1. Technical Field
The present disclosure relates to the use of chemical-mechanical planarization (CMP) of 10-100 nanometer-sized integrated circuit features and, in particular, to techniques for achieving feature-scale uniformity within a die.
2. Description of the Related Art
CMP is a polishing technique used in the semiconductor industry to planarize (i.e., make flat) the surface of a semiconductor wafer at various times during an integrated circuit fabrication process. Typically, it is desirable to planarize the wafer surface after completing deposition and patterning of a layer, before proceeding to deposit a next layer of material. If planarization is omitted, the topography of the un-planarized surface can be transferred to, or accentuated in, subsequent layers. Such topography effects are more likely to occur if materials used in subsequent layers have poor ability to fill surface recesses.
A CMP process typically entails polishing the wafer surface using a rotating pad and a slurry made from various chemicals and abrasive particulates, so that both chemical and physical removal mechanisms contribute to the planarization. Depending on the materials and the features being polished, the CMP process may gouge the surface, causing CMP-induced topography and thereby degrading the surface uniformity. Such gouging of the surface is sometimes referred to as “dishing.” If local erosion is too great, the CMP process used during subsequent layers may not effectively remove material (e.g., metal) from recessed areas. Puddle defects in which residual metal is left behind in the recessed areas can cause short circuits.
Non-uniform topography may occur on any of three different scales: wafer scale, die scale, and feature scale. Wafer-scale topography variation results from radial variation in the CMP process, from the center of a semiconductor wafer to the edge of the wafer. Wafer-scale topography variation can be addressed by adjusting CMP equipment parameters or materials used in the CMP process itself. Die-scale variation depends primarily on the pattern density of circuit features, which is largely determined by circuit mask designs. Wafer-scale and die-scale variation can also be compensated for in a lithography scanner through focus-level adjustment by measuring wafer surface heights before each exposure. Today, optical or mechanical detection of long-range wafer surface height variation and focus adjustment is possible in most advanced lithography systems.
Feature-scale topography variation, however, is dependent on individual line widths, line spaces, or feature shapes, and cannot be compensated for in a lithography step because the variation is within an individual exposure field. Thus, non-uniform topography at the feature level poses a critical challenge for CMP process development as feature sizes continue to shrink. Reducing feature-scale post-CMP non-uniformities for advanced technology generations is therefore of considerable interest to semiconductor technologists.
A new sequence of processing steps presented herein is used to prevent dishing and to reduce significantly the local pitch- and pattern density-induced CMP non-uniformity for copper metal lines having widths and spacing in the range of about 32-128 nm. While an integrated circuit is being made, a non-uniform pattern of trenches is created in a high-k inter-layer dielectric. Copper metal lines are inlaid by partially filling the trenches, with the result that the thickness of the copper varies according to changes in width, depth of trenches, as well as the density of the trenches in the non-uniform pattern. Next, a silicon carbide/nitride (SiCxNy) blocking layer is blanket deposited. A multi-step CMP process then planarizes the entire wafer with the result that areas of the planarized irregular surface that have narrow features will have the blocking layer removed, while the blocking layer protects trenches that have wide features.
In the drawings, identical reference numbers identify similar elements. The sizes and relative positions of elements in the drawings are not necessarily drawn to scale.
In the following description, certain specific details are set forth in order to provide a thorough understanding of various aspects of the disclosed subject matter. However, the disclosed subject matter may be practiced without these specific details. In some instances, well-known structures and methods of semiconductor processing comprising embodiments of the subject matter disclosed herein have not been described in detail to avoid obscuring the descriptions of other aspects of the present disclosure.
Unless the context requires otherwise, throughout the specification and claims that follow, the word “comprise” and variations thereof, such as “comprises” and “comprising” are to be construed in an open, inclusive sense, that is, as “including, but not limited to.”
Reference throughout the specification to “one embodiment” or “an embodiment” means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearance of the phrases “in one embodiment” or “in an embodiment” in various places throughout the specification are not necessarily all referring to the same aspect. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more aspects of the present disclosure.
Reference throughout the specification to integrated circuits is generally intended to include integrated circuit components built on semiconducting substrates, whether or not the components are coupled together into a circuit or able to be interconnected. Throughout the specification, the term “layer” is used in its broadest sense to include a thin film, a cap, or the like.
Reference throughout the specification to conventional thin film deposition techniques for depositing silicon nitride, silicon dioxide, metals, or similar materials include such processes as chemical vapor deposition (CVD), low-pressure chemical vapor deposition (LPCVD), metal organic chemical vapor deposition (MOCVD), plasma-enhanced chemical vapor deposition (PECVD), plasma vapor deposition (PVD), atomic layer deposition (ALD), molecular beam epitaxy (MBE), electroplating, electro-less plating, and the like. Specific embodiments are described herein with reference to examples of such processes. However, the present disclosure and the reference to certain deposition techniques should not be limited to those described. For example, in some circumstances, a description that references CVD may alternatively be done using PVD, or a description that specifies electroplating may alternatively be accomplished using electro-less plating. Furthermore, reference to conventional techniques of thin film formation may include growing a film in-situ. For example, in some embodiments, controlled growth of an oxide to a desired thickness can be achieved by exposing a silicon surface to oxygen gas or to moisture in a heated chamber.
Reference throughout the specification to conventional photolithography techniques, known in the art of semiconductor fabrication for patterning various thin films, includes a spin-expose-develop process sequence typically followed by an etch process. Alternatively or additionally, photoresist can also be used to pattern a hard mask (e.g., a silicon nitride hard mask), which, in turn, can be used to pattern an underlying film.
Reference throughout the specification to conventional etching techniques known in the art of semiconductor fabrication for selective removal of polysilicon, silicon nitride, silicon dioxide, metals, photoresist, polyimide, or similar materials includes such processes as wet chemical etching, reactive ion (plasma) etching (RIE), washing, wet cleaning, pre-cleaning, spray cleaning, chemical-mechanical planarization (CMP) and the like. Specific embodiments are described herein with reference to examples of such processes. However, the present disclosure and the reference to certain deposition techniques should not be limited to those described. In some instances, two such techniques may be interchangeable. For example, stripping photoresist may entail immersing a sample in a wet chemical bath or, alternatively, spraying wet chemicals directly onto the sample.
Specific embodiments are described herein with reference to planarized metal interconnect structures that have been produced; however, the present disclosure and the reference to certain materials, dimensions, and the details and ordering of processing steps are exemplary and should not be limited to those shown. The terms “planarize” and “polish” are used synonymously throughout the specification.
In the figures, identical reference numbers identify similar features or elements. The sizes and relative positions of the features in the figures are not necessarily drawn to scale.
The non-uniform surface pattern 102 shown in
Although, in the example shown, the inlaid features are made of metal, problems associated with polishing non-uniform surface patterns 102 are not necessarily limited to the materials shown in the examples herein. Likewise, solutions presented herein for processing metal features of disparate sizes can be generally applied to similarly disparate features made of other materials that may be inlaid in other substrates 100.
At 202, the non-uniform surface pattern 102 of trenches 115 is formed in a substrate 125.
At 204, metal is blanket deposited on the surface, a deposition process (e.g., CVD or PVD) in which the metal over-fills the narrow trenches but only partially fills the wide trenches. Such a variation in metal thickness thus forms an irregular surface.
At 206, the irregular surface is covered with a blocking layer.
At 208, a multi-step polishing process is performed. Details of the uniform CMP method 200 are presented below, with reference to
At 214, the substrate 125 is formed as a thick ultra-low-k (ULK) dielectric on a support layer 222. In the embodiment shown, the ULK dielectric desirably has a dielectric constant, k, in the range of about 2.0-3.0 and a thickness target of about 250 nm. The support layer 222 can be made of, for example, silicon carbide-nitride SiCxNy having a thickness of about 10-20 nm.
At 216, trenches 115 are patterned in the ULK dielectric substrate 15 by conventional lithography and reactive ion etching (RIE) processes. The irregular surface features may also be formed by depositing and etching to create non-uniform layers of significantly different heights, for example gates formed over a substrate, sidewall spacers adjacent the gates, gate electrodes overlying the gates, and further insulation layers overlying such gate electrodes; all of which are adjacent to openings to a silicon semiconductor substrate, which is another technique by which surface structures having very different heights may be formed. Patterning the ULK generally produces the narrow trenches 117, wide trenches 119, and intermediate width trenches 229, in close proximity to one another within a common die. In one embodiment, the depth of the trenches 115 is in the range of about 100-200 nm so that the narrow trenches 117 have a high aspect ratio (e.g., in the range of about 5:1 to about 10:1) that substantially exceeds the desired aspect ratio of adjacent structures (e.g., about 3:1).
At 218, a conformal, thin trench liner 226 is deposited in the trenches 115. The trench liner 226 forms a barrier between the ULK material and the trench fill material to be deposited next. The trench liner 226 can be made of tantalum nitride (TaN), for example, having a representative thickness of a few nm. Other material choices for the trench liner 226 can include titanium or titanium nitride (TiN).
At step 204, the trenches 115 are at least partially filled with a trench fill material 228 (
At step 206, a blocking layer 238 is deposited over the irregular surface 230 to protect the wide inlaid features 106. The blocking layer 238 can be formed either as a conformal deposition layer or as a non-conformal layer. Even formed as a non-conformal, filling layer, often called a planarizing layer in the art, it will still have some non-uniform features and variations in height because of the great difference in the height of the irregular surface features of the uppermost surfaces of the uppermost surface 230. In one embodiment, the blocking layer is an insulating material that is substantially conformal with the underlying trench fill topography. In one embodiment, composition of the blocking layer 238 is a nitride film such as a silicon carbide-nitride (SiCxNy) having a thickness within the range within the range of about 50-100 nm. Other insulating silicon nitride compositions can also be used, as well as other insulating materials that deposit substantially conformally.
At step 208, a multi-step CMP process is performed in which exposed metal features are removed by the CMP etching down to almost the level 236 of the metal layer 228. In one embodiment, a three-step planarization process can be carried out as follows:
At 240, the blocking layer 238 is removed from the substrate 125 irregular surface 230 sufficient to remove the top part of substrate 125, to expose the nanowires 108. The CMP process used to remove the blocking layer 238 can include a slurry made from silica and hydrogen peroxide (H2O2), and use of a soft polish pad. Meanwhile, the metal fields 228 remain covered by the blocking layer 238 where it has not yet been removed.
At 242, the exposed fill material 228 is polished overlying the narrow inlaid features 104. Such polishing may also remove an upper portion of the nanowires 108. Because the metal fields 228 are protected over trenches 119 and 224 by the blocking layer 238, at these wide locations the metal layer 228 remains unaffected and therefore dishing is prevented of the metal layer itself.
At 244, a touch CMP process is performed to gently remove remnants of the blocking layer 238 from the wide inlaid features 224 and 119. The touch CMP process can be a brief surface polish in which the polish pad rotation speed and pressure are set to relatively low values to remove residual amounts of material while limiting the degree of surface abrasion. Alternatively, a touch clean can be substituted for the touch CMP process. The touch clean can use, for example, a wet clean chemistry that includes hydrofluoric acid (HF) diluted with de-ionized water (DI) in a 1000:1 ratio (DI:HF). Alternatively, the chemistry of the etch slurry in the CMP etch may be changed to be less aggressive in etching the blocking layer 238, or, in some cases, the metal layer 228. For example, the first etch chemistry of the first CMP etch as carried out in step 240 may be an aggressive, high pressure etch that etches almost all surface features evenly, namely blocking layer 238, metal layer 228, inter-metal dielectric, as well as any lining layers 226 are etched at a generally uniform rate by the first CMP process 240. This first CMP process 240 continues until a selected etch stop time. It may be a timed etch that will stop after a selected time period. Alternatively, it may be an end-of-point etch that is designed to stop upon reaching a selected feature, such as detecting the presence of the substrate material 125 as being etched, or some other end point indicating that the aggressive CMP is to be concluded, and a light CMP, (also referred to herein as a touch CMP), process is then to be carried out. As mentioned, the second CMP process may have a chemical composition which is different from the first, which is not as aggressive in etching the metal layer 228. Therefore, during the second CMP step, removal of the metal layer 228 is predominantly carried out by the polishing aspect of the CMP process rather than by the chemical aspect of the CMP process. A final planar surface 246 is thus achieved without much, if any, chemical etching of the metal layer 228. Because the metal fields 228 are only polished, and not subject to chemical removal, the gouges 117 and associated puddle defects are prevented. The diagram in
After step 242 is completed, a further etch 244 is performed in order to remove all the portions of the blocking layer 238 which may remain. The light touch CMP process may continue until line 239, which may etch some into the metal layer 228 inside of the trench 224, reducing the height 234. When the etching process reaches approximately line 239, shown in
The use of a multistep CMP process is not required, according to one embodiment of the invention. In one embodiment, a CMP process is selected which is preferentially selective to the blocking layer 238 from the chemistry standpoint, and performs little to no etching from a chemical interaction standpoint of the metal layer 228. This can be a single etch step which is carried out in a somewhat aggressive fashion against the blocking layer 238 and also any other layers that are exposed with respect to a polishing standpoint, although from a chemical standpoint only a layer 238 is attacked chemically, and the remainder are etched away mainly by the mechanical polishing process. This process therefore would not cause a dishing effect in the metal layer 228 inside the wide trench 119, even if carried out as the only CMP etch until all etching is completed. In one embodiment, this single CMP etch continues until past the height 236 in which the metal layer 228 in the widest trench 119 is exposed. In such situations it is not necessary to perform the final wet etch in step 244 for removing the blocking layer with a wet chemical etch.
The various embodiments described above can be combined to provide further embodiments. All of the U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet are incorporated herein by reference, in their entirety. Aspects of the embodiments can be modified, if necessary to employ concepts of the various patents, applications and publications to provide yet further embodiments.
It will be appreciated that, although specific embodiments of the present disclosure are described herein for purposes of illustration, various modifications may be made without departing from the spirit and scope of the present disclosure. Accordingly, the present disclosure is not limited except as by the appended claims.
These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
This patent application claims benefit under 35 U.S.C. §119(e) of U.S. Provisional Patent Application No. 61/711,002, filed on Oct. 8, 2012, which is hereby incorporated by reference in its entirety.
Number | Date | Country | |
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61711002 | Oct 2012 | US |