The present disclosure relates generally to thermal processing chambers and more particularly to millisecond anneal thermal processing chambers used for processing substrates, such as semiconductor substrates.
Millisecond anneal systems can be used for semiconductor processing for the ultra-fast heat treatment of substrates, such as silicon wafers. In semiconductor processing, fast heat treatment can be used as an anneal step to repair implant damage, improve the quality of deposited layers, improve the quality of layer interfaces, to activate dopants, and to achieve other purposes, while at the same time controlling the diffusion of dopant species.
Millisecond, or ultra-fast, temperature treatment of semiconductor substrates can be achieved using an intense and brief exposure of light to heat the entire top surface of the substrate at rates that can exceed 104° C. per second. The rapid heating of just one surface of the substrate can produce a large temperature gradient through the thickness of the substrate, while the bulk of the substrate maintains the temperature before the light exposure. The bulk of the substrate therefore acts as a heat sink resulting in fast cooling rates of the top surface.
Aspects and advantages of embodiments of the present disclosure will be set forth in part in the following description, or may be learned from the description, or may be learned through practice of the embodiments.
One example aspect of the present disclosure is directed to a thermal processing system. The thermal processing system includes a top chamber separated from a bottom chamber by a wafer plane plate. The system includes a plurality of heat sources configured to provide heat for the thermal treatment of a substrate. The system includes a plurality of gas inlets configured to inject gas into the processing chamber. One or more of the direction, size, position shape, or arrangement of the gas inlets are configured to increase laminar flow across the wafer plane plate.
Another example aspect of the present disclosure is directed to a millisecond anneal system. The millisecond anneal system includes a processing chamber having a top chamber separated from a bottom chamber by a wafer plane plate. The system includes one or more arc lamps configured to provide a flash for the thermal treatment of a substrate. The system includes one or more gas inlets configured to inject gas into the processing chamber. The wafer plane plate has at least one gas channel. A length of the gas channel is equal to about a width of the processing chamber.
Another example aspect of the present disclosure is directed to a millisecond anneal system. The millisecond anneal system includes a processing chamber having a top chamber separated from a bottom chamber by a wafer plane plate. The system includes one or more arc lamps configured to provide a flash for the thermal treatment of a substrate. The system includes one or more gas inlets configured to inject gas into the processing chamber. The system can include a liner plate disposed in parallel relationship above the wafer plane plate.
Other example aspects of the present disclosure are directed to systems, methods, devices, and processes for thermally treating a substrate.
These and other features, aspects and advantages of various embodiments will become better understood with reference to the following description and appended claims. The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments of the present disclosure and, together with the description, serve to explain the related principles.
Detailed discussion of embodiments directed to one of ordinary skill in the art are set forth in the specification, which makes reference to the appended figures, in which:
Reference now will be made in detail to embodiments, one or more examples of which are illustrated in the drawings. Each example is provided by way of explanation of the embodiments, not limitation of the present disclosure. In fact, it will be apparent to those skilled in the art that various modifications and variations can be made to the embodiments without departing from the scope or spirit of the present disclosure. For instance, features illustrated or described as part of one embodiment can be used with another embodiment to yield a still further embodiment. Thus, it is intended that aspects of the present disclosure cover such modifications and variations.
Example aspects of the present disclosure are directed to gas flow improvement in a millisecond anneal system. Aspects of the present disclosure are discussed with reference to a “wafer” or semiconductor wafer for purposes of illustration and discussion. Those of ordinary skill in the art, using the disclosures provided herein, will understand that the example aspects of the present disclosure can be used in association with any workpiece, semiconductor substrate or other suitable substrate. The use of the term “about” in conjunction with a numerical value is intended to refer to within 10% of the stated numerical value.
The thermal treatment of semiconductor substrates in a millisecond anneal processing chamber can be carried out in a controlled gas ambient at atmospheric pressure. The main gas can be Nitrogen (N2), but other gases (e.g., Ar, O2, NH3 or other gases) are also compatible with the chamber. During substrate exchange, the process chamber can be opened to the surrounding air of the wafer handling module. For this reason, the chamber has to be purged prior to the start of the heat treatment.
In many instances, the gas flow pattern in a millisecond anneal system can have an impact on the heat transfer of the semiconductor substrate and therefore also on the temperature uniformity across the semiconductor substrate. Locally, gas flow influences the cooling rate at a particular region of the semiconductor substrate by forced convection. A uniform, laminar flow pattern across and around the semiconductor substrate can have a reduced impact on wafer temperature uniformity.
In addition, the gas flow pattern can have impact on how particles are moving through the chamber and how they are re-distributed. Typical particle sources are the wafer handling mechanisms (e.g., a wafer lift mechanism and robot end effector for moving placing the semiconductor substrates). Hot semiconductor substrates can repel particles due to the thermophoresis effect. However, turbulent flow and stagnant flow regions can lead to re-distribution and accumulation of particles such that they are deposited onto the semiconductor wafer.
Moreover, the gas flow pattern can influence how gaseous contaminants from the wafer are moving through the chamber. These contaminants are usually released during the heat treatment of the wafer and stem from surface layers or are a result of other processing steps prior to the heat treatment step. In embodiments where the millisecond anneal system is a cold wall system (e.g., includes fluid cooled reflective mirrors), these contaminates can be deposited on the reflective mirrors, reducing the reflectivity and hence have an adverse effect on the wafer temperature uniformity
According to example aspects of the present disclosure, a gas flow pattern inside the process chamber of a millisecond anneal system can be improved by implementing one or more of the following: (1) altering the direction, size, position, shape and arrangement of the gas injection inlet nozzles, or a combination hereof; (2) changing the dimensions of gas channels in a wafer plane plate connecting the upper chamber with the lower chamber of a millisecond anneal system; and/or (3) decreasing the effective volume of the processing chamber using a liner plate disposed above the semiconductor substrate.
For example, in some embodiments, a thermal processing system can include a processing chamber having a top chamber separated from a bottom chamber by a wafer plane plate. The system can include a plurality of heat sources configured to provide heat for the thermal treatment of a substrate. The system can include a plurality of gas inlets configured to inject gas into the processing chamber. One or more of the direction, size, position, shape, or arrangement of the gas inlets are arranged relative to the wafer plane plate to increase laminar flow across the wafer plane plate.
In some embodiments, the plurality of gas inlets can be arranged in separate top corners of the top chamber. The gas inlets can be oriented to point to the substrate. In some embodiments, at least one of the plurality of gas inlets is positioned proximate to the wafer plane plate. For instance, at least one of the plurality of gas inlets can be positioned a first distance from a ceiling of the top chamber and a second distance from the wafer plane plate. The first distance is greater than the second distance. In these embodiments, the system can in some examples, additionally include a plurality of gas inlets located in separate top corners of the top chamber.
In some embodiments, at least one of the plurality of gas inlets is positioned opposite a gate valve proximate the wafer plane plate. The gas flow system can further include one or more vents positioned proximate to the gate valve.
In some embodiments, one or more of the plurality of gas inlets includes a pipe penetrating into the processing chamber through a reflective mirror. In some embodiments, the pipe can have a straight open end. In some embodiments, the pipe can have an opening perpendicular to a pipe axis. In some embodiments, the pipe can have an opening that is at a non-perpendicular angle with respect to a pipe axis.
Another example embodiment of the present disclosure is directed to a millisecond anneal system. The millisecond anneal system includes a processing chamber having a top chamber separated from a bottom chamber by a wafer plane plate. The system includes one or more arc lamps configured to provide a flash for the thermal treatment of a substrate. The system includes one or more gas inlets configured to inject gas into the processing chamber. The wafer plane plate has at least one gas channel. A length of the gas channel is equal to about a width of the processing chamber.
In some embodiments, the wafer plane plate includes a plurality of gas channels disposed on separate sides of the wafer plane plate. For instance, in some embodiments, the wafer plane plate includes a first set of gas channels disposed on opposing sides of the wafer plane plate and a second set of gas channels disposed on different opposing sides of the wafer plane plate. The first set of gas channels each have a first length and the second set of gas channels each have a second length. The first length can be greater than the second length. For instance, the first length can be equal to about a width of the processing chamber and the second length can be less than the width of the processing chamber.
Another example embodiment of the present disclosure is directed to a millisecond anneal system. The millisecond anneal system includes a processing chamber having a top chamber separated from a bottom chamber by a wafer plane plate. The system includes one or more arc lamps configured to provide a flash for the thermal treatment of a substrate. The system includes one or more gas inlets configured to inject gas into the processing chamber. The system can include a liner plate disposed in parallel relationship above the wafer plane plate.
In some embodiments, the liner plate can be quartz. In some embodiments, a distance between the wafer plane plate and the liner is in the range of about 30 mm to about 60 mm.
An example millisecond anneal system can be configured to provide an intense and brief exposure of light to heat the top surface of a wafer at rates that can exceed, for instance, about 104° C./s.
An example millisecond anneal system can include a plurality of arc lamps (e.g., four Argon arc lamps) as light sources for intense millisecond long exposure of the top surface of the semiconductor substrate—the so called “flash.” The flash can be applied to the semiconductor substrate when the substrate has been heated to an intermediate temperature (e.g., about 450° C. to about 900° C.). A plurality of continuous mode arc lamps (e.g., two Argon arc lamps) can be used to heat the semiconductor substrate to the intermediate temperature. In some embodiments, the heating of the semiconductor substrate to the intermediate temperature is accomplished through the bottom surface of the semiconductor substrate at a ramp rate which heats the entire bulk of the wafer.
As shown in
A plurality of continuous mode arc lamps 240 (e.g., two Argon arc lamps) located proximate the bottom chamber 204 can be used to heat the semiconductor substrate 60 to the intermediate temperature. In some embodiments, the heating of the semiconductor substrate 60 to the intermediate temperature is accomplished from the bottom chamber 204 through the bottom surface of the semiconductor substrate at a ramp rate which heats the entire bulk of the semiconductor substrate 60.
As shown in
As further illustrated in
The temperature uniformity of the semiconductor substrate can be controlled by manipulating the light density falling onto different regions of the semiconductor substrate. In some embodiments, uniformity tuning can be accomplished by altering the reflection grade of small size reflectors to the main reflectors and/or by use of edge reflectors mounted on the wafer support plane surrounding the wafer.
For instance, edge reflectors can be used to redirect light from the bottom lamps 240 to an edge of the semiconductor substrate 60. As an example,
In some embodiments, additional reflectors can also be mounted on chamber walls near the wafer plane plate 210. For example,
In some embodiments, as the electrodes experience a high heat load, one or more of the electrodes can each include a tip 232. The tip can be made from tungsten. The tip can be coupled to and/or fused to a water cooled copper heat sink 234. The copper heat sink 234 can include at least a portion the internal cooling system of the electrodes (e.g., one or more water cooling channels 236. The electrodes can further include a brass base 235 with water cooling channels 236 to provide for the circulation of water or other fluid and the cooling of the electrodes.
The arc lamps used in example millisecond anneal systems according to aspects of the present disclosure can be an open flow system for water and Argon gas. However, for conservation reasons, both media can be circulated in a close loop system in some embodiments.
More particularly, high purity water 302 and Argon 304 is fed to the lamp 220. The high purity water 302 is used for the water wall and the cooling of the electrodes. Leaving the lamp is a gas/water mixture 306. This water/gas mixture 306 is separated into gas free water 302 and dry Argon 304 by separator 310 before it can be re-fed to the inlets of the lamp 220. To generate the required pressure drop across the lamp 220, the gas/water mixture 306 is pumped by means of a water driven jet pump 320.
A high power electric pump 330 supplies the water pressure to drive the water wall in the lamp 220, the cooling water for the lamp electrodes, and the motive flow for the jet pump 320. The separator 310 downstream to the jet pump 320 can be used extracting the liquid and the gaseous phase from the mixture (Argon). Argon is further dried in a coalescing filter 340 before it re-enters the lamp 220. Additional Argon can be supplied from Argon source 350 if needed.
The water is passing through one or more particle filters 350 to remove particles sputtered into the water by the arc. Ionic contaminations are removed by ion exchange resins. A portion of water is run through mixed bed ion exchange filters 370. The inlet valve 372 to the ion exchange bypass 370 can be controlled by the water resistivity. If the water resistivity drops below a lower value the valve 372 is opened, when it reaches an upper value the valve 372 is closed. The system can contain an activated carbon filter bypass loop 380 where a portion of the water can be additionally filtered to remove organic contaminations. To maintain the water temperature, the water can pass through a heat exchanger 390.
Millisecond anneal systems according to example embodiments of the present disclosure can include the ability to independently measure temperature of both surfaces (e.g., the top and bottom surfaces) of the semiconductor substrate.
A simplified representation of the millisecond anneal system 200 is shown in
The readings of the temperature sensors 152 and 154 can be emissivity compensated. As shown in
In some embodiments, the millisecond anneal system 200 can include water windows. The water windows can provide an optical filter that suppresses lamp radiation in the measurement band of the temperature sensors 152 and 154 so that the temperature sensors 152 and 154 only measure radiation from the semiconductor substrate.
The readings of the temperature sensors 152 and 154 can be provided to a processor circuit 160. The processor circuit 160 can be located within a housing of the millisecond anneal system 200, although alternatively, the processor circuit 160 may be located remotely from the millisecond anneal system 200. The various functions described herein may be performed by a single processor circuit if desired, or by other combinations of local and/or remote processor circuits.
The readings of the temperature sensors 152 and 154 can be used by the processor circuit 160 to determine a temperature profile across the substrate. The temperature profile can provide a measure of the temperature of the substrate at various locations across the surface of the substrate. The temperature profile can provide a measure of thermal uniformity of the substrate during processing.
Purging can be accomplished by flowing high purity process nitrogen gas at high rates (100 l/min) through the chamber. The remaining contamination level can be measured by an O2-sensor 320. The O2 sensor 320 can send signals to one or more control devices 350 indicative of the O2 level in the processing chamber. The control devices 350 can be any suitable control device, such as a controller, microcontroller, application specific integrated circuit, processor configured to execute computer-readable instructions, etc. The end of the purge step can be reached when the desired O2 level (e.g., 20 ppm) is reached. At this time, the control devices 350 can reduce the flow rate of N2 The O2 sensor 320 can be located at the wafer plane plate 210 level of the processing chamber as shown in
According to example embodiments of the present disclosure, the gas flow pattern inside a processing chamber of a millisecond anneal system can be improved by altering one or more of the direction, size, position, shape, and/or arrangement (or combination thereof) of inlet nozzels associated with gas inlets used to inject gas into the processing chamber.
In some embodiments, the angle at which the gas inlets are oriented is modified. By changing the angle of orientation, the gas flow distribution in the center of the chamber can be influenced.
In some embodiments, the diameter of the gas inlet nozzles are modified. This can be performed to adjust the outlet velocity of the gas jet from an inlet nozzle. A smaller diameter can increase the velocity and can extend the reach of the gas jet. In addition, a smaller diameter can lead to more turbulent gas flow at high volumetric flow, which can be beneficial for purging and dilution of impurity gases. A larger diameter, at the same volumetric flow, can slow down the gas jet. This can help in keeping a laminar flow regime around the semiconductor substrate during heat treatment. This can benefit temperature uniformity. In some embodiments, the shape of the gas inlets can be modified to be rectangular or elliptical, rather than circular. In some embodiments, the number of inlets can be increased to provide a comb-like gas inlet arrangement.
In some embodiments, one or more gas inlets (e.g., additional gas inlets) are positioned at a level at or proximate to the wafer plane plate. For instance, as shown in
In some example implementations, the flow pattern can be adjusted for the different stages of the processing recipe by switching valves. For instance, during purge, all gas inlets—also the top gas inlets 302—are open for fast and efficient cleaning. During heat treatment, the top gas inlets 302 are closed and only the inlets 340 near the wafer plane 210 are on, generating a laminar flow regime across the substrate 60. In some embodiments, the processing chamber can include a linear array of gas inlets running along the sides opposite the gate valve and along the sides with the gate valve.
Another embodiment is to extend the plurality of gas inlets into the chamber by pipes penetrating the chamber wall mirrors. The pipe ends can have a straight open end, an opening perpendicular to the pipe axis, or other suitable shape. For instance,
According to example embodiments of the present disclosure, the gas flow pattern inside a processing chamber of a millisecond anneal system can be improved by altering gas flow channels defined in a wafer plane plate connecting a top chamber and a bottom chamber in the millisecond anneal system. A process chamber in a millisecond anneal system can be divided by the wafer plane plate into a top chamber and a bottom chamber. To facilitate gas flow from the top chamber (where gas is entering the chamber) and the bottom chamber (where gas is vented from the chamber), each side of the wafer plane plate can include gas flow channels (e.g., slots).
According to example aspects of the present disclosure, the gas flow pattern in a millisecond anneal system can be improved by manipulating the size and the geometry of the gas channels. For instance, by modifying the length, the flow pattern in the corner of the chamber can be affected. With shorter channels, simulation shows that there is an upward flow in the corner of the chamber. Upward flow is thought to be responsible for poor purging and a re-distribution of particles in the chamber. However, extending the channel length to approximately the full width of the chamber according to example aspects of the present disclosure provides for an increase in downward flow in the corners.
For instance,
In some embodiments, a length of the channel in the wafer plane plate opposite the gate valve is extended to approximately the full width of the chamber. The channel length on the gate valve side of the chamber can also be the full width. The channels on the other sides of the chamber can remain shorter than the chamber width to allow mounting of the plate to the chamber frame. By pairwise matching of the flow resistance of the channels front and rear as well as left and right, the flow pattern can be made symmetric while at the same time providing for downward flow in all corners.
For example,
According to example embodiments of the present disclosure, a gas flow pattern inside a processing chamber of a millisecond anneal system can be improved by decreasing the effective volume of the chamber through use of a liner plate above the semiconductor substrate. For instance, in one embodiment, a liner plate can be placed above the wafer plane plate for holding semiconductor substrate in spaced parallel relationship.
In some embodiments, a distance between the wafer plane plate 210 and the liner plate 380 can be in the range of about 30 mm to about 60 mm. In some embodiments, the liner plate does not seal against the chamber walls, thus allowing process gas to flow into the volume below the plate, above the substrate 60. The liner plate 380 can generate a laminar flow regime around the substrate 60 by suppressing convection rolls and changing the flow vectors to be predominately parallel to the surface of the substrate 60. In some embodiments, additional gas inlets 385 can be located on the chamber wall in the region between the substrate 60 and the liner plate 380.
An additional effect of the liner plate 380 is that it can shield the chamber wall from contaminants released by the substrate 60. The liner plate 38—can be passively heated by the semiconductor substrate and the lamp radiation, effectively reducing the deposition probability compared to the cold chamber walls.
Another effect of the liner plate 380 is that it can reduce the effective purge volume. Impurity gas outside a shielded volume formed by the substrate 60 and the liner plate 380 can shielded. The leak-in rate of gas outside the shielded volume can be set by the gap between the liner plate perimeter and chamber wall.
While the present subject matter has been described in detail with respect to specific example embodiments thereof, it will be appreciated that those skilled in the art, upon attaining an understanding of the foregoing may readily produce alterations to, variations of, and equivalents to such embodiments. Accordingly, the scope of the present disclosure is by way of example rather than by way of limitation, and the subject disclosure does not preclude inclusion of such modifications, variations and/or additions to the present subject matter as would be readily apparent to one of ordinary skill in the art.
The present application claims the benefit of priority of U.S. Provisional Patent Application Ser. No.: 62/272,804, filed Dec. 30, 2015, entitled “Gas Flow Control for Millisecond Anneal System,” which is incorporated herein by reference.
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