Relaxed SiGe platform for high speed CMOS electronics and high speed analog circuits

Abstract
Structures and methods for fabricating high speed digital, analog, and combined digital/analog systems using planarized relaxed SiGe as the materials platform. The relaxed SiGe allows for a plethora of strained Si layers that possess enhanced electronic properties. By allowing the MOSFET channel to be either at the surface or buried, one can create high-speed digital and/or analog circuits. The planarization before the device epitaxial layers are deposited ensures a flat surface for state-of-the-art lithography.
Description
BACKGROUND OF THE INVENTION

The invention relates to the field of relaxed SiGe platforms for high speed CMOS electronics and high speed analog circuits.


Si CMOS as a platform for digital integrated circuits has progressed predictably through the industry roadmap. The progress is created through device miniaturization, leading to higher performance, greater reliability, and lower cost. However, new bottlenecks in data flow are appearing as the interconnection hierarchy is expanded. Although digital integrated circuits have progressed at unprecedented rates, analog circuitry has hardly progressed at all. Furthermore, it appears that in the near future, serious economic and technological issues will confront the progress of digital integrated circuits.


The digital and communication chip markets need an enhancement to Si CMOS and the maturing roadmap. One promising candidate material that improves digital integrated circuit technology and introduces new analog integrated circuit possibilities is relaxed SiGe material on Si substrates. Relaxed SiGe alloys on Si can have thin layers of Si deposited on them, creating tension in the thin Si layers. Tensile Si layers have many advantageous properties for the basic device in integrated circuits, the metal-oxide field effect transistor (MOSFET). First, placing Si in tension increases the mobility of electrons moving parallel to the surface of the wafer, thus increasing the frequency of operation of the MOSFET and the associated circuit. Second, the band offset between the relaxed SiGe and the tensile Si will confine electrons in the Si layer. Therefore, in an electron channel device (n-channel), the channel can be removed from the surface or ‘buried’. This ability to spatially separate the charge carriers from scattering centers such as ionized impurities and the ‘rough’ oxide interface enables the production of low noise, high performance analog devices and circuits.


A key development in this field was the invention of relaxed SiGe buffers with low threading dislocation densities. The key background inventions in this area are described in U.S. Pat. No. 5,442,205 issued to Brasen et al. and U.S. Pat. No. 6,107,653 issued to Fitzgerald. These patents define the current best methods of fabricating high quality relaxed SiGe.


Novel device structures in research laboratories have been fabricated on early, primitive versions of the relaxed buffer. For example, strained Si, surface channel nMOSFETs have been created that show enhancements of over 60% in intrinsic gm with electron mobility increases of over 75% (Rim et al, IEDM 98 Tech. Dig. p. 707). Strained Si, buried channel devices demonstrating high transconductance and high mobility have also been fabricated (U. Konig, MRS Symposium Proceedings 533, 3 (1998)). Unfortunately, these devices possess a variety of problems with respect to commercialization. First, the material quality that is generally available is insufficient for practical utilization, since the surface of SiGe on Si becomes very rough as the material is relaxed via dislocation introduction. These dislocations are essential in the growth of relaxed SiGe layers on Si since they compensate for the stress induced by the lattice mismatch between the materials. For more than 10 years, researchers have tried to intrinsically control the surface morphology through epitaxial growth, but since the stress fields from the misfit dislocations affect the growth front, no intrinsic epitaxial solution is possible. The invention describes a method of planarization and regrowth that allows all devices on relaxed SiGe to possess a significantly flatter surface. This reduction in surface roughness increases the yield for fine-line lithography, thus enabling the manufacture of strained Si devices.


A second problem with the strained Si devices made to date is that researchers have been concentrating on devices optimized for very different applications. The surface channel devices have been explored to enhance conventional MOSFET devices, whereas the buried channel devices have been constructed in ways that mimic the buried channel devices previously available only in III–V materials systems, like AlGaAs/GaAs. Recognizing that the Si manufacturing infrastructure needs a materials platform that is compatible with Si, scalable, and capable of being used in the plethora of Si integrated circuit applications, the disclosed invention provides a platform that allows both the enhancement of circuits based on Si CMOS, as well as the fabrication of analog circuits. Thus, high performance analog or digital systems can be designed with this platform. An additional advantage is that both types of circuits can be fabricated in the CMOS process, and therefore a combined, integrated digital/analog system can be designed as a single-chip solution.


With these advanced SiGe material platforms, it is now possible to provide a variety of device and circuit topologies that take advantage of this new materials system. Exemplary embodiments of the invention describe structures and methods to fabricate advanced strained-layer Si devices, and structures and methods to create circuits based on a multiplicity of devices, all fabricated from the same starting material platform. Starting from the same material platform is key to minimizing cost as well as to allowing as many circuit topologies to be built on this platform as possible.


SUMMARY OF THE INVENTION

Accordingly, the invention provides a material platform of planarized relaxed SiGe with regrown device layers. The planarization and regrowth strategy allows device layers to have minimal surface roughness as compared to strategies in which device layers are grown without planarization. This planarized and regrown platform is a host for strained Si devices that can possess optimal characteristics for both digital and analog circuits. Structures and processes are described that allow for the fabrication of high performance digital logic or analog circuits, but the same structure can be used to host a combination of digital and analog circuits, forming a single system-on-chip.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a schematic block diagram of a structure including a relaxed SiGe layer epitaxially grown on a Si substrate;



FIG. 2 is a schematic block diagram of an exemplary structure showing that the origin of the crosshatch pattern is the stress fields from injected misfit dislocations;



FIG. 3 is a table showing surface roughness data for relaxed SiGe buffers produced by dislocation injection via graded SiGe layers on Si substrates;



FIGS. 4A–4D show an exemplary process flow and resulting platform structure in accordance with the invention;



FIGS. 5A–5D are schematic diagrams of the corresponding process flow and layer structure for a surface channel FET platform in accordance with the invention;



FIGS. 6A–6D are schematic diagrams of the corresponding process flow and layer structure for a buried channel FET platform in accordance with the invention;



FIGS. 7A–7D are schematic diagrams of a process flow for a surface channel MOSFET in accordance with the invention;



FIGS. 8A and 8B are schematic block diagrams of surface channel devices with protective layers;



FIGS. 9A and 9B are schematic block diagrams of surface channel devices with Si layers on Ge-rich layers for use in silicide formation;



FIG. 10 is schematic diagram of a buried channel MOSFET after device isolation in accordance with the invention;



FIG. 11 is a schematic flow of the process, for any heterostructure FET device deposited on relaxed SiGe, in accordance with the invention;



FIGS. 12A–12D are schematic diagrams of a process flow in the case of forming the surface channel MOSFET in the top strained Si layer in accordance with the invention;



FIGS. 13A–13D are schematic diagrams of a process flow in the case of forming the surface channel MOSFET in the buried strained Si layer in accordance with the invention; and



FIGS. 14A and 14B are schematic diagrams of surface and buried channel devices with Si1-yGey channels on a relaxed Si1-zGez layer.





DETAILED DESCRIPTION OF THE INVENTION


FIG. 1 is a schematic block diagram of a structure 100 including a relaxed SiGe layer epitaxially grown on a Si substrate 102. In this structure, a compositionally graded buffer layer 104 is used to accommodate the lattice mismatch between the uniform SiGe layer 106 and the Si substrate. By spreading the lattice mismatch over a distance, the graded buffer minimizes the number of dislocations reaching the surface and thus provides a method for growing high-quality relaxed SiGe films on Si.


Any method of growing a high-quality, relaxed SiGe layer on Si will produce roughness on the surface of the SiGe layer in a well-known crosshatch pattern. This crosshatch pattern is typically a few hundred angstroms thickness over distances of microns. Thus, the crosshatch pattern is a mild, undulating surface morphology with respect to the size of the electron or hole. For that reason, it is possible to create individual devices that achieve enhancements over their control Si device counterparts. However, commercialization of these devices requires injection of the material into the Si CMOS process environment to achieve low cost, high performance targets. This processing environment requires that the material and device characteristics have minimal impact on the manufacturing process. The crosshatch pattern on the surface of the wafer is one limiting characteristic of relaxed SiGe on Si that affects the yield and the ease of manufacture. Greater planarity is desired for high yield and ease in lithography.


The origin of the crosshatch pattern is the stress fields from the injected misfit-dislocations. This effect is depicted by the exemplary structure 200 shown in FIG. 2. By definition, the dislocations must be introduced in order to accommodate the lattice-mismatch between the SiGe alloy and the Si substrate. The stress fields originate at the dislocations, and are terminated at the surface of the film. However, the termination at the surface creates crystal lattices that vary from place to place on the surface of the wafer. Since growth rate can be correlated to lattice constant size, different thicknesses of deposition occur at different points on the wafer. One may think that thick layer growth beyond the misfit dislocations will smooth the layer of these thickness differences. Unfortunately, the undulations on the surface have a relatively long wavelength; therefore, surface diffusion is typically not great enough to remove the morphology.



FIG. 3 is a table that displays surface roughness data for relaxed SiGe buffers produced by dislocation injection via graded SiGe layers on Si substrates. Note that the as-grown crosshatch pattern for relaxed Si0.8Ge0.2 buffers creates a typical roughness of approximately 7.9 nm. This average roughness increases as the Ge content in the relaxed buffer is increased. Thus, for any SiGe layer that is relaxed through dislocation introduction during growth, the surface roughness is unacceptable for state-of-the-art fabrication facilities. After the process in which the relaxed SiGe is planarized, the average roughness is less than 2 nm (typically 0.57 nm), and after device layer deposition, the average roughness is 0.77 nm with a 1.5 μm regrowth thickness. Therefore, after the complete structure is fabricated, over one order of magnitude of roughness reduction can be achieved.


The regrowth device layers can be either greater than or less than the critical thickness of the regrowth layer. In general, in any lattice-mismatched epitaxial growth, thin layers can be deposited without fear of dislocation introduction at the interface. At a great enough thickness, any lattice-mismatch between the film and substrate will introduce misfit dislocations into the regrown heterostructure. These new dislocations can cause additional surface roughness. Thus, if the lattice-mismatch between the regrowth device layers and relaxed SiGe buffer is too great, the effort of planarizing the relaxed SiGe may be lost since massive dislocation introduction will roughen the surface.


There are two distinct possibilities with respect to the regrowth thickness and the quality of surface. If the regrowth layers are very thin, then exact lattice matching of the regrowth layer composition and the relaxed buffer composition is not necessary. In this case, the surface roughness will be very low, approximately equal to the post-planarization flatness. However, in many applications for devices, the regrowth layer thickness will be 1–2 μm or more. For a 1% difference in Ge concentration between the relaxed SiGe and the regrowth layer, the critical thickness is approximately 0.5 μm. Thus, if optimal flatness is desired, it is best to keep the regrowth layer below approximately 0.5 μm unless excellent control of the uniformity of Ge concentration across the wafer is achieved. Although this composition matching is achievable in state-of-the-art tools, FIG. 3 shows that less precise matching, i.e., within 2% Ge, results in misfit dislocation introduction and introduction of a new crosshatch pattern. However, because the lattice mismatch is so small, the average roughness is still very low, approximately 0.77 nm. Thus, either lattice-matching or slight mismatch will result in excellent device layer surfaces for processing.


It is also noted that the relaxed SiGe alloy with surface roughness may not necessarily be a uniform composition relaxed SiGe layer on a graded composition layer. Although this material layer structure has been shown to be an early example of high quality relaxed SiGe, there are some disadvantages to this structure. For example, SiGe alloys possess a much worse coefficient of thermal conductivity than pure Si. Thus, for electronic devices located at the surface, it may be relatively difficult to guide the heat away from the device areas due to the thick graded composition layer and uniform composition layer.


Another exemplary embodiment of the invention, shown in FIGS. 4A–4D, solves this problem and creates a platform for high power SiGe devices. FIGS. 4A–4D show an exemplary process flow and resulting platform structure in accordance with the invention. The structure is produced by first forming a relaxed uniform SiGe alloy 400 via a compositionally graded layer 402 on a Si substrate 404. The SiGe layer 400 is then transferred to a second Si substrate 406 using conventional bonding. For example, the uniform SiGe alloy 400 on the graded layer 402 can be planarized to remove the crosshatch pattern, and that relaxed SiGe alloy can be bonded to the Si wafer. The graded layer 402 and the original substrate 404 can be removed by a variety of conventional processes. For example, one process is to grind the original Si substrate away and selectively etch to the SiGe, either by a controlled dry or wet etch, or by embedding an etch stop layer. The end result is a relaxed SiGe alloy 400 on Si without the thick graded layer. This structure is more suited for high power applications since the heat can be conducted away from the SiGe layer more efficiently.


The bond and substrate removal technique can also be used to produce SiGe on insulator substrates, or SGOI. An SGOI wafer is produced using the same technique shown in FIGS. 4A–4D; however, the second substrate is coated with a SiO2 layer before bonding. In an alternative embodiment, both wafers can be coated with SiO2 to enable oxide-to-oxide bonding. The resulting structure after substrate removal is a high quality, relaxed SiGe layer on an insulating film. Devices built on this platform can utilize the performance enhancements of both strained Si and the SOI architecture.


It will be appreciated that in the scenario where the SiGe layer is transferred to another host substrate, one may still need to planarize before regrowing the device layer structure. The SiGe surface can be too rough for state of the art processing due to the substrate removal technique. In this case, the relaxed SiGe is planarized, and the device layers are regrown on top of the high-quality relaxed SiGe surface.


Planarization of the surface via mechanical or other physical methods is required to flatten the surface and to achieve CMOS-quality devices. However, the field effect transistors (FETs) that allow for enhanced digital and analog circuits are very thin, and thus would be removed by the planarization step. Thus, a first part of the invention is to realize that relaxed SiGe growth and planarization, followed by device layer regrowth, is key to creating a high-performance, high yield enhanced CMOS platform. FIGS. 5 and 6 show the process sequence and regrowth layers required to create embodiments of surface channel and buried channel FETs, respectively.



FIGS. 5A–5D are schematic diagrams of a process flow and resulting layer structure in accordance with the invention. FIG. 5A shows the surface roughness 500, which is typical of a relaxed SiGe alloy 502 on a substrate 504, as an exaggerated wavy surface. Note that the substrate is labeled in a generic way, since the substrate could itself be Si, a relaxed compositionally graded SiGe layer on Si, or another material in which the relaxed SiGe has been transferred through a wafer bonding and removal technique. The relaxed SiGe alloy 502 is planarized (FIG. 5B) to remove the substantial roughness, and then device regrowth layers 506 are epitaxially deposited (FIG. 5C). It is desirable to lattice-match the composition of the regrowth layer 506 as closely as possible to the relaxed SiGe 502; however, a small amount of mismatch and dislocation introduction at the interface is tolerable since the surface remains substantially planar. For a surface channel device, a strained Si layer 508 of thickness less than 0.1 μm is then grown on top of the relaxed SiGe 502, i.e., the strain-inducing material, with an optional sacrificial layer 510, as shown in FIG. 5D. The strained layer 508 is the layer that will be used as the channel in the final CMOS devices.



FIGS. 6A–6D are schematic diagrams of the corresponding process flow and layer structure for a buried channel FET platform in accordance with the invention. In this structure, the regrowth layers 606 include a lattice matched SiGe layer 602, a strained Si channel layer 608 with a thickness of less than 0.05 μm, a SiGe separation or spacer layer 612, a Si gate oxidation layer 614, and an optional sacrificial layer 610 used to protect the heterostructure during the initial device processing steps.


Once the device structure has been deposited, the rest of the process flow for device fabrication is very similar to that of bulk Si. A simplified version of the process flow for a surface channel MOSFET in accordance with the invention is shown in FIGS. 7A–7D. This surface channel MOSFET contains a relaxed SiGe layer 700, i.e., the strain-inducing material, and a strained Si layer 702. The device isolation oxide 704, depicted in FIG. 7A, is typically formed first. In this step, the SiN layer 706, which is on top of a thin pad oxide layer 708, serves as a hard mask for either local oxidation of silicon (LOCOS) or shallow trench isolation (STI). Both techniques use a thick oxide (relative to device dimensions) to provide a high threshold voltage between devices; however, STI is better suited for sub-quarter-micron technologies. FIG. 7B is a schematic of the device area after the gate oxide 716 growth and the shallow-source drain implant. The implant regions 710 are self-aligned by using a poly-Si gate 712 patterned with photoresist 714 as a masking layer. Subsequently, deep source-drain implants 718 are positioned using conventional spacer 720 formation and the device is electrically contacted through the formation of silicide 722 at the gate and silicide/germanides 724 at the source and drain (FIG. 7C). FIG. 7D is a schematic of the device after the first level of metal interconnects 726 have been deposited and etched.


Since there are limited-thickness layers on top of the entire structure, the removal of surface material during processing becomes more critical than with standard Si. For surface channel devices, the structure that is regrown consists primarily of nearly lattice-matched SiGe, and a thin surface layer of strained Si. Many of the processes that are at the beginning of a Si fabrication sequence strip Si from the surface. If the processing is not carefully controlled, the entire strained Si layer can be removed before the gate oxidation. The resulting device will be a relaxed SiGe channel FET and thus the benefits of a strained Si channel will not be realized.


A logical solution to combat Si removal during initial processing is to make the strained Si layer thick enough to compensate for this removal. However, thick Si layers are not possible for two reasons. First, the enhanced electrical properties originate from the fact that the Si is strained and thick layers experience strain relief through the introduction of misfit dislocations. Second, the misfit dislocations themselves are undesirable in significant quantity, since they can scatter carriers and increase leakage currents in junctions.


In order to prevent removal of strained Si layers at the surface, the cleaning procedures before gate oxidation must be minimized and/or protective layers must be applied. Protective layers are useful since their removal can be carefully controlled. Some examples of protective layers for surface channel devices are shown in FIGS. 8A and 8B. FIG. 8A shows a strained Si heterostructure of a relaxed SiGe layer 800 and a strained Si channel layer 802 protected by a surface layer 804 of SiGe. The surface SiGe layer 804 should have a Ge concentration similar to that of the relaxed SiGe layer 800 below, so that the thickness is not limited by critical thickness constraints. During the initial cleans, the SiGe sacrificial layer is removed instead of the strained Si channel layer. The thickness of the sacrificial layer can either be tuned to equal the removal thickness, or can be made greater than the removal thickness. In the latter case, the excess SiGe can be selectively removed before the gate oxidation step to reveal a clean, strained Si layer at the as grown thickness. If the particular fabrication facility prefers a Si terminated surface, a sacrificial Si layer may be deposited on top of the SiGe sacrificial cap layer.



FIG. 8B shows a structure where a layer 806 of SiO2 and a surface layer 808 of either a poly-crystalline or an amorphous material are used as protective layers. In this method, an oxide layer is either grown or deposited after the epitaxial growth of the strained Si layer. Subsequently, a polycrystalline or amorphous layer of Si, SiGe, or Ge is deposited. These semiconductor layers protect the strained-Si layer in the same manner as a SiGe cap during the processing steps before gate oxidation. Prior to gate oxidation, the poly/amorphous and oxide layers are selectively removed. Although the sacrificial layers are shown as protection for a surface channel device, the same techniques can be employed in a buried channel heterostructure.


Another way in which conventional Si processing is modified is during the source-drain silicide-germanide formation (FIG. 7C). In conventional Si processing, a metal (typically Ti, Co, or Ni) is reacted with the Si and, through standard annealing sequences, low resistivity suicides are formed. However, in this case, the metal reacts with both Si and Ge simultaneously. Since the silicides have much lower free energy than the germanides, there is a tendency to form a silicide while the Ge is expelled. The expelled germanium creates agglomeration and increases the resistance of the contacts. This increase in series resistance offsets the benefits of the extra drive current from the heterostructure, and negates the advantages of the structure.


Ti and Ni can form phases in which the Ge is not rejected severely, thus allowing the formation of a good contact. Co is much more problematic. However, as discussed above for the problem of Si removal, a protective layer(s) at the device epitaxy stage can be applied instead of optimizing the SiGe-metal reaction. For example, the strained Si that will become the surface channel can be coated with a high-Ge-content SiGe alloy (higher Ge content than the initial relaxed SiGe), followed by strained Si. Two approaches are possible using these surface contact layers. Both methods introduce thick Si at the surface and allow the conventional silicide technology to be practiced without encountering the problems with SiGe-metal reactions.


The first approach, shown on a surface channel heterostructure 900 in FIG. 9A, uses a Ge-rich layer 906 thin enough that it is substantially strained. The layer 906 is provided on a strained Si channel layer 904 and relaxed SiGe layer 902, i.e., the strain-inducing material. In this case, if a subsequent Si layer 908 is beyond the critical thickness, the compressive Ge-rich layer 906 acts as a barrier to dislocations entering the strained Si channel 904. This barrier is beneficial since dislocations do not adversely affect the silicide process; thus, their presence in the subsequent Si layer 908 is of no consequence. However, if the dislocations were to penetrate to the channel, there would be adverse effects on the device.


A second approach, shown in FIG. 9B, is to allow a Ge-rich layer 910 to intentionally exceed the critical thickness, thereby causing substantial relaxation in the Ge-rich layer. In this scenario, an arbitrarily thick Si layer 912 can be applied on top of the relaxed Ge-rich layer. This layer will contain more defects than the strained channel, but the defects play no role in device operation since this Si is relevant only in the silicide reaction. In both cases, the process is free from the metal-SiGe reaction concerns, since the metal will react with Si-only. Once the silicide contacts have been formed, the rest of the sequence is a standard Si CMOS process flow, except that the thermal budget is carefully monitored since, for example, the silicide-germanicide (if that option is used) typically cannot tolerate as high a temperature as is the conventional silicide. A major advantage of using Si/SiGe FET heterostructures to achieve enhanced performance is the compatibility with conventional Si techniques. Many of the processes are identical to Si CMOS processing, and once the front-end of the process, i.e., the processing of the Si/SiGe heterostructure, is complete, the entire back-end process is uninfluenced by the fact that Si/SiGe lies below.


Even though the starting heterostructure for the buried channel device is different from that of the surface channel device, its process flow is very similar to the surface channel flow shown in FIGS. 7A–7D. FIG. 10 is a schematic block diagram of a buried channel MOSFET structure 1000 after the device isolation oxide 1016 has been formed using a SiN mask 1014. In this case, the strained channel 1002 on a first SiGe layer 1010 is separated from the surface by the growth of another SiGe layer 1004, followed by another Si layer 1006. This Si layer is needed for the gate oxide 1008 since gate-oxide formation on SiGe produces a very high interface state density, thus creating non-ideal MOSFETs. One consequence of this Si layer, is that if it is too thick, a substantial portion of the Si layer will remain after the gate oxidation. Carriers can populate this residual Si layer, creating a surface channel in parallel with the desired buried channel and leading to deleterious device properties. Thus, the surface layer Si must be kept as thin as possible, typically less than 50 Å and ideally in the range of 5–15 Å.


Another added feature that is necessary for a buried channel device is the supply layer implant. The field experienced in the vertical direction when the device is turned on is strong enough to pull carriers from the buried channel 1002 and force them to populate a Si channel 1006 near the Si/SiO2 interface 1012, thus destroying any advantage of the buried channel. Thus, a supply layer of dopant must be introduced either in the layer 1004 between the buried channel and the top Si layer 1006, or below the buried channel in the underlying SiGe 1010. In this way, the device is forced on with little or no applied voltage, and turned off by applying a voltage (depletion mode device).



FIG. 11 is a schematic flow of the process, for any heterostructure FET device deposited on relaxed SiGe, in accordance with the invention. The main process steps are shown in the boxes, and optional steps or comments are shown in the circles. The first three steps (1100,1102,1104) describe the fabrication of the strained silicon heterostructure. The sequence includes production of relaxed SiGe on Si, planarization of the SiGe, and regrowth of the device layers. Once the strained heterostructure is complete (1106), MOS fabrication begins with device isolation (1112) using either STI (1110) or LOCOS (1108). Before proceeding to the gate oxidation, buried channel devices undergo a supply and threshold implant (1114), and any protective layers applied to either a buried or surface channel heterostructure must be selectively removed (1116). The processing sequence after the gate oxidation (1118) is similar to conventional Si CMOS processing. These steps include gate deposition, doping, and definition (1120), self-aligned shallow source-drain implant (1122), spacer formation (1124), self-aligned deep source-drain implant (1126), salicide formation (1128), and pad isolation via metal deposition and etch (1130). The steps requiring significant alteration have been discussed.


One particular advantage of the process of FIG. 11 is that it enables the use of surface channel and buried channel devices on the same platform. Consider FIGS. 12A–12D and FIGS. 13A–13D, which show a universal substrate layer configuration and a process that leads to the co-habitation of surface and buried channel MOSFETs on the same chip. The universal substrate is one in which both surface channel and buried channel devices can be fabricated. There are two possibilities in fabricating the surface channel device in this sequence, shown in FIGS. 12 and 13. The process flows for combining surface and buried channel are similar to the previous process described in FIG. 7. Therefore, only the critical steps involved in exposing the proper gate areas are shown in FIGS. 12 and 13.



FIGS. 12A and 13A depict the same basic heterostructure 1200,1300 for integrating surface channel and buried channel devices. There is a surface strained Si layer 1202,1302, a SiGe spacer layer 1204,1304, a buried strained Si layer 1206,1306, and a relaxed platform of SiGe 1208,1308. Two strained Si layers are necessary because the buried channel MOSFET requires a surface Si layer to form the gate oxide and a buried Si layer to form the device channel. The figures also show a device isolation region 1210 that separates the buried channel device area 1212,1312 from the surface channel device area 1214,1314.


Unlike the buried channel device, a surface channel MOSFET only requires one strained Si layer. As a result, the surface channel MOSFET can be fabricated either in the top strained Si layer, as shown in FIGS. 12B–12D, or the buried Si layer channel, as shown in FIGS. 13B–13D. FIG. 12B is a schematic diagram of a surface channel gate oxidation 1216 in the top Si layer 1202. In this scenario, a thicker top Si layer is desired, since after oxidation, a residual strained Si layer must be present to form the channel. FIG. 12B also shows a possible position for the buried channel supply implant 1218, which is usually implanted before the buried channel gate oxide is grown. Since the top Si layer is optimized for the surface channel device, it may be necessary to strip some of the top strained Si in the regions 1220 where buried channel devices are being created, as shown in FIG. 12C. This removal is necessary in order to minimize the surface Si thickness after gate oxide 1222 formation (FIG. 12D), and thus avoid the formation of a parallel device channel.


When a surface channel MOSFET is formed in the buried strained Si layer, the top strained Si layer can be thin, i.e., designed optimally for the buried channel MOSFET. In FIG. 13B, the top strained Si and SiGe layers are removed in the region 1312 where the surface channel MOSFETs are formed. Because Si and SiGe have different properties, a range of selective removal techniques can be used, such as wet or dry chemical etching. Selective oxidation can also be used since SiGe oxidizes at much higher rates than Si, especially under wet oxidation conditions. FIG. 13C shows the gate oxidation 1314 of the surface channel device as well as the supply layer implant 1316 for the buried channel device. Finally, FIG. 13D shows the position of the buried channel gate oxide 1318. No thinning of the top Si layer is required prior to the oxidation since the epitaxial thickness is optimized for the buried channel device. Subsequent to these initial steps, the processing for each device proceeds as previously described.


Another key step in the process is the use of a localized implant to create the supply layer needed in the buried channel device. In a MOSFET structure, when the channel is turned on, large vertical fields are present that bring carriers to the surface. The band offset between the Si and SiGe that confines the electrons in the buried strained Si layer is not large enough to prevent carriers from being pulled out of the buried channel. Thus, at first, the buried channel MOSFET would appear useless. However, if enough charge were present in the top SiGe layer, the MOSFET would become a depletion-mode device, i.e. normally on and requiring bias to turn off the channel. In the surface/buried channel device platform, a supply layer implant can be created in the regions where the buried channel will be fabricated, thus easing process integration. If for some reason the supply layer implant is not possible, note that the process shown in FIG. 11 in which the surface channel is created on the buried Si layer is an acceptable process, since the dopant can be introduced into the top SiGe layer during epitaxial growth. The supply layer is then removed from the surface channel MOSFET areas when the top SiGe and strained Si layers are selectively etched away.


In the processes described in FIGS. 10, 12 and 13, it is assumed that the desire is to fabricate a buried channel MOSFET. If the oxide of the buried channel device is removed, one can form a buried channel device with a metal gate (termed a MODFET or HEMT). The advantage of this device is that the transconductance can be much higher since there is a decrease in capacitance due to the missing oxide. However, there are two disadvantages to using this device. First, all thermal processes after gate definition have to be extremely low temperature, otherwise the metal will react with the semiconductor, forming an alloyed gate with a very low, or non-existent, barrier. Related to this issue is the second disadvantage. Due to the low thermal budget, the source and drain formation and contacts are typically done before the gate definition. Inverting these steps prevents the gate from being self-aligned to the source and drain, thus increasing the series resistance between the gate and the source and drain. Therefore, with a carefully designed buried channel MOSFET, the self-aligned nature can be a great advantage in device performance. Another benefit of the MOSFET structure is that the gate leakage is very low.


The combination of buried n-channel structures with n and p type surface channel MOSFETs has been emphasized heretofore. It is important to also emphasize that in buried n-channel devices as well as in surface channel devices, the channels need not be pure Si. Si1-yGey channels can be used to increase the stability during processing. FIGS. 14A and 14B are schematic diagrams of surface 1400 and buried 1450 channel devices with Si1-yGey channels 1402 on a relaxed Si1-zGez layer 1404. The devices are shown after salicidation and thus contain a poly-Si gate 1410, gate oxide 1408, silicide regions 1412, spacers 1414, and doped regions 1416. In the surface channel device 1400, a thin layer 1406 of Si must be deposited onto the Si1-yGey layer 1402 to form the gate oxide 1408, as previously described for buried channel devices. In the buried Si1-yGey channel device 1450, the device layer sequence is unchanged and consists of a buried strained channel 1402, a SiGe spacer layer 1418, and a surface Si layer 1420 for oxidation.


To maintain tensile strain in the channel of an NMOS device, the lattice constant of the channel layer must be less than that of the relaxed SiGe layer, i.e., y must be less than z. Since n-channel devices are sensitive to alloy scattering, the highest mobilities result when the Ge concentration in the channel is low. In order to have strain on this channel layer at a reasonable critical thickness, the underlying SiGe should have a Ge concentration in the range of 10–50%.


Experimental data indicates that p channels are less sensitive to alloy scattering. Thus, surface MOSFETs with alloy channels are also possible. In addition, the buried channel devices can be p-channel devices simply by having the Ge concentration in the channel, y, greater than the Ge concentration in the relaxed SiGe alloy, z, and by switching the supply dopant from n-type to p-type. This configuration can be used to form Ge channel devices when y=1 and 0.5<z<0.9.


With the ability to mix enhancement mode surface channel devices (n and p channel, through implants as in typical Si CMOS technology) and depletion-mode buried channel MOSFETs and MODFETs, it is possible to create highly integrated digital/analog systems. The enhancement mode devices can be fabricated into high performance CMOS, and the regions of an analog circuit requiring the high performance low-noise depletion mode device can be fabricated in the buried channel regions. Thus, it is possible to construct optimal communication stages, digital processing stages, etc. on a single platform. These different regions are connected electrically in the backend of the Si CMOS chip, just as transistors are connected by the back-end technology today. Thus, the only changes to the CMOS process are some parameters in the processes in the fabrication facility, and the new material, but otherwise, the entire manufacturing process is transparent to the change. Thus, the economics favor such a platform for integrated Si CMOS systems on chip.


Although the present invention has been shown and described with respect to several preferred embodiments thereof, various changes, omissions and additions to the form and detail thereof, may be made therein, without departing from the spirit and scope of the invention.

Claims
  • 1. A method comprising: providing a substrate; andforming a FET by;forming a gate stack over the substrate, thereby defining a channel below the gate stack, andproviding a strain-inducing material over at least a portion of the substrate,wherein the strain-inducing material induces a strain in the channel, the strained channel has an average surface roughness of no more than approximately 2 nm, and forming the FET comprises forming a metal suicide region.
  • 2. The method of claim 1, wherein the strained channel comprises at least one of silicon and germanium.
  • 3. The method of claim 1, wherein the strained channel is tensilely strained.
  • 4. The method of claim 1, wherein the strained channel is compressively strained.
  • 5. The method of claim 1, wherein the strained channel has a surface roughness of less than approximately 0.77 nm.
  • 6. The method of claim 1, wherein the strain-inducing material comprises silicon.
  • 7. The method of claim of claim 6, further comprising: forming a device isolation region for the FET.
  • 8. The method of claim 7, wherein the device isolation region is proximate the strain-inducing material.
  • 9. The method of claim 7, wherein the device isolation region is selected from the group consisting of an STI region and a LOCOS region.
  • 10. The method of claim 1, wherein the strain-inducing material comprises germanium.
  • 11. The method of claim of claim 10, further comprising: forming a device isolation region for the FET.
  • 12. The method of claim 11, wherein the device isolation region is disposed proximate the strain-inducing material.
  • 13. The method of claim 11, wherein the device isolation region is selected from the group consisting of an STI region and a LOCOS region.
  • 14. The method of claim 1, wherein providing the substrate comprises providing an insulator layer, and the strained channel is defined over the insulator layer.
  • 15. The method of claim 14, wherein the insulator layer comprises SiO2.
  • 16. The method of claim 14, wherein providing the insulator layer comprises wafer bonding.
  • 17. The method of claim 1, wherein the strained channel is disposed over an insulator layer.
  • 18. The method of claim 1, wherein the strained channel is disposed over a relaxed material.
  • 19. The method of claim 1, wherein providing the strain-inducing material comprises epitaxial growth.
  • 20. The method of claim 1, wherein the metal suicide region comprises an alloy of a metal and SiGe.
  • 21. The method of claim 20, wherein the metal is selected from the group consisting of titanium, cobalt, and nickel.
  • 22. The method of claim 1, wherein forming the metal silicide region comprises deposition and annealing.
  • 23. The method of claim 1, wherein forming the FET comprises providing a source region and a drain region, and the metal silicide region is formed over at least one of the source and the drain regions.
  • 24. The method of claim 23, further comprising: providing a layer comprising at least one of silicon and germanium in at least one of the source and the drain regions prior to forming the metal silicide region.
  • 25. The method of claim 24, wherein the layer comprising at least one of silicon and germanium is substantially strained.
  • 26. The method of claim 1, wherein the strained channel is disposed proximate a material comprising germanium.
  • 27. The method of claim of claim 1, further comprising: forming a device isolation region for the FET.
  • 28. The method of claim 27, wherein the device isolation region is formed proximate a material comprising germanium.
  • 29. The method of claim 27, wherein the device isolation region is selected from the group consisting of an STI region and a LOGOS region.
  • 30. A method comprising: providing a substrate consisting essentially of one or more semiconductor materials; and forming a FET by: forming a gate stack over the substrate, thereby defining a channel below the gate stack,providing a strain-inducing material over at least a portion of the substrate,providing a source region and a drain region, andforming a metal silicide region over at least one of the source region and the drain region, the metal silicide region comprising an alloy of nickel and SiGe,wherein (i) the strain-inducing material induces a strain in the channel, (ii) the strain-inducing material comprises SiGe, and is disposed in the source region and the drain region, and (iii) the strained channel has an average surface roughness of less than approximately 0.77 nm and consists essentially of silicon.
  • 31. The method of claim 30, wherein the strain-inducing material consists essentially of SiGe.
  • 32. The method of claim 30, wherein the substrate consists essentially of Si and Ge.
  • 33. The method of claim 30, wherein the substrate consists essentially of Si.
  • 34. The method of claim 29, wherein the strained channel is compressively strained.
PRIORITY INFORMATION

This application is a continuation of U.S. Ser. No. 10/774,890, filed Feb. 9, 2004, which is a continuation of U.S. Ser. No. 09/906,200, filed Jul. 16, 2001 now U.S. Pat. No. 6,703,688, which claims priority to and the benefit of U.S. Ser. No. 60/273,112, filed Mar. 2, 2001, the entire disclosure of each of these applications being incorporated herein by reference.

US Referenced Citations (356)
Number Name Date Kind
4010045 Ruehrwein Mar 1977 A
4522662 Bradbury et al. Jun 1985 A
4710788 Dambkes et al. Dec 1987 A
4717681 Curran Jan 1988 A
4749441 Christenson et al. Jun 1988 A
4755478 Abernathey et al. Jul 1988 A
4786615 Liaw et al. Nov 1988 A
4803539 Psaras et al. Feb 1989 A
4963506 Liaw et al. Oct 1990 A
4969031 Kobayashi et al. Nov 1990 A
4987462 Kim et al. Jan 1991 A
4990979 Otto Feb 1991 A
4997776 Harame et al. Mar 1991 A
5013681 Godbey et al. May 1991 A
5034348 Hartswick et al. Jul 1991 A
5089872 Ozturk et al. Feb 1992 A
5091767 Bean et al. Feb 1992 A
5108946 Zdebel et al. Apr 1992 A
5155571 Wang et al. Oct 1992 A
5166084 Pfiester Nov 1992 A
5177583 Endo et al. Jan 1993 A
5198689 Fujioka et al. Mar 1993 A
5202284 Kamins et al. Apr 1993 A
5207864 Bhat et al. May 1993 A
5208182 Narayan et al. May 1993 A
5212110 Pfiester et al. May 1993 A
5212112 Lynch May 1993 A
5217923 Suguro et al. Jun 1993 A
5221413 Brasen et al. Jun 1993 A
5225703 Nakatani et al. Jul 1993 A
5240876 Gaul et al. Aug 1993 A
5241197 Murakami et al. Aug 1993 A
5242847 Ozturk et al. Sep 1993 A
5243207 Plumton et al. Sep 1993 A
5250445 Bean et al. Oct 1993 A
5285086 Fitzgerald Feb 1994 A
5291439 Kauffmann et al. Mar 1994 A
5294564 Karapiperis et al. Mar 1994 A
5298452 Meyerson Mar 1994 A
5304834 Lynch Apr 1994 A
5310451 Tejwani et al. May 1994 A
5316958 Meyerson May 1994 A
5334861 Pfiester et al. Aug 1994 A
5336903 Ozturk et al. Aug 1994 A
5346840 Fujioka et al. Sep 1994 A
5346848 Grupen-Shemansky et al. Sep 1994 A
5374564 Bruel Dec 1994 A
5399522 Ohori Mar 1995 A
5413679 Godbey May 1995 A
5424243 Takasaki Jun 1995 A
5426069 Selvakumar et al. Jun 1995 A
5426316 Mohammad Jun 1995 A
5442205 Brasen et al. Aug 1995 A
5461243 Ek et al. Oct 1995 A
5461250 Burghartz et al. Oct 1995 A
5462883 Dennard et al. Oct 1995 A
5476813 Naruse Dec 1995 A
5479033 Baca et al. Dec 1995 A
5484664 Kitahara et al. Jan 1996 A
5496750 Moslehi Mar 1996 A
5496771 Cronin et al. Mar 1996 A
5523243 Mohammad Jun 1996 A
5523592 Nakagawa et al. Jun 1996 A
5534713 Ismail et al. Jul 1996 A
5536361 Kondo et al. Jul 1996 A
5540785 Dennard et al. Jul 1996 A
5571373 Krishna et al. Nov 1996 A
5572043 Shimizu et al. Nov 1996 A
5596527 Tomioka et al. Jan 1997 A
5617351 Bertin et al. Apr 1997 A
5630905 Lynch et al. May 1997 A
5633202 Brigham et al. May 1997 A
5659187 Legoues et al. Aug 1997 A
5659194 Iwamatsu et al. Aug 1997 A
5683934 Candelaria Nov 1997 A
5698869 Yoshimi et al. Dec 1997 A
5705421 Matsushita et al. Jan 1998 A
5710450 Chau et al. Jan 1998 A
5714777 Ismail et al. Feb 1998 A
5728623 Mori Mar 1998 A
5739567 Wong Apr 1998 A
5759898 Ek et al. Jun 1998 A
5777347 Bartelink Jul 1998 A
5786612 Otani et al. Jul 1998 A
5786614 Chuang et al. Jul 1998 A
5792679 Nakato Aug 1998 A
5808344 Ismail et al. Sep 1998 A
5821577 Crabbé et al. Oct 1998 A
5844260 Ohori et al. Dec 1998 A
5847419 Imai et al. Dec 1998 A
5869359 Prabhakar Feb 1999 A
5877070 Goesele et al. Mar 1999 A
5877535 Matsumoto et al. Mar 1999 A
5891769 Liaw et al. Apr 1999 A
5906708 Robinson et al. May 1999 A
5906951 Chu et al. May 1999 A
5912479 Mori et al. Jun 1999 A
5933741 Tseng et al. Aug 1999 A
5943560 Chang et al. Aug 1999 A
5963817 Chu et al. Oct 1999 A
5966622 Levine et al. Oct 1999 A
5976939 Thompson et al. Nov 1999 A
5998807 Lustig et al. Dec 1999 A
6008111 Fushida et al. Dec 1999 A
6013134 Chu et al. Jan 2000 A
6030887 Desai et al. Feb 2000 A
6030889 Aulicino et al. Feb 2000 A
6033974 Henley et al. Mar 2000 A
6033995 Muller Mar 2000 A
6058044 Sugiura et al. May 2000 A
6059895 Chu et al. May 2000 A
6066563 Nagashima et al. May 2000 A
6074919 Gardner et al. Jun 2000 A
6096590 Chan et al. Aug 2000 A
6096647 Yang et al. Aug 2000 A
6103559 Gardner et al. Aug 2000 A
6107653 Fitzgerald Aug 2000 A
6111267 Fischer et al. Aug 2000 A
6117750 Bensahel et al. Sep 2000 A
6121100 Andideh et al. Sep 2000 A
6130453 Mei et al. Oct 2000 A
6132806 Dutartre Oct 2000 A
6133124 Horstmann et al. Oct 2000 A
6133799 Favors et al. Oct 2000 A
6140687 Shimomura et al. Oct 2000 A
6143636 Forbes et al. Nov 2000 A
6153495 Kub et al. Nov 2000 A
6154475 Soref et al. Nov 2000 A
6159852 Nuttall et al. Dec 2000 A
6159856 Nagano et al. Dec 2000 A
6160303 Fattaruso Dec 2000 A
6162688 Gardner et al. Dec 2000 A
6184111 Henley et al. Feb 2001 B1
6187657 Xiang et al. Feb 2001 B1
6191007 Matsui et al. Feb 2001 B1
6191432 Sugiyama et al. Feb 2001 B1
6194722 Fiorini et al. Feb 2001 B1
6204529 Lung et al. Mar 2001 B1
6207977 Augusto Mar 2001 B1
6210988 Howe et al. Apr 2001 B1
6214679 Murthy et al. Apr 2001 B1
6218677 Broekaert Apr 2001 B1
6228694 Doyle et al. May 2001 B1
6232138 Fitzgerald et al. May 2001 B1
6235567 Huang May 2001 B1
6235568 Murthy et al. May 2001 B1
6235575 Kasai et al. May 2001 B1
6242324 Kub et al. Jun 2001 B1
6242327 Yokoyama et al. Jun 2001 B1
6246077 Kobayashi et al. Jun 2001 B1
6249022 Lin et al. Jun 2001 B1
6251755 Furukawa et al. Jun 2001 B1
6251780 Sohn et al. Jun 2001 B1
6261929 Gehrke et al. Jul 2001 B1
6266278 Harari et al. Jul 2001 B1
6268257 Wieczorek et al. Jul 2001 B1
6271551 Schmitz et al. Aug 2001 B1
6271726 Fransis et al. Aug 2001 B1
6281532 Doyle et al. Aug 2001 B1
6291321 Fitzgerald Sep 2001 B1
6294448 Chang et al. Sep 2001 B1
6306698 Wieczorek et al. Oct 2001 B1
6313016 Kibbel et al. Nov 2001 B1
6313486 Kencke et al. Nov 2001 B1
6315384 Ramaswami et al. Nov 2001 B1
6316301 Kant Nov 2001 B1
6316357 Lin et al. Nov 2001 B1
6319799 Ouyang et al. Nov 2001 B1
6319805 Iwamatsu et al. Nov 2001 B1
6323108 Kub et al. Nov 2001 B1
6326281 Violette et al. Dec 2001 B1
6326664 Chau et al. Dec 2001 B1
6329063 Lo et al. Dec 2001 B2
6335546 Tsuda et al. Jan 2002 B1
6339232 Takagi Jan 2002 B1
6342421 Mitani et al. Jan 2002 B1
6344375 Orita et al. Feb 2002 B1
6350311 Chin et al. Feb 2002 B1
6350993 Chu et al. Feb 2002 B1
6352909 Usenko Mar 2002 B1
6362071 Nguyen et al. Mar 2002 B1
6368733 Nishinaga Apr 2002 B1
6368927 Lee et al. Apr 2002 B1
6369438 Sugiyama et al. Apr 2002 B1
6372356 Thornton et al. Apr 2002 B1
6372593 Hattori et al. Apr 2002 B1
6376318 Lee et al. Apr 2002 B1
6380008 Kwok et al. Apr 2002 B2
6391798 DeFelice et al. May 2002 B1
6399970 Kubo et al. Jun 2002 B2
6403975 Brunner et al. Jun 2002 B1
6406973 Lee et al. Jun 2002 B1
6406986 Yu Jun 2002 B1
6407406 Tezuka Jun 2002 B1
6410371 Yu et al. Jun 2002 B1
6420937 Akatsuka et al. Jul 2002 B1
6425951 Chu et al. Jul 2002 B1
6429061 Rim Aug 2002 B1
6461960 Lee et al. Oct 2002 B2
6486520 Okuno et al. Nov 2002 B2
6492216 Yeo et al. Dec 2002 B1
6498359 Schmidt et al. Dec 2002 B2
6500694 Enquist Dec 2002 B1
6503833 Ajmera et al. Jan 2003 B1
6509587 Sugiyama et al. Jan 2003 B2
6521041 Wu et al. Feb 2003 B2
6521508 Cheong et al. Feb 2003 B1
6524935 Canaperi et al. Feb 2003 B1
6555839 Fitzgerald Apr 2003 B2
6555880 Cabral, Jr. et al. Apr 2003 B2
6562703 Maa et al. May 2003 B1
6563152 Roberds et al. May 2003 B2
6566718 Wieczorek et al. May 2003 B2
6573126 Cheng et al. Jun 2003 B2
6573160 Taylor, Jr. et al. Jun 2003 B2
6583015 Fitzgerald et al. Jun 2003 B2
6591321 Arimilli et al. Jul 2003 B1
6593191 Fitzgerald Jul 2003 B2
6593641 Fitzgerald Jul 2003 B1
6597016 Yuki et al. Jul 2003 B1
6602613 Fitzgerald Aug 2003 B1
6603156 Rim Aug 2003 B2
6605498 Murthy et al. Aug 2003 B1
6607948 Sugiyama et al. Aug 2003 B1
6621131 Murthy et al. Sep 2003 B2
6646322 Fitzgerald Nov 2003 B2
6649480 Fitzgerald et al. Nov 2003 B2
6657223 Wang et al. Dec 2003 B1
6674150 Takagi et al. Jan 2004 B2
6677192 Fitzgerald Jan 2004 B1
6682965 Noguchi et al. Jan 2004 B1
6686617 Agnello et al. Feb 2004 B2
6690043 Usuda et al. Feb 2004 B1
6699765 Shideler et al. Mar 2004 B1
6703144 Fitzgerald Mar 2004 B2
6703271 Yeo et al. Mar 2004 B2
6703648 Xiang et al. Mar 2004 B1
6703688 Fitzgerald Mar 2004 B1
6709903 Christiansen et al. Mar 2004 B2
6709929 Zhang et al. Mar 2004 B2
6713326 Cheng et al. Mar 2004 B2
6723661 Fitzgerald Apr 2004 B2
6724008 Fitzgerald Apr 2004 B2
6724019 Oda et al. Apr 2004 B2
6730551 Lee et al. May 2004 B2
6737670 Cheng et al. May 2004 B2
6743651 Chu et al. Jun 2004 B2
6743684 Liu Jun 2004 B2
6750130 Fitzgerald Jun 2004 B1
6787864 Paton et al. Sep 2004 B2
6797571 Nagaoka et al. Sep 2004 B2
6812086 Murthy et al. Nov 2004 B2
6818537 Cheong et al. Nov 2004 B2
6818938 Naem et al. Nov 2004 B1
6828632 Bhattacharyya Dec 2004 B2
6830976 Fitzgerald Dec 2004 B2
6855649 Christiansen Feb 2005 B2
6855990 Yeo et al. Feb 2005 B2
6861318 Murthy et al. Mar 2005 B2
6876053 Ma et al. Apr 2005 B1
6881360 Stange et al. Apr 2005 B2
6885084 Murthy et al. Apr 2005 B2
6887762 Murthy et al. May 2005 B1
6887773 Gunn, III et al. May 2005 B2
6890835 Chu et al. May 2005 B1
6900103 Fitzgerald May 2005 B2
6909186 Chu Jun 2005 B2
6936509 Coolbaugh et al. Aug 2005 B2
6953972 Yeo et al. Oct 2005 B2
6974733 Boyanov et al. Dec 2005 B2
6982433 Hoffman et al. Jan 2006 B2
6992355 Mouli Jan 2006 B2
6995430 Langdo et al. Feb 2006 B2
20010001724 Kwok et al. May 2001 A1
20010003269 Wu et al. Jun 2001 A1
20010003364 Sugawara et al. Jun 2001 A1
20010009303 Tang et al. Jul 2001 A1
20010031535 Agnello et al. Oct 2001 A1
20010045604 Oda et al. Nov 2001 A1
20020001948 Lee Jan 2002 A1
20020019127 Givens Feb 2002 A1
20020024395 Akatsuka et al. Feb 2002 A1
20020043660 Yamazaki et al. Apr 2002 A1
20020048910 Taylor, Jr. et al. Apr 2002 A1
20020052084 Fitzgerald May 2002 A1
20020056879 Wieczorek et al. May 2002 A1
20020063292 Armstrong et al. May 2002 A1
20020068393 Fitzgerald et al. Jun 2002 A1
20020072130 Cheng et al. Jun 2002 A1
20020084000 Fitzgerald Jul 2002 A1
20020096717 Chu et al. Jul 2002 A1
20020100942 Fitzgerald et al. Aug 2002 A1
20020123167 Fitzgerald Sep 2002 A1
20020123183 Fitzgerald Sep 2002 A1
20020123197 Fitzgerald et al. Sep 2002 A1
20020125471 Fitzgerald et al. Sep 2002 A1
20020125497 Fitzgerald Sep 2002 A1
20020140031 Rim Oct 2002 A1
20020168864 Cheng et al. Nov 2002 A1
20020190284 Murthy et al. Dec 2002 A1
20030003679 Doyle et al. Jan 2003 A1
20030013323 Hammond et al. Jan 2003 A1
20030025131 Lee et al. Feb 2003 A1
20030034529 Fitzgerald et al. Feb 2003 A1
20030057439 Fitzgerald Mar 2003 A1
20030080361 Murthy et al. May 2003 A1
20030089901 Fitzgerald May 2003 A1
20030102498 Braithwaite et al. Jun 2003 A1
20030113971 Nagaoka et al. Jun 2003 A1
20030162348 Yeo et al. Aug 2003 A1
20030199126 Chu et al. Oct 2003 A1
20030203600 Chu et al. Oct 2003 A1
20030215990 Fitzgerald et al. Nov 2003 A1
20030218189 Christiansen et al. Nov 2003 A1
20030227029 Lochtefeld et al. Dec 2003 A1
20030227057 Lochtefeld et al. Dec 2003 A1
20040005740 Lochtefeld et al. Jan 2004 A1
20040007724 Murthy et al. Jan 2004 A1
20040014276 Murthy et al. Jan 2004 A1
20040014304 Bhattacharyya Jan 2004 A1
20040031979 Lochtefeld Feb 2004 A1
20040041210 Mouli Mar 2004 A1
20040061191 Paton et al. Apr 2004 A1
20040070035 Murthy et al. Apr 2004 A1
20040075148 Kumagai et al. Apr 2004 A1
20040075149 Fitzgerald et al. Apr 2004 A1
20040084735 Murthy et al. May 2004 A1
20040119101 Schrom et al. Jun 2004 A1
20040121564 Gogoi Jun 2004 A1
20040142545 Ngo et al. Jul 2004 A1
20040173815 Yeo et al. Sep 2004 A1
20040175892 Vatus et al. Sep 2004 A1
20040217430 Chu Nov 2004 A1
20040219726 Fitzgerald Nov 2004 A1
20040251776 Hoffmann et al. Dec 2004 A1
20040253774 Boyanov et al. Dec 2004 A1
20040256613 Oda et al. Dec 2004 A1
20040262683 Bohr et al. Dec 2004 A1
20050009263 Yeo et al. Jan 2005 A1
20050042849 Currie et al. Feb 2005 A1
20050077511 Fitzgerald Apr 2005 A1
20050112048 Tsakalakos et al. May 2005 A1
20050130454 Murthy et al. Jun 2005 A1
20050156169 Chu Jul 2005 A1
20050156180 Zhang et al. Jul 2005 A1
20050156210 Currie et al. Jul 2005 A1
20050161711 Chu Jul 2005 A1
20050167652 Hoffmann et al. Aug 2005 A1
20050176204 Langdo et al. Aug 2005 A1
20050250298 Bauer Nov 2005 A1
20050277272 Singh et al. Dec 2005 A1
20050280026 Isaacson et al. Dec 2005 A1
20050280098 Shin et al. Dec 2005 A1
20060008958 Yeo et al. Jan 2006 A1
20060009001 Huang et al. Jan 2006 A1
20060057825 Bude et al. Mar 2006 A1
Foreign Referenced Citations (51)
Number Date Country
41 01 167 Jul 1992 DE
0390661 Oct 1990 EP
0 514 018 Nov 1992 EP
0 587 520 Mar 1994 EP
0 683 522 Nov 1995 EP
0 828 296 Mar 1998 EP
0 829 908 Mar 1998 EP
0 838 858 Apr 1998 EP
1 020 900 Jul 2000 EP
1 174 928 Jan 2002 EP
2 701 599 Sep 1993 FR
2 342 777 Apr 2000 GB
61141116 Jun 1986 JP
2210816 Aug 1990 JP
3036717 Feb 1991 JP
4-74415 Mar 1992 JP
4-307974 Oct 1992 JP
5-166724 Jul 1993 JP
6-177046 Jun 1994 JP
6-244112 Sep 1994 JP
6-252046 Sep 1994 JP
7-094420 Apr 1995 JP
7-106446 Apr 1995 JP
7-240372 Sep 1995 JP
10-270685 Oct 1998 JP
11-233744 Aug 1999 JP
2000-021783 Jan 2000 JP
2000-031491 Jan 2000 JP
2001-319935 Nov 2001 JP
2002-076334 Mar 2002 JP
2002-164520 Jun 2002 JP
2002-324765 Aug 2002 JP
2002-289533 Oct 2002 JP
9859365 Dec 1998 WO
9953539 Oct 1999 WO
0048239 Aug 2000 WO
0054338 Sep 2000 WO
0122482 Mar 2001 WO
0154202 Jul 2001 WO
0193338 Dec 2001 WO
0199169 Dec 2001 WO
0213262 Feb 2002 WO
0215244 Feb 2002 WO
0227783 Apr 2002 WO
0247168 Jun 2002 WO
02071488 Sep 2002 WO
02071491 Sep 2002 WO
02071495 Sep 2002 WO
02082514 Oct 2002 WO
04006311 Jan 2004 WO
04006327 Jan 2004 WO
Related Publications (1)
Number Date Country
20050077511 A1 Apr 2005 US
Provisional Applications (1)
Number Date Country
60273112 Mar 2001 US
Continuations (2)
Number Date Country
Parent 10774890 Feb 2004 US
Child 10967998 US
Parent 09906200 Jul 2001 US
Child 10774890 US