This description relates to semiconductor devices and related assemblies. More specifically, this description relates to preventing metallization oxidation in semiconductor devices and/or semiconductor assemblies.
Semiconductor devices, which can be included in packages and/or module assemblies, can include metallization layers that are formed during semiconductor processing. Such metallization layers can be used within a semiconductor device to route supply power busses and to form signal traces, which can be referred to as wires, to conduct signals for operation of circuitry included in the semiconductor device (e.g., active circuitry). At least some portions of these metallization layers can be disposed within, and protected by other layers (e.g., thin films) of the semiconductor device, such as dielectric layers and/or passivation layers. These dielectric and/or passivation layers can electrically isolate different metallization layers, or portions of metallization layers from each other, as well as from other elements of the circuitry of the semiconductor device.
Other portions of such metallization layers are used for making electrical connections external to the semiconductor device and, as such, are typically exposed (e.g., to an ambient environment through a passivation layer) to facilitate establishing such electrical connections. Similarly, apparatus used for producing semiconductor device assemblies, such as direct-bonded-metal substrates, can also include exposed metallization layers, which can be used for defining, e.g., electrical connections to an associated semiconductor device. These exposed metallization layers, or exposed portions of metallization layers, can be subject to corrosion (e.g., oxidation or otherwise) as a result of exposure to an ambient environment (e.g., air), and such corrosion can inhibit formation of low resistance electrical connections to the exposed metallization.
Various approaches have been implemented to prevent and/or remove such corrosion, including deposition of protective layers and/or performing cleaning operations. For instance, some current approaches include forming a thin protective layer on the exposed metallization, such as a polymer monolayer or a thin metal-oxide layer (deposited using atomic-layer deposition). Some current approaches also include performing a cleaning process, such as a plasma cleaning process, to remove corrosion and/or remove an applied protective layer just prior to forming electrical connections. These approaches, however, have certain drawbacks such as complexity, cost, and integration with other manufacturing operations, as well as potentially causing cross contamination and/or reducing electrical connection quality (e.g., increasing electrical resistance, reducing wire bond quality, etc.) if not completely removed or broken through to the underlying metallization.
In some aspects, the techniques described herein relate to an electronic device including: a substrate; a metallization layer, the metallization layer having: a first surface disposed on the substrate; a second surface opposite the first surface; and a corrosion-prevention implant layer disposed in the metallization layer, the corrosion-prevention implant layer extending from the second surface to a depth from the second surface in the metallization layer, the depth being less than a thickness of the metallization layer; and an electrical connector coupled with the second surface.
In some aspects, the techniques described herein relate to an electronic device, wherein the substrate includes a semiconductor device.
In some aspects, the techniques described herein relate to an electronic device, wherein: the substrate includes a ceramic substrate; and the metallization layer is direct-bonded to the ceramic substrate.
In some aspects, the techniques described herein relate to an electronic device, wherein the metallization layer includes a copper metallization layer.
In some aspects, the techniques described herein relate to an electronic device, wherein the metallization layer includes one of an aluminum metallization layer, an aluminum-copper metallization layer, a titanium-nickel-copper metallization layer, or a titanium-nickel- silver metallization layer.
In some aspects, the techniques described herein relate to an electronic device, wherein the corrosion-prevention implant layer includes one of an aluminum implant layer, a magnesium implant layer, or a nitrogen implant layer.
In some aspects, the techniques described herein relate to an electronic device, wherein the electrical connector includes one of a conductive clip, or a bond wire.
In some aspects, the techniques described herein relate to an electronic device, wherein: the thickness of the metallization layer is greater than or equal to 2 micrometers; and the depth of the corrosion-prevention implant layer is less than or equal to 100 nanometers.
In some aspects, the techniques described herein relate to an electronic device, wherein the depth of the corrosion-prevention implant layer is less than or equal to ten percent of the thickness of the metallization layer.
In some aspects, the techniques described herein relate to an electronic device, wherein the corrosion-prevention implant layer is: disposed in a first portion of the metallization layer that is coupled with the electrical connector; and excluded from a second portion of the metallization layer, the second portion being different than the first portion.
In some aspects, the techniques described herein relate to a semiconductor device including: a semiconductor substrate; a metallization layer disposed on the semiconductor substrate; a passivation layer including an opening, the opening exposing a surface of a portion of the metallization layer; a corrosion-prevention implant layer disposed in the portion of the metallization layer, the corrosion-prevention implant layer extending from the exposed surface to a depth from the exposed surface in the metallization layer, the depth being less than a thickness of the metallization layer; and an electrical connector coupled with the exposed surface.
In some aspects, the techniques described herein relate to a semiconductor device, wherein the metallization layer includes a copper metallization layer.
In some aspects, the techniques described herein relate to a semiconductor device, wherein the metallization layer includes one of an aluminum metallization layer, an aluminum-copper metallization layer, or a titanium-nickel-silver metallization layer.
In some aspects, the techniques described herein relate to a semiconductor device, wherein the corrosion-prevention implant layer includes one of an aluminum implant layer, a magnesium implant layer, or a nitrogen implant layer.
In some aspects, the techniques described herein relate to a semiconductor device, wherein the electrical connector includes one of a conductive clip, or a bond wire.
In some aspects, the techniques described herein relate to a semiconductor device, wherein: the thickness of the metallization layer is greater than or equal to 2 micrometers; and the depth of the corrosion-prevention implant layer is less than or equal to 100 nanometers.
In some aspects, the techniques described herein relate to a semiconductor device, wherein the depth of the corrosion-prevention implant layer is less than or equal to ten percent of the thickness of the metallization layer.
In some aspects, the techniques described herein relate to a method for producing an electronic device, the method including: forming a metallization layer on a substrate, the metallization layer having: a first surface disposed on the substrate; and a second surface opposite the first surface; forming a corrosion-prevention implant layer in the metallization layer, the corrosion-prevention implant layer extending from the second surface to a depth from the second surface in the metallization layer, the depth being less than a thickness of the metallization layer; and coupling an electrical connector with the second surface.
In some aspects, the techniques described herein relate to a method, wherein the corrosion-prevention implant layer includes one of an aluminum implant layer, a magnesium implant layer, or a nitrogen implant layer.
In some aspects, the techniques described herein relate to a method, wherein the electrical connector includes one of a conductive clip, or a bond wire.
In the drawings, which are not necessarily drawn to scale, like reference symbols may indicate like and/or similar components (elements, structures, etc.) in different views. The drawings illustrate generally, by way of example, but not by way of limitation, various implementations discussed in the present disclosure. Reference symbols show in one drawing may not be repeated for the same, and/or similar elements in related views. Reference symbols that are repeated in multiple drawings may not be specifically discussed with respect to each of those drawings, but are provided for context between related views. Also, not all like elements in the drawings are specifically referenced with a reference symbol when multiple instances of that element are illustrated.
This disclosure is directed to approaches preventing corrosion (oxidation, etc.) of metallization, e.g., exposed metallization, in semiconductor devices and/or semiconductor device assemblies, where such corrosion can cause poor electrical interconnection quality, such as due to poor wire bond or conductive clip adhesion. Thus, the approaches described herein facilitate producing electric interconnections for semiconductor devices and/or semiconductor device assemblies with good adhesion quality, and good conductivity (low resistance). The approaches described herein can also overcome at least some of the drawbacks of current approaches. For instance, the disclosed approaches can be less complex, can be easily integrated with existing manufacturing processes, may be lower cost than the current approaches, and can prevent cross-contamination.
In the approaches described herein, a corrosion-prevention implant process can be performed in an upper portion of metallization layers to inhibit corrosion of, or portions, of those metallization layers prior to forming electrical connections using, e.g., wire bonds and/or conductive clips. In some implementations, by way of example, aluminum (Al), magnesium (Mg) and/or nitrogen (N) (e.g., Al, Mg and/or N ions) can be implanted in an upper portions of a metallization layer, such as copper (Cu) metallization, aluminum-copper (AlCu) metallization, titanium-nickel-copper (TiNiCu) metallization, or titanium-nickel-silver (TiNiAg) metallization.
While generally described with respective to semiconductor devices, and semiconductor wafer fabrication, the approaches described herein can also be applied in conjunction with other components of semiconductor device assemblies, such as metallization layers included on a substrate, such a direct-bonded metal (DBM) substrate. In some implementations, metallization layers described herein can be referred to as top metallization layers, where additional metallization layers can be included with the top metallization layers in a stack, with dielectric layers and/or passivation layers being disposed between different layers of metallization, such as in a semiconductor device produced with a process that includes forming multiple layers of interconnected patterned metallization.
In this example, the metallization layer 120 can be a top level metallization layer that is patterned, e.g., using photolithography, where such patterning is appropriate for a given implementation. The metallization layer 120 can have a surface 121, which can be fully exposed, or can be partially exposed, such as through a passivation layer (not shown). In some implementations, the metallization layer 120 can include one or more of Cu, AlCu, TiNiCu, or TiNiAg, though other metals can be used.
In some implementations, the substrate 110 can be a ceramic substrate, such as included in a DBM substrate. For instance, the substrate 110 can include aluminum-oxide, or aluminum-nitride, though other materials can be used. In this example, the metallization layer 120 can be a patterned metallization layer (e.g., Cu layer) that is direct-bonded, e.g., using a sintering process, and can be used for electrical connection to a corresponding semiconductor device, e.g., using the electrical connector 130.
As further shown in
The corrosion-prevention implant 122 can be formed using an ion beam with an energy and ion dose that is appropriate for the particular implementation. For example, the implantation energy and dose can depend on the composition of the metallization layer 120 and/or on a process used to produce the metallization layer 120, e.g., sputtering, plating, etc. As one example, a Cu metallization layer that is formed using sputtering can be implanted with Al ions using an energy in a range of 10 of kiloelectron volts (keV) and 60 keV, and an implant dose in a range of 1×1015 cm-2 to 6×1015 cm−2.
In this example, the corrosion-prevention implant 122 is only formed in a portion of the metallization layer 120 along the surface 121, while other portions of the metallization layer 120 along the surface 121 exclude the corrosion-prevention implant 122. Such an approach could be used for bond pads of a semiconductor device, where the portions of the metallization layer 120 that exclude the corrosion-prevention implant 122 may be covered by passivation that blocks the corrosion-prevention implant 122 during its formation. In other implementations, the corrosion-prevention implant 122 can be formed over the entirety of the surface 121 of the metallization layer 120, such as for metallization of a redistribution layer for a chip-scale package, or for metallization included in a DBM substrate. Such an approach can be referred to as a blanket implant.
As illustrated in
In the apparatus 100, the electrical connector 130 is disposed on, and electrically coupled with the surface 121 corresponding with the portion of the metallization layer 120 including the corrosion-prevention implant 122. Depending on the particular implementation, the electrical connector 130 can be a wire bond, a conductive clip, a solder ball, and so forth, where the electrical connector 130 can facilitate electrical connection with the metallization layer 120 and/or the substrate 110. In such an arrangement, the corrosion-prevention implant 122, by preventing corrosion (oxidation, or otherwise) of the metallization layer 120, can facilitate a low resistance and mechanically robust connection between the metallization layer 120 and the electrical connector 130, while avoiding drawbacks of current approaches.
As compared with the corrosion-prevention implant 122 of the apparatus 100, the metallization layer 220 includes a corrosion-prevention implant 222 that is disposed (e.g., using a blanket implant) in the metallization layer 220 along an entirety of a surface 221 (e.g., using a blanket implant). In this example, the corrosion-prevention implant 222 is formed through the surface 221 of the metallization layer 220. As with the corrosion-prevention implant 122, in implementations, the corrosion-prevention implant 222 includes one or more materials that inhibit corrosion of the metallic layer 220. The particular materials included in the corrosion-prevention implant 222 can depend, at least in part, on the composition of the metallization layer 220. For instance, in some implementations, the metallization layer 220 can include one or more of Cu, AlCu, TiNiCu, or TiNiAg, though other metals can be used. In some implementations, the corrosion-prevention implant 222 can include Al, Mg and/or N, e.g., implanted as ions. In some implementations, the corrosion-prevention implant 222 can include other substances.
Also, as with the corrosion-prevention implant 122, the corrosion-prevention implant 222 can be formed using an ion beam with an energy and ion dose that is appropriate for the particular implementation. For example, the implantation energy and dose can depend on the composition of the metallization layer 220 and/or on a process used to produce the metallization layer 220, e.g., sputtering, plating, etc. In some implementations, the metallization layer 220 can have a thickness consistent with the ranges described with respect to the metallization layer 120, and the corrosion-prevention implant 222 can have a depth consistent with ranges described above with respect to the corrosion-prevention implant 122.
The metallization layer 320 includes a corrosion-prevention implant 322 that is disposed in the metallization layer 320 along only a portion of a surface 321 and is excluded from other portions of the metallization layer 320, such as with the corrosion-prevention implant 122 in the metallization layer 120 of
Also, as with the corrosion-prevention implant 122 and the corrosion-prevention implant 222, the corrosion-prevention implant 322 can be formed using an ion beam with an energy and ion dose that is appropriate for the particular implementation. For example, the implantation energy and dose can depend on the composition of the metallization layer 320 and/or on a process used to produce the metallization layer 320, e.g., sputtering, plating, etc. In some implementations, the metallization layer 320 can have a thickness consistent with the ranges described with respect to the metallization layer 120, and the corrosion-prevention implant 322 can have a depth consistent with ranges described above with respect to the corrosion-prevention implant 122.
As shown in
As with the corrosion-prevention implants of
Also, as with the corrosion-prevention implants of
Referring to
At block 530, the method 500 includes performing a corrosion-prevention implant on the metallization layer of block 520, which can be a blanket implant, such as described herein. At block 540, the method 500 includes forming a passivation layer, such as the passivation layer 450 of
Referring to
At block 650, the method 600 includes performing a corrosion-prevention implant on the metallization layer of block 640. At block 660, the method includes performing a back grind and back metal process, such as described with respect to
It will be understood that, in the foregoing description, when an element, such as a layer, a region, or a substrate, is referred to as being on, connected to, electrically connected to, coupled to, or electrically coupled to another element, it may be directly on, connected or coupled to the other element, or one or more intervening elements may be present. In contrast, when an element is referred to as being directly on, directly connected to or directly coupled to another element or layer, there are no intervening elements or layers present. Although the terms directly on, directly connected to, or directly coupled to may not be used throughout the detailed description, elements that are shown as being directly on, directly connected or directly coupled can be referred to as such. The claims of the application may be amended to recite exemplary relationships described in the specification or shown in the figures.
As used in this specification, a singular form may, unless definitely indicating a particular case in terms of the context, include a plural form. Spatially relative terms (e.g., over, above, upper, under, beneath, below, lower, top, bottom, and so forth) are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. In some implementations, the relative terms above and below can, respectively, include vertically above and vertically below. In some implementations, the term adjacent can include laterally adjacent to or horizontally adjacent to.
Some implementations may be implemented using various semiconductor processing and/or packaging techniques. Some implementations may be implemented using various types of semiconductor processing techniques associated with semiconductor substrates including, but not limited to, for example, Silicon (Si), Silicon Carbide (SiC), Gallium Arsenide (GaAs), Gallium Nitride (GaN), and/or so forth. Some implementations may be implemented using various types of semiconductor assemblies, such as assemblies include substrates including, but not limited to, direct-bonded metal (DBM) substrates.
While certain features of the described implementations have been illustrated as described herein, many modifications, substitutions, changes and equivalents will now occur to those skilled in the art. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes as fall within the scope of the implementations. It should be understood that they have been presented by way of example only, not limitation, and various changes in form and details may be made. Any portion of the apparatus and/or methods described herein may be combined in any combination, except mutually exclusive combinations. The implementations described herein can include various combinations and/or sub-combinations of the functions, components and/or features of the different implementations described.
This application is a continuation application of U.S. application Ser. No. 17/658,232, filed on Apr. 6, 2022, entitled “OXIDATION AND CORROSION PREVENTION IN SEMICONDUCTOR DEVICES AND SEMICONDUCTOR DEVICE ASSEMBLIES”, which claims priority to and the benefit of U.S. Provisional Application No. 63/174,422, filed Apr. 13, 2021, entitled “SEMICONDUCTOR DEVICES AND METHODS”, the disclosures of which are incorporated by reference herein in their entireties.
Number | Date | Country | |
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63174422 | Apr 2021 | US |
Number | Date | Country | |
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Parent | 17658232 | Apr 2022 | US |
Child | 18787369 | US |