Lid assembly for a processing system to facilitate sequential deposition techniques

Information

  • Patent Grant
  • 10280509
  • Patent Number
    10,280,509
  • Date Filed
    Tuesday, March 7, 2017
    7 years ago
  • Date Issued
    Tuesday, May 7, 2019
    5 years ago
Abstract
Embodiments of the disclosure generally relate to apparatuses for processing substrates. In one embodiment, a substrate processing system is provided and includes a lid having an upper lid surface opposed to a lower lid surface, a plurality of gas inlet passages extending from the upper lid surface to the lower lid surface, a gas manifold disposed on the lid, at least one valve coupled with the gas manifold and configured to control a gas flow through one of the gas inlet passages, wherein the at least one valve is configured to provide an open and close cycle having a time period of less than about 1 second during a gas delivery cycle for enabling an atomic layer deposition process. The substrate processing system further contains a gas reservoir fluidly connected between the gas manifold and at least one precursor source.
Description
BACKGROUND OF THE DISCLOSURE

Field of the Disclosure


This disclosure relates to semiconductor processing. More particularly, this disclosure relates to a processing system and method of distributing fluid therein to facilitate sequential deposition of films on a substrate.


Description of the Related Art


The semiconductor processing industry continues to strive for larger production yields while increasing the uniformity of layers deposited on substrates having increasingly larger surface areas. These same factors in combination with new materials also provide higher integration of circuits per unit area of the substrate. As circuit integration increases, the need for greater uniformity and process control regarding layer thickness rises. As a result, various technologies have been developed to deposit layers on substrates in a cost-effective manner, while maintaining control over the characteristics of the layer. Chemical vapor deposition (CVD) is a common deposition process employed for depositing layers on a substrate. CVD is a flux-dependent deposition technique that requires precise control of the substrate temperature and precursors introduced into the processing chamber in order to produce a desired layer of uniform thickness. These requirements become more critical as substrate size increases, creating a need for more complexity in chamber design and fluid flow technique to maintain adequate uniformity.


A variant of CVD that demonstrates superior step coverage is a sequential deposition technique known as atomic layer deposition (ALD). ALD has steps of chemisorption that deposit monolayers of reactive precursor molecules on a substrate surface. To that end, a pulse of a first reactive precursor is introduced into a processing chamber to deposit a first monolayer of molecules on a substrate disposed in the processing chamber. A pulse of a second reactive precursor is introduced into the processing chamber to form an additional monolayer of molecules adjacent to the first monolayer of molecules. In this manner, a layer is formed on a substrate by alternating pulses of an appropriate reactive precursor into a deposition chamber. Each injection of a reactive precursor is separated by an inert fluid purge to provide a new atomic layer additive to previous deposited layers to form a uniform layer on the substrate. The cycle is repeated to form the layer to a desired thickness. The control over the relatively small volume of gas utilized in each pulse is problematic. Pulse frequency is limited by the response times of valves and flow lag within the chamber's gas delivery system. The lag is at least partially due to the relative remote position of control valves to the process chamber. Consequently, ALD techniques result in a deposition rate that is much lower than typical CVD techniques.


Therefore, a need exists to reduce the time required to deposit films employing sequential deposition techniques.


SUMMARY OF THE DISCLOSURE

Provided is a lid assembly for a semiconductor system, an exemplary embodiment of which includes a support having opposed first and second surfaces, with a valve coupled to the first surface. A baffle plate is mounted to the second surface. The valve is coupled to the support to direct a flow of fluid along a path in an original direction and at an injection velocity. The baffle plate is disposed in the path to disperse the flow of fluid in a plane extending transversely to the original direction. The proximity of the valve to the baffle plate allows enhanced rate and control of fluid disposed through the lid assembly.


In one aspect of the disclosure, one embodiment of a lid assembly for a semiconductor processing system includes a lid having a gas manifold coupled to a first surface and a baffle plate coupled to a second surface. The gas manifold includes a body having a first channel, a second channel and a third channel extending therethrough. The baffle plate includes a recess formed in a first side of the baffle plate and defining a plenum with a second surface of the lid. The plenum communicates with the first, second and third channels via a plurality of inlet channels disposed in the lid. The baffle plate has a center passage disposed therethrough which provides a singular passageway between the plenum and the second side of the baffle plate. Optionally, any combination of the lid, gas manifold or baffle plate may additionally include features for controlling the heat transfer therebetween.


In another aspect of the disclosure, a baffle plate for distributing gases into a semiconductor processing chamber is provided. In one embodiment, the baffle plate includes a plate having a first side and a second side. A recess is formed in the first side and defines a plenum adapted to receive gases prior to entering the processing chamber. A center passage is disposed through the plate concentrically and is concentric with the recess. The center passage provides a single passageway between the recess and the second side of the plate.





BRIEF DESCRIPTION OF THE DRAWINGS

A more particular description of the disclosure, briefly summarized above, may be had by reference to the embodiments thereof which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only typical embodiments of this disclosure and are therefore not to be considered limiting of its scope, for the disclosure may admit to other equally effective embodiments.



FIG. 1 is a simplified top perspective view of a plasma-based semiconductor processing system in accordance with one embodiment of the present disclosure;



FIG. 2 is a top perspective view of one embodiment of a lid assembly of the disclosure;



FIG. 3 is a sectional view of one embodiment of a lid assembly of the disclosure;



FIG. 4 is a sectional view of the embodiment of the lid assembly of FIG. 3; and



FIG. 5A depicts a bottom view of one embodiment of a gas manifold;



FIG. 5B depicts a partial sectional view of the gas manifold taken along section line 5B-5B of FIG. 5A;



FIG. 6 is a perspective view of one embodiment of a baffle plate;



FIG. 7 is a sectional view of the baffle plate taken along section line 7-7 of FIG. 6;



FIG. 8 is a partial sectional view of one embodiment of a mixing lip; and



FIG. 9 is a cross-sectional view of the processing chamber of FIGS. 1 connected to various subsystems associated with system.





To facilitate understanding, identical reference numerals have been used, wherever possible, to designate identical elements that are common to the figures.


DETAILED DESCRIPTION

Referring to FIG. 1, a semiconductor processing system 10 in accordance with one embodiment of the present disclosure includes an enclosure assembly 12 formed from a process-compatible material, such as aluminum or anodized aluminum. The enclosure assembly 12 includes a housing 14, defining a processing chamber 16 with an opening 44 selectively covered and a vacuum lid assembly 20. The vacuum lid assembly 20 is pivotally coupled to the housing 14 via hinges 22. A handle 24 is attached to the vacuum lid assembly 20 opposite the hinges 22. The handle 24 facilitates moving the vacuum lid assembly 20 between opened and closed positions. In the opened position, the interior of the chamber 16 is exposed. In the closed position shown in FIG. 1, the vacuum lid assembly 20 covers the chamber 16 forming a fluid-tight seal with the housing 14. In this manner, a vacuum formed in the processing chamber 16 is maintained as the vacuum lid assembly 20 seals against the housing 14.


To facilitate access to processing chamber 16 depicted in FIG. 1, without compromising the fluid-tight seal between vacuum lid assembly 20 and housing 14, a slit valve opening 44 is disposed in housing 14, as well as a vacuum lock door (not shown). Slit valve opening 44 allows transfer of a wafer (not shown) between processing chamber 16 and the exterior of system 10. Any conventional wafer transfer device (not shown) may achieve the aforementioned transfer. An example of a conventional wafer transfer device is described in commonly assigned U.S. Pat. No. 4,951,601, the complete disclosure of which is incorporated herein by reference.



FIG. 2 is a top perspective view of one embodiment of a vacuum lid assembly 20. The vacuum lid assembly 20 includes a lid 20a and a process fluid injection assembly 30 to deliver reactive, carrier, purge, cleaning and/or other fluids into the processing chamber 16. Lid 20a includes opposing surfaces 21a and 21b. The fluid injection assembly 30 includes a gas manifold 34 mounting a plurality of control valves, 32a, 32b, and 32c, and a baffle plate 36 (shown in FIG. 3). Valves 32a, 32b, and 32c provide rapid and precise gas flow with valve open and close cycles of less than about one second, and in one embodiment, of less than about 0.1 second. In one embodiment, the valves 32a, 32b, and 32c are surface mounted, electronically controlled valves. One valve that may be utilized is available from Fujikin Inc., located in Osaka, Japan, as part number FR-21-6.35 UGF-APD. Other valves that operate at substantially the same speed and precision may also be used.


The lid assembly 20 further includes one or more, (two are shown in FIG. 1) gas reservoirs 33, 35 which are fluidically connected between one or more process gas sources and the gas manifold 34. The gas reservoirs 33, 35 provide bulk gas delivery proximate to each of the valves 32a, 32b, and 32c. The reservoirs 33, 35 are sized to insure that an adequate gas volume is available proximate to the valves 32a, 32b, and 32c during each cycle of the valves 32a, 32b, and 32c during processing to minimize time required for fluid delivery thereby shortening sequential deposition cycles. For example, the reservoirs 33, 35 may be about 5 times the volume required in each gas delivery cycle.


Gas lines 37, 39 extend between connectors 41, 43 and the reservoirs 33, 35 respectively. The connectors 41, 43 are coupled to the lid 20a. The process gases are typically delivered through the housing 14 to the connectors 41, 43 before flowing into the reservoirs 33, 35 through the gas lines 37, 39.


Additional connectors 45, 47 are mounted adjacent the gas manifold 34 down stream from the reservoirs 33, 35 and connect to the reservoirs by gas lines 49, 51. The connectors 45, 47 and gas lines 49, 51 generally provide a flowpath for process gases from the reservoir 33, 35 to the gas manifold 34. A purge gas line 53 is similarly connected between a connector 55 and a connection 57 on the gas manifold 34. In one embodiment, a tungsten source gas, such as tungsten hexafluoride, is connected to the first reservoir 33 and a reducing gas such as silane or diborane is connected to the second reservoir 35.



FIGS. 3 and 4 are partial sectional views of the vacuum lid assembly 20. The gas manifold 34 includes a body defining three valve mounting surfaces 59, 61, and 64 (mounting surface 64 is shown in FIG. 4) and an upper surface 63 for mounting an upper valve 65. The gas manifold 34 includes three pairs of gas channels 67a, 67b, 69a, 69b, 69c, 71a, and 71b (71a and 71b are shown on FIG. 4) that fluidly couple the two process gases and a purge gas (shown as fluid sources 68a-c in FIG. 9) to the interior of the processing chamber 16 controllably through the valves 32a, 32b, and 32c, thereby allowing thermal conditioning of the gases by the gas manifold 34 before reaching the valves 32a, 32b, and 32c. Gas channels 67a, 69a, and 71a (also termed thermal conditioning channels) are fluidly coupled to the connectors 45, 47, and 57 and provide passage of gases through the gas manifold 34 to the valves 32a, 32b, and 32c. Gas channels 67b, 69b, and 71b deliver gases from the valves 32a, 32b, and 32c through the gas manifold 34. The gas channel 71b delivers gas from the valve 32c through the gas manifold 34 and into a gas channel 73 passing through a member 26. The channels 67b, 69b, and 73 are fluidly coupled to a respective inlet passage 302, 304 and 306 disposed through the lid 20a. Gases or other fluids flowing through the inlet passages 302, 304, and 306 flow into a plenum or region 308 defined between the lid 20a and baffle plate 36 before entering the chamber 16.


The channel 73 additionally is coupled to the upper surface 63. The valve 65 is disposed between the upper surface 63 of the gas manifold 34 and a cleaning source 38. The cleaning source 38 is a compact system for providing cleaning reagents, typically in the form of fluorine or fluorine radicals, for removing contaminants and deposition byproducts from the chamber 16. In one embodiment, the cleaning source 38 is a remote plasma source that typically includes subsystems (not shown) such as a microwave generator in electrical communication with a plasma applicator, an autotuner and an isolator. The gas channel 73 through which the cleaning gases are delivered from the cleaning source 38 is additionally connected with the gas channel 71b that delivers purge gas to the chamber 16 through the plenum 308 disposed in the baffle plate 36. In this manner, as purge gas is delivered to the chamber 16, any cleaning reagents remaining in the channel 73 between the gas channel 71b and the chamber 16 may be flushed and exhausted from the chamber 16 prior to the next deposition process.


The gas manifold 34 further includes a conduit 75 for flowing a heat transfer medium therethrough, thus allowing temperature control of the gas manifold 34. In tungsten deposition processes, for example, the gas manifold 34 is typically cooled. For other processes, such as titanium nitride deposition, the gas manifold 34 may be heated to prevent condensation of the reactive gases within the manifold. To further assist in temperature control of the gas manifold 34, a lower surface 77 of the gas manifold 34 may be configured to tailor the surface area contact with a first surface 42 of the lid 20a, thus controlling the thermal transfer between the housing 14 and manifold through the lid 20a. Alternatively, the housing 14 and manifold 34 may be configured to maximize the contact area.


Optionally, a plurality of recesses 28 may be formed in a second surface 44 of the lid 20a that contacts the baffle plate 36. The recesses 28 allow the contact area between the baffle plate 36 and lid 20a to be tailored to promote a desired rate of heat transfer. The baffle plate 36 may alternately be configured to control the contact area with the lid 20a as described with reference to FIGS. 6 and 7 below.


Referring to FIGS. 5A and 5B, the lower surface 77 of the gas manifold 34 is illustrated configured to minimize surface area contact with the lid 20a. Each of the three gas channels 67b, 69b, and 73 pass respectively through bosses 502, 504 and 506 that project from the gas manifold 34. Each boss 502, 504, and 506 has an o-ring chase 79, 81, and 83 that respectively surrounds each gas channel 67b, 69b, and 73 to prevent fluids passing therethrough from leaking between the gas manifold 34 and the lid 20a. A mounting surface 508 surrounds the bosses 502, 504, and 506 and includes a plurality of mounting holes 510 which facilitate coupling the gas manifold 34 to the cover 20a. In one embodiment, the gas manifold 34 is fastened by screws threading into blind holes formed in the lid 20a (screws and blind holes not shown). As the bosses 502, 504, and 506 and mounting surface 508 provide a controlled contact area between the gas manifold 34 and the cover 20a, the thermal transfer therebetween can be minimized. The contact area between the gas manifold 34 and the cover 20a may utilize other geometries to tailor the heat transfer therebetween. For example, the lower surface 77 of the gas manifold 34 can be planar to provide maximum contact area with the lid 20a and thus maximize heat transfer between the lid 20a and the gas manifold 34.


Returning to FIG. 4, temperature control of system 10 may be achieved by flowing a heat transfer medium through a temperature control channel 20g disposed within the lid 20a. The temperature control channel 20g is in fluid communication with heat transfer medium supply (not shown) that provides and/or regulates the temperature of the heat transfer medium flowing through the channel 20g to control (e.g., heat, cool, or maintain constant) the temperature of the lid 20a.



FIGS. 6 and 7 depict one embodiment of the baffle plate 36. The baffle plate 36 is coupled to the lid 20a opposite the gas manifold 34. The baffle plate 36 is generally comprised of a process compatible material such as aluminum and is utilized to mix and uniformly distribute gases entering the chamber 16 from the gas manifold 34. The baffle plate 36 may be removed from the lid 20a for cleaning and/or replacement. Alternatively, the baffle plate 36 and lid 20a may be fabricated as a single member.


The baffle plate 36 is generally annular and includes a first side 36a disposed proximate the lid 20a and a second side 36b generally exposed to interior of the processing chamber 16. The baffle plate 36 has a passage 700 disposed between the first side 36a and the second side 36b. A recess 702, typically concentric with the passage 700, extends into the first side 36a. The recess 702 and lid 20a define a plenum therebetween. The recess 702, typically circular in form, is configured to extend radially from a center line of the baffle plate 36 to a diameter that extends beyond the inlet passages 302, 304, and 306 disposed in the lid 20a so that gases flowing from the inlet passages enter the plenum and exit through the passage 700.


A bottom 712 of the recess 702 defines a mixing lip 704 that extends radially inward into the passage 700. The transition from a wall 714 of the recess 702 to the bottom 712 includes a radius 710 to assist in directing fluid flow within the recess 702 while maximizing the swept volume of the recess 702. Gases flowing into the plenum from the inlet passages 302, 304, and 306 are re-directed by the flat surface of the mixing lip 704 generally towards the center of the recess 702 before passing through the passage 700 and into the process chamber 16. The recess 702 combined with a singular exit passage for delivering gases to the chamber 16 (e.g., the passage 700) advantageously reduces the surface area and orifices requiring purging and cleaning over conventional showerheads having multiple orifices for gas delivery.



FIG. 8 depicts a partial sectional view of one embodiment of the mixing lip 704. The mixing lip 704 may include an optional sculptured surface 802 that directs the gas flows towards one another or induces turbulence to enhance mixing and/or cleaning. The sculptured surface 802 may includes any one or combination of turbulence-inducing features such as one or more bumps, grooves, projections, indentations, embossed patterns and the like. Alternatively, bottom 712 of the recess 702 defining the mixing lip 704 may be smooth. In one embodiment, the mixing lip 704 directs gases moving substantially axially from the lid 20a transversely towards the center of the passage 700 in either a turbulent flow as depicted by flow lines 804, laminar flow or combination thereof, where the converging gas flows mix before exiting the passage 700.


The mixing lip 704 may include a rounded tip 806 to assist in directing the flow through the passage 700 and into the chamber 16 with minimal pressure drop. In one embodiment, the mixing lip 704 includes a transition angle 808 between the tip 804 and the second side 36b of the baffle plate 36 to enhance the radial flow and uniformity of fluids exiting the passage 700 and into the chamber 16.


Returning to FIGS. 6 and 7, the first side 36a of the baffle plate 36 may additionally include features for reducing the contact area between the baffle plate 36 and the lid 20a. Providing reduced contact area allows the baffle plate 36 to be operated at a higher temperature than the lid 20a, which in some processes enhances deposition performance. In the embodiment depicted in FIG. 7, the first side 36a of the baffle plate 36 includes a plurality of bosses 602, each having a mounting hole 604 passing therethrough. The bosses 602 allow the baffle plate 36 to be coupled to the lid 20a by fasteners passing through the mounting holes 604 into blind threaded holes formed in the lid 20a (fasteners and threaded holes not shown). Additionally, a ring 606 projects from the first side 36a and circumscribes the recess 702. The ring 606 and bosses 602 project to a common elevation that allows the baffle plate 36 to be coupled to the lid 20a in a spaced-apart relation. The spaced-apart relation and the controlled contact area permit controlled thermal transfer between the baffle plate 36 and the lid 20a. Accordingly, the contact area provided by bosses 602 and the ring 606 may be designed to tailor the amount and location of the solid to solid contact area available for thermal transfer between the baffle plate 36 and the lid 20a as a particular deposition process requires.


Referring to FIG. 9, disposed within processing chamber 16 is a heater/lift assembly 46 that includes a wafer support pedestal 48 connected to a support shaft 48a and conduit 46a. The support pedestal 48 is positioned between the shaft 48a and the vacuum lid assembly 20 when the vacuum lid assembly 20 is in the closed position. The support shaft 48a extends from the wafer support pedestal 48 away from vacuum lid assembly 20 through a passage formed in the housing 14. A bellows 50 is attached to a portion of the housing 14 disposed opposite to the lid assembly 20 to prevent leakage into the chamber 16 from between the support shaft 48a and housing 14. The heater/lift assembly 46 may be moved vertically within the chamber 16 so that a distance between support pedestal 48 and vacuum lid assembly 20 may be controlled. A sensor (not shown) provides information concerning the position of support pedestal 48 within processing chamber 16. An example of a lifting mechanism for the support pedestal 48 is described in detail in U.S. Pat. No. 5,951,776, which is hereby incorporated by reference in its entirety.


The support pedestal 48 includes an embedded thermocouple 50a that may used to monitor the temperature thereof. For example, a signal from the thermocouple 50a may be used in a feedback loop to control power applied to a heater element 52a by a power source 52. The heater element 52a may be a resistive heater element or other thermal transfer device disposed in or in contact with the pedestal 48 utilized to control the temperature thereof. Optionally, support pedestal 48 may be heated using a heat transfer fluid (not shown).


The support pedestal 48 may be formed from any process-compatible material, including aluminum nitride and aluminum oxide (Al2O3 or alumina) and may also be configured to hold a substrate thereon employing a vacuum, e.g., support pedestal 48 may be a vacuum chuck. To that end, support pedestal 48 may include a plurality of vacuum holes (not shown) that are placed in fluid communication with a vacuum source, such as pump system via vacuum tube routed through the support shaft 48a.


A liner assembly is disposed in the processing chamber 16 and includes a cylindrical portion 54 and a planar portion. The cylindrical portion 54 and the planar portion may be formed from any suitable material such as aluminum, ceramic and the like. The cylindrical portion 54 surrounds the support pedestal 48. The cylindrical portion 54 additionally includes an aperture 60 that aligns with the slit valve opening 44 disposed a side wall 14b of the housing 14 to allow entry and egress of substrates from the chamber 16.


The planar portion extends transversely to the cylindrical portion 54 and is disposed against a chamber bottom 14a of processing chamber 16 disposed opposite to lid assembly 20. The liner assembly defines a chamber channel 58 between the housing 14 and both cylindrical portion 54 and planar portion. Specifically, a first portion of channel 58 is defined between the chamber bottom 14a and planar portion. A second portion of channel 58 is defined between the side wall 14b of the housing 14 and the cylindrical portion 54. A purge gas is introduced into the channel 58 to minimize inadvertent deposition on the chamber walls along with controlling the rate of heat transfer between the chamber walls and the liner assembly.


Disposed along the side walls 14b of the chamber 16 proximate the lid assembly 20 is a pumping channel 62. The pumping channel 62 includes a plurality of apertures, one of which is shown as a first aperture 62a. The pumping channel 62 includes a second aperture 62b that is coupled to a pump system 18 by a conduit 66. A throttle valve 18a is coupled between the pumping channel 62 and the pump system 18. The pumping channel 62, the throttle valve 18a, and the pump system 18 control the amount of flow from the processing chamber 16. The size and number and position of apertures 62a in communication with the chamber 16 are configured to achieve uniform flow of gases exiting the lid assembly 20 over support pedestal 48 and substrate seated thereon. A plurality of supplies 68a, 68b, and 68c of process and/or other fluids, is in fluid communication with one of valves 32a, 32b, or 32c through a sequence of conduits (not shown) formed through the housing 14, lid assembly 20, and gas manifold 34.


A controller 70 regulates the operations of the various components of system 10. The controller 70 includes a processor 72 in data communication with memory, such as random access memory 74 and a hard disk drive 76 and is in communication with at least the pump system 18, the power source 52, and valves 32a, 32b, and 32c.


Although any type of process fluid may be employed, one example of process fluids are B2H6 gas and WF6 gas, and a purge fluid is Ar gas. N2 may also be used as a purge gas. The chamber pressure is in the range of 1 Torr to 5 Torr, and the pedestal 48 is heated in the range of 350° to 400° C. Each of the process fluids is flowed into the processing chamber 16 with a carrier fluid, such as Ar. It should be understood, however, that the purge fluid might differ from the carrier fluid, discussed more fully below.


One cycle of the sequential deposition technique in accordance with the present disclosure includes flowing the purge fluid, Ar, into the processing chamber 16 during time t1, before B2H6 is flowed into the processing chamber 16. During time t2, the process fluid B2H6 is flowed into the processing chamber 16 along with a carrier fluid, which in this example is Ar. After the flow of B2H6 terminates, the flow of Ar continues during time t3, purging the processing chamber 16 of B2H6. During time t4, the processing chamber 16 is pumped so as to remove all process fluids. After pumping of the processing chamber 16, the carrier fluid Ar is introduced during time t5, after which time the process fluid WF6 is introduced into the processing chamber 16, along with the carrier fluid Ar during time t6. After the flow of WF6 into the processing chamber 16 terminates, the flow of Ar continues during time t7. Thereafter, the processing chamber 16 is pumped so as to remove all process fluids therein, during time t8, thereby concluding one cycle of the sequential deposition technique in accordance with the present disclosure. This sequence of cycles is repeated until the layer being formed thereby has desired characteristics, such as thickness, conductivity and the like. It can be seen that the time required during each period t1-t7 greatly affects the throughput of system 10. To maximize the throughput, the lid assembly 20 and the injection assembly 30 are configured to minimize the time required to inject process fluids into the processing chamber 16 and disperse the fluids over the process region proximate to the support pedestal 48. For example, the proximity of the reservoirs 33, 35 and valves 32a-32b to the gas manifold 34 reduce the response times of fluid delivery, thereby enhancing the frequency of pulses utilized in ALD deposition processes. Additionally, as the purge gases are strategically delivered through the lower portion of the passage 73, sweeping of cleaning agents from the gas manifold 34 and baffle plate 36 is ensured and process uniformity with smaller process gas volumes is enhanced.


Although the disclosure has been described in terms of specific embodiments, one skilled in the art will recognize that various modifications may be made that are within the scope of the present disclosure. For example, although three valves are shown, any number of valves may be provided, depending upon the number of differing process fluids employed to deposit a film. Therefore, the scope of the disclosure should not be based upon the foregoing description. Rather, the scope of the disclosure should be determined based upon the claims recited herein, including the full scope of equivalents thereof.

Claims
  • 1. A substrate processing system, comprising: a lid having an upper lid surface opposed to a lower lid surface;a plurality of gas inlet passages extending from the upper lid surface to the lower lid surface;a gas manifold coupled to the lid;at least one valve coupled with the gas manifold and configured to control a gas flow through one of the gas inlet passages;a gas reservoir fluidly connected between the gas manifold and at least one precursor source; anda remote plasma source disposed on the lid.
  • 2. The substrate processing system of claim 1, further comprising a second gas reservoir, and the second gas reservoir is fluidly connected to the gas manifold through a gas line.
  • 3. The substrate processing system of claim 2, wherein the second gas reservoir is fluidly connected between the gas manifold and at least one precursor source.
  • 4. The substrate processing system of claim 1, wherein the gas reservoir has about 5 times the volume than required in each gas delivery cycle.
  • 5. The substrate processing system of claim 1, wherein the remote plasma source is fluidly coupled to the at least one gas inlet passage.
  • 6. The substrate processing system of claim 1, wherein the gas manifold comprises: an upper manifold surface and a lower manifold surface; anda first gas channel and a second gas channel each extending from the upper manifold surface, through the gas manifold, and to the lower manifold surface.
  • 7. The substrate processing system of claim 6, wherein the first gas channel is in fluid communication with a first gas inlet passage of the plurality of gas inlet passages, and the second gas channel is in fluid communication with a second gas inlet passage of the plurality of gas inlet passages.
  • 8. The substrate processing system of claim 7, wherein the first and second gas inlet passages are extended through the lid in a direction perpendicular to the upper lid surface.
  • 9. The substrate processing system of claim 6, further comprising a third gas channel extending from the upper manifold surface to the lower manifold surface.
  • 10. The substrate processing system of claim 1, wherein the gas manifold further comprises a conduit disposed therein and configured to flow a heat transfer fluid therethrough.
  • 11. A substrate processing system, comprising: a lid having an upper lid surface opposed to a lower lid surface;a plurality of gas inlet passages extending from the upper lid surface to the lower lid surface;a gas manifold coupled to the lid;at least one valve coupled to the gas manifold and configured to control a gas flow through one of the gas inlet passages, wherein the at least one valve is configured to provide an open and close cycle having a time period of less than about 1 second for enabling an atomic layer deposition process;a gas reservoir fluidly connected between the gas manifold and at least one precursor source; anda remote plasma source disposed on the lid.
  • 12. The substrate processing system of claim 11, further comprising a second gas reservoir, and the second gas reservoir is fluidly connected to the gas manifold through a gas line.
  • 13. The substrate processing system of claim 12, wherein the second gas reservoir is fluidly connected between the gas manifold and at least one precursor source.
  • 14. The substrate processing system of claim 11, wherein the remote plasma source is fluidly coupled to the at least one gas inlet passage.
  • 15. The substrate processing system of claim 11, wherein the gas manifold comprises: an upper manifold surface and a lower manifold surface; anda first gas channel and a second gas channel each extending from the upper manifold surface, through the gas manifold, and to the lower manifold surface.
  • 16. The substrate processing system of claim 15, wherein the first gas channel is in fluid communication with a first gas inlet passage of the plurality of gas inlet passages, and the second gas channel is in fluid communication with a second gas inlet passage of the plurality of gas inlet passages.
  • 17. The substrate processing system of claim 16, wherein the first and second gas inlet passages are extended through the lid in a direction perpendicular to the upper lid surface.
  • 18. The substrate processing system of claim 11, wherein the gas manifold further comprises a conduit disposed therein and configured to flow a heat transfer fluid therethrough.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No. 14/152,730, filed Jan. 10, 2014, which is a continuation of U.S. application Ser. No. 13/012,341, filed Jan. 24, 2011, now abandoned, which is a continuation of U.S. application Ser. No. 10/993,924, filed Nov. 19, 2004, now U.S. Pat. No. 7,905,959, which is a continuation of U.S. application Ser. No. 10/016,300, filed Dec. 12, 2001, now U.S. Pat. No. 6,878,206, which claims benefit of U.S. Prov. Appl. No. 60/305,970, filed Jul. 16, 2001, which are incorporated herein by reference in their entireties. Additionally, this application is related to U.S. Pat. Nos. 6,333,123 and 6,660,126, as well as U.S. application Ser. No. 09/798,258, filed on Mar. 2, 2001, published as US 20020121241, now abandoned, which are incorporated herein by reference in their entireties.

US Referenced Citations (347)
Number Name Date Kind
3592575 Jaeger et al. Jul 1971 A
4058430 Suntola et al. Nov 1977 A
4389973 Suntola et al. Jun 1983 A
4413022 Suntola et al. Nov 1983 A
4415275 Dietrich Nov 1983 A
4486487 Skarp et al. Dec 1984 A
4538653 Shea Sep 1985 A
4741354 DeMild, Jr. May 1988 A
4761269 Conger Aug 1988 A
4767494 Kobayashi et al. Aug 1988 A
4790262 Nakayama Dec 1988 A
4806321 Nishizawa et al. Feb 1989 A
4813846 Helms et al. Mar 1989 A
4829022 Kobayashi et al. May 1989 A
4834831 Nishizawa et al. May 1989 A
4838983 Schumaker et al. Jun 1989 A
4838993 Aoki et al. Jun 1989 A
4840921 Matsumoto Jun 1989 A
4842683 Cheng Jun 1989 A
4845049 Sunakawa Jul 1989 A
4859625 Matsumoto Aug 1989 A
4859627 Sunakawa et al. Aug 1989 A
4861417 Mochizuki et al. Aug 1989 A
4872947 Wang Oct 1989 A
4876218 Pessa et al. Oct 1989 A
4908095 Kagatsume Mar 1990 A
4917556 Stark et al. Apr 1990 A
4927670 Erbil May 1990 A
4931132 Aspnes et al. Jun 1990 A
4951601 Maydan et al. Aug 1990 A
4960720 Shimbo et al. Oct 1990 A
4975252 Nishizawa et al. Dec 1990 A
4993357 Scholz Feb 1991 A
4993358 Mahawili Feb 1991 A
5000113 Wang Mar 1991 A
5013400 Kurasaki May 1991 A
5013683 Petroff et al. May 1991 A
5027746 Frijlink et al. Jul 1991 A
5028565 Chang et al. Jul 1991 A
5082798 Arimoto et al. Jan 1992 A
5085885 Foley et al. Feb 1992 A
5091217 Hey Feb 1992 A
5091320 Aspnes et al. Feb 1992 A
5130269 Kitahara et al. Jul 1992 A
5166092 Mochizuki et al. Nov 1992 A
5173327 Sandhu et al. Dec 1992 A
5173474 Connell et al. Dec 1992 A
5186718 Tepman et al. Feb 1993 A
5205077 Wittstock et al. Apr 1993 A
5225366 Yoder Jul 1993 A
5232164 Resch et al. Aug 1993 A
5234561 Randhawa et al. Aug 1993 A
5246536 Nishizawa et al. Sep 1993 A
5250148 Nishizawa et al. Oct 1993 A
5254207 Nishizawa et al. Oct 1993 A
5256244 Ackerman Oct 1993 A
5259881 Edwards et al. Nov 1993 A
5261959 Gasworth Nov 1993 A
5270247 Sakuma et al. Dec 1993 A
5273588 Foster Dec 1993 A
5278435 Van Hove et al. Jan 1994 A
5281274 Yoder Jan 1994 A
5286296 Sato et al. Feb 1994 A
5290748 Knuuttila et al. Mar 1994 A
5294286 Nishizawa et al. Mar 1994 A
5296403 Nishizawa et al. Mar 1994 A
5300186 Kitahara et al. Apr 1994 A
5311055 Goodman et al. May 1994 A
5316615 Copel et al. May 1994 A
5316793 Wallace et al. May 1994 A
5330610 Eres et al. Jul 1994 A
5336324 Stall et al. Aug 1994 A
5338362 Imahashi Aug 1994 A
5338389 Nishizawa et al. Aug 1994 A
5348911 Jurgensen et al. Sep 1994 A
5356476 Foster Oct 1994 A
5368062 Okumura Nov 1994 A
5374570 Nasu et al. Dec 1994 A
5376166 Hoffmann Dec 1994 A
5395791 Cheng et al. Mar 1995 A
5411590 Hawkins May 1995 A
5423936 Tomita Jun 1995 A
5429650 Hoffmann Jul 1995 A
5438952 Otsuka et al. Aug 1995 A
5439876 Graf et al. Aug 1995 A
5441703 Jurgensen Aug 1995 A
5443033 Nishizawa et al. Aug 1995 A
5443647 Aucoin et al. Aug 1995 A
5455072 Bension et al. Oct 1995 A
5458084 Thorne et al. Oct 1995 A
5469806 Mochizuki et al. Nov 1995 A
5480678 Rudolph Jan 1996 A
5480818 Matsumoto et al. Jan 1996 A
5483919 Yokoyama et al. Jan 1996 A
5484664 Kitahara et al. Jan 1996 A
5500256 Watabe Mar 1996 A
5503875 Imai et al. Apr 1996 A
5516366 Kanno May 1996 A
5521126 Okamura et al. May 1996 A
5527733 Nishizawa et al. Jun 1996 A
5532511 Nishizawa et al. Jul 1996 A
5534073 Kinoshita Jul 1996 A
5540783 Eres et al. Jul 1996 A
5567267 Kazama Oct 1996 A
5580380 Liu et al. Dec 1996 A
5599397 Anderson Feb 1997 A
5601651 Watabe et al. Feb 1997 A
5609689 Kato et al. Mar 1997 A
5616181 Yamamoto et al. Apr 1997 A
5637530 Gaines et al. Jun 1997 A
5641984 Aftergut et al. Jun 1997 A
5644128 Wollnik et al. Jul 1997 A
5667592 Boitnott et al. Sep 1997 A
5674786 Turner et al. Oct 1997 A
5693139 Nishizawa et al. Dec 1997 A
5695564 Imahashi et al. Dec 1997 A
5705224 Murota et al. Jan 1998 A
5707880 Aftergut et al. Jan 1998 A
5711811 Suntola et al. Jan 1998 A
5725673 Anderson Mar 1998 A
5730801 Tepman et al. Mar 1998 A
5730802 Ishizumi et al. Mar 1998 A
5746875 Maydan May 1998 A
5747113 Tsai May 1998 A
5749974 Habuka et al. May 1998 A
5755886 Wang May 1998 A
5788447 Yonemitsu et al. Aug 1998 A
5788799 Steger et al. Aug 1998 A
5796116 Nakata et al. Aug 1998 A
5801634 Young et al. Sep 1998 A
5807792 Ilg et al. Sep 1998 A
5830270 McKee et al. Nov 1998 A
5835677 Li et al. Nov 1998 A
5851849 Comizzoli et al. Dec 1998 A
5855675 Doering et al. Jan 1999 A
5855680 Soininen et al. Jan 1999 A
5856219 Naito et al. Jan 1999 A
5858102 Tsai Jan 1999 A
5866213 Foster et al. Feb 1999 A
5866795 Wang et al. Feb 1999 A
5879459 Gadgil et al. Mar 1999 A
5879461 Adams Mar 1999 A
5882165 Maydan et al. Mar 1999 A
5882413 Beaulieu et al. Mar 1999 A
5895530 Shrotriya Apr 1999 A
5904565 Nguyen et al. May 1999 A
5916365 Sherman Jun 1999 A
5923056 Lee et al. Jul 1999 A
5923985 Aoki et al. Jul 1999 A
5925574 Aoki et al. Jul 1999 A
5928389 Jevtic Jul 1999 A
5942040 Kim et al. Aug 1999 A
5947710 Cooper et al. Sep 1999 A
5968276 Lei et al. Oct 1999 A
5972430 DiMeo, Jr. et al. Oct 1999 A
5976260 Kinoshita Nov 1999 A
5976261 Moslehi Nov 1999 A
5989345 Hatano et al. Nov 1999 A
6001669 Gaines et al. Dec 1999 A
6015590 Suntola et al. Jan 2000 A
6019848 Frankel et al. Feb 2000 A
6025627 Forbes et al. Feb 2000 A
6036773 Wang et al. Mar 2000 A
6042652 Hyun et al. Mar 2000 A
6043177 Falconer et al. Mar 2000 A
6051286 Zhao et al. Apr 2000 A
6062798 Muka May 2000 A
6068703 Chen May 2000 A
6071572 Mosely et al. Jun 2000 A
6071808 Merchant et al. Jun 2000 A
6079426 Subrahmanyam Jun 2000 A
6084302 Sandhu Jul 2000 A
6086677 Umotoy et al. Jul 2000 A
6110556 Bang Aug 2000 A
6113977 Soininen et al. Sep 2000 A
6117244 Bang et al. Sep 2000 A
6123775 Hao Sep 2000 A
6124158 Dautartas et al. Sep 2000 A
6130147 Major et al. Oct 2000 A
6139700 Kang et al. Oct 2000 A
6140237 Chan et al. Oct 2000 A
6140238 Kitch Oct 2000 A
6143659 Leem Nov 2000 A
6144060 Park et al. Nov 2000 A
6158446 Mohindra et al. Dec 2000 A
6161500 Kopacz Dec 2000 A
6170492 Ueda et al. Jan 2001 B1
6174377 Doering et al. Jan 2001 B1
6174809 Kang et al. Jan 2001 B1
6176198 Kao et al. Jan 2001 B1
6176930 Koai et al. Jan 2001 B1
6178918 van Os Jan 2001 B1
6183563 Choi et al. Feb 2001 B1
6190459 Takeshita Feb 2001 B1
6197683 Kang et al. Mar 2001 B1
6200893 Sneh Mar 2001 B1
6203613 Gates et al. Mar 2001 B1
6206967 Mak et al. Mar 2001 B1
6207302 Sugiura et al. Mar 2001 B1
6231672 Choi et al. May 2001 B1
6248605 Harkonen et al. Jun 2001 B1
6270572 Kim et al. Aug 2001 B1
6271148 Kao et al. Aug 2001 B1
6277200 Xia Aug 2001 B2
6287965 Kang et al. Sep 2001 B1
6291876 Stumborg et al. Sep 2001 B1
6302964 Umotoy Oct 2001 B1
6302965 Umotoy et al. Oct 2001 B1
6305314 Sneh et al. Oct 2001 B1
6306216 Kim et al. Oct 2001 B1
6316098 Yitzchaik et al. Nov 2001 B1
6368987 Kopacz Apr 2002 B1
6387185 Doering et al. May 2002 B2
6416822 Chiang et al. Jul 2002 B1
6446573 Hirayama et al. Sep 2002 B2
6447607 Soininen et al. Sep 2002 B2
6454860 Metzner Sep 2002 B2
6478872 Chae et al. Nov 2002 B1
6481945 Hasper et al. Nov 2002 B1
6511539 Raaijmakers Jan 2003 B1
6551406 Kilpi Apr 2003 B2
6572705 Suntola et al. Jun 2003 B1
6578287 Aswad Jun 2003 B2
6579372 Park Jun 2003 B2
6593484 Yasuhara et al. Jul 2003 B2
6630030 Suntola et al. Oct 2003 B1
6630201 Chiang et al. Oct 2003 B2
6660126 Nguyen et al. Dec 2003 B2
6716287 Santiago et al. Apr 2004 B1
6718126 Lei Apr 2004 B2
6734020 Lu et al. May 2004 B2
6772072 Ganguli et al. Aug 2004 B2
6773507 Jallepally et al. Aug 2004 B2
6777352 Tepman et al. Aug 2004 B2
6778762 Shareef et al. Aug 2004 B1
6812157 Gadgil Nov 2004 B1
6815285 Choi et al. Nov 2004 B2
6818094 Yudovsky Nov 2004 B2
6821563 Yudovsky Nov 2004 B2
6866746 Lei et al. Mar 2005 B2
6868859 Yudovsky Mar 2005 B2
6878206 Tzu Apr 2005 B2
6958174 Klaus et al. Oct 2005 B1
7905959 Tzu Mar 2011 B2
9587310 Tzu Mar 2017 B2
20010000866 Sneh et al. May 2001 A1
20010009140 Bondestam et al. Jul 2001 A1
20010011526 Doering et al. Aug 2001 A1
20010013312 Soininen et al. Aug 2001 A1
20010014371 Kilpi Aug 2001 A1
20010031562 Raaijmakers et al. Oct 2001 A1
20010034123 Jeon et al. Oct 2001 A1
20010041250 Werkhoven et al. Nov 2001 A1
20010042523 Kesala Nov 2001 A1
20010042799 Kim et al. Nov 2001 A1
20010054377 Lindfors et al. Dec 2001 A1
20020000196 Park Jan 2002 A1
20020002948 Hongo Jan 2002 A1
20020007790 Park Jan 2002 A1
20020009544 McFeely et al. Jan 2002 A1
20020009896 Sandhu et al. Jan 2002 A1
20020015855 Sajoto Feb 2002 A1
20020017242 Hamaguchi et al. Feb 2002 A1
20020033183 Sun Mar 2002 A1
20020041931 Suntola et al. Apr 2002 A1
20020052097 Park May 2002 A1
20020066411 Chiang et al. Jun 2002 A1
20020073924 Chiang et al. Jun 2002 A1
20020076481 Chiang et al. Jun 2002 A1
20020076507 Chiang et al. Jun 2002 A1
20020076508 Chiang et al. Jun 2002 A1
20020086106 Park et al. Jul 2002 A1
20020092471 Kang et al. Jul 2002 A1
20020094689 Park Jul 2002 A1
20020104481 Chiang et al. Aug 2002 A1
20020108570 Lindfors Aug 2002 A1
20020110991 Li Aug 2002 A1
20020115886 Yasuhara et al. Aug 2002 A1
20020121241 Nguyen et al. Sep 2002 A1
20020121342 Nguyen et al. Sep 2002 A1
20020127745 Lu et al. Sep 2002 A1
20020134307 Choi Sep 2002 A1
20020144655 Chiang et al. Oct 2002 A1
20020144657 Chiang et al. Oct 2002 A1
20020146511 Chiang et al. Oct 2002 A1
20020197856 Matsuse et al. Dec 2002 A1
20030000473 Chae et al. Jan 2003 A1
20030004723 Chihara Jan 2003 A1
20030010451 Tzu Jan 2003 A1
20030017697 Choi et al. Jan 2003 A1
20030022338 Ruben et al. Jan 2003 A1
20030042630 Babcoke et al. Mar 2003 A1
20030053799 Lei Mar 2003 A1
20030057527 Chung et al. Mar 2003 A1
20030072913 Chou et al. Apr 2003 A1
20030075273 Kilpela et al. Apr 2003 A1
20030075925 Lindfors et al. Apr 2003 A1
20030079686 Chen et al. May 2003 A1
20030089308 Raaijmakers May 2003 A1
20030101927 Raaijmakers Jun 2003 A1
20030101938 Ronsse et al. Jun 2003 A1
20030106490 Jallepally et al. Jun 2003 A1
20030113187 Lei et al. Jun 2003 A1
20030116087 Nguyen Jun 2003 A1
20030121469 Lindfors et al. Jul 2003 A1
20030121608 Chen et al. Jul 2003 A1
20030140854 Kilpi Jul 2003 A1
20030143328 Chen et al. Jul 2003 A1
20030143747 Bondestam et al. Jul 2003 A1
20030153177 Tepman et al. Aug 2003 A1
20030172872 Thakur Sep 2003 A1
20030194493 Chang et al. Oct 2003 A1
20030196603 Nguyen et al. Oct 2003 A1
20030198754 Xi et al. Oct 2003 A1
20030213560 Wang Nov 2003 A1
20030216981 Tillman Nov 2003 A1
20030219942 Choi et al. Nov 2003 A1
20030221780 Lei Dec 2003 A1
20030224107 Lindfors et al. Dec 2003 A1
20030235961 Metzner Dec 2003 A1
20040005749 Choi Jan 2004 A1
20040011404 Ku Jan 2004 A1
20040011504 Ku et al. Jan 2004 A1
20040013577 Ganguli et al. Jan 2004 A1
20040014320 Chen et al. Jan 2004 A1
20040015300 Ganguli et al. Jan 2004 A1
20040016404 Gregg Jan 2004 A1
20040025370 Guenther Feb 2004 A1
20040048451 Marsh et al. Mar 2004 A1
20040065255 Yang et al. Apr 2004 A1
20040069227 Ku et al. Apr 2004 A1
20040071897 Verplancken et al. Apr 2004 A1
20040129212 Gadgil et al. Jul 2004 A1
20040144308 Yudovsky Jul 2004 A1
20040144311 Chen et al. Jul 2004 A1
20040219784 Kang et al. Nov 2004 A1
20040224506 Choi et al. Nov 2004 A1
20040235285 Kang et al. Nov 2004 A1
20050006799 Gregg et al. Jan 2005 A1
20050059240 Choi et al. Mar 2005 A1
20050095859 Chen et al. May 2005 A1
20050104142 Narayanan et al. May 2005 A1
20050252449 Nguyen Nov 2005 A1
20080063798 Kher Mar 2008 A1
20090232986 Choi Sep 2009 A1
20110114020 Tzu May 2011 A1
20140179114 van Schravendijk Jun 2014 A1
Foreign Referenced Citations (201)
Number Date Country
19627017 Jan 1997 DE
19820147 Jul 1999 DE
0344352 Dec 1989 EP
0429270 May 1991 EP
0442290 Aug 1991 EP
0497267 Aug 1992 EP
0799641 Oct 1997 EP
1167569 Jan 2002 EP
2626110 Jul 1989 FR
2692597 Dec 1993 FR
2355727 May 2001 GB
58098917 Jun 1983 JP
58100419 Jun 1983 JP
60065712 Apr 1985 JP
61035847 Feb 1986 JP
61210623 Sep 1986 JP
62069508 Mar 1987 JP
62091495 Apr 1987 JP
62141717 Jun 1987 JP
62167297 Jul 1987 JP
62171999 Jul 1987 JP
62232919 Oct 1987 JP
63062313 Mar 1988 JP
63085098 Apr 1988 JP
63090833 Apr 1988 JP
63222420 Sep 1988 JP
63222421 Sep 1988 JP
63227007 Sep 1988 JP
63252420 Oct 1988 JP
63266814 Nov 1988 JP
64009895 Jan 1989 JP
64009896 Jan 1989 JP
64009897 Jan 1989 JP
64037832 Mar 1989 JP
64082615 Mar 1989 JP
64082617 Mar 1989 JP
64082671 Mar 1989 JP
64082676 Mar 1989 JP
1103982 Apr 1989 JP
1103996 Apr 1989 JP
64090524 Apr 1989 JP
1117017 May 1989 JP
1143221 Jun 1989 JP
1143233 Jun 1989 JP
1154511 Jun 1989 JP
1290221 Jun 1989 JP
1236657 Sep 1989 JP
1245512 Sep 1989 JP
1264218 Oct 1989 JP
1270593 Oct 1989 JP
1272108 Oct 1989 JP
1290222 Nov 1989 JP
1296673 Nov 1989 JP
1303770 Dec 1989 JP
1305894 Dec 1989 JP
1313927 Dec 1989 JP
2012814 Jan 1990 JP
2014513 Jan 1990 JP
2017634 Jan 1990 JP
2063115 Mar 1990 JP
2074029 Mar 1990 JP
2074587 Mar 1990 JP
2106822 Apr 1990 JP
2129913 May 1990 JP
2162717 Jun 1990 JP
2172895 Jul 1990 JP
2196092 Aug 1990 JP
2203517 Aug 1990 JP
2230690 Sep 1990 JP
2230722 Sep 1990 JP
02-246161 Oct 1990 JP
2264491 Oct 1990 JP
2283084 Nov 1990 JP
2304916 Dec 1990 JP
3019211 Jan 1991 JP
3022569 Jan 1991 JP
3023294 Jan 1991 JP
3023299 Jan 1991 JP
3044967 Feb 1991 JP
3048421 Mar 1991 JP
3070124 Mar 1991 JP
3185716 Aug 1991 JP
3208885 Sep 1991 JP
3234025 Oct 1991 JP
3286522 Dec 1991 JP
3286531 Dec 1991 JP
4031391 Feb 1992 JP
4031396 Feb 1992 JP
4100292 Apr 1992 JP
4111418 Apr 1992 JP
4132214 May 1992 JP
4132681 May 1992 JP
4151822 May 1992 JP
4162418 Jun 1992 JP
4175299 Jun 1992 JP
4186824 Jul 1992 JP
4212411 Aug 1992 JP
4260696 Sep 1992 JP
4273120 Sep 1992 JP
4285167 Oct 1992 JP
4291916 Oct 1992 JP
4325500 Nov 1992 JP
4328874 Nov 1992 JP
5029228 Feb 1993 JP
5047665 Feb 1993 JP
5047668 Feb 1993 JP
5074717 Mar 1993 JP
5074724 Mar 1993 JP
5102189 Apr 1993 JP
5047666 Jun 1993 JP
5160152 Jun 1993 JP
5175143 Jul 1993 JP
5175145 Jul 1993 JP
5182906 Jul 1993 JP
5186295 Jul 1993 JP
5206036 Aug 1993 JP
5234899 Sep 1993 JP
5235047 Sep 1993 JP
5251339 Sep 1993 JP
5270997 Oct 1993 JP
5283336 Oct 1993 JP
5291152 Nov 1993 JP
5304334 Nov 1993 JP
5343327 Dec 1993 JP
5343685 Dec 1993 JP
6045606 Feb 1994 JP
6132236 May 1994 JP
6177381 Jun 1994 JP
6196809 Jul 1994 JP
6222388 Aug 1994 JP
6224138 Aug 1994 JP
6230421 Aug 1994 JP
6252057 Sep 1994 JP
6291048 Oct 1994 JP
7070752 Mar 1995 JP
7086269 Mar 1995 JP
8181076 Jul 1996 JP
8245291 Sep 1996 JP
8264530 Oct 1996 JP
9260786 Oct 1997 JP
9293681 Nov 1997 JP
10188840 Jul 1998 JP
10190128 Jul 1998 JP
10-308283 Nov 1998 JP
11269652 Oct 1999 JP
2000-031387 Jan 2000 JP
2000-058777 Feb 2000 JP
2000068072 Mar 2000 JP
2000087029 Mar 2000 JP
2000138094 May 2000 JP
2000212752 Aug 2000 JP
2000218445 Aug 2000 JP
2000319772 Nov 2000 JP
2000340883 Dec 2000 JP
2000353666 Dec 2000 JP
2001020075 Jan 2001 JP
200162244 Mar 2001 JP
2001-172767 Jun 2001 JP
2001152339 Jun 2001 JP
2001189312 Jul 2001 JP
2001-220294 Aug 2001 JP
2001217206 Aug 2001 JP
2001220287 Aug 2001 JP
2001-254181 Sep 2001 JP
2001240972 Sep 2001 JP
2001284042 Oct 2001 JP
2001303251 Oct 2001 JP
2001328900 Nov 2001 JP
9002216 Mar 1990 WO
9110510 Jul 1991 WO
9302110 Feb 1993 WO
9617107 Jun 1996 WO
9618756 Jun 1996 WO
9806889 Feb 1998 WO
9851838 Nov 1998 WO
9901595 Jan 1999 WO
9913504 Mar 1999 WO
9929924 Jun 1999 WO
9941423 Aug 1999 WO
9965064 Dec 1999 WO
0011721 Mar 2000 WO
0015865 Mar 2000 WO
0015881 Mar 2000 WO
0016377 Mar 2000 WO
0054320 Sep 2000 WO
0063957 Oct 2000 WO
0079019 Dec 2000 WO
0079576 Dec 2000 WO
0115220 Mar 2001 WO
0117692 Mar 2001 WO
0127346 Apr 2001 WO
0127347 Apr 2001 WO
0129280 Apr 2001 WO
0129891 Apr 2001 WO
0129893 Apr 2001 WO
0136702 May 2001 WO
0140541 Jun 2001 WO
0166832 Sep 2001 WO
0208488 Jan 2002 WO
0245871 Jun 2002 WO
0323835 Mar 2003 WO
Non-Patent Literature Citations (50)
Entry
Notice of Allowance for U.S. Appl. No. 14/152,730 dated Jun. 9, 2016.
“Applications of Integrated processing”, Solid State Technology, US, Cowan Pub., vol. 37, No. 12 (Dec. 1, 1994), pp. 45-47.
Bader, et al. “Integrated Processing Equipment”, Solid State Technology, Cowan Pub., vol. 33, No. 5 (May 1, 1990), pp. 149-154.
Bedair, S.M. “Atomic layer epitaxy deposition processes”, J. Vac. Sci. Techol. 12(1) (Jan./Feb. 1994).
Choi, et al. “Stability of TiB.sub.2 as a Diffusion Barrier on Silicon”, J. Electrochem. Soc. 138(10) (Oct. 1991), pp. 3062-3067.
Choi, et al. “The effect of annealing on resistivity of low pressure chemical vapor deposited titanium diboride”, J. Appl. Phys. 69(11) (Jun. 1, 1991), pp. 7853-7861.
Eisenbraum, et al. “Atomic Layer Deposition (ALD) of Tantalum-based materials for zero thickness copper barrier applications,” Proceedings of the IEEE 2001 International Interconnect Technology Conference (Cat. No. 01EX461) 2001.
Elers, et al. “NbCl.sub.5 as a precursor in atomic layer epitaxy”, Appl. Surf. Sci., vol. 82/83 (1994), pp. 468-474.
George, et al. “Atomic layer controlled deposition of SiO.sub.2 and Al.sub.2O.sub.3 using ABAB . . . binary reaction sequence chemistry”, Appl. Surf. Sci., vol. 82/83 (1994), pp. 460-467.
George, et al. “Surface Chemistry for Atomic Layer Growth”, J. Phys. Chem., vol. 100 (1996), pp. 13121-13131.
Hultman, et al. “Review of the thermal and mechanical stability of TiN-based thin films”, Zeitschrift Fur Metallkunde, 90(10) (Oct. 1999), pp. 803-813.
IBM Tech. Disc. Bull. Knowledge-Based Dynamic Scheduler in Distributed Computer Control, (Jun. 1990), pp. 80-84.
IBM Tech. Disc. Bull. “Multiprocessor and Multi-tasking Architecture for Tool Control of the Advanced via Inspection Tools” (May 1992), pp. 190-191.
Jeong, et al. “Plasma-assisted Atomic Layer Growth of High-Quality Aluminum Oxide Thin Films,” Jpn. J. Appl. Phys. 1, Regul. Pap. Short Notes, vol. 40, No. 1, Jan. 2001.
Jeong, et al., “Growth and Characterization of Aluminum Oxide Al.sub.2O.sub.3 Thin Films by Plasma-assisted Atomic Layer ontrolled Deposition,” J. Korean Inst. Met. Mater., vol. 38, No. 10, Oct. 2000.
Juppo, et al., “Deposition of Copper Films by an Alternate Supply of CuCl and Zn,” Journal of Vacuum Science & Technology, vol. 15, No. 4 (Jul. 1997), pp. 2330-2333.
Kitigawa, et al. “Hydrogen-mediated low-temperature epitaxy of Si in plasma-enhanced chemical vapor deposition”, Applied Surface Science (2000), pp. 30-34.
Klaus, et al. “Atomic Layer Deposition of SiO.sub.2 Using Catalyzed and Uncatalyzed Self-Limiting Surface Reactions”, Surface Review & Letters, vol. 6, Nos. 3&4 (1999), pp. 435-448.
Klaus, et al. “Atomically controlled growth of tungsten and tungsten nitride using sequential surface reactions”. Appl. Surf. Sci., vol. 162-163 (Jul. 1999), pp. 479-491.
Lee, C. “The Preparation of Titanium-Based Thin Film by CVD Using Titanium Chlorides as Precursors”, Chemical Vapor Deposition, vol. 5, No. 2, (Mar. 1999), pp. 69-73.
Lee, et al. “Pulsed nucleation for ultra-high aspect ratio tungsten plugfill”, Novellus Systems, Inc. (2001), pp. 1-2.
Martensson, et al. “Atomic Layer Epitaxy of Copper on Tantalum”, Chemical Vapor Deposition, 3(1) (Feb. 1, 1997), pp. 45-50.
Martensson, et al. “Atomic Layer Epitaxy of Copper, Growth & Selectivity in the Cu (II)-2,2,6,6-Tetramethyl-3, 5-Heptanedionate/H.sub.2 Process”, J. Electrochem. Soc. ,145(8) (Aug. 1998), pp. 2926-2931.
Martensson, et al. “Cu(THD).sub.2 as Copper Source in Atomic Layer Epitaxy” , Electrochemical Society Proceedings vol. 97-25, (1998), pp. 1529-1536.
Maydan, et al. “Cluster Tools for Fabrication of Advanced devices,” Jap. J. of Applied Physics, Extended Abstracts, 22nd Conference Solid State Devices and Materials (1990), pp. 849-852 XP000178141.
McGeachin, S., “Synthesis and properties of some .beta.-diketimines derived from acetylacetone, and their metal ,complexes”, Canadian J. of Chemistry, vol. 46 (1968), pp. 1903-1912.
Min, et al. “Atomic layer deposition of TiN thin films by sequential introduction of Ti precursor and NH.sub.3”, Symp.: Advanced Interconnects and Contact Materials and Processes for Future Integrated Circuits (Apr. 13-16, 1998), pp. 337-342.
Min, et al. “Chemical Vapor Deposition of Ti—Si—N Films with Alternating Source Supply”, Mat., Res. Soc. Symp. Proc., vol. 564 (Apr. 5, 1999), pp. 207-210.
Min, et al. “Metal-Organic Atomic-Layer Deposition of Titanium-Silicon-Nitride Films”, Applied Physics Letters, American Inst. of Physics, vol. 75(11) (Sep. 13, 1999).
Niinisto, et al. “Synthesis of oxide thin films and overlayers by atomic layer epitaxy for advanced applications”, Mat. Sci. & Eng., vol. B41 (1996), pp. 23-29.
Ohba, et al. “Thermal Decomposition of Methylhydrazine and Deposition Properties of CVD TiN Thin Films”, Conference Proceedings, Advanced Metallization for ULSI Applications in 1993 (1994), pp. 143-149.
Paranjpe, et al. “Atomic Layer Deposition of AlO.sub.x for Thin Film Head Gap Applications,” J. Elec. Soc., vol. 148, No. 9 Sep. 2001 pp. G465-G471.
Ritala, et al. “Atomic Layer Epitaxy Growth of TiN Thin Films”, J. Electrochem. Soc., 142(8) (Aug. 1995), pp. 2731-2737.
Ritala, et al. “Perfectly conformal TiN and Al.sub.2O.sub.3 films deposited by atomic layer deposition”, Chemical Vapor Deposition, vol. 5(1) (Jan. 1999), pp. 7-9.
Rossnagel, et al. “Plasma-enhanced Atomic Layer Deposition of Ta and Ti for Interconnect Diffusion Barriers,” J. Vacuum Sci. & Tech. B., vol. 18, No. 4 (Jul. 2000), pp. 2016-2020.
Scheper, et al. “Low-temperature deposition of titanium nitride films from dialkylhydrazine-based precursors”, Materials Science in Semiconductor Processing 2 (1999), pp. 149-157.
Solanki, et al. “Atomic Layer deposition of Copper Seed Layers”, Electrochemical and Solid State Letters, 3(10) (2000), pp. 479-480.
Suzuki, et al. “A 0.2-.mu.m contact filing by 450.degree. C.-hydrazine-reduced TiN film with low resistivity”, IEDM 92-979, pp. 11.8.1-11.8.3.
Suzuki, et al. “LPCVD-TiN Using Hydrazine and TiCl.sub.4”, VMIC Conference (Jun. 8-9, 1993), pp. 418-423.
Wise, et al. “Diethyldiethoxysilane as a new precursor for SiO.sub.2 growth on silicon”, Mat. Res. Soc. Symp. Proc., vol. 334 (1994), pp. 37-43.
Yamaga, et al. “Atomic layer epitaxy of ZnS by a new gas supplying system in a low-pressure metalorganic vapor phase epitaxy”, J. of Crystal Growth 117 (1992), pp. 152-155.
Yamaguchi, et al. “Atomic-layer chemical-vapor-deposition of silicon dioxide films with extremely low hydrogen content”, Appl. Surf. Sci., vol. 130-132 (1998) , pp. 202-207.
European Search Report dated Sep. 23, 2005 from European Application No. 03257169.7.
Office Action for U.S. Appl. No. 13/012,341 dated Jul. 17, 2012.
Final Office Action for U.S. Appl. No. 13/012,341 dated Nov. 19, 2012.
Office Action for U.S. Appl. No. 13/012,341 dated May 14, 2013.
Final Office Action for U.S. Appl. No. 13/012,341 dated Sep. 10, 2013.
Office Action for U.S. Appl. No. 10/993,924 dated Mar. 29, 2017.
Office Action for U.S. Appl. No. 10/016,300 dated Jun. 20, 2003.
Final Office Action for U.S. Appl. No. 10/016,300 dated Dec. 17, 2003.
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