The present invention relates to plasma treatment of containers, and more specifically, to a gas lance of a container coating device for introducing a coating material on an inner wall of the containers.
There is an increasing trend at the present time for containers, such as, for example, PET bottles, to be coated on the interior, for example with a thin SiOx layer. This internal coating is carried out in a coating device, which comprises a vacuum chamber to receive the container. The device further contains a plasma generator, such as a microwave generator, and a gas lance with an outlet opening protruding into the container for introducing a material to be deposited on the inner wall of the container. For example, a process gas, such as siloxane gas, is introduced into the container, which is deposited in the plasma formed by the plasma generator, then in the form of SiOx layers on the inner wall of the container. Such coating devices are known from DE 10 2010 023119 A1 or from EP 1 507 893 B1.
It is now to be taken into account that in the beverage industry sector such a coating device has a substantial throughput. For example, in one day tens of thousands of bottles can be coated and several thousand bottles per hour. One problem with such devices is that the outlet opening of the gas lance becomes clogged relatively quickly due to the coating. This requires frequent cleaning and more frequent replacement of the gas lance. The object of the invention is therefore to provide a coating device with which the expense and effort of maintenance and cleaning is reduced.
This object is solved by a coating device in accordance with claim 1. Advantageous further embodiments of the invention are the object of the dependent claims. Advantageous embodiments of the invention are also presented in the description and the drawings.
According to the invention, the inside diameter of the gas lance in the region of the outlet opening is enlarged relative to the inside diameter of a main section of the gas lance. In this situation, the gas lance has a multiple function, in that it is by way of this gas lance that the introduction of the respective process gases for the coating takes place, and this gas lance further serves as an antenna for the electromagnetic field orientation in the vacuum chamber.
In an alternative embodiment, it is also possible, by means of the gas lance, for at least a part quantity of the gas to be suctioned out of the container and/or out of the vacuum chamber, as well as the relaxing gas, as a rule air, to be introduced. The main section forms the predominant part of the length of the gas lance, preferably more than 50%, and in particular more than 90%, of the length of the gas lance. In this main section, the inside diameter of the gas lance is preferably constant, i.e. a defined value.
According to the invention, the outlet opening is larger in relation to the conventional gas lance, in which up to now the outlet opening was defined solely by the inside diameter of the gas lance. Due to the enlarged outlet opening, the emerging process gas, such as, for example, siloxane, when emerging from the gas lance and entering into the plasma, is substantially less inclined to deposit SiOx layers on the end edge of the gas lance surrounding the outlet opening.
Since the gas lance is located in the spatial area of the coating process, it is subjected to the microwave field in the vacuum chamber. As a result, field elevations or field concentrations form on the outlet side, for example at the cylindrical tube end, which favours a preferred depositing of process products, such as SiOx, and therefore a growth of layers. This coating process leads, after a relatively short time, to a reduction of the outlet opening or of the outlet cross-section, such that the ideal flow relationships of the gas mixture are no longer provided, and the coating values are no longer attained.
The electromagnetic field orientation and field concentration in the widened opening is massively reduced. Added to this is the fact that the tendency of the process gas to form reduced vortices at the outer edge of the gas lance, which are very much fewer than with conventional cylindrical gas lances with constant inside diameters. Due to the fact that the outlet opening is widened, the inclination to the formation of deposits, as in the case of siloxane the formation of SiOx layers, at the end edge of the gas lance surrounding the outlet opening, is substantially less than with previous gas lances. Any deposits which do settle at the end edge, to a lesser degree than formerly, will therefore not lead so quickly to a reduction in the size of the outlet opening. The service interval times for the cleaning of the outlet opening or for replacing the gas lance can therefore be substantially lengthened.
In an advantageous further embodiment of the invention, the gas lance is widened in the shape of a trumpet in the region of the outlet opening. In this way, the inside diameter of the gas lance continually expands in the region of the outlet opening, such that no edge is formed at which vortices could occur. In addition to this, due to the widening of the outlet opening, the end edge is moved out of the direct jet range of the gas blown into the container by the gas lance. Accordingly, the tendency for the depositing of SiOx layers on the outer edge of the gas lance in the region of the outlet opening is very substantially reduced, which results in considerably longer service intervals for the cleaning of the gas lance. In this context, it is essentially not of consequence whether the widening of the inside diameter of the gas lance is also associated with an enlargement of its outer diameter. If this is the case, then the widening of the inside diameter can in any event be applied to an extent which goes beyond the wall thickness of the gas lance (this would be the restriction on the increase in the inside diameter, if the outer diameter of gas lance were to remain constant). The trumpet-shaped widening has the advantage that no edges are present on the inner surface of the gas lance, on which SiOx layers could be deposited.
In an alternative embodiment to this, the gas lance can also be widened in conical form in the region of the outlet opening. Such an embodiment is easier to manufacture, even if it not so favourable in terms of flow technology as a gas lance widened in the shape of a trumpet.
As an alternative or in addition, the inside diameter of the gas lance can be widened in the region of the outlet opening in relation to the inside diameter in a main section of the gas lance, i.e. for example as a widened cylindrical section. In this situation it is not absolutely necessary that the outer diameter of the gas lance be increased, but the larger inside diameter can be achieved, for example, by a reduction in the wall thickness of the gas lance. This can be produced very economically. This embodiment design can in principle also be combined with the trumpet-shaped or conical widening of the gas lance in the region of the outlet opening. In principle, simply a greater inside diameter of the gas lance in the region of the outlet opening in relation to the inside diameter in a main section of the gas lance is already sufficient to reduce the tendency to undesirable depositing at the outlet opening.
When reference is made here to the region of the outlet opening of the gas lance, this relates to the end section of the gas lance, for example the last 5 cm, in particular the last 3 cm, before the outlet opening.
Preferably, in the region of the outlet opening the gas lance consists of a different material than in a main section. In this way, for example, a material can be selected with which the tendency to the formation of deposits in the plasma process will be reduced. Such a material is, for example, a ceramic containing Al2O3.
Preferably, the gas lance consists at least in part of special steel, and/or at least in part of Al2O3. These two materials have proved their worth in the production of gas lances.
Advantageously, the gas lance is multi-part, with a main section, forming the larger axial length of the gas lance, and an axial shorter end section, in which the outlet opening is arranged. In this way, the end section of the gas lance can preferably be held to the main section of the gas lance in the region of the outlet opening in such a way that it can be replaced. In this way, the end section or the tip of the gas lance can be easily replaced when the cleaning of the end section comprising the outlet opening is no longer possible. Accordingly, it is not necessary for the entire gas lance to be replaced, which is economically advantageous. The connection between the main section and the end section is provided, for example, by means of friction or other inherently known detachable connection techniques (screw thread, bayonet fitting, etc.).
Preferably, the gas lance exhibits at the outlet opening an inside diameter which is at least twice as large, in particular three times as large, as the inside diameter in the main section of the gas lance. When reference is made in this Application to a main section of the gas lance, this relates to the axial large part of the gas lance, which preferably exhibits a constant inside diameter. This main section therefore forms the predominant part of the gas lance, which during the coating process intrudes in whole or in part into the bottle.
Preferably, the end section of the gas lance is arranged in a mounting part, which can be mounted onto the main section of the gas lance. In this way, not only is the tendency reduced for the SiOx layers to adhere to the gas lance in the region of the outlet opening, but, in the event of the outlet opening arranged in the mounting part becoming so heavily dirt contaminated that it can no longer be rendered clean, the mounting part with the outlet opening can be easily replaced. In this way, interruptions in the coating process can be reduced to a minimum in terms of time.
Preferably, the mounting part contains a sleeve, which engages around the main section of the gas lance and secures the mounting part on the main section. This securing arrangement can be formed by means of a friction grip, or also by a screw thread or bayonet closure, or other inherently known detachable connection techniques.
Preferably, the inside diameter of the mounting part corresponds, at its end facing towards the main section of the gas lance, to the inside diameter of the main section of the gas lance. In this way, no edge is formed at the connection between the main section and the mounting part of the gas lance which could incur vortices, and therefore lead to an increased depositing of the reaction products from the gas discharge, such as SiOx, on the inside wall or in the region of the outlet opening.
Preferably, the inside wall of the mounting part and the inside wall of the main section of the gas lance are flush with one another at their mutually facing ends. This not only leads to there being no step present at the connection point, but also that the inclination of the wall is even, whereby there is no crease present in the wall which in turn could lead to vortices in the gas being introduced. The inside diameter of the inside wall of the main section therefore merges smoothly into the inside wall of the mounting part, without any step, edge, or crease, the inside diameter of the mounting part being widened in the region of the outlet opening in relation to the inside diameter of the main section of the gas lance.
Preferably, the coating device is configured as a mass coating system with a coating capacity of at least 1,000 containers per hour, and in particular at least 10,000 containers per hour. The coating device contains not only the vacuum chamber, the receivers for the containers, in particular PET bottles, but also the entire movement mechanisms and robots, which arrange the bottles in the vacuum chamber above the gas lance. It is of course also possible in this arrangement for the gas lance to be moved axially into the container. The coating device is designed in particular for the SiOx coating of PET bottles, but can also be used for coating with other materials, for example for sterilising or hygiene treatment or fungicidal treatment, etc.
In an advantageous further embodiment of the invention, the end edge of the gas lance surrounding the outlet opening is rounded. This leads to a reduced inclination of the depositing of SiOx layers at this end edge, and therefore to a reduced inclination of the clogging of the outlet opening due to deposited SiOx layers. This in turn lengthens the service intervals, and therefore makes possible longer uninterrupted work cycles.
Preferably, the end edge of the gas lance surrounding the outlet opening is seamed outwards around the edges, which in turn reduces the tendency to the depositing of SiOx layers.
It is obvious to the person skilled in the art that the embodiment forms described heretofore can be combined with one another. In a mass coating device it is of course possible for a large number of vacuum chambers and a large number of gas lances to be arranged, in order, batch by batch or continuously, for a large number of containers, in particular PET bottles, to be coated simultaneously.
As a rule, in the coating device the gas lance is inserted from below, perpendicularly upwards into the container, in particular the PET bottle. Any other alignment of the gas lance in the vacuum chamber is, however, also possible. It is also possible for the gas lance to be held stationary during the coating process, or, during the coating process, to be moved into the container or out of the container.
Preferably, the inside diameter is constant in the main section of the gas lance.
The invention is described hereinafter by way of examples and on the basis of the schematic drawings in which:
Connected here, downstream, is usually a filling machine, not represented, or a device for decoration, such as a labelling machine or a printing machine.
The end section 24 of the gas lance 20 in
A further alternative embodiment of the gas lance 20 is represented in
As an alternative or in addition, the sleeve 34 can also engage around the inner wall of the tubular main section 22. Here, it would then be possible for the wall thickness of the main section to be reduced on the inner side, such that, due to the rear engagement of the tube of the gas lance 20 by the sleeve 34, the inside diameter of the gas lance 20 is not reduced, and, additionally, no step is formed at which vortices could occur of the coating gas, in particular process gas, such as siloxane gas.
Finally,
It is obvious that the embodiments described heretofore do not restrict the basic principle of the invention. This can be varied within the framework of the following claims.
For example, the idea of the widened diameter of the end section 24 of the gas lance 20 in relation to the main section 22 (
Number | Date | Country | Kind |
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10 2017 108 992.6 | Apr 2017 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2018/060648 | 4/26/2018 | WO | 00 |