The present disclosure relates to a plasma processing apparatus and method; and, more particularly, to a plasma processing apparatus and method for generating plasma by using a microwave as a plasma source.
A semiconductor device such as a LSI (Large Scale Integrated Circuit) or the like is manufactured by performing a plurality of processes such as etching, CVD (Chemical Vapor Deposition), sputtering, and so forth on a semiconductor substrate (wafer) which is a target substrate to be processed. As for such processes as etching, CVD and sputtering, there is known a processing method of using plasma as an energy supply source. That is, there are known processing methods such as plasma etching, plasma CVD, plasma sputtering, and the like.
Here, a plasma processing apparatus using a microwave as a plasma generating source is disclosed in Japanese Patent Laid-open Publication No. 2005-100931 (Patent Document 1). According to the Patent Document 1, a tapered protruding portion or recess portion is formed on the bottom surface of a top plate (dielectric plate) installed in the plasma processing apparatus. An optimal resonance region of electric field is formed at the tapered protruding portion or recess portion on the bottom surface of the top plate by means of a microwave generated by a microwave generator, and stable plasma is generated in a chamber (processing vessel), whereby the aforementioned etching process or the like is performed.
In the plasma processing apparatus using the microwave as a plasma source, the introduced microwave forms a standing wave in the thickness direction of the dielectric plate, and by this standing wave, an electric field is generated inside the processing chamber, specifically, under the dielectric plate in the processing chamber. Here, a plasma igniting condition by the microwave, i.e., an application power for igniting the plasma or the like may be differed depending on electric field intensity inside the processing apparatus. The level of the electric field intensity varies depending on a distance between a holding table for holding the target substrate to be processed thereon and the dielectric plate. Here, in case that the holding table is fixed as in the Patent Document 1, even if plasma could be generated by setting up a certain plasma igniting condition under a preset condition, the electric field intensity inside the processing chamber would be changed under a condition different from the preset condition, for example, if a pressure inside the processing chamber is changed. In such case, there is a concern that plasma generation under the aforementioned certain plasma igniting condition cannot be achieved.
Meanwhile, the distance between the dielectric plate and the holding table suitable for generating the plasma is not always coincident with the distance between the dielectric plate and the holding table suitable for performing the plasma process. In this regard, it may not be reasonable to perform the plasma process under the plasma igniting condition all the time.
In view of the foregoing, the present disclosure provides a plasma processing apparatus capable of performing a plasma process appropriately, while improving plasma ignition property.
The present disclosure also provides a plasma processing method capable of performing a plasma process appropriately, while improving plasma ignition property.
In accordance with one aspect of the present invention, there is provided a plasma processing apparatus including: a processing chamber for performing therein a plasma process on a target substrate to be processed; a reactant gas supply unit for supplying a reactant gas for the plasma process into the processing chamber; a holding table disposed in the processing chamber, for holding thereon the target substrate; a microwave generator for generating a microwave for plasma excitation; a dielectric plate disposed at a position facing the holding table, for introducing the microwave into the processing chamber; a plasma igniting unit for carrying out plasma ignition in a state where an electric filed is generated inside the processing chamber by the introduced microwave, and then generating plasma within the processing chamber; and a control unit for performing control operations to alter a distance between the holding table and the dielectric plate to a first distance, to drive the plasma igniting unit, to alter the distance between the holding table and the dielectric plate to a second distance different from the first distance, and to carry out the plasma process on the target substrate.
By using this plasma processing apparatus, it is possible to perform the plasma ignition by setting the distance between the holding table and the dielectric plate to the first distance. By doing this, the plasma ignition can be easily carried out by selecting the distance at which electric field intensity increases as the first distance, so that plasma ignition property can be improved. Further, during the plasma process of the target substrate, the distance between the holding table and the dielectric plate is set to the second distance, which is appropriate for the plasma process, so that the plasma process of the target substrate can be carried out appropriately. As a result, the plasma ignition property can be improved, and the plasma process can be performed properly.
It is desirable that the control unit includes an elevating mechanism for altering the distance between the holding table and the dielectric plate by moving the holding table up and down.
It is more desirable that the control unit varies the first distance based on periodicity of a standing wave formed in the dielectric plate by the introduction of the microwave.
Further, the reactant gas supply unit may supply the reactant gas having dissociation property, and the control unit may make the second distance shorter than the first distance.
It is desirable that the plasma process performed on the target substrate by the control unit is an etching process for an oxide-based film.
Further, the reactant gas supply unit may supply the reactant gas not having dissociation property, and the control unit may make the second distance longer than the first distance.
Desirably, the plasma process performed on the target substrate by the control unit is an etching process for a polysilicon-based film.
In accordance with the other aspect of the present invention, there is provided a plasma processing method for performing a plasma process on a target substrate to be processed, the method including: holding the target substrate on a holding table installed in a processing chamber; generating a microwave for plasma excitation; generating an electric field in the processing chamber by introducing the microwave into the processing chamber via a dielectric plate disposed at a position facing the holding table; generating plasma in the processing chamber by igniting the plasma in a state where a distance between the holding table and the dielectric plate is set to a first distance and an electric field is generated in the processing chamber; and setting the distance between the holding table and the dielectric plate to a second distance different from the first distance after generating the plasma and performing the plasma process on the target substrate.
By employing this plasma processing method, it is possible to perform the plasma ignition by setting the distance between the holding table and the dielectric plate to the first distance. By doing this, the plasma ignition can be carried out by selecting the distance at which the electric field intensity increases as the first distance, so that plasma ignition property can be improved. Further, during the plasma process of the target substrate, the distance between the holding table and the dielectric plate is set to the second distance, which is appropriate for the plasma process, so that the plasma process can be carried out appropriately. As a result, the plasma excitation property can be improved, and the plasma process can be performed properly.
By using the above-stated plasma processing apparatus and plasma processing method, it is possible to perform the plasma ignition by setting the distance between the holding table and the dielectric plate to the first distance. By doing this, the plasma ignition can be carried out by selecting the distance at which the electric field intensity increases as the first distance, so that plasma ignition property can be improved. Further, during the plasma process of the target substrate, the distance between the holding table and the dielectric plate is set to the second distance, which is appropriate for the plasma process, so that the plasma process can be carried out appropriately. As a result, the plasma ignition property can be improved, and the plasma process can be performed properly.
The disclosure may best be understood by reference to the following description taken in conjunction with the following figures:
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
Referring to
The plasma processing apparatus 11 includes a vacuum pump (not shown), a gas exhaust pipe (not shown), and so forth, and is capable of setting the internal pressure of the processing chamber 12 to a preset pressure level such as a vacuum by depressurizing the processing chamber 2. The top portion of the processing chamber 12 is opened, and the processing chamber 12 is configured to be hermetically sealed by a sealing member (not shown) and the dielectric plate 16 disposed at the top portion of the processing chamber 12.
The dielectric plate 16 has a circular plate shape and is made of a dielectric material. The dielectric plate 16 is provided with a plurality of annular recess portions 34 depressed in tapered shapes on its bottom portion.
The plasma processing apparatus 11 is equipped with an elevating mechanism 18 serving as an elevating unit for elevating the holding table 14. The elevating mechanism 18 elevates the holding table 14 by moving a supporting column 19 installed at a bottom surface 33 of the holding table 14 up and down. By elevating the holding table 14 within a predetermined spatial range by means of the elevating mechanism 18, the distance between the holding table 14 and the dielectric plate 16 fixed by the processing chamber 12 or the like can be varied. Specifically, a distance L1 between the top surface 32 of the semiconductor substrate W held on the holding table 14 and the bottom surface 31 of the dielectric plate 16 can be altered.
The microwave generator 15 is made up of a high frequency power supply (not shown) and the like. Also connected to the holding table 14 is a high frequency power supply for supplying a bias voltage thereto. Further, installed inside the holding table 14 is a non-illustrated heater for heating the semiconductor substrate W up to a preset temperature condition during the plasma process.
The plasma processing apparatus 11 also includes a waveguide 21 for introducing the microwave generated by the microwave generator 15 into the processing apparatus; a wavelength shortening plate 22 for propagating the microwave; and a slot antenna 24 of a thin circular plate shape for introducing the microwave into the dielectric plate 16 from a plurality of slot holes 23. The waveguide 21 incorporates a microwave tuning unit 25 for tuning the microwave generated by the microwave generator 15 on its path from the microwave generator 15 to the wavelength shortening plate 22. Installed in the microwave tuning unit 25 are wavelength control units 26 having paths, the lengths of which are variable. The microwave is tuned by altering the lengths of the paths by the wavelength control units 26. Further, in
The microwave generated by the microwave generator 15 is propagated to the wavelength shortening plate 22 through the waveguide 21 and then is introduced into the dielectric plate 16 from the plurality of slot holes 23 provided at the slot antenna 24. At this time, the dielectric plate 16 vibrates in a vertical direction, i.e., either in a direction of an arrow A in
The intensity of the electric field generated under the dielectric plate 16 by the standing waves as described above has correlation with a gap between the semiconductor substrate W and the dielectric plate 16, i.e., the distance L1 between the top surface 32 of the semiconductor substrate W held on the holding table 14 and the bottom surface 31 of the dielectric plate 16. Specifically, the electric field intensity has a periodicity. For example, the electric field intensity increases for about every 30 mm of the distance L1 between the top surface 32 of the semiconductor substrate W and the bottom surface 31 of the dielectric plate 16.
Here, the control unit 20 incorporated in the plasma processing apparatus 11 performs control operations to alter the distance between the holding table 14 and the dielectric plate 16 to a first distance by using the elevating mechanism 18; to drive the plasma igniting unit; then to alter the distance between the holding table 14 and the dielectric plate 16 to a second distance different from the first distance by using the elevating mechanism 18; and to carry out the plasma process on the semiconductor substrate W.
Further, as for the detailed configuration of the plasma processing apparatus 11, about Ø 200 mm, for instance, is selected as a size of the holding table 14. Further, the variation range of the gap in the plasma processing apparatus 11, i.e., the movement range of the holding table 14 in the vertical direction is selected within a range where the distance from the bottom surface 35 of the processing chamber 12 ranges from about 115 to 135 mm within the range shown in
Hereinafter, a plasma processing method for the semiconductor substrate W in accordance with an embodiment of the present invention, which is performed by using the plasma processing apparatus 11 configured as described above, will be explained.
First, as described above, the semiconductor substrate W which is a target substrate to be processed is mounted on the holding table 14. Then, the inside of the processing chamber 12 is depressurized to a preset pressure level, and a reactant gas is supplied by the gas shower head 13.
Thereafter, a microwave for plasma excitation is generated by the microwave generator 15 and then is introduced into the processing chamber 12 via the dielectric plate 16. Here, standing waves are formed in the dielectric plate 16 in a vertical direction, so that an electric field is generated under the dielectric plate 16 inside the processing chamber 12.
Subsequently, by moving the holding table 14 up and down by means of the elevating mechanism 18, the distance between the holding table 14 and the dielectric plate 16 is altered. Such variation of the distance is carried out depending on distances selected so as to increase the electric field intensity based on given conditions, for example, the internal pressure of the processing chamber 12, the kind of the reactant gas, the power of the microwave, and the like. This distance is defined as a first distance. In this case, it may be desirable to select the distance indicated by the points P1 to P9 at which the electric field intensity increases periodically under the condition illustrated in
Afterward, a preset power is applied by the plasma igniting unit to ignite plasma, thereby generating the plasma.
After generating the plasma, a plasma process is performed by altering the distance between the holding table 14 and the dielectric plate 16 so as to allow the semiconductor substrate W held on the holding table 14 to be processed properly based on the given conditions. This distance is defined as a second distance. That is, the plasma process of the semiconductor substrate W is performed by setting the distance between the holding table 14 and the dielectric plate 16 to the second distance suitable for the plasma process.
By setting up the process as described above, the plasma ignition can be carried out by setting the distance between the holding table 14 and the dielectric plate 16 to the first distance. In this way, the distance at which the electric field intensity increases can be selected as the first distance, so that the plasma ignition can be carried out readily. That is, since the plasma ignition can be carried out after increasing the margin of the plasma ignition, plasma ignition property can be improved. Moreover, in the plasma process of the semiconductor substrate W, the distance between the holding table 14 and the dielectric plate 16 is set to the second distance, so that the plasma process of the semiconductor substrate W can be performed after selecting the appropriate distance for the plasma process. Accordingly, the plasma process can be carried out properly. As a result, it becomes possible to ameliorate the plasma ignition property and carry out the plasma process appropriately.
Below, plasma ignition efficiency is shown in Table 1.
Table 1 shows success or failure in plasma ignition when the gap was varied while the microwave power applied for the plasma ignition was set to about 1700 W. As for conditions for the evaluation test shown in Table 1, a pressure was set to be about 20 mTorr; the reactant gas was set to “CF4/O2=105/9 sccm”, respectively; and a SiO2 dummy wafer was employed. In Table 1, the mark O stands for a success in plasma ignition, whereas the mark X indicates a failure in plasma ignition. Further, if plasma was not ignited within 5 seconds, it was regarded as failure. In addition, the first time in Table 1 indicates an experiment in which the gap was increased by about 2 mm from about 115 mm to 135 mm, and the second time indicates an experiment in which the gap was narrowed by about 2 mm from about 135 mm to 115 mm. As can be seen from Table 1, plasma ignition succeeds in all of the cases where the gap is about 115 mm, 117 mm, 133 mm and 135 mm. Accordingly, during the plasma ignition, it is desirable to select these gap values as the first distance.
As can be seen from
Further, the electric field intensity greatly changes for a gap difference of about 1 mm.
Here, when using a gas having dissociation property is used as the reactant gas necessary for the plasma process, it is desirable to make the second distance shorter than the first distance. That is, after generating the plasma by the plasma ignition, the gap between the holding table 14 and the dielectric plate 16 is narrowed, as illustrated in
For example, when C4F4 is selected as the reactant gas having the dissociation property, the C4F4 would be dissociated if it stays in the processing chamber 12 for a long time, resulting in generation of C2F4 in addition to CF3, CF2, CF, or the like. If such by-products are generated, there is a likelihood that etching selectivity for the semiconductor substrate W in the plasma process would be changed, for example, thus resulting in failure to carry out the plasma process properly. Further, the residence time of the reactant gas is calculated based on (pressure×volume)/(gas flow rate), and the dissociation degree of the reactant gas is calculated based on (residence time)×(electron density)×(electron temperature). As an example, etching of an oxide-based film of the semiconductor substrate W is performed by using the reactant gas having the dissociation property.
Further, when using a reactant gas not having dissociation property, it is desirable to make the second distance longer than the first distance. That is, after generating the plasma by the plasma ignition, the gap between the holding table 14 and the dielectric plate 16 is increased, as illustrated in
Here, a relationship between the gap and an etching rate is explained.
Referring to
Here, shown in electronographies of
Further, in the above-described embodiment, though the distance between the holding table and the dielectric plate is described to be varied by moving the holding table for holding the semiconductor substrate W thereon up and down, the present invention is not limited thereto. For example, the distance between the holding table and the dielectric plate can be altered by moving the dielectric plate up and down. Moreover, it may be also possible to change the distance between the holding table and the dielectric plate by setting up configuration in which both the holding table and the dielectric plate are movable up and down.
Furthermore, though the above-mentioned embodiment has been described for the case of performing the etching process by the plasma, the present invention is not limited thereto, but can be applied to a plasma CVD process, or the like.
The above description of the present invention is provided for the purpose of illustration, and it would be understood by those skilled in the art that various changes and modifications may be made without changing technical conception and essential features of the present invention. Thus, it is clear that the above-described embodiments are illustrative in all aspects and do not limit the present invention.
The scope of the present invention is defined by the following claims rather than by the detailed description of the embodiment. It shall be understood that all modifications and embodiments conceived from the meaning and scope of the claims and their equivalents are included in the scope of the present invention.
Number | Date | Country | Kind |
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2008-045023 | Feb 2008 | JP | national |