This application claims priority to Korean Patent Application No. 10-2017-0098469 filed on Aug. 3, 2017 in the Korean Intellectual Property Office, the disclosure of which is hereby incorporated herein by reference in its entirety.
The inventive concept relates generally to semiconductor devices and, more particularly, to methods of fabricating semiconductor devices using a fringe signal.
A volatile memory device loses stored data when power is removed or lost. Volatile memory devices generally include static random access memory (SRAM), dynamic RAM (DRAM), synchronous DRAM (SDRAM), and the like. A nonvolatile memory device retains stored data even when power is removed or turned off. Nonvolatile memory devices general include flash memory devices, read only memory (ROM), programmable ROM (PROM), electrically programmable ROM (EPROM), electrically erasable and programmable ROM (EEPROM), resistive memory device, for example, phase-change RAM (PRAM), ferroelectric RAM (FRAM), resistive RAM (RRAM)), and the like.
Integration density of the nonvolatile memory devices keeps increasing in order to meet customer demands for better performance and lower cost. However, for the two-dimensional or planar memory device, the integration density is determined by the area occupied by the unit memory cells. Therefore, in recent years, three-dimensional (3D) memory device with vertical arrangement of unit memory cells has been developed.
Some embodiments of the present inventive concept provide methods of fabricating a semiconductor device, which forms a mold layer having a stepped structure by controlling the degree of etching of side surfaces of a photoresist pattern using a fringe signal measurement.
In some embodiments of the present inventive concept, a method for fabricating a semiconductor device is provided including forming a stacked structure, wherein the stacked structure comprises a first mold layer and a second mold layer sequentially stacked on a substrate, forming a first photoresist pattern on the stacked structure, etching the second mold layer using the first photoresist pattern as a mask, forming a second photoresist pattern by etching a portion of the first photoresist pattern, measuring a first fringe signal generated by an interference phenomenon between first reflected lights reflected from the first photoresist pattern, forming a stepped structure by etching the second mold layer and the first mold layer which is exposed, using the second photoresist pattern as a mask, measuring a second fringe signal generated by an interference phenomenon between second reflected lights reflected from the second mold layer, calculating a third fringe signal by summing the first fringe signal and the second fringe signal, calculating a first etch rate of an upper surface of the first photoresist pattern using the third fringe signal, calculating a second etch rate of a side surface of the first photoresist pattern using the first etch rate, and controlling a degree of etching the side surface of the second photoresist pattern using the second etch rate.
In further embodiments of the present inventive concept, methods for fabricating a semiconductor device are providing including providing a substrate comprising a first region, a second region and a third region, forming a stacked structure, wherein the stacked structure comprises a first mold layer and a second mold layer sequentially stacked on the substrate, forming a photoresist pattern on the stacked structure to overlap the first region and the second region, etching the second mold layer formed on the third region using the photoresist pattern as a mask, etching a portion of an upper surface of the photoresist pattern and the photoresist pattern overlapping the second region, measuring a first signal using first reflected light reflected from the upper surface of the photoresist pattern while the portion of the upper surface of the photoresist pattern is being etched, etching the second mold layer formed on the second region and the first mold layer formed on the third region, using the etched photoresist pattern overlapping the first region as a mask, measuring a second signal using second reflected light reflected from the second mold layer while the second mold layer formed on the second region is being etched, calculating a third signal by summing the first signal and the second signal, calculating a first etch rate of the upper surface of the photoresist pattern using the third signal, calculating a second etch rate of a side surface of the photoresist pattern using the first etch rate, and controlling a degree of etching the side surface of the second photoresist pattern using the second etch rate.
In still further embodiments of the present inventive concept, methods for fabricating a semiconductor device are provided including forming a stacked structure, wherein the stacked structure comprises a first mold layer, a second mold layer, and a third mold layer sequentially stacked on a substrate, forming a first photoresist pattern on the stacked structure, etching the third mold layer using the first photoresist pattern as a mask, forming a second photoresist pattern by etching a portion of an upper surface and a portion of a side surface of the first photoresist pattern, measuring a first fringe signal generated by an interference phenomenon between first reflected lights reflected from the upper surface of the first photoresist pattern while forming the second photoresist pattern, forming a stepped structure by etching the third mold layer and the second mold layer which is exposed, using the second photoresist pattern as a mask, measuring a second fringe signal generated by an interference phenomenon between second reflected lights reflected from the third mold layer while the third mold layer is being etched, calculating a third fringe signal by summing the first fringe signal and the second fringe signal, calculating a first etch rate of the upper surface of the first photoresist pattern using the third fringe signal, calculating a second etch rate of the side surface of the first photoresist pattern using the first etch rate, forming a third photoresist pattern by etching a portion of the upper surface and a portion of the side surface of the second photoresist pattern using the first etch rate and the second etch rate, and forming a stepped structure by etching the third mold layer, the second mold layer which is exposed, and the first mold layer which is exposed, using the third photoresist pattern.
The above and other embodiments, features and advantages of the present inventive concept will become more apparent to those of ordinary skill in the art by describing in detail embodiments thereof with reference to the accompanying drawings, in which:
Specific embodiments of the inventive concept now will be described with reference to the accompanying drawings. This inventive concept may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the inventive concept to those skilled in the art. In the drawings, like numbers refer to like elements. It will be understood that when an element is referred to as being “connected” or “coupled” to another element, it can be directly connected or coupled to the other element or intervening elements may be present. As used herein the term “and/or” includes any and all combinations of one or more of the associated listed items.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the inventive concept. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless expressly stated otherwise. It will be further understood that the terms “includes,” “comprises,” “including” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this inventive concept belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the specification and the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
Methods for fabricating semiconductor devices according to some embodiments of the present inventive concept will be discussed with respect to
By way of example, embodiments will be described herein with reference to an etching process for forming a word line pad having a stepped structure in a vertical NAND flash memory fabrication process. However, embodiments of the present inventive concept are not limited thereto. For example, in some embodiments, a method for fabricating a semiconductor device according to the present inventive concept may also be used for forming a structure having a stepped structure in the manufacturing processes of any of a planar NAND flash memory, a PRAM memory, or a DRAM memory.
Referring first to
The stacked structure 120 may include a first sacrificial layer 104 and a second sacrificial layer 106 alternately stacked on the substrate 100. In these embodiments, each of the first mold layer 112, the second mold layer 114 and the third mold layer 116 may include one first sacrificial layer 104 and one second sacrificial layer 106.
While
While
The first sacrificial layer 104 may be formed of a material having an etch selectivity to the second sacrificial layer 106. The first sacrificial layer 104 may include silicon nitride and the second sacrificial layer 106 may include silicon oxide. However, embodiments of the present inventive concept are not limited thereto. For example, in some embodiments, the first sacrificial layer 104 and the second sacrificial layer 106 may respectively include films made from silicon oxides having different etch rate from each other.
Referring to
Referring to
Referring to
A second photoresist pattern 140 may be formed by etching a portion of the upper surface and a portion of the side surface of the first photoresist pattern 130 (
For example, a side portion of the first photoresist pattern 130 (
A first etched thickness t1 of the upper surface of the first photoresist pattern 130 (
While
During etching of the portion of the upper surface and the portion of the side surface of the first photoresist pattern 130 (
Measuring the first fringe signal F1 may be performed simultaneously during the etching of the portion of the upper surface and the portion of the side surface of the first photoresist pattern 130 (
Referring to
Occurrence of one constructive interference and one destructive interference between the first reflected lights L1 may be defined as one cycle of the first fringe signal F1. For example, as shown in
For example, in
Some embodiments of the present inventive concept can calculate a third fringe signal using the number of cycles of the first fringe signal F1 according to the etching process time. These embodiments will be discussed further herein.
Referring to
In particular, using the second photoresist pattern 140 as a mask, the third mold layer 116 overlapping the third region R3 of the substrate 100, and the second mold layer 114 overlapping the fourth region R4 of the substrate 100 may be etched, respectively.
This may result in exposure of the upper surface of the second mold layer 114 on the third region R3 of the substrate 100, and the upper surface of the first mold layer 112 on the fourth region R4 of the substrate 100, respectively. Through this etching process, a stepped structure may be formed.
During etching of the third mold layer 116 overlapping the third region R3 of the substrate 100, light may be irradiated onto the upper surface of the third mold layer 116 in real time, and a second fringe signal F2, which is generated by the interference phenomenon between the second reflected lights L2 reflected from the upper surface of the third mold layer 116, may be measured.
Measuring the second fringe signal F2 may be performed simultaneously during the etching of the third mold layer 116. However, embodiments of the present inventive concept are not limited thereto. For example, in some embodiments, measuring the second fringe signal F2 may be performed after a predetermined time interval from the etching of the third mold layer 116.
Referring to
Occurrence of one constructive interference and one destructive interference between the second reflected lights L2 may be defined as one cycle of the second fringe signal F2. For example, as shown in
Likewise
For example, in
Some embodiments of the present inventive concept can calculate a third signal at (block S150), by summing up the number of cycles of the first fringe signal F1 (
The number of cycles of the third fringe signal corresponds to a sum of the number of cycles (i.e., 3.25) of the first fringe signal F1 (
A first etch rate of the upper surface of the first photoresist pattern 130 (
In particular, the first etch rate may be calculated by using a predetermined ratio of a first etched thickness t1 (
A second etch rate of the side surface of the first photoresist pattern 130 (
In particular, the second etch rate may be calculated by using a predetermined ratio of the first etch rate to the second etch rate. In these embodiments, the first etch rate and the second etch rate may be different from each other. For example, the first etch rate may be less than the second etch rate. In these embodiments, a first etched thickness t1 (
For example, when the ratio of the first etch rate to the second etch rate is 0.8, the ratio of the first etched thickness t1 (
Although in embodiments discussed above, the first etch rate and the second etch rate are different from each other, embodiments of the present inventive concept are not limited thereto. Accordingly, in some embodiments, the first etch rate and the second etch rate may be equal to each other without departing from the scope of the present inventive concept.
Referring to
In particular, the first etch rate of the upper surface of the first photoresist pattern 130 (
Using the calculated first etch rate, the first etched thickness t1 (
Accordingly, the second etched thickness t2 (
Referring to
For example, the portion of the side surface of the second photoresist pattern 140 (
The portion of the upper surface and the portion of the side surface of the second photoresist pattern 140 (
In these embodiments, the first etched thickness t1 (
This may result in the width of the exposed upper surface of the third mold layer 116 on the second region R2 of the substrate 100 to be equal to the width of the exposed upper surface of the second mold layer 114 on the third region R3 of the substrate 100. For example, the width of the second region R2 of the substrate 100 may be defined to be equal to the width of the third region R3 of the substrate 100.
However, embodiments of the present inventive concept are not limited thereto. For example, in some embodiments, the first etched thickness t1 (
This may result in the width of the exposed upper surface of the third mold layer 116 on the second region R2 of the substrate 100 to be different from the width of the exposed upper surface of the second mold layer 114 on the third region R3 of the substrate 100. For example, the width of the second region R2 of the substrate 100 may be defined to be different from the width of the third region R3 of the substrate 100.
Referring to
This may result in exposure of the upper surface of the second mold layer 114 on the second region R2 of the substrate 100, the upper surface of the first mold layer 112 on the third region R3 of the substrate 100, and the upper surface of the impurity region 102 on the fourth region R4 of the first region R4, respectively. Through this etching process, a stepped structure may be formed.
Methods for fabricating semiconductor devices according to some embodiments of the present inventive concept are capable of precisely controlling the second etched thickness t2 (
Accordingly, methods for fabricating a semiconductor device according to some embodiments of the present inventive concept are capable of precisely controlling the widths of the upper surfaces of the respective mold layers having a stepped structure by precisely controlling the etched thickness t2 (
Hereinafter, methods for fabricating a semiconductor device according to some embodiments of the present inventive concept will be described with reference to
Referring to
The fourth photoresist pattern 160 may be formed so as to overlap the first and second regions R1 and R2 of the substrate 100. This may result in exposure of the upper surface of the third mold layer 116 of the stacked structure 120 formed on the third region R3 of the substrate.
A third etched thickness t3 of the upper surface of the first photoresist pattern 130 (
The third etched thickness t3 and the fourth etched thickness t4 are equal to each other because the etch rate of the upper surface of the first photoresist pattern 130 (
Referring to
This may result in exposure of the upper surface of the second mold layer 114 on the third region R3 of the substrate 100, and the upper surface of the first mold layer 112 on the fourth region R4 of the substrate 100, respectively. Through this etching process, a stepped structure may be formed.
Referring to
The fifth photoresist pattern 160 may be formed so as to overlap the first region R1 of the substrate 100. This may result in exposure of the upper surface of the third mold layer 116 of the stacked structure 120 formed on the second region R2 of the substrate.
A third etched thickness t3 of the upper surface of the fourth photoresist pattern 160 (
The third etched thickness t3 and the fourth etched thickness t4 are equal to each other because the etch rate of the upper surface of the fourth photoresist pattern 160 (
Referring to
This may result in exposure of the upper surface of the second mold layer 114 on the second region R2 of the substrate 100, the upper surface of the first mold layer 112 on the third region R3 of the substrate 100, and the upper surface of the impurity region 102 on the fourth region R4 of the first region R4, respectively. Through this etching process, a stepped structure may be formed.
Exemplary embodiments according to the present inventive concept were explained hereinabove with reference to the drawings attached, but it should be understood that embodiments of the present inventive concept are not limited to the aforementioned embodiments, but may be fabricated in various different forms, and may be implemented by a person skilled in the art in other specific forms without altering the disclosure or characteristics of the present disclosure. Accordingly, it will be understood that the embodiments described above are only illustrative, and should not be construed as limiting.
Number | Date | Country | Kind |
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10-2017-0098469 | Aug 2017 | KR | national |