This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2011-023998 filed in Japan on Feb. 7, 2011; the entire contents of which are incorporated herein by reference.
Embodiments described herein relate generally to method for manufacturing a semiconductor device.
In the recent years, in accordance with miniaturization and sophistication of an electric apparatus and the like, for example, in CMOS transistors configuring a SRAM (Static Random Access Memory) cell and the like, an improvement in carrier mobility is demanded in order to improve driving power.
The carrier mobility depends on stresses caused by a phase orientation, an axial direction, a lattice strain and the like of a substrate onto which an element is to be formed, and a direction along which the carrier mobility is improved or deteriorated differs depending on carriers.
For example, in forming an n-type transistor and a p-type transistor with a <110> axial direction of a (100) face of an Si substrate as a channel longitudinal direction, in the n-type transistor the carrier mobility can be improved by providing a tensile stress in an (X direction) and a direction vertical to a substrate surface (Z direction), whereas in the p-type transistor, the carrier mobility can be improved by providing a compressive stress in the (X direction) and the direction vertical to the substrate surface (Z direction).
Such tensile stress and compressive stress are provided by causing a film character of a barrier film (insulating film) such as SiN formed on a gate electrode to be different for each element.
Certain embodiments provide a method for manufacturing a semiconductor device having an element region formed on a semiconductor substrate and including a first region and a second region, a first contact connected to the first region, and a second contact connected to the second region. The method includes forming the element region on the semiconductor substrate; forming a first insulating film on the first region; forming a second insulating film on the second region; irradiating UV light; forming a first opening on the first insulating film and a second opening on the second insulating film; and forming the first contact in the first contact and the second contact in the second opening. The second insulating film differs from the first insulating film in the membrane stress, and is an insulating film with an etching rate that approaches an etching rate of the first insulating film by the UV light being irradiated. Irradiating the UV light is selectively irradiating the UV light to the second contact region where the second contact is to be formed in the second insulating film. Forming the first opening and the second opening is forming the first opening on the first insulating film and the second opening in the second insulating film by concurrently etching the first contact region in the first insulating film where the first contact is to be formed and the second contact region after having irradiated the UV light.
Hereinbelow, embodiments of a method for manufacturing a semiconductor device will be explained. Note that, hereinbelow, a semiconductor device including an n-type transistor and a p-type transistor, and contacts, arranged on impurity regions of these transistors, that are electrically connected to these impurity regions will be used as an example of the semiconductor device, and a method for manufacturing such a semiconductor device will be explained.
Firstly, as shown in
Firstly, an STI (Shallow Trench Isolation) 12 is formed on the semiconductor substrate 11, and separates a region where the n-type transistor region 11a is to be formed and a region where the p-type transistor region 11b is to be formed. Next, in each of the separated regions, an impurity diffused region 13a, a silicide film 13b, a gate electrode 14a, and a gate side wall 14b are formed. Accordingly, the n-type transistor region 11a and the p-type transistor region 11b are formed.
Next, as shown in
Note that, since the film density of the SiN film 15 should be low, the SiN film 15 is deposited under the aforementioned low temperature/low power condition.
Next, as shown in
As shown in
The deposited SiN film 15 is a film having a large number of Si—H bonding and N—H bonding, and having a relatively sparse film density. When the UV is irradiated onto such a SiN film 15, the Si—H bonding and the N—H bonding are once cut off, where H breaks away, and Si and N bonds again (whereby forming Si—N bonding). Due to this, the film density of the SiN film 15 becomes more dense than prior to the UV irradiation, so the etching rate decreases by the UV irradiation.
Next, as shown in
Next, as shown in
Note that, since a film density of the SiN film 16 should be high, the SiN film 16 further uses H2 gas and Ar gas that are not used in forming the SiN film 15 as above, and is formed by further applying an RF of low frequency. When the SiN film is formed as above, the SiN film 16 with high film density is formed by striking H and Ar onto the film and forcing a distance between atoms in the Si—N bonding to narrow.
The UV process (1) is performed on the SiN film 15 upon forming the SiN film 15, but no UV process is performed on the SiN film 16 upon forming the SiN film 16. This is because if the UV process is performed on the SiN film 16, a film stress thereof decreases.
Next, as shown in
By going through the respective processes as above, the SiN film 15 (Tensile SiN film) for providing the tensile stress to the region 11a is formed on the n-type transistor region 11a, and the SiN film 16 (Compressive SiN film) for providing the compressive stress to the region 11b is formed on the p-type transistor region 11b.
After the SiN film 15 and the SiN film 16 are formed at predetermined positions, as shown in FIG. (1), an SiO2 film 17 is formed on the SiN films 15, 16 as a barrier film (insulating film) (Act 1-7).
Next, as shown in
Next, as shown in
Next, as shown in
In this UV process (2), the UV light is irradiated on contact forming regions 15a, 16a of the SiN films 15, 16 where the mask 18 is not formed. However, since the UV light is absorbed by the resist (mask 18), the UV light does not reach regions 15b, 16b of the SiN films 15, 16 covered by the mask 18.
The SiN film 15 already has the UV process performed by the UV process (1). Accordingly, as show in
As shown in
The deposited SiN film 16 is a film having a smaller number of Si—H bonding and N—H bonding than the SiN film 15, and having a relatively dense film density. When the UV is irradiated onto such SiN film 16, similar to the SiN film 15, the S—H bonding and the N—H bonding are once cut off, where H breaks away, and Si and N bonds again (whereby forming Si—N bonding). However, since the number of the Si—H bondings and the N—H bondings is small, even if the UV is irradiated, the number of the Si—N bondings does not increase so much.
However, in the Si—N bonding included in the SiN film 16, the distance between atoms of Si and N is made narrow. When the UV is irradiated onto this SiN film 16, the Si—N bonding is cut off, where H breaks away, and the distance of atoms of Si and N returns to their normal distance when Si and N bonds again. Due to this, the film density of the SiN film 16 is made more sparse than prior to the UV irradiation. Accordingly, the etching rate increases by the UV irradiation.
After having performed the UV process on the contact forming regions 15a, 16a as above, as shown in
Contrary to this, if the etching condition is adjusted so that the contact forming region 15a is etched at the etching amount as planned, the SiN film 16 is under-etched, and a part of the SiN film 16 that should be removed remains.
Accordingly, in the case of not suitably irradiating the UV light to the SiN film 15 and the SiN film 16, a shape of the opening 15c and a shape of opening 16c that are formed vary due to the difference in their etching rates.
According to the present embodiment, the over-etching of the SiN film 15 and the under-etching of the SiN film 16 are suppressed, and the variation in the shapes of the substrate contacts 19a, 19b and the etching variation can be suppressed. Further, since the UV process is performed only on the contact forming regions 15a, 16a, no influence is imposed on the film property (membrane stress and the like) of the remaining SiN film 15b and SiN film 16b by the UV irradiation.
As aforementioned, according to the present embodiment, in forming the substrate contacts in the SiN films having film properties different from one another such as respectively having the tensile stress and the compressive stress, even if the concurrent etching is performed, the variation in the shape of the openings formed in the SiN films by the etching can be suppressed. Thus, a control performance of eh shapes in forming the substrate contacts can be improved. Further, in addition to suppressing the variation in the shapes of the substrate contacts and stabilizing a property of a semiconductor device, a decrease in yield caused by a margin being curtailed according to the miniaturization of the semiconductor device can be suppressed.
As shown in
In this step, the UV light is irradiated with contact forming regions 27a in the SiO2 film 27 not being removed. However, since the SiO2 film is transparent to the UV light, so the UV light irradiated on the mask 28 does not attenuate at the SiO2 film 27, and reaches the SiN films 25, 26. Accordingly, in this step, the UV process is performed on the contact forming regions 25a, 26a of the SiN films 25, 26.
Accordingly, after having performed the UV process on the contact forming regions 25a, 26a, as shown in
Accordingly, by performing the UV process (2) prior to removing the SiO2 film 27, the SiN films 25, 26 can be etched succeedingly after having etched the SiO2 film 27. Further, similar to the first embodiment, by performing the UV process prior to forming the substrate contacts 29a, 29b on the SiN films 25, 26, the difference in the etching rates upon forming the substrate contacts 29a, 29b on the n-type transistor 21a and the p-type transistor 21b can be made small. Accordingly, even if the SiN film 25 and the SiN film 26 are concurrently etched, the etching can be performed such that the etching amount of the SiN film 25 and the etching amount of the SiN film 26 both come to be at etching amounts as planned. Accordingly, a shape of the opening 25c formed on the SiN film 25 and a shape of the opening 26c formed on the SiN film 26 can both be in shapes as planned, so variations in the shape of the opening 25c and the shape of the opening 26c can be suppressed.
Especially, in the case of not performing the UV process (2) on the SiN film 26, if the etching condition is adjusted so that the contact forming region 26a is etched by the etching amount as planned, the SiN film 25 is over-etched (etched excessively), and an opening formed by the SiN film 25 being removed is widened to a side (a substrate surface direction), or a SALICIDE of a lower part thereof is damaged.
Contrary to this, if the etching condition is adjusted so that the contact forming region 25a is etched at the etching amount as planned, the SiN film 26 is under-etched, and a part of the SiN film 26 that should be removed remains.
Accordingly, in the case of not suitably irradiating the UV light to the SiN film 25 and the SiN film 26, the shape of the opening 25c and the shape of opening 26c that are formed vary due to the difference in their etching rates.
According to the present embodiment, the over-etching of the SiN film 25 and the under-etching of the SiN film 26 are suppressed, and the variation in the shapes of the substrate contacts 29a, 29b and the etching variation can be suppressed. Further, since the UV process is performed only on the contact forming regions 25a, 26a, no influence is imposed on the film property (membrane stress and the like) of the remaining SiN film 25b and SiN film 26b by the UV irradiation.
As aforementioned, according to the present embodiment also, similar to the first embodiment, in forming the substrate contacts in the SiN films having film properties different from one another such as respectively having the tensile stress and the compressive stress, even if the concurrent etching is performed, the variation in the shape of the openings formed in the SiN films by the etching can be suppressed. Thus, a control performance of eh shapes in forming the substrate contacts can be improved. Further, in addition to suppressing the variation in the shapes of the substrate contacts and stabilizing a property of a semiconductor device, a decrease in yield caused by a margin being curtailed according to the miniaturization of the semiconductor device can be suppressed.
Further, according to the present embodiment, by performing the UV process (2) prior to removing the SiO2 film 27, the SiN films 25, 26 can be etched succeedingly after having etched the SiO2 film 27. Accordingly, compared to the first embodiment, the semiconductor device can be manufactured more easily.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
For example, as the top view is shown in
Further, in the UV process (2) in each of the aforementioned embodiments, although the UV process is performed on both of the contact forming regions of both SiN films having the different film property, the UV process does not necessarily have to be performed on both of them (entire surface). That is, the UV light may be irradiated only on one of the SiN films such that the difference in the etching rates of the two SiN films having the different film property becomes small. For example, in the UV process (2), by performing the UV process only on the contact forming region of the SiN film to which the UV process is not predeterminedly performed (the SiN film providing the compressive stress), the difference in the etching rates of the two SiN films having the different film properties can be made small. Note that, in this case, prior to performing the UV process (2), the SiN film onto which the UV process is predeterminedly performed needs to be masked.
Number | Date | Country | Kind |
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2011-023998 | Feb 2011 | JP | national |