The present application claims the benefit under 35 U.S.C. §119 of German Patent Application No. DE 102012201976.6 filed on Feb. 10, 2012, which is expressly incorporated herein by reference in its entirety.
The present invention relates to a method for manufacturing a component having a through-connection.
BACKGROUND INFORMATION
Electrically conductive structures which extend through a substrate are becoming more and more important. Such structures which are also referred to as through-connections or vias (vertical interconnect access) make it possible to manufacture space-saving components. This advantage is, for example, used for the development of ever smaller components (MEMS, micro-electro-mechanical systems). One concept applied in this regard and referred to as “MEMS 3D integration” is related to stacking individual components or chips (in particular a sensor, a sensor cap, and an evaluation circuit) to form a so-called package, vertical electrical connections being implemented with the aid of through-connections. It is usually strived for that the through-connections are designed to have a relatively high mechanical stability and a relatively low electrical resistance.
Such properties apply to metallic through-connections which may be manufactured by metal coating recesses or holes of a substrate. For the metallic filling, processes such as a chemical vapor deposition (CVD) or an electroplating process are typically carried out. These conventional metal coating processes are, however, associated with a relatively high complexity and relatively high costs and require the use of expensive processing equipment. Moreover, other layers (e.g., a diffusion barrier layer and a starting layer or seed layer in the case of an electroplating process) are implemented in addition to the actual metal coating process.
An object of the present invention is to provide an improved approach to the manufacture of a component having a metallic through-connection.
According to an example embodiment of the present invention, a method is provided for manufacturing a component having a through-connection. The example method includes providing a semiconductor substrate, forming a recess in the semiconductor substrate, and introducing into the recess a pourable starting material which has a metal. The method furthermore includes carrying out a heating process, an electrically conductive structure forming the through-connection being developed from the pourable starting material.
The example method enables a simple and cost-effective manufacture of the through-connection which extends (at least partially) through the semiconductor substrate. This is, in particular, due to the use of the pourable metallic starting or filling material which may be introduced into the recess in a relatively easy manner, solidified through heating, and thereby “converted” into the electrically conductive structure. Compared to conventional metal coating processes, such as CVD or electroplating processes, the metal coating may be carried out in this way with less complexity and using more cost-effective processing equipment. The formation of additional diffusion barrier layers and starting layers may be dispensed with, thus allowing for a space-saving geometry of the through-connection. Moreover, the metal plating may be carried out locally in contrast to CVD or electroplating processes.
In one preferred specific embodiment, the semiconductor substrate is a silicon substrate. In particular in such an embodiment, the component to be manufactured may, for example, be a micromechanical component or a sensor chip, e.g., an inertial sensor. Alternatively, the component may be an integrated circuit (IC), for example, or a semiconductor chip. In this case, it is also possible that the provided semiconductor substrate is formed before the through-connection is formed and already has the appropriate micromechanical and/or electrical or electronic structures.
In another preferred specific embodiment, the pourable starting material has metallic particles. In this way, it is possible to reliably transfer the pourable starting material into the electrically conductive through-connection structure by heating. Within the scope of the heating process, the metallic particles may be connected to one another or sintered to form a solidified structure. For this purpose, metallic particles having a size in the nanometer range (“nanoparticles”) are preferably used. As the material for the particles, a metal such as silver, but also another metal such as copper, may be considered.
In another preferred specific embodiment, the pourable starting material is an ink. In this way, it is possible to carry out the heating process for forming the electrically conductive structure at a relatively low temperature. The ink may be in the form of a liquid in which the metal may be present in particular in the form of the previously described particles or nanoparticles (“nanoparticle ink”). As the liquid integral part, the ink may include one or multiple organic solvent(s). In this case, the heating process leads to an evaporation of the liquid portion in addition to the above-named sintering of the metal particles, thus resulting in a drying of the ink.
In one alternative preferred specific embodiment, the pourable starting material is a paste. The paste may have a viscous integral part in which the metal may (also) be present in particular in the form of the above-described particles or nanoparticles. The viscous integral part may include one or multiple organic solvent(s) as well as one or multiple other components (e.g., plastics or polymers). In this case, the heating process may cause a curing of the paste or the viscous integral part of the paste, associated with the solvent(s) being expelled, in addition to the above-described sintering of the metal particles.
With the aid of the example method, it is possible for not just a single through-connection, but for multiple or a plurality of through-connections to be formed generally simultaneously or in parallel in the semiconductor substrate. For this purpose, multiple recesses are accordingly formed in the substrate into which the pourable starting material is introduced and which are converted into through-connections by heating.
In the course of the introduction of the pourable starting material into the recess, it is also possible to provide a part of an outside of the semiconductor substrate with the pourable starting material. In this way, it is possible to simultaneously manufacture the through-connection, produced by heating, and a connecting structure present at the substrate side. In this case, it may also be provided that the connecting structure is formed as a rewiring or a printed conductor structure which may be implemented by applying the pourable starting material to the semiconductor substrate having an appropriate structure.
The pourable starting material may be applied to the semiconductor substrate and thus introduced into the recess in various ways. For example, it may be considered that the pourable starting material is applied to or dispensed on the semiconductor substrate using an appropriate metering device which may be positioned in the area of the recess.
In another preferred specific embodiment, it is provided that the pourable starting material is introduced into the recess (or applied to the semiconductor substrate) with the aid of a printing process. In this way, it is possible to provide the recess locally (or also multiple recesses as well as an outside of the substrate) with the pourable starting material in a cost-effective and targeted manner, thereby metal-coating it. Printing processes, which may be considered, are, for example, an inkjet printing process or a screen printing process.
In another preferred specific embodiment, an insulating layer is formed in the recess. Due to the insulating layer, the electrically conductive structure which is (subsequently) produced from the pourable starting material may be insulated from the surrounding semiconductor substrate or substrate material. The insulating layer may not only be formed within the recess, but also outside the recess or at an outside of the semiconductor substrate in order to be able to also insulate a connecting structure of the through-connection situated here.
In the example method, the wetting behavior of the pourable starting material is used to be able to wet and thereby to metal-coat certain areas in a targeted manner using the starting material. To reliably delimit the areas to be wetted, it is provided in another preferred specific embodiment for a non-adhesive layer to be formed on the semiconductor substrate before the pourable starting material is introduced into the recess. Due to the non-adhesive layer, which may be designed to have an appropriate structure, the areas to be wetted (i.e., the recess, but also the areas on an outside of the substrate for a connecting structure, for example) may be predefined. In this way, it is possible for a quantity of the pourable starting material suitable for the metal coating to be situated in these areas.
In another preferred specific embodiment, the recess into which the pourable starting material is introduced is formed as a through hole in the semiconductor substrate. It is thus possible to introduce the pourable starting material into the recess by using vacuum, e.g., by using a vacuum table. In this way, it is possible to reliably fill or wet the recess using the pourable starting material.
In one alternative preferred specific embodiment, the recess into which the pourable starting material is introduced is formed as a blind hole in the semiconductor substrate. Such a recess is accessible only from one substrate side. Furthermore, after carrying out the heating process, a thinning of the semiconductor substrate on an (opposing) substrate side is carried out to expose here the electrically conductive structure which was produced by heating from the pourable starting material.
In another preferred specific embodiment, the method also includes forming a contact structure which is connected to the electrically conductive structure. The contact structure which may, for example, be produced on the semiconductor substrate after the manufacture of the through-connection may be formed by carrying out comparable steps, i.e., applying a pourable metallic starting material (e.g., metallic particles added to an ink or a paste) and heating. For applying the pourable starting material, here too, a cost-effective printing process may be used. The contact structure may be provided on a substrate side which is opposed to the substrate side on which a connecting structure is situated which has been produced, if needed, at the same time as the through-connection. For the contact structure, an embodiment in the form of a rewiring or printed conductor structure may (also) be considered.
The contact structure may also be a buried structure, in particular a buried printed conductor structure, which may be formed within the scope of providing the semiconductor substrate and thus prior to manufacturing the through-connection. The buried contact structure may be embedded into an insulation or an insulating layer. Furthermore, the buried contact structure may be situated in the area of a first substrate side, and the through-connection may extend from an opposing second substrate side to the contact structure. Within the scope of the through-connection manufacture, it may be provided that the recess (starting from the second substrate side) is designed to reach the insulation of the buried contact structure, one part of the insulation being exposed. Furthermore, an (additional) insulating layer may be formed in the recess. Before introducing the pourable starting material into the recess, the insulating layer and the insulation of the buried contact structure may be opened in a bottom area of the recess. In this way, the buried contact structure may be exposed or opened in this area, thus allowing the pourable starting material to be (also) applied to the contact structure.
The advantageous embodiments and refinements of the present invention described above—except for the cases of unambiguous contingencies or incompatible alternatives, for example—may be used alone or also in any combination with each other.
The present invention is explained below in greater detail with reference to the figures.
Based on the following figures, specific embodiments of a simple and cost-effective method for manufacturing a component having a metallic through-connection 155 are described. Through-connection 155 produced according to the example method distinguishes itself by a space-saving geometry, a high mechanical stability, and a low electrical volume resistance. During the manufacturing process, processes, e.g., CMOS (complementary metal oxide semiconductor) processes and MEMS processes, which are customary in the semiconductor or microsystem technology, may be carried out, and customary materials may be used, so this will be discussed only partially. It is also pointed out that in addition to the illustrated and described method steps and processes, other method steps may be carried out to complete the manufacture of the shown components.
In the method, a semiconductor substrate 105 is provided in a step 201 (cf.
In a subsequent step 202 (cf.
After mask layer 110 is formed, a trench etching process is carried out, whereby a recess 120 is formed in substrate 105 in the form of a blind hole as shown in
In the context of step 202, a continuous insulating layer 130 is also formed, as shown in
Subsequently, a thinning of substrate 105 takes place, as shown in
Following the formation of “insulated” recess 121, a non-adhesive layer 140 is formed outside of recess 121 on substrate 105 or on its insulating layer 130 in a subsequent step 203 (cf.
In another step 204 (cf.
Pourable starting material 150, which will be explained in the following in greater detail, has such a viscosity and such filling and wetting properties that it is possible to (generally) entirely wet the side walls of recess 121 and to fill recess 121 without cavities or voids. It may thus be ensured that boundary conditions with regard to the electrical resistance and the mechanical stability of later through-connection 155 may be met, but also with regard to the ability to further process substrate 105.
As pourable starting material 150, a conductive ink may, for example, be used which may include the metal provided for metal-coating in the form of metal particles, in particular having a size in the nanometer range. The particles or nanoparticles may, for example, be formed from silver or also another metal, e.g., copper (“nano-silver ink,” “nano-copper ink”). As the liquid integral part or carrier, the ink may include one or multiple organic solvent(s). These are preferably easily expellable solvents.
Alternatively, pourable starting material 150 may also be provided in the form of a conductive paste in which the metal used for metal coating may also be included in the form of metal particles, in particular having a size in the nanometer range. As the metal, silver, or any other metal, e.g., copper, may again be considered (“nano-silver paste,” “nano-copper paste”). In addition to metallic particles, the paste has a viscous integral part which may include one or multiple (in particular easily expellable) organic solvents as well as one or multiple other components (e.g., plastics or polymers).
Pourable metallic starting material 150 may be applied in various ways. For example, a suitable metering device may be positioned in the area of recess 121 to dispense starting material 150 in this area. Furthermore, a printing process may also be carried out, whereby it is possible to apply starting material 150 locally onto substrate 105 (or its insulating layer 130) in a cost-effective and targeted manner and to thereby fill recess 121. When using ink as starting material 150, an inkjet process may be carried out, in particular. When using paste as starting material 150, a screen printing process may be carried out, however.
The design of through hole 121 furthermore offers the option of assisting the reliable filling of through hole 121 with starting material 150 applied in the area of substrate front side 107 by providing a vacuum in the area of back side 108, thus resulting in starting material 150 being sucked through or into through hole 121. For this purpose, substrate 105 may, for example, be situated on a vacuum table.
In another step 205 (cf.
In one embodiment of pourable starting material 150 as an ink, the heating process results, in addition to the sintering of the metal particles, in the liquid portion being vaporized or the solvent(s) being expelled, and thus in a drying of the ink. The use of ink makes it possible to carry out the heating process at a relatively low temperature, e.g., in a temperature range between 100° C. and 400° C. In this way, it is possible to achieve a high compatibility of the method applied (if necessary) as the “via-last process” with CMOS and/or MEMS manufacturing steps carried out previously. A low heating temperature may, in particular, be present when easily expellable solvents are used. The heating of the ink may be associated with such a volume reduction that section 151 of metal-coated through-connection 155 no longer fills recess 121 completely, but is present in the form of a side wall coating of recess 121. The side wall coating may enclose a cavity and transition into section 152 at the front-side rim of recess 121 (not illustrated).
With regard to the use of a paste as pourable starting material 150, the heating process is carried out at a higher temperature, e.g., up to 800° C. Due to the heating, a curing of the paste or the viscous paste portion, associated with the solvent(s) being expelled, is caused in addition to the sintering of the metal particles. Since a paste, in contrast to an ink, may be subject to volume expansion during heating, the used paste preferably has a thermal expansion coefficient which is adapted to the substrate material (silicon) so that mechanical stress may be prevented from occurring. In through-connection 155 produced by curing of the paste, section 151 may (continue to) fill out recess 121 completely.
Instead of applying pourable starting material 150 (step 204) and heating starting material 150 to “convert” it into through-connection 155 (step 205) consecutively, these steps 204, 205 may also be carried out (generally) simultaneously. Such a procedure may, in particular, be considered for the above-described use of vacuum when applying starting material 150 to bring about a drying or curing of starting material 150 while it is sucked through recess 121.
With regard to outside section 152 of through-connection 155, which may be used as a connecting structure, it may be considered that this section 152 is present in the form of a rewiring or printed conductor structure or that it transitions into such a structure. This may be implemented by applying pourable starting material 150 onto substrate 105 (or its insulating layer 130) having a corresponding shape. Non-adhesive layer 140 is (previously) formed accordingly having a structure corresponding thereto.
In another step 206 (cf.
Moreover, another connecting structure, which is referred to in the following as contact structure 160 and which is in contact with through-connection 155, is formed in the area of back side 108 of substrate 105. Contact structure 160 may be designed in the form of a rewiring or printed conductor structure as (other) connecting structure 152. To form contact structure 160, another insulating layer 131 (for example, silicon oxide) is initially applied on substrate back side 108, and an opening 132 is formed in insulating layer 131 in the area of through-connection 155. The subsequent production of contact structure 160, which is formed on insulating layer 131 and on through-connection 155 open in the area of substrate back side 108, may take place comparably to through-connection 155, i.e., by applying a pourable metallic starting material (e.g., metallic particles added to an ink or a paste) and heating. For applying the pourable starting material, here too, a cost-effective printing process may be used. The use of a non-adhesive layer for establishing the wetting areas may also be provided.
In the context of step 206, other processes may furthermore be carried out, such as a passivation of the front and/or back side of substrate 105. This may, for example, take place by applying a suitable oxide or nitride material. In
It is possible to produce multiple components 100 in parallel from or on substrate 105. Another process which may be carried out in the context of step 206 is therefore a separation process to separate component 100 from other components 100. In this regard, it is pointed out that with the aid of the method, a plurality of through-connections 155 may be formed essentially simultaneously or in parallel in substrate 105 by carrying out the above-described method steps, i.e., multiple insulated recesses 121 may be produced accordingly in substrate 105 and multiple through-connections 155 may be manufactured by applying starting material 150 (in particular with the aid of a printing process) and by heating same.
The method may be modified in such a way that recess 120 is not manufactured with the aid of the above-described trench etching process. Instead, a laser may be used to accordingly remove substrate material up to a certain depth starting from substrate front side 107. In such a process, which is referred to as “laser drilling,” the use of mask layer 110 may be dispensed with. The consequence thereof is that subsequently formed insulating layer 130 is also situated outside of recesses 120 and 121 directly on actual substrate 105 or on its front side 107 (not illustrated).
In another variant, a blind hole 120, which may be subsequently “ground open,” is (initially) metal-coated instead of metal-coating a through hole 121. A method carried out in this regard for manufacturing a component 100 having a through-connection 155 is described in the following with reference to
In the method, a semiconductor substrate 105, in particular a wafer made of silicon, is provided again in a step 201 (cf.
In a subsequent step 202 (cf.
After the formation of “insulated” recess 120, a non-adhesive layer 140, which is used as the wetting protection, is formed outside of recess 120 on substrate 105 or on its insulating layer 130 in another step 203 (cf.
In another step 204 (cf.
In a subsequent step 205 (cf.
In another step 207 (cf.
In another step 206 (cf.
With the aid of the method described with reference to
The manufacture of through-connection 155 according to the above-described approaches may be used, in particular, within the scope of the manufacture of a micromechanical component. A possible specific embodiment of such a component 100 is schematically shown in
In component 100 of
Substrate 105 of component 100 of
Another possible modification of the metal coating processes described with reference to
In the method, a substrate 105 is provided in a step 201 (cf.
In a subsequent step 202 (cf.
In the context of step 202, an opening 169 is furthermore formed in insulating layers 130, 163 in the bottom area of recess 120, thus exposing contact structure 161, as shown in
Subsequently, the others of the above-described processes may be carried out, i.e., forming a non-adhesive layer used as wetting protection outside of recess 120 on insulating layer 130 (step 203, not illustrated here), and applying a pourable metallic starting material 150 on substrate 105 (step 204); a wetting may take place in a section 151 within recess 120 and in a front-side section 152 outside of recess 120, as shown in
In a subsequent step 205 (cf.
To complete component 100 shown in
With the aid of the method described with reference to
The specific embodiments explained with reference to the figures represent preferred or exemplary specific embodiments of the present invention. Instead of the described specific embodiments, other specific embodiments are possible which may include other modifications or combinations of the described features. For example, the above-named materials may be replaced by other materials. Also, it is possible to use other substrates which include a different material or semiconductor material than silicon. Moreover, different processes may be carried out than the ones described and/or additional elements and structures may be formed.
It is also possible to jointly carry out the processes for manufacturing a through-connection 155 and for manufacturing other structures, as described with reference to
It is furthermore possible to apply a pourable starting material 150 in another way, e.g., over a wide area of a substrate 105, a wetting being “controlled” again with the aid of an appropriately formed non-adhesive layer 140. For example, a centrifugation process with a rotating substrate 105 may be carried out. Another possible method is spray deposition of pourable starting material 150 onto substrate 105.
With regard to the method described with reference to
It may also be considered to carry out processes in another sequence, if necessary. For example, the process sequence of
In addition to that, it is pointed out that, when component 100 or functional substrate 105 shown in
Number | Date | Country | Kind |
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10 2012 201 976.6 | Feb 2012 | DE | national |