This invention is based on Japanese Patent Application No. 2005-087685 and No. 2006-045448, the content of which is incorporated herein by reference in its entirety.
1. Field of the Invention
The invention relates to a semiconductor device and its manufacturing method, particularly, a semiconductor device with a bonding pad made of a wiring layer including aluminum and its manufacturing method.
2. Description of the Related Art
A bonding pad has been known as an electrode for external connection of an input/output terminal or a power supply terminal of a semiconductor integrated circuit or the like. The bonding pad is formed using an aluminum (Al) wiring, for example, and connected with a lead frame or the like through a bonding wire or the like.
Next, a conventional semiconductor device with the bonding pad made of an aluminum (Al) wiring will be described referring to figures.
A transistor 10T is formed on a semiconductor substrate 10 (to be a semiconductor die) as shown in
A first interlayer insulation film 14 made of, for example, a silicon oxide film (SiO2) is formed on this semiconductor substrate 10, contact holes are formed by etching or the like, corresponding to the source 13 and the drain 13 of the transistor 10T, and first plugs 15 are embedded therein respectively. Furthermore, a first barrier layer 16 made of titanium (Ti) and titanium nitride (TiN) layered in this order is formed on the first interlayer insulation film 14. A first wiring layer 17 made of aluminum (Al) is deposited on this first barrier layer 16 by, for example, a sputtering method, being formed into a predetermined pattern. The source 13 and the drain 13 of the transistor 10T and the first wiring layer 17 are electrically connected through the first plugs 15 respectively.
Furthermore, a second barrier layer 18 which is the same as the first barrier layer 16 is formed on the first wiring layer 17. These first barrier layer 16, first wiring layer 17, and second barrier layer 18 are formed into a predetermined pattern. Then, a second interlayer insulation film 19 which is the same as the first interlayer insulation film 14 is formed on the second barrier layer 18. A contact hole is formed in the second interlayer insulation film 19 according to needs, and a second plug 20 is embedded therein. The second plug electrically connects the first wiring layer 17 with a second wiring layer 22 which will be described below.
Furthermore, a third barrier layer 21 which is the same as the first barrier layer 16 is formed on the second interlayer insulation film 19, and the second wiring layer 22 made of aluminum (Al) is deposited thereon by, for example, a sputtering method. An antireflection layer 53 made of, for example, titanium nitride (TiN) is formed on the second wiring layer 22. Then, patterning is performed to the third barrier layer 21, the second wiring layer 22, and the antireflection layer 53. In this patterning, reflection of exposure to a photoresist (not shown) used as a mask for the patterning can be prevented by the antireflection layer 53. Thus, the exposure and development of the photoresist can be performed with high precision, and thus the patterning of the second wiring layer 22 can be performed with high precision.
Next, a passivation layer 55 covering the second wiring layer 22 and the antireflection layer 53 is formed. Then, the antireflection layer 53 and the passivation layer 55 are etched so as to form an opening 54 exposing the second wiring layer 22. The second wiring layer 22 exposed in this opening 54 is to be a bonding pad which is to be formed with a bonding wire 56 connecting the second wiring layer 22 with a lead frame (not shown).
The relevant technology is described in Japanese Patent Application Publication No. 2004-158678.
As shown in
This problem occurs since the moisture 30 containing impurities that adheres to the second wiring layer 22 and the antireflection layer 53 functions as an electrolyte to cause cell reaction between the aluminum (Al) component of the second wiring layer 22 and the titanium (Ti) component of the antireflection layer 53. Since the ionization tendency of titanium (Ti) is lower than the ionization tendency of aluminum (Al) in the cell reaction, aluminum (Al) ions move more than titanium (Ti) ions and thus aluminum is eluted.
As a result, a connection failure occurs between the second wiring layer 22 as the bonding pad and the lead frame (not shown) when a wire is bonded thereto, reducing the yield of the semiconductor device.
The invention provides a semiconductor device with a bonding pad made of a wiring layer including aluminum and its manufacturing method that enhance the yield of the semiconductor device.
The invention provides a semiconductor device including: a semiconductor die; a wiring layer formed on the semiconductor die; an antireflection layer formed on a portion of the wiring layer; and a passivation layer covering the wiring layer and the antireflection layer, wherein the passivation layer has an opening exposing a portion of the wiring layer and not exposing an end portion of the antireflection layer.
The invention also provides a semiconductor device including: a semiconductor die; a wiring layer formed on the semiconductor die; and a passivation layer covering the wiring layer, wherein the passivation layer is formed so as to have an opening exposing a portion of the wiring layer and directly contact the wiring layer that is not exposed.
The invention also provides a semiconductor device including: a semiconductor die; a wiring layer formed on the semiconductor die; an antireflection layer formed on a portion of the wiring layer; and a passivation layer covering the wiring layer and the antireflection layer, wherein the passivation layer exposes an end portion of the antireflection layer and the end portion of the antireflection layer is covered with a metal layer.
The invention also provides a method of manufacturing a semiconductor device including: forming a wiring layer and an antireflection layer on a semiconductor substrate and patterning these layers; removing a portion of the antireflection layer by etching; forming a passivation layer covering the wiring layer and the antireflection layer; and exposing a portion of the wiring layer where the antireflection layer is not formed, and removing a portion of the passivation layer by etching so as not to expose an end portion of the antireflection layer.
The invention also provides a method of manufacturing a semiconductor device including: forming a wiring layer and an antireflection layer on a semiconductor substrate and patterning these layers; removing the whole antireflection layer by etching; forming a passivation layer so as to directly contact the wiring layer; and removing a portion of the passivation layer by etching so as to expose a portion of the wiring layer.
The invention also provides a method of manufacturing a semiconductor device including: forming a wiring layer and an antireflection layer on a semiconductor substrate and patterning these layers; forming a first passivation layer so as to cover the wiring layer and the antireflection layer; removing a portion of the antireflection layer and a portion of the first passivation layer by etching so as to expose a portion of the wiring layer; forming a second passivation layer so as to cover the wiring layer and the first passivation layer; and removing the second passivation layer by etching so as to expose a portion of the wiring layer again.
In this method, the removing of the second passivation layer is performed by a sputter etching.
The invention also provides a method of manufacturing a semiconductor device including: forming a wiring layer and an antireflection layer on a semiconductor substrate and patterning these layers; forming a passivation layer so as to cover the wiring layer and the antireflection layer; removing a portion of the antireflection layer and a portion of the passivation layer by etching so as to expose a portion of the wiring layer to form an opening exposing an end portion of the antireflection layer, and forming a metal layer so as to cover the end portion of the antireflection layer.
The invention also provides a method of manufacturing a semiconductor device including: forming a wiring layer and an antireflection layer on a semiconductor substrate; removing a portion of the antireflection layer by etching; forming a passivation layer covering the wiring layer and the antireflection layer; and removing a portion of the passivation layer by etching so as to expose a portion of the wiring layer where the antireflection layer is not formed and so as not to expose an end portion of the antireflection layer.
The invention can prevent metal that forms the wiring layer from being eluted to form a defect portion or deposit an eluted component. Therefore, when a wire is bonded to the wiring layer, a connection failure as has been seen in the conventional art can be prevented. As a result, the yield can be increased by this semiconductor device with the bonding pad made of a wiring layer including aluminum and its manufacturing method.
FIGS. 1 to 4 are cross-sectional views showing a method of manufacturing a semiconductor device of the first embodiment of the invention.
FIGS. 6 to 9 are cross-sectional views showing a method of manufacturing a semiconductor device of the second embodiment of the invention.
FIGS. 11 to 15 are cross-sectional views showing a method of manufacturing a semiconductor device of the third embodiment of the invention.
FIGS. 17 to 21 are cross-sectional views showing a method of manufacturing a semiconductor device of the fourth embodiment of the invention.
FIGS. 23 to 27 are cross-sectional views showing a method of manufacturing a semiconductor device of the fifth embodiment of the invention.
FIGS. 29 to 33 are cross-sectional views showing a method of manufacturing a semiconductor device of the sixth embodiment of the invention.
FIGS. 35 to 38 are cross-sectional views showing a method of manufacturing a semiconductor device of the seventh embodiment of the invention.
A semiconductor device of the first embodiment of the invention will be described referring to figures. FIGS. 1 to 4 are cross-sectional views showing a method of manufacturing the semiconductor device of this embodiment.
The semiconductor device of this embodiment has the same components as the conventional semiconductor device shown in
A second wiring layer 22 and an antireflection layer 23A are formed into a predetermined pattern through patterning processes including a photolithography (exposure and development of a resist layer (not shown)), as shown in
The antireflection layer 23A has the same function as the antireflection layer 53 of
Next, a first resist layer 101 is formed so as to cover a portion of the third barrier layer 21 and a portion of the antireflection layer 23A, as shown in
Next, a passivation layer 25A is formed so as to cover the third barrier layer 21, the second wiring layer 22, and the antireflection layer 23A, as shown in
Next, a second resist layer 102 is formed on the passivation layer 25A in a region corresponding to a portion of the third barrier layer 21, the remaining antireflection layer 23A, and a portion of the second wiring layer 22 where the antireflection layer 23A does not remain, as shown in
Thus, an opening 24 exposing a portion of the second wiring layer 22 and not exposing an end portion of the antireflection layer 23A is formed in the passivation layer 25A. That is, the end portion of the antireflection layer 23A is covered with the passivation layer 25A. Although the cross-sectional view of
Next, the semiconductor substrate 10 and the layers layered thereon are divided into a plurality of semiconductor dice 10A by dicing along a dicing line (not shown), as shown in
As described above, the antireflection layer 23A is covered with the passivation layer 25A and not exposed in the opening 24 in this embodiment. Furthermore, since the passivation layer 25A is formed by a plasma CVD method, the layer 25A is firmly bonded to the second wiring layer 22.
Thus, moisture containing impurities, that is, moisture used in the manufacturing process (e.g. water for dicing containing CO2 for preventing static electricity), moisture in the air, or the like does not reach the antireflection layer 23A, and this prevents cell reaction occurring between a titanium (Ti) component of the antireflection layer and an aluminum (Al) component of the second wiring layer 22 as has been seen in the conventional art. That is, aluminum that forms the second wiring layer 22 is prevented from being eluted. As a result, a connection failure when a wire is bonded to the second wiring layer 22 exposed in the opening 24 can be minimized, and the yield of the semiconductor device can be enhanced.
Next, a semiconductor device of the second embodiment of the invention will be described referring to figures. FIGS. 6 to 9 are cross-sectional views showing a method of manufacturing the semiconductor device of this embodiment.
The description of the semiconductor device of this embodiment will be made on the components formed above the second wiring layer 22 only in FIGS. 6 to 10, as in the first embodiment. The other components and the manufacturing method thereof are the same as those of the conventional art shown in
The second wiring layer 22 and an antireflection layer 23B are formed into a predetermined pattern through patterning processes including a photolithography, as shown in
Next, as shown in
Next, a passivation layer 25B is formed so as to cover the third barrier layer 21 and the second wiring layer 22, as shown in
Next, as shown in
Next, the semiconductor substrate 10 and the layers layered thereon are divided into a plurality of semiconductor dice 10B by dicing along a dicing line (not shown), as shown in
As described above, the antireflection layer 23B does not exist on the second wiring layer 22 in this embodiment. This prevents cell reaction from occurring between a titanium (Ti) component of the antireflection layer and an aluminum (Al) component of the second wiring layer 22 as has been seen in the conventional art, and aluminum that forms the second wiring layer 22 from being eluted. As a result, a connection failure when a wire is bonded to the second wiring layer 22 exposed in the opening 24 can be minimized, and the yield of the semiconductor device can be enhanced.
Next, a semiconductor device of the third embodiment of the invention will be described referring to figures. FIGS. 11 to 15 are cross-sectional views showing a method of manufacturing the semiconductor device of this embodiment.
The description of the semiconductor device of this embodiment will be made on the components formed above the second wiring layer 22 only in FIGS. 11 to 16, as in the first embodiment. The other components and the manufacturing method thereof are the same as those of the conventional art shown in
The second wiring layer 22 and an antireflection layer 23C are formed into a predetermined pattern through patterning processes including a photolithography, as shown in
Next, a first passivation layer 25C is formed so as to cover the third barrier layer 21, the second wiring layer 22, and the antireflection layer 23C as shown in
Next, as shown in
Furthermore, as shown in
Next, as shown in
Thus, an opening 24B exposing a portion of the second wiring layer 22 and not exposing an end portion of the antireflection layer 23C is formed in the first passivation layer 25C and the second passivation layer 27C.
Generally, a resist layer on the bottom portion of the sidewall of an opening is not always patterned precisely due to reflection of exposure. Therefore, the bottom portion of the sidewall of the opening 24B can be removed more than need be when the second passivation layer 27C is etched, thereby exposing the antireflection layer 23C. By forming the sixth resist layer 106 onto the second wiring layer 22 where the antireflection layer 23C does not remain, as in this embodiment, the second passivation layer 27C can completely cover the end portion of the antireflection layer 23C in the opening 24B even after the etching.
Next, the semiconductor substrate 10 and the layers layered thereon are divided into a plurality of semiconductor dice 10C by dicing along a dicing line (not shown), as shown in
As described above, the antireflection layer 23C is covered with the second passivation layer 27C and is not exposed in the opening 24B, in this embodiment. Thus, moisture containing impurities, that is, moisture used in the manufacturing process (e.g. water for dicing containing CO2 for preventing static electricity), moisture in the air, or the like does not reach the antireflection layer 23C, and this prevents cell reaction occurring between a titanium (Ti) component of the antireflection layer and an aluminum (Al) component of the second wiring layer 22 as has been seen in the conventional art. That is, aluminum that forms the second wiring layer 22 is prevented from being eluted. As a result, a connection failure when a wire is bonded to the second wiring layer 22 exposed in the opening 24B can be minimized, and the yield of the semiconductor device can be enhanced.
Next, a semiconductor device of the fourth embodiment of the invention will be described referring to figures. FIGS. 17 to 21 are cross-sectional views showing a method of manufacturing the semiconductor device of this embodiment.
The description of the semiconductor device of this embodiment will be made on the components formed above the second wiring layer 22 only in FIGS. 17 to 22, as in the first embodiment. The other components and the manufacturing method thereof are the same as those of the conventional art shown in
The second wiring layer 22 and an antireflection layer 23D are formed into a predetermined pattern through patterning processes including a photolithography, as shown in
Next, a first passivation layer 25D is formed so as to cover the third barrier layer 21, the second wiring layer 22, and the antireflection layer 23D as shown in
Next, as shown in
Next, a second passivation layer 27D is formed so as to cover the first passivation layer 25D and the inner surface of the opening 24A, as shown in
Next, the surface of the second passivation layer 27D is sputter-etched with an argon gas until the surface of the second wiring layer 22 is exposed, as shown in
Thus, an opening 24C exposing a portion of the second wiring layer 22 and not exposing an end portion of the antireflection layer 23D is formed in the first passivation layer 25D and the second passivation layer 27D.
Next, the semiconductor substrate 10 and the layers layered thereon are divided into a plurality of semiconductor dice 10D by dicing along a dicing line (not shown), as shown in
As described above, the antireflection layer 23D is covered with the second passivation layer 27D and not exposed in the opening 24C in this embodiment. Thus, moisture containing impurities, that is, moisture used in the manufacturing process (e.g. water for dicing containing CO2 for preventing static electricity), moisture in the air, or the like does not reach the antireflection layer 23D, and this prevents cell reaction occurring between a titanium (Ti) component of the antireflection layer and an aluminum (Al) component of the second wiring layer 22 as has been seen in the conventional art. That is, aluminum that forms the second wiring layer 22 is prevented from being eluted. As a result, a connection failure when a wire is bonded to the second wiring layer 22 exposed in the opening 24C can be minimized, and the yield of the semiconductor device can be enhanced.
Next, a semiconductor device of the fifth embodiment of the invention will be described referring to figures. FIGS. 23 to 27 are cross-sectional views showing a method of manufacturing the semiconductor device of this embodiment.
The description of the semiconductor device of this embodiment will be made on the components formed above the second wiring layer 22 only in FIGS. 23 to 28, as in the first embodiment. The other components and the manufacturing method thereof are the same as those of the conventional art shown in
The second wiring layer 22 and an antireflection layer 23E are formed into a predetermined pattern through patterning processes including a photolithography, as shown in
Next, a first passivation layer 25E is formed so as to cover the third barrier layer 21, the second wiring layer 22, and the antireflection layer 23E as shown in
Next, as shown in
Furthermore, as shown in
Next, as shown in
Thus, an opening 24D exposing a portion of the second wiring layer 22 and not exposing an end portion of the antireflection layer 23E is formed in the passivation layer 25E and the metal layer 28.
Generally, a resist layer on the bottom portion of the sidewall of an opening is not always patterned precisely due to reflection of exposure. Therefore, the bottom portion of the sidewall of the opening 24D can be removed more than need be when the metal layer 28 is etched, thereby exposing the antireflection layer 23E. By forming the ninth resist layer 109 onto the second wiring layer 22 where the antireflection layer 23E does not remain, as in this embodiment, the metal layer 28 can completely cover the end portion of the antireflection layer 23E in the opening 24D even after the etching.
Next, the semiconductor substrate 10 and the layers layered thereon are divided into a plurality of semiconductor dice 10E by dicing along a dicing line (not shown), as shown in
As described above, the antireflection layer 23E is covered with the metal layer 28 and not exposed in the opening 24D in this embodiment. Thus, moisture containing impurities, that is, moisture used in the manufacturing process (e.g. water for dicing containing CO2 for preventing static electricity), moisture in the air, or the like does not reach the antireflection layer 23E, and this prevents cell reaction occurring between a titanium (Ti) component of the antireflection layer and an aluminum (Al) component of the second wiring layer 22 as has been seen in the conventional art. That is, aluminum that forms the second wiring layer 22 is prevented from being eluted. As a result, a connection failure when a wire is bonded to the second wiring layer 22 exposed in the opening 24D can be minimized, and the yield of the semiconductor device can be enhanced.
Next, a semiconductor device of the sixth embodiment of the invention will be described referring to figures. FIGS. 29 to 33 are cross-sectional views showing a method of manufacturing the semiconductor device of this embodiment.
The description of the semiconductor device of this embodiment will be made on the components formed above the second wiring layer 22 only in FIGS. 29 to 34, as in the first embodiment. The other components and the manufacturing method thereof are the same as those of the conventional art shown in
The second wiring layer 22 and an antireflection layer 23F are formed into a predetermined pattern through patterning processes including a photolithography, as shown in
Next, a first passivation layer 25F is formed so as to cover the third barrier layer 21, the second wiring layer 22, and the antireflection layer 23F, as shown in
Next, as shown in
Furthermore, as shown in
Next, as shown in
Next, the semiconductor substrate 10 and the layers layered thereon are divided into a plurality of semiconductor dice 10F by dicing along a dicing line (not shown), as shown in
As described above, the antireflection layer 23F and the second wiring layer 22 are covered with the metal layer 28 and not exposed in the opening 24E in this embodiment. Thus, moisture containing impurities, that is, moisture used in the manufacturing process (e.g. water for dicing containing CO2 for preventing static electricity), moisture in the air, or the like does not reach the antireflection layer 23A, and this prevents cell reaction occurring between a titanium (Ti) component of the antireflection layer and an aluminum (Al) component of the second wiring layer 22 as has been seen in the conventional art. That is, aluminum that forms the second wiring layer 22 is prevented from being eluted. As a result, a connection failure when a wire is bonded to the second wiring layer 22 exposed in the opening 24E can be minimized, and the yield of the semiconductor device can be enhanced.
Next, a semiconductor device of the seventh embodiment of the invention will be described referring to figures. FIGS. 35 to 38 are cross-sectional views showing a method of manufacturing the semiconductor device of this embodiment.
The description of the semiconductor device of this embodiment will be made on the components formed above the second wiring layer 22 only in FIGS. 35 to 39, as in the first embodiment. The other components and the manufacturing method thereof are the same as those of the conventional art shown in
A twelfth resist layer 112 is formed on a portion of an antireflection layer 23G as shown in
Next, as shown in
Next, a passivation layer 25G is formed so as to cover the third barrier layer 21, the second wiring layer 22, and the antireflection layer 23G, as shown in
Next, as shown in
Thus, an opening 24 exposing a portion of the second wiring layer 22 and not exposing an end portion of the antireflection layer 23G is formed in the passivation layer 25G. After this etching, the fourteenth resist layer 114 is removed.
Next, the semiconductor substrate 10 and the layers layered thereon are divided into a plurality of semiconductor dice 10G by dicing along a dicing line (not shown), as shown in
As described above, the antireflection layer 23G is covered with the passivation layer 25G and not exposed in the opening 24 in this embodiment. Thus, moisture containing impurities, that is, moisture used in the manufacturing process (e.g. water for dicing containing CO2 for preventing static electricity), moisture in the air, or the like does not reach the antireflection layer 23G, and this prevents cell reaction occurring between a titanium (Ti) component of the antireflection layer and an aluminum (Al) component of the second wiring layer 22 as has been seen in the conventional art. That is, aluminum that forms the second wiring layer 22 is prevented from being eluted. As a result, a connection failure when a wire is bonded to the second wiring layer 22 exposed in the opening 24 can be minimized, and the yield of the semiconductor device can be enhanced.
Although the second wiring layer 22 is the bonding pad and the structures of the layers formed below this layer 22 are the same as those of the conventional semiconductor device shown in
Number | Date | Country | Kind |
---|---|---|---|
2005-087685 | Mar 2005 | JP | national |
2006-045448 | Feb 2006 | JP | national |