This application is based upon and claims the benefit of priority of the prior Japanese Patent Application No. 2015-087119, filed on Apr. 21, 2015, the entire contents of which are incorporated herein by reference.
The embodiments discussed herein are directed to a compound semiconductor device, a method of manufacturing the same, and the like.
A nitride semiconductor has characteristics such as a high saturation electron velocity and a wide band gap. Accordingly, various studies have been made on application of nitride semiconductor to high-withstand voltage and high-output semiconductor devices by utilizing these characteristics. For example, the band gap of GaN as one of nitride semiconductors is 3.4 eV, which is larger than the band gap (1.1 eV) of Si and the band gap (1.4 eV) of GaAs. Thus, GaN has high breakdown electric field intensity and holds great promise as a material of a semiconductor device for power supplies which obtain a high withstand voltage and high output.
With respect to semiconductor devices including nitride semiconductor, various reports have been made on field effect transistors, particularly high electron mobility transistors (HEMT). For example, as a GaN-based HEMT, an AlGaN/GaN-HEMT is attracting attention, in which GaN is used for a carrier transit layer (channel layer) and AlGaN is used for a carrier supply layer (barrier layer). A distortion caused by a lattice mismatch between GaN and AlGaN occurs in the AlGaN in the AlGaN/GaN-HEMT. Two-dimensional electron gas (2 DEG) at a high concentration is obtained due to piezoelectric polarization generated by the distortion and autonomous polarization of the AlGaN. Thus, the AlGaN/GaN-HEMT is expected as a high-withstand voltage power device preferred for transmitting power amplifiers of a base station, high-efficiency switch elements, electric vehicles, and the like.
However, when a high voltage is applied to a drain electrode, a leak current may flow between the drain electrode and a substrate, or a sufficient breakdown withstand voltage may not be obtained. They are significant particularly when Si is used as a material for a substrate for the purpose of cost reduction. Although a technique to use a buffer layer having a superlattice structure containing carbon has been proposed, it cannot achieve a sufficient withstand voltage.
Patent Literature 1: Japanese Laid-Open Patent Publication No. 2008-171843
Patent Literature 2: Japanese Laid-Open Patent Publication No. 2013-30725
According to an aspect of the embodiments, a compound semiconductor device includes: a substrate; a nucleation layer over the substrate; a first buffer layer over the nucleation layer; a second buffer layer between the nucleation layer and the first buffer layer, the second buffer layer containing an acceptor impurity element or a donor impurity element at a higher concentration than the first buffer layer; a carrier transit layer in contact with the first buffer layer; a carrier supply layer over the carrier transit layer; and a gate electrode, a source electrode, and a drain electrode above the carrier supply layer.
According to another aspect of the embodiments, a method of manufacturing a compound semiconductor device includes: forming a nucleation layer over a substrate; forming a first buffer layer over the nucleation layer; forming a second buffer layer between the nucleation layer and the first buffer layer, the second buffer layer containing an acceptor impurity element or a donor impurity element at a higher concentration than the first buffer layer; forming a carrier transit layer in contact with the first buffer layer; forming a carrier supply layer over the carrier transit layer; and forming a gate electrode, a source electrode, and a drain electrode above the carrier supply layer.
The object and advantages of the invention will be realized and attained by means of the elements and combinations particularly pointed out in the claims.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are not restrictive of the invention.
Hereinafter, embodiments will be explained specifically with reference to accompanying drawings.
First, a first embodiment will be explained. The first embodiment is an example of a high electron mobility transistor (HEMT).
The compound semiconductor device 100 according to the first embodiment includes, as illustrated in
The substrate 101 is, for example, a Si substrate, a SiC substrate, a sapphire substrate, or a GaN substrate. The nucleation layer 102 is, for example, an AlN layer having a thickness of about 200 nm. The lower buffer layer 103 is, for example, an Al0.2Ga0.8N layer (p-type AlGaN layer) having a thickness of about 200 nm and containing Mg at a concentration of about 5×1019 cm−3. Mg is an example of an acceptor impurity. The upper buffer layer 104 is, for example, an Al0.2Ga0.8N layer (i-type AlGaN layer) having a thickness of about 100 nm to 600 nm and being not intentionally doped with impurity. The carrier transit layer 105 is, for example, a GaN layer (i-type GaN layer) having a thickness of about 1 μm and being not intentionally doped with impurity. The carrier supply layer 106 is, for example, an Al0.2Ga0.8N layer (n-type AlGaN layer) having a thickness of about 20 nm and containing a donor impurity such as Si or an Al0.2Ga0.8N layer (i-type AlGaN layer) having a thickness of about 20 nm and being not intentionally doped with impurity. The gate electrode 111 includes, for example, a Ni film and an Au film over the Ni film, and the source electrode 112 and the drain electrode 113 include, for example, a Ti film and an Al film over the Ti film. The gate electrode 111 is in Schottky contact with a layered structure 107 of the nucleation layer 102, the lower buffer layer 103, the upper buffer layer 104, the carrier transit layer 105, and the carrier supply layer 106. The source electrode 112 and the drain electrode 113 are in ohmic contact with the layered structure 107.
In the first embodiment, since the lower buffer layer 103 contains an acceptor impurity element at a higher concentration than the upper buffer layer 104, the potential of the nucleation layer 102 is high on the lower buffer layer 103 side, as illustrated in
In a reference example illustrated in
Here, simulations related to the first embodiment carried out by the present inventor will be explained. In the simulations, a technology CAD (technology computer aided design: TCAD) was used to calculate a withstand voltage and a band structure in a model illustrated in
In the simulation of the withstand voltage, the ohmic electrode 115 was grounded, the voltage to be applied to the ohmic electrode 114 was changed, and the current flowing between the ohmic electrode 114 and the ohmic electrode 115 was calculated. Results thereof are illustrated in
As illustrated in
Next, a method of manufacturing the compound semiconductor device according to the first embodiment will be explained.
First, as illustrated in
Then, an element isolation region is formed, which defines an element region in the layered structure 107 of the nucleation layer 102, the lower buffer layer 103, the upper buffer layer 104, the carrier transit layer 105, and the carrier supply layer 106. In formation of the element isolation regions, for example, a pattern of a photoresist exposing a region where the element isolation region is to be formed is formed over the carrier supply layer 106, and this pattern is used as a mask to inject ions of Ar or the like. Dry etching using a chlorine-based gas with this pattern being an etching mask may be performed instead of the ion-injection. Thereafter, as illustrated in
Then a protection film, wirings, and so on are formed as necessary, thereby completing the compound semiconductor device.
Next, a second embodiment will be explained. The second embodiment is an example of a high electron mobility transistor (HEMT).
The compound semiconductor device 200 according to the second embodiment includes, as illustrated in
In the second embodiment, since the lower buffer layer 103 contains an acceptor impurity element at a higher concentration than the upper buffer layer 204, the potential of the nucleation layer 102 is high on the lower buffer layer 103 side, as illustrated in
Further, the upper buffer layer 204 of the superlattice structure may alleviate a lattice distortion more than the upper buffer layer 104 of AlGaN, and thus the layered structure 207, which includes the upper buffer layer 204, may be formed thicker than the layered structure 107. Therefore, a higher withstand voltage may be obtained.
When the compound semiconductor device 200 is manufactured, the upper buffer layer 204 may be formed instead of the upper buffer layer 104 by the crystal growth method such as an MOCVD method or an MBE method.
Next, a third embodiment will be explained. The third embodiment is an example of a high electron mobility transistor (HEMT).
The compound semiconductor device 300 according to the third embodiment includes, as illustrated in
In the third embodiment, since the lower buffer layer 303 contains a donor impurity element at a higher concentration than the upper buffer layer 104, the potential of the nucleation layer 102 is high on the lower buffer layer 303 side, as illustrated in
For manufacturing the compound semiconductor device 300, the lower buffer layer 303 may be formed instead of the lower buffer layer 103 by a crystal growth method such as an MOCVD method or an MBE method.
Next, a fourth embodiment will be explained. The fourth embodiment is an example of a high electron mobility transistor (HEMT).
The compound semiconductor device 400 according to the fourth embodiment includes, as illustrated in
According to the fourth embodiment, the same effects as those of the second embodiment and the third embodiment may be obtained.
A thickness of a lower buffer layer is not particularly limited, and is preferably 200 nm or less. In general, the thicker a compound semiconductor layer is formed, the easier it may be cracked due to the influence of a lattice distortion or the like. On the other hand, although depending on the usage, sufficient effects may be obtained easily even when a thickness of a lower buffer layer is not more than 200 nm. Therefore, a thickness of a lower buffer layer is preferably 200 nm or less.
A lower buffer layer preferably has a thickness corresponding to a voltage applied to a drain electrode.
An Element for an acceptor impurity or a donor impurity contained in a lower buffer layer is not limited in particular. Mg and Zn are exemplified as the acceptor impurity element, for example. Si, O, Ge, Te, and Se are exemplified as the donor impurity element, for example. A concentration of an acceptor impurity element or a donor impurity element is not limited in particular, and is preferred to be 1×1018 cm−3 or more and 1×1021 cm−3 or less. When a concentration of an impurity element is less than 1×1018 cm−3, there is a possibility that sufficient effects are not obtained. When a concentration of an impurity element is more than 1×1021 cm−3, there is a possibility that sufficient crystallinity is not obtained.
Whether an impurity contained in a lower buffer layer is an acceptor impurity elements or an donor impurity elements, it is preferred that the carrier concentration in the lower buffer layer is equal to or more than 1×1018 cm−3. When the carrier concentration is less than 1×1018 cm−3, there is a possibility that sufficient effects are not obtained. Change of carrier contained in a lower buffer layer will be explained.
In the case where the activation energy of impurity contained in a lower buffer layer is low, carriers are released by heat energy even in thermal equilibrium, as illustrated in
On the other hand, in the case where the activation energy of impurity contained in a lower buffer layer is high, carriers are not released by heat energy of about 25 meV in thermal equilibrium, as illustrated in
The nucleation layer 102 is preferably not intentionally doped with an impurity. When an impurity such as Si is doped in the nucleation layer 102, pits 121 are generated easily due to a difference in lattice constant, thermal expansion coefficient or the like from the substrate 101, as illustrated in
The upper buffer layer 204 of superlattice structure is preferably not doped with an acceptor impurity element such as carbon. As illustrated in
A layer may exist between the lower buffer layer and the nucleation layer, but preferably a lower surface of the lower buffer layer is in contact with an upper surface of the nucleation layer. This is because when a layer which is not particularly needed exists, this may lead to decrease in the thicknesses of the buffer layer, the carrier transit layer, and the carrier supply layer by the thickness of that layer, since the thicker the compound semiconductor layer is formed, the easier it can be cracked due to the influence of a lattice distortion or the like, as described above.
Although the Schottky gate structure is employed in the first to fourth embodiments, a structure in which a gate insulating film exists between the gate electrode and the carrier supply layer, that is, an MIS (metal insulator semiconductor) structure may be employed.
Next, a fifth embodiment is described. The fifth embodiment relates to a discrete package of a compound semiconductor device which includes a GaN-based HEMT.
In the fifth embodiment, as illustrated in
The discrete package may be manufactured by the procedures below, for example. First, the HEMT chip 1210 is bonded to the land 1233 of a lead frame, using a die attaching agent 1234 such as solder. Next, with the wires 1235g, 1235d and 1235s, the gate pad 1226g is connected to the gate lead 1232g of the lead frame, the drain pad 1226d is connected to the drain lead 1232d of the lead frame, and the source pad 1226s is connected to the source lead 1232s of the lead frame, respectively, by wire bonding. The molding with the molding resin 1231 is conducted by a transfer molding process. The lead frame is then cut away.
Next, a sixth embodiment is described. The sixth embodiment relates to a PFC (power factor correction) circuit equipped with a compound semiconductor device which includes a GaN-based HEMT.
A PFC circuit 1250 has a switching element (transistor) 1251, a diode 1252, a choke coil 1253, capacitors 1254 and 1255, a diode bridge 1256, and an AC power source (AC) 1257. The drain electrode of the switching element 1251, the anode terminal of the diode 1252, and one terminal of the choke coil 1253 are connected with each other. The source electrode of the switching element 1251, one terminal of the capacitor 1254, and one terminal of the capacitor 1255 are connected with each other. The other terminal of the capacitor 1254 and the other terminal of the choke coil 1253 are connected with each other. The other terminal of the capacitor 1255 and the cathode terminal of the diode 1252 are connected with each other. A gate driver is connected to the gate electrode of the switching element 1251. The AC 1257 is connected between both terminals of the capacitor 1254 via the diode bridge 1256. A DC power source (DC) is connected between both terminals of the capacitor 1255. In the embodiment, the compound semiconductor device according to any one of the first to fourth embodiments is used as the switching element 1251.
In the method of manufacturing the PFC circuit 1250, for example, the switching element 1251 is connected to the diode 1252, the choke coil 1253 and so forth with solder, for example.
Next, a seventh embodiment is described. The seventh embodiment relates to a power supply apparatus equipped with a compound semiconductor device which includes a GaN-based HEMT.
The power supply apparatus includes a high-voltage, primary-side circuit 1261, a low-voltage, secondary-side circuit 1262, and a transformer 1263 arranged between the primary-side circuit 1261 and the secondary-side circuit 1262.
The primary-side circuit 1261 includes the PFC circuit 1250 according to the sixth embodiment, and an inverter circuit, which may be a full-bridge inverter circuit 1260, for example, connected between both terminals of the capacitor 1255 in the PFC circuit 1250. The full-bridge inverter circuit 1260 includes a plurality of (four, in the embodiment) switching elements 1264a, 1264b, 1264c and 1264d.
The secondary-side circuit 1262 includes a plurality of (three, in the embodiment) switching elements 1265a, 1265b and 1265c.
In the embodiment, the compound semiconductor device according to any one of first to fourth embodiments is used for the switching element 1251 of the PFC circuit 1250, and for the switching elements 1264a, 1264b, 1264c and 1264d of the full-bridge inverter circuit 1260. The PFC circuit 1250 and the full-bridge inverter circuit 1260 are components of the primary-side circuit 1261. On the other hand, a silicon-based general MIS-FET (field effect transistor) is used for the switching elements 1265a, 1265b and 1265c of the secondary-side circuit 1262.
Next, an eighth embodiment is explained. The eighth embodiment relates to an amplifier equipped with the compound semiconductor device which includes a GaN-based HEMT.
The amplifier includes a digital predistortion circuit 1271, mixers 1272a and 1272b, and a power amplifier 1273.
The digital predistortion circuit 1271 compensates non-linear distortion in input signals. The mixer 1272a mixes the input signal having the non-linear distortion already compensated, with an AC signal. The power amplifier 1273 includes the compound semiconductor device according to any one of the first to fourth embodiments, and amplifies the input signal mixed with the AC signal. In the embodiment, the signal on the output side may be mixed, upon switching, with an AC signal by the mixer 1272b, and may be sent back to the digital predistortion circuit 1271. The amplifier may be used as a high-frequency amplifier or a high-output amplifier.
In the above-described compound semiconductor device and the like, a leak current can be suppressed even when a high voltage is applied to a drain electrode because an appropriate second buffer layer is included.
All examples and conditional language provided herein are intended for the pedagogical purposes of aiding the reader in understanding the invention and the concepts contributed by the inventor to further the art, and are not to be construed as limitations to such specifically recited examples and conditions, nor does the organization of such examples in the specification relate to a showing of the superiority and inferiority of the invention. Although one or more embodiments of the present invention have been described in detail, it should be understood that the various changes, substitutions, and alterations could be made hereto without departing from the spirit and scope of the invention.
Number | Date | Country | Kind |
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2015-087119 | Apr 2015 | JP | national |