Patent Application
20120314281
The present invention relates to methods for producing a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a stress on the substrate, and in which there is arranged between the multilayer system and the substrate a layer of material, wherein the thickness thereof is dimensioned in such a way that the stress of the multilayer system is compensated for, and also to methods for producing a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a first multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a layer stress on the substrate, and which has a second multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts an opposite layer stress on the substrate and is arranged between the first multilayer system and the substrate.
In addition, the invention relates to reflective optical elements produced by these methods. Furthermore, the invention relates to a projection system and an illumination system and also to an EUV lithography apparatus comprising at least one reflective optical element of this type.
In EUV lithography apparatuses, reflective optical elements for the extreme ultraviolet (EUV) or soft X-ray wavelength range (e.g. wavelengths of between approximately 5 nm and 20 nm) such as, for instance photomasks or multilayer mirrors are used for the lithography of semiconductor components. Since EUV lithography apparatuses generally have a plurality of reflective optical elements, the latter have to have a highest possible reflectivity in order to ensure a sufficiently high total reflectivity. Since a plurality of reflective optical elements are usually arranged one behind another in an EUV lithography apparatus, even relatively minor impairments of the reflectivity for each individual reflective optical element already affect the total reflectivity within the EUV lithography apparatus to a relatively large extent.
Reflective optical elements for the EUV and soft wavelength range generally have multilayer systems. These are alternately applied layers of a material having a higher real part of the refractive index at the operating wavelength (also called spacers) and of a material having a lower real part of the refractive index at the operating wavelength (also called absorbers), wherein an absorber-spacer pair forms a stack or a period. This in a certain way simulates a crystal whose network planes correspond to the absorber layers at which Bragg reflection takes place. The thicknesses of the individual layers and also of the repeating stacks can be constant over the entire multilayer system, or else vary, depending on which reflection profile is intended to be achieved.
Within multilayer systems, as early as during the coating process a stress can build up which acts on the underlying substrate and deform it to such a great extent that the optical imaging at the corresponding reflective optical element is critically disturbed. The type of stress depends, inter alia, on the materials used as spacers and absorbers and the thickness ratios present within a stack or a period. A measure of this thickness ratio is defined as , the ratio of absorber layer thickness to total thickness of a period. The basic profile of the stress as a function of
is illustrated schematically for a multilayer system on the basis of molybdenum as absorber material and silicon as spacer material in
in the region of approximately 0.4 are used. A compressive stress is to be expected there. A tensile stress is to be expected at higher values of
. The concrete relationship between the stress in the multilayer system and the
value, that is to say in particular the gradient and the precise position of the zero crossing, in this case depends on the choice of the coating process and the respective coating parameters.
The relationship between stress and can be utilized to produce stress-reduced reflective optical elements. For this purpose, there is arranged between the substrate and the multilayer system optimized for a high reflectivity at the respective operating wavelength a further multilayer system, which is optimized in particular through the choice of an appropriate
for the purpose of as far as possible compensating for the stress of the highly reflective multilayer system or minimizing the total stress within the reflective optical element. However, it should be taken into consideration that in the case of the coating processes suitable for the production of reflective optical elements for the soft X-ray and extreme ultraviolet wavelength range, namely magnetron sputtering, ion-beam-assisted sputtering and electron beam evaporation, with conventional coating parameters, starting from a certain thickness, a crystallization of the respective layer occurs particularly in the case of the absorber layer. In the case of molybdenum, for example, said crystallization already occurs starting from a layer thickness of approximately 2 nm. The crystallite sizes increase as the layer thickness increases, which leads to an increase in the microroughness and hence the surface roughness. At the high
values necessary for the stress reduction, it is already possible to ascertain a roughening which in total, that is to say over the entire stress-reducing multilayer system, brings about an appreciable increase in the roughness at the surface of the stress-reducing multilayer system. Since this roughness also continues in the overlying highly reflective multilayer system, both the reflectivity and the optical imaging of the reflective optical element deteriorate. This deterioration is usually avoided by choosing the
of the stress-reducing multilayer system to be small enough to avoid a roughening, and in return providing a larger number of periods of the stress-reducing multilayer system in order to sufficiently compensate for the stress. However, this entails the disadvantage of a coating process having an increased time duration and hence also a greater risk of failure as a result of incorrect coating.
It is an object of the present invention to provide reflective optical elements for operating wavelengths in the soft X-ray and extreme ultraviolet wavelength range and a method for producing them in which both a stress reduction and a high reflectivity are achieved.
In a first aspect of the invention, this object is achieved by a method for producing a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a stress on the substrate, and in which there is arranged between the multilayer system and the substrate a layer of material, wherein the thickness thereof is dimensioned in such a way that the stress of the multilayer system is compensated for, wherein layer-forming particles having an energy of at least 40 eV are used for the deposition of the stress-compensating layer.
This object is also achieved by a method for producing a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a first multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a layer stress on the substrate, and which has a second multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts an opposite layer stress on the substrate and is arranged between the first multilayer system and the substrate, wherein layer-forming particles having an energy of at least 40 eV are used for the deposition of layers of the second multilayer system.
Particularly preferably, in the second multilayer system the layers of the material having a lower real part of the refractive index at the operating wavelength are deposited with the aid of layer-forming particles having an energy of at least 40 eV. In further preferred embodiments, all the layers of the second multilayer system are deposited with the aid of layer-forming particles having an energy of at least 40 eV.
Furthermore the said object is achieved by a method for producing a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a first multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a layer stress on the substrate, and which has a second multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts an opposite layer stress on the substrate and is arranged between the first multilayer system and the substrate, wherein an interlayer is deposited between the first multilayer system and the second multilayer system, wherein particles having an energy of at least 40 eV are used for depositing the interlayer or for smoothing the interlayer.
It has been found that through the coating by high-energy particles, a crystallization can be effectively prevented even in the case of relatively thick layers. Consequently, for the same thickness, it is possible to apply layers which have a lower surface roughness. In the case of stress-reducing multilayer systems, in particular, as a result higher values can be chosen and significantly lower numbers of periods suffice to sufficiently compensate for the stress of an overlying highly reflective multilayer system without having to accept losses in the reflectivity and the optical imaging properties. It may already be sufficient to apply only one stress-compensating layer by high-energy layer-forming particles. As a result, the coating process can be shortened and the probability of failure on account of defective coatings can be reduced.
The deposition of interlayers with the aid of layer-forming particles having an energy of 40 eV or interlayers that are smoothed with the aid of an ion beam permits existing coating processes to be altered with little outlay in order to provide reflective optical elements which have both low stress and a high reflectivity. In this case, the interlayer can also both be deposited with higher-energy layer-forming particles and be subsequently polished by an ion beam. The smooth or smoothed interlayer has the function of compensating for inhomogeneities in the surface of the underlying stress-reducing multilayer system and of thereby reducing the surface roughness.
In a further aspect of the invention, said object is achieved by a reflective optical element produced according to one of the methods mentioned. In particular, this object is achieved by reflective optical elements whose stress-compensating layer or in whose second multilayer system the layers of the material having a lower real part of the refractive index at the operating wavelength, that is to say the absorber layers, are amorphous. Preferably, the stress-compensating layer, the interlayer or the layers of the material having a lower real part of the refractive index at the operating wavelength of the second multilayer system have a surface roughness of less than 0.2 nm, preferably less than 0.15 nm. The surface roughness here and hereinafter is the so-called rms roughness (root-mean-squared roughness) which corresponds to the mean of the square deviations of the actual surface points from a center line corresponding to the ideally planar course of the surface. In this case, the surface roughness refers to a lateral spatial wavelength range which here and hereinafter corresponds to an area in the range of 0.01 μm×0.01 to 1000 μm×1000 μm.
In addition, said object is achieved by a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a layer stress on the substrate, wherein an amorphous layer of the material having a lower real part of the refractive index at the operating wavelength is arranged between the multilayer system and the substrate, wherein the layer thickness is dimensioned in such a way that the layer stress of the multilayer system is compensated for, wherein the layer has a surface roughness of less than 0.20 nm.
The object is furthermore achieved by a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a first multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a layer stress on the substrate, and which has a second multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts an opposite layer stress on the substrate and is arranged between the first multilayer system and the substrate, wherein an interlayer is arranged between the first multilayer system and the second multilayer system, said interlayer having a surface roughness of less than 0.20 nm.
Furthermore, this object is achieved by a reflective optical element for an operating wavelength in the soft X-ray and extreme ultraviolet wavelength range, in particular for use in an EUV lithography apparatus, which has a first multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts a layer stress on the substrate, and which has a second multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength on a substrate, which exerts an opposite layer stress on the substrate and is arranged between the first multilayer system and the substrate, wherein in the second multilayer system the layers of the material having a lower real part of the refractive index at the operating wavelength are amorphous; by such a reflective optical element wherein in the second multilayer system the layers of the material having a lower real part of the refractive index at the operating wavelength have a surface roughness of less than 0.20 nm; by such a reflective optical element wherein in the second multilayer system the ratio of the thickness of a layer of the material having a lower real part of the refractive index at the operating wavelength to the thickness of a period comprising a layer of the material having a lower real part and a layer of the material having a higher real part at the operating wavelength is greater than 0.75 and by such a reflective optical element wherein the number of periods comprising a layer of the material having a lower real part and a layer of the material having a higher real part at the operating wavelength in the second multilayer system is at most half as large as the number of periods in the first multilayer system.
In yet another aspect of the invention, said object is achieved by a projection system, in particular for an EUV lithography apparatus, comprising at least one of the reflective optical elements mentioned above, by an illumination system, in particular for an EUV lithography apparatus, comprising at least one of the reflective optical elements mentioned above, by a beam shaping system, in particular for an EUV lithography apparatus, comprising at least one of the reflective optical elements mentioned above, and also by an EUV lithography apparatus comprising at least one of the reflective optical elements mentioned above.
Advantageous configurations are found in the dependent claims.
The present invention will be explained in greater detail with reference to a preferred exemplary embodiment. For this purpose:
a-d schematically show the construction of different embodiments of a reflective optical element;
a-d show flow charts concerning different embodiments of the method for producing reflective optical elements;
in a multilayer system and the stress in this multilayer system.
By way of example, a plasma source or else a synchrotron can serve as radiation source 111 for the beam shaping system 110. For the wavelength range of 5 nm to 12 nm, in particular, X-ray lasers (X-FEL) are also appropriate as radiation source. The emerging radiation is firstly concentrated in a collector mirror 112. In addition, the desired operating wavelength is filtered out with the aid of a monochromator 113 by varying the angle of incidence. In the wavelength range mentioned the collector mirror 112 and the monochromator 113 are usually embodied as reflective optical elements which, in order to achieve a reflection of the radiation of the operating wavelength, have a multilayer system composed of at least two alternating materials having different real parts of the refractive index at the operating wavelength. Collector mirrors are often reflective optical elements embodied in shell-shaped fashion in order to achieve a focusing or collimating effect. In this case, both the collector mirror 112 and the monochromator 113 can be configured as stress-reduced reflective optical elements, as will be explained in detail later. Depending on the choice of the radiation source and the configuration of the collector mirror, a monochromator can also be dispensed with.
The operating beam conditioned with regard to wavelength and spatial distribution in the beam shaping system 110 is then introduced into the illumination system 120. In the example illustrated in
In the example illustrated in
a-d show, by way of example and only schematically, different stress-reduced reflective optical elements 1 for the extreme ultraviolet and soft X-ray wavelength range, in particular for use in EUV lithography apparatuses, e.g. as mirror of the projection or illumination system or else as photomask, collector mirror or monochromator. In all the examples illustrated here, the reflective optical elements 1 have a multilayer system 4 and substrate 2.
The multilayer system 4 essentially comprises multiply repeating stacks or periods 40. The essential layers 41, 42 of a period, which lead to sufficiently high reflection at an operating wavelength in particular as a result of the multiple repetition of the periods 40, are the so-called absorber layers 41 composed of material having a lower real part of the refractive index and the so-called spacer layers 42 composed of a material having a higher real part of the refractive index. This to a certain extent simulates a crystal, wherein the absorber layers 41 correspond to the network planes within the crystal which are at a distance from one another that is defined by the respective spacer layers 42 and at which reflection of incident EUV or soft X-ray radiation takes place. The thicknesses of the layers are chosen such that at a specific operating wavelength the radiation reflected at each absorber layer 41 is superimposed constructively in order thus to achieve a high reflectivity of the reflective optical element. It should be pointed out that the thicknesses of the individual layers 41, 42 and also of the repeating stacks 20 can be constant over the entire multilayer system, or else vary, depending on which reflection profile is intended to be achieved. In particular, it is possible to optimize multilayer systems for specific wavelengths in the case of which the maximum reflectivity and/or the reflected bandwidth is greater than in the case of non-optimized multilayer systems. In the case of radiation having this wavelength, the corresponding reflective optical element 1 is used e.g. during EUV lithography, for which reason this wavelength for which the reflective optical element 1 has been optimized is also called the operating wavelength.
Moreover, a protective layer 3 has additionally been applied to the multilayer system 4 for protection against external influences such as contamination, which protective layer can be constructed from a plurality of different material layers. Furthermore, it is also possible to provide interlayers (not illustrated here) which, as diffusion barriers between the absorber layers and spacer layers, increase the thermodynamic and thermal stability of the multilayer system 4.
If the absorber material of the multilayer system 4 is molybdenum and the spacer material is silicon, for example a number of periods of 40 to 50 is preferably employed, in the case of a period thickness of approximately 6.7 nm to 7.5 nm and a value in the range of 3.5 to 4.5, in order to obtain multilayer systems which have a maximum reflectivity at an operating wavelength in the range of 12.5 nm to 14 nm.
In the example illustrated in value of 1 is achieved, and consequently, a particularly good stress compensation per layer thickness.
In the case of multilayer systems 4 on the basis of molybdenum and silicon, for example, the stress-reducing layer 5 is particularly preferably composed of molybdenum.
In the case of multilayer systems 4 applied with particularly low stress, the single stress-reducing layer 5 can suffice for the stress compensation. This is the case particularly for molybdenum-silicon multilayer systems if they have been applied by for example electron beam evaporation. In order to compensate for typical compressive stresses of approximately −130 MPa to −180 MPa without interlayers or −220 MPa to −300 MPa with interlayers thicknesses of the layer 5 in the range of approximately 100 nm to 250 nm would suffice. By way of example, a compressive stress of approximately −180 MPa could be compensated for by a layer 5 having a thickness of approximately 150 nm. The layer 5 is preferably applied by the pulsed laser coating (also PLD (pulsed laser deposition) method), which usually provides a significant proportion of layer-forming particles around approximately 100 eV, as will be explained in greater detail below.
In the example illustrated in
The absorber layers 61 of the multilayer system 6 are amorphous. The multilayer system 6 has high values, preferably of greater than 0.75, particularly preferably of greater than 0.8. As a result, a good stress compensation is made possible even in the case of high stresses of the multilayer system 4. In particular, the absorber layer thicknesses can be over 3 nm or more. The surface roughness is less than 0.20 nm, preferably less than 0.15 nm. Consequently, the reflectivity and/or the optical imaging properties of the multilayer system 4 of the reflective optical element 1 are not influenced to such an adverse extent that the reflective optical element 1 could not be used in the context of EUV lithography. The number of periods 60 within the multilayer system 6 is significantly lower than in the case of conventional stress-reduced reflective optical elements. While approximately just as many periods compared with the highly reflective multilayer system are conventionally necessary for the stress-reducing multilayer system in order to compensate for the stress of said highly reflective multilayer system, the stress-reduced optical elements described here have significantly fewer periods in the stress-reducing multilayer system than in the highly reflective multilayer system. They advantageously have at most half as many periods in the stress-reducing multilayer system as in the highly reflective multilayer system.
By way of example, it is possible to produce a stress-reduced reflective optical element 1 for EUV lithography as illustrated in value of 0.8 to a substrate 2 by a PLD method. In this case, the laser parameters are set such that average kinetic energies of the ions generated in the plasma of around 100 eV are obtained. 7.2 nm thick amorphous absorber layers 61 composed of molybdenum having a low surface roughness of less than 0.15 nm are formed as a result. Optionally, the individual layers 61, 62 can each be additionally smoothed by an ion beam after their application. The post-processing using an ion beam additionally has the advantage that the respective layer is densified, such that when the reflective optical element is put into operation, in the course of which it can be subjected to a considerable thermal load as a result of the soft X-ray or EUV radiation, subsequent compaction of the multilayer system 6, which could alter the optical properties of the reflective optical element, does not take place. Once 17 periods 60 of the stress-reducing multilayer system 6 have been applied, the coating is continued by electron beam evaporation in a conventional manner in order to deposit 50 periods 40 likewise composed of molybdenum as absorber layer 41 and silicon as spacer layer 42. In this case, the thickness of a period 40 is 7.0 nm given a
of 0.4. If the coating processes are carried out by a PLD method and by electron beam evaporation in different chambers, the reflective optical element 1 is preferably brought from one chamber into the other chamber via a lock. By this, contamination or damage of the reflective optical element 1 during the change of chamber can be avoided and the time expended for the change of chamber can be kept particularly short. The reflective optical element 1 described in this example has a total stress over both multilayer systems 4, 6 of approximately 3.6 MPa. This should be compared with a stress of −180 MPa that the highly reflective multilayer system 4 has. The stress of the reflective optical element 1 described in this example is negligibly small by comparison therewith.
Owing to the small number of periods 60, this exemplary stress-reduced reflective optical element 1 is produced in shorter coating times than conventional reflective optical elements. The failure rate during production on account of coating deviations therefore also decreases. By virtue of the fact that the layers of the stress-compensating multilayer system are amorphous on account of the high energy of the layer-forming particles, the surface roughness thereof is so low that the reflectivity of the highly reflective multilayer system is not adversely influenced.
The example illustrated in
The example illustrated in
It should be pointed out that the interlayer 7 is in particular also suitable for being provided in conventional stress-reduced reflective optical elements, in order to compensate for the surface roughness of the conventional stress-compensating multilayer systems. An improvement in the reflectivity and in the optical imaging properties can thus be improved by only minor modification of existing coating processes.
Some examples for producing stress-reduced reflective optical elements is explained in conjunction with
In the example illustrated in
In the example illustrated in
In accordance with the example illustrated in
Preferably, at least the topmost layer is subsequently polished, on which the highly reflective multilayer system is subsequently deposited (step 311). It is also possible for all the layers or else the amorphous layer from the example illustrated in
The example illustrated in
It should be pointed out that the individual method steps can also be modified and combined with one another in a wide variety of ways by the person skilled in the art in order to produce a stress-reduced reflective optical element which is optimally adapted to the respective requirements.
The above description of the preferred embodiments has been given by way of example. From the disclosure given, those skilled in the art will not only understand the present invention and its attendant advantages, but will also find apparent various changes and modifications to the structures and methods disclosed. The applicant seeks, therefore, to cover all such changes and modifications as fall within the spirit and scope of the invention, as defined by the appended claims, and equivalents thereof.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10 2008 042 212.6 | Sep 2008 | DE | national |
This is a Continuation of U.S. application Ser. No. 13/051,782 with a filing date of Mar. 18, 2011, which is a Continuation of International Application PCT/EP2009/006112, with an international filing date of Aug. 22, 2009, which was published under PCT Article 21(2) in English, which claims priority under 35 U.S.C. §119(a) to German Patent Application No. 10 2008 042 212.6, filed on Sep. 19, 2008; the present application also claims the benefit under 35 U.S.C. §119(e)(1) of U.S. Provisional Application No. 61/098,568, filed on Sep. 19, 2008. The entire contents of the International Application and the priority applications are hereby incorporated into the present application by reference.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 13051782 | Mar 2011 | US |
| Child | 13589703 | US | |
| Parent | PCT/EP2009/006112 | Aug 2009 | US |
| Child | 13051782 | US |
