer on the cell array region CR and the peripheral circuit region PR to form upper impurity region 135 and second upper impurity region 138.
The first lower impurity region 136 and a second lower impurity region 139 in the second epitaxial semiconductor layer 133 may also be formed simultaneously such that the second lower impurity region 139 has the same type of conductivity as the first lower impurity region 136. Alternatively, the lower part of the second epitaxial semiconductor layer 133 may be left as is, i.e., in its intrinsic epitaxial state.
Referring to
A peripheral transistor PT is then formed in the peripheral circuit region PR. The peripheral transistor PT includes a gate insulation layer 152 contacting the second epitaxial semiconductor layer 133, a gate electrode 151 on the gate insulation layer 152, and a source/drain region 154 adjacent to the gate electrode 151. A spacer 153 may be formed on sidewalls of the gate electrode 151. The source/drain region 154 is formed in the second epitaxial semiconductor layer 133. For example, if the peripheral transistor PT is an NMOS, an n-type impurity region is formed in the second epitaxial semiconductor layer 133 as the source/drain region 154. Then an interlayer insulation layer 128 is formed on the peripheral circuit region PR over the peripheral transistor PT.
Next, upper portions of the diodes D are removed to expose upper parts of the inner surfaces of the interlayer insulating layer 166 which delimit the sides of the second openings 146. The upper portions of the diodes D may be removed through a selective etching process. Accordingly, the top surface of the second epitaxial semiconductor layer 133 may become located at a level above that of the top surfaces of the diodes D.
Referring to
Referring to
Next, a third interlayer insulation layer 164 exposing the lower electrode structures and the third insulation layer patterns 167 is formed on the substrate 100 in the cell array region CR. Then variable resistance patterns 181 are formed in the third interlayer insulation layer 164. The variable resistance patterns 181 are elongated in the X-direction. The variable resistance patterns 181 may be of phase change material. In this respect, refer to the descriptions above.
In this embodiment, the variable resistance patterns 181 are prevented from contacting the entirety of the lower electrode patterns 172 by the third insulation layer patterns 167. That is, the contact area between each lower electrode pattern 172 and the overlying variable resistance pattern 181 is in effect reduced by a third insulation layer pattern 167. Accordingly, a reset current Ireset is in effect reduced.
Next, second conductive lines 116 are formed on the variable resistance patterns 181 in a manner similar to that shown in and described with reference to
In addition, a contact plug CP is formed as electrically connected to each first conductive line 111. More specifically, a contact hole 145 is formed through the interlayer insulation layers 166, 167, 164 and 165 to expose the conductive line 111. Then the contact hole 145 is filled with conductive material such as a doped semiconductor, a metal, or a conductive metal nitride.
In this embodiment as well, as shown in
And like the previously described embodiment, the second epitaxial semiconductor layer 133 may be formed together with the diodes D of the cell array region CR. That is, the second epitaxial semiconductor layer 133 may be formed by the same epitaxial process used to form the diodes D. Therefore, this embodiment of a method of manufacturing a variable resistance memory device is also relatively simple.
A memory system that employs a variable resistance memory device according to the inventive concept will now be described with reference to
Referring to
The semiconductor memory device 1300 includes a variable resistance memory device 1100 according to the inventive concept (i.e., of any of the types described above) and a memory controller 1200. The variable resistance memory device 1100 stores data provided through the user interface 1600 or data processed by the CPU 1400, as dictated by the memory controller 1200. The variable resistance memory device 1100 may be embodied as a solid state drive (SSD) so as to have a characteristically high write speed.
Additionally, the memory system 1000 may be employed as the memory system of a Personal Digital Assistant (PDA), a portable computer, a web tablet, a wireless phone, a mobile phone, a digital music player, a memory card, or any other known device for transmitting and receiving information in a wireless environment.
Furthermore, a variable resistance memory device or a memory system according to the inventive concept may be packaged in various ways. For example, the variable resistance memory device or memory system may be assembled as part of a Package on Package (PoP), Ball Grid Array (BGA) package, Chip Scale Package (CSP), Plastic Leaded Chip Carrier (PLCC), Plastic Dual In-Line Package (PDIP), Die in Waffle Pack, Die in Wafer Form, Chip On Board (COB) package, Ceramic Dual In-Line Package (CERDIP), Plastic Metric Quad Flat Pack (MQFP), Thin Quad Flat Pack (TQFP), Small Outline Integrated Circuit (SOIC) package, Shrink Small Outline Package (SSOP), Thin Small Outline Package (TSOP), System In Package (SIP), Multi-Chip Package (MCP), Wafer-level Fabricated Package (WFP), or Wafer-level Processed Stack Package (WSP).
Finally, embodiments of the inventive concept and examples thereof have been described above in detail. The inventive concept may, however, be embodied in many different forms and should not be construed as being limited to the embodiments described above. Rather, these embodiments were described so that this disclosure is thorough and complete, and fully conveys the inventive concept to those skilled in the art. Thus, the true spirit and scope of the inventive concept is not limited by the embodiment and examples described above but by the following claims.
Number | Date | Country | Kind |
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10-2011-0016637 | Feb 2011 | KR | national |