1. Field of the Invention
The present invention relates generally to the field of semiconductors, particularly to manufacturing methods for fabricating semiconductor devices, and more particularly to the Back-End-Of-Line (BEOL) semiconductor manufacturing process using via first dual damascene processes.
2. Description of the Prior Art
The semiconductor manufacturing process, when likened to an assembly line, includes two major components, namely the Front-End-of-Line (FEOL) which includes the multilayer process of the actual forming of semiconductor devices (transistors, etc.) on a semiconductor substrate, and the Back-End-Of-Line (BEOL) which includes the metallization after the semiconductor devices have been formed. Like all electronic devices, semiconductor devices in a microchip such as an integrated circuit (IC) need to be electronically connected through wiring. In an integrated circuit, such wiring is done through multilayer metallization on top of the multilayered semiconductor devices formed on the semiconductor substrate. The complexity of this wiring becomes immediately appreciable once one realizes that there are usually hundreds of millions or more semiconductor devices (transistors in particular) formed on a single IC, and all these semiconductor devices need to be properly connected. This is accomplished by multilayer metallization, with each metallization layer designated as Metal 1, Metal 2, so on, where Metal 1 is the metallization layer closest to the underlying semiconductor devices to provide local connections among neighboring devices, and other metallization layers provide increasingly global connections from Metal 2 to the top metallization layer. Each metallization layer consists of a grid of metal lines sandwiched between dielectric layers for electrical integrity. Modern semiconductor manufacturing process can involve six or more metallization layers.
Although in the early years of semiconductor industry BEOL was generally less important than FEOL, the recent advancements have changed that equation. Microchip interconnect technology has become a critical challenge for future IC advancements due to the increasing difficulties to reduce signal propagation delay or interference caused by the increasingly dense interconnects. The problem is particularly acute considering that while an increase of metallization density means longer signal delays caused by the interconnects, a corresponding increase of transistor density means shorter signal traveling time between local semiconductor devices, making metallization increasingly a bottleneck in enhancing IC performance.
Enhancements in integrated circuit (IC) density and performance as predicted by Moore's Law have fueled the semiconductor industry and resultant Information Revolution for over 40 years. The fabrication of deep submicron Ultra-Large Scale Integrated (ULSI) circuits requires long interconnects having small contacts and small cross-sections. In the past generation of semiconductor manufacturing process technology, aluminum (Al) and Al alloys have been used as conventional chip wiring materials while tungsten (W) has been used as contact plug between metal layers. The newer generation of the semiconductor manufacturing process technology has made it necessary to replace the Al technology with a technology based on a different metal. The introduction of copper (Cu) metallization served as an enabler for aggressive interconnects scaling due to its lower resistivity as compared with traditional Al metallization as well as improved reliability (such as less electromigration) and generally a reduced number of steps for fabrication.
Developing along with the transition from Al to Cu has been the process of dual damascene etching. Unlike single damascene, dual damascene scheme forms vias and trenches for metal interconnect simultaneously. There are a number of different dual damascene schemes known and used. One such scheme is shown in
The result of formation of the vias and trenches on the wafer 10 are both horizontal and vertical via chains as shown in
In
In
In
In
Finally, in
The undercut itself is a problem because it causes problem for the barrier layer deposition and hence prevents Cu from properly bonding to the via 12 sidewalls 32. This problem is shown in
One aspect of the present invention is directed to a method of minimizing undercut of a hard mask in an integrated circuit (IC) structure including steps of providing an IC structure having a substrate, a interlayer dielectric layer, and a hard mask, forming a via in said IC structure, and depositing an organic planarizing layer (OPL) over the IC structure such that it fills the vias formed therein. The method also includes steps of forming a masking structure layer over the OPL, forming an opening in the masking structure that has a critical dimension (CD) smaller than an opening design dimension, anisotropic etching the OPL such that sidewall of the via remains covered with the OPL while forming a trench, and removing any remaining OPL on the sidewalls and trench, wherein the undercut of the sidewalls with respect to the hard mask is minimized by the covering of OPL during the anisotropic etching process.
The present invention will now be described in more complete detail, with frequent reference being made to the figures identified below.
a is a schematic representation of an IC showing a via structure formed using known techniques following further deposition OPL, OLO, anti-reflective layers, lithography of a photo resist layer and finish the dual damascene photo masking;
b is a schematic representation of the IC of
c is a schematic representation of a via and trench structure formed using known techniques and having a hard mask undercut caused by removal of the damaged layer by dilute hydrogen fluoride (DHF) clean shown in
d is a schematic representation of a via and trench structure showing the problem area for barrier metallization;
a is a schematic view of an IC undergoing a first step in a method of the present invention with the CD decreased by a taper formed in the OLO layer.
a is a schematic view of an IC undergoing a second step in a method of the present invention with the CD decreased by a taper formed in the OLO layer;
As described above with reference to a known dual damascene process, via sidewalls are damaged during a via strip step, and then are further damaged by processing steps including the trench etch, etc. To minimize this damage, one aspect of the present invention is directed to a scheme which protects the sidewalls during the trench reactive ion etch (RIE) process, in a via first dual damascene process.
In one aspect of the present invention, an etch sequence is used on masking structure for example an oxide-like over-layer (OLO) and an OPL integration scheme where the via sidewalls closest to the trench are protected by the OPL during OPL etch, an oxide hard mask open and main etches to avoid any unnecessary exposure to the sidewalls. In addition it has been found that this process does not affect the CD of trench only structures, having no via sidewalls to be concerned with.
The effect of this shrinking the CD of the opening 23, is shown in
There are a variety of methods for changing the CD of the opening, such that the OPL layer 22 is not etched to expose the sidewalls 32 of the via 12. One method utilizing the IC manufacturing equipment is direct current DC superposition during the reactive-ion etch (RIE) process. In this process the voltage VDC applied to one of the electrodes during the RIE process is varied to change the CD. The increase in VDC causes an increase in the plasma density within the reaction vessel. The change in plasma density helps to stimulate the polymerization chemistry while at the same time the plasma potential decreases which reduces the ion energy available for the reactive ion etch.
In one non-limiting example the CD was decreased from 145 to 118 to 100 nm by changing the VDC from 0 to 500 to 750 VDC. Thus in an instance where the design dimensions is 140 nm application of a 750VDC superposition during the RIE process would easily result in a reduction of the CD by approximately 32%
Another method of changing the CD is to change an amount of CHF3 used during the RIE process. In one embodiment, this is achieved by adjusting the proportion of polymerizing gases used in the plasma. It has been observed that as the ratio of CHF3 to CF4 is increased, more sidewall polymer is generated which decreases the size of the opening.
In one experiment, where all other parameters where kept constant, varying amounts of CF4/CHF3 were used. Initially, mixture of 150/0 CF4/CHF3 SCCM was used. Subsequently a mixture of 150/20 CF4/CHF3 SCCM was used. Finally a mixture of 150/40 CF4/CHF3 SCCM was used. Measurements were made at a total of nine locations in each test. The results were as follows.
Accordingly, by adding more CHF3 the size of the CD can be reduced. Those of skill in the art will appreciate that other combinations of polymerizing gasses may also be used including but not limited to C4F8/Ar, CF4/CH2F2/Ar, CF4/CHF3/Ar, and others, also the exact combination of gasses may vary depending upon the material of the OPL layer 22.
Alternatively, as shown in
The effect of this tapering of the oxide-like over layer 24, is shown in
Next, as shown in
In
By using such a scheme for forming the vias 12 and trenches 34 without damaging the sidewalls of the vias, one may believe that in a trench only portion of the IC 10, the dimension of such a trench might be reduced. This might be expected because the CD of the trench would appear to have been reduced by, for example, 20% using the preceding processes. However, experience shows that following the OLO etch shown in
This increase in trench size in the trench only portion of the IC 10 through the dilute HF clean is another portion of the equation in regulating the changes in CD following the initial reduction described above to protect the sidewalls of the trench. Using the two similar processes described above where the etching is done with a combination of CF4/CHF3 in a ratio of 150/x sccm, the damage to the sidewalls, which is subsequently removed as shown in
By the foregoing example, the use of the CHF3 in the etching can be used first to reduce the size of the CD to prevent removal of all of the OPL layer from the via sidewall and thus reduce the damage to the sidewalls initially. Finally the damage layer in trench only structures are removed through cleaning using dilute HF which compensates for the initial reduction in the CD in the trench only portion of the IC.
The above description, including the specification and drawings, is illustrative and not restrictive. Many variations of the invention will become apparent to those of skill in the art upon review of this disclosure. Various features and aspects of the above-described disclosure may be used individually or jointly. Further, the present disclosure can be utilized in any number of environments and applications beyond those described herein without departing from the broader spirit and scope of the specification. The scope of the invention should, therefore, be determined not with reference to the above description, but instead should be determined with reference to the appended claims along with their full scope of equivalents. In addition, it will be recognized that the terms “comprising,” “including,” and “having,” as used herein, are specifically intended to be read as open-ended terms of art. The term “or” as used herein is not a logic operator in an exclusive sense unless explicitly described as such.