Priority is claimed to Japanese Patent Application Numbers JP2005-023328, filed on Jan. 31, 2005, and JP2005-346916, filed on Nov. 30, 2005, the disclosures of which are incorporated herein by reference in its entireties.
1. Field of the Invention
The present invention relates to a circuit device and a method of manufacturing the same, and more particularly relates to a circuit device in which large circuit elements are connected with solder and a method of manufacturing the same.
2. Description of the Related Art
With reference to
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However, as shown in
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Particularly, the sink of the solder 109A frequently occurs in the step of fixing the chip component 104B by use of the solder 109B. Specifically, in this step, solder paste applied to the small pad 108B is heated and melted to fix the chip component 104B and the like. By the heating and melting in this step, the solder 109A previously formed on the surface of the relatively large pad 108A is also remelted. Since the remelted solder 109A includes no flux unlike the solder paste, a large surface tension acts thereon. Therefore, sink occurs in the remelted solder 109A.
As shown in
Furthermore, activation of an interface between the alloy layer 110 and the solder 109A by melting of the alloy made of copper and tin into the solder 109A is also one of the causes of the occurrence of the sink described above.
As shown in
Furthermore, although not clearly shown in the SEM image, a number of hemispherical protrusions, each of which has a size of about 5 to 10 μm, for example, and is made of the intermetallic compound, are formed on the entire upper surface of the alloy layer 110. The alloy layer 110 has a relatively smooth surface. The formation of the protrusions reduces an interface resistance on the upper surface of the alloy layer 110 and leads to a situation where the solder 109A is likely to slip on the surface. Thus, occurrence of the sink described above is promoted.
Meanwhile, in consideration of the environments, lead-free solder has recently been used. If the lead-free solder is used as the solder 109A, the problem of the sink described above occurs more prominently. This is because the lead-free solder contains more tin than lead eutectic solder does. To be more specific, a proportion of tin contained in a general lead eutectic solder is about 60 wt %. On the other hand, a proportion of tin contained in the lead-free solder is about 90 wt %, which is relatively large. Furthermore, when the lead-free solder is melted, a temperature is higher than that on the occasion when the lead eutectic solder is melted. This is also the cause of formation of the thick alloy layer 110. To be more specific, when the lead eutectic solder is melted, the temperature is about 200° C. Meanwhile, when a lead-free solder having a composition of Sn-3.0Ag-0.5Cu, for example, is melted, the temperature is about 240° C. As described above, the higher the melting temperature is, the more the chemical reaction is accelerated. Thus, the alloy layer 110 having poor wettability is formed to be thicker.
When the sink of the solder 109A occurs, the pad 108A and the circuit element are not connected to each other in the portion where the sink occurs. Therefore, thermal resistance in the portion where the sink occurs is increased. Furthermore, strength of a solder connection part is lowered by the occurrence of the sink. Thus, connection reliability of the solder connection part with respect to a change in temperature is lowered.
The present invention has been made in consideration for the foregoing problems. The present invention provides a circuit device which suppresses occurrence of sink of solder and improves connection reliability of a solder connection part and the present invention provides a manufacturing method thereof.
A circuit device of the present invention includes: a substrate on which a conductive pattern including a pad is formed; and a circuit element fixed to the pad with solder interposed therebetween. The solder is attached to a plated film formed on a surface of the pad.
A method of manufacturing a circuit device of the present invention includes: forming a conductive pattern on a surface of a substrate, the conductive pattern including a pad covered with a plated film; applying solder paste to a surface of the plated film; and heating and melting the solder paste to fix a circuit element to the pad by use of solder which comes into contact with the plated film.
Furthermore, a method of manufacturing a circuit device of the present invention includes: forming a conductive pattern on a surface of a substrate, the conductive pattern including a first pad covered with a plated film and a second pad smaller than the first pad; applying solder paste to the plated film formed on the first pad and heating and melting the solder paste to form solder on a surface of the plated film; fixing a circuit element to the second pad; and fixing a circuit element to the first pad by remelting the solder formed on the plated film which covers the first pad.
In this embodiment, with reference to
As shown in
As the substrate 16, a metal substrate mainly made of aluminum, copper or the like, a substrate made of a resin material such as an epoxy resin, a substrate made of a flexible sheet, for example, a printed board, or the like is used. Moreover, a ceramic substrate made of alumina and the like, a glass substrate and the like can also be adopted as the substrate 16. If a substrate made of aluminum is adopted as the substrate 16, a surface of the substrate 16 is subjected to alumite treatment. A specific size of the substrate 16 is, for example, about length×breadth×thickness=60 mm×40 mm×1.5 mm.
An insulating layer 17 is formed so as to cover the entire surface of the substrate 16. The insulating layer 17 is made of an epoxy resin or the like, which is filled with a large amount of fillers such as Al2O3. Thus, heat generated from the circuit element included in the device can be actively discharged to the outside through the substrate 16. A specific thickness of the insulating layer 17 is, for example, about 50 μm.
The conductive pattern 18 is formed of metal mainly made of copper and is formed on a surface of the insulating layer 17 so as to realize a predetermined electric circuit. Moreover, the conductive pattern 18 forms pads 18A to 18C. The respective pads will be described in detail later with reference to
A plated film 20 is formed so as to cover surfaces of the pads 18A to 18C formed of the conductive pattern 18. A thickness of the plated film 20 is, for example, about 3 μm. As a material of the plated film 20, nickel is preferable. When solder is attached to a surface of the plated film 20 made of nickel, an intermetallic compound is generated, which is made of tin contained in the solder and of nickel. The intermetallic compound made of tin and nickel has solder wettability better than that of the above-described intermetallic compound made of tin and copper. Therefore, in the manufacturing steps, occurrence of sink due to generation of the intermetallic compound including tin contained in the solder is suppressed.
The plated film 20 may be formed only on the large pad 18A, which has a risk of occurrence of sink, or may be formed on all the pads. Furthermore, the plated film 20 is also formed on an upper surface of a bonding pad 18E in order to facilitate formation of a thin metal wire.
In this embodiment, the plated film 20 is preferably formed by use of an electroplating method. As a method of forming the plated film, there are the electroplating method and an electroless plating method. The plated film 20 can be formed by use of either method. However, if the plated film 20 is formed by the electroless plating method, phosphorus (P) used as a catalyst is mixed into the plated film 20. Thus, phosphorus is also mixed into an alloy layer 13 formed on an interface between the plated film 20 and the solder 19. In the alloy layer 13 containing phosphorus, its mechanical strength is lowered. Thus, when stress acts on the alloy layer 13 in use, there arises a problem that the alloy layer 13 is easily separated from the plated film 20. On the other hand, in the electroplating method, since no phosphorus is used, no phosphorus is mixed into the plated film 20 to be formed. Thus, the plated film 20 having excellent mechanical strength can be formed.
Circuit elements such as a power transistor 14A, a chip component 14B and a small signal transistor 14C are fixed to the predetermined conductive patterns 18 with the solder 19 interposed therebetween. The power transistor 14A is fixed to the pad 18A with the heat sink 14D interposed therebetween. Thus, heat release properties are improved. The chip component 14B has electrodes on its both ends, which are fixed to the conductive pattern 18 by use of the solder 19. The small signal transistor 14C is fixed to the pas 18B with the solder 19 interposed therebetween. Here, the power transistor 14A is, for example, a transistor through which a current of 1A or more flows. The small signal transistor 14C is a transistor through which a current of less than 1A flows. Furthermore, an electrode on a surface of the power transistor 14A is connected to the conductive pattern 18 through a thick wire 15A that is a thin metal wire having a thickness of 100 μm or more. Moreover, an electrode formed on a surface of the small signal transistor 14C is connected to the conductive pattern 18 through a thin wire 15B having a thickness of about 80 μm or less.
As circuit elements mounted on the substrate 16, semiconductor elements such as a transistor, an LSI chip and a diode can be adopted. Moreover, chip components such as a chip resistor, a chip condenser, an inductance, a thermistor, an antenna and an oscillator can also be adopted as the circuit elements. Furthermore, a circuit device of a plastic molding type can also be included in the hybrid integrated circuit device 10.
A lead 11 is fixed to the pad 18C provided in a peripheral part of the substrate 16 and has a function of performing input and output from and to the outside. Here, a number of leads 11 are fixed to one side of the substrate 16. Note that the leads 11 can also be derived from four sides of the substrate 16 or can also be derived from two opposite sides thereof.
The sealing resin 12 is formed by transfer molding using a thermosetting resin. As shown in
As shown in
With reference to a cross-sectional view of
In this embodiment, by covering the surfaces of the pad 18A and the like with a plated film 20, it is possible to prevent destruction of a connection part connected by solder 19. To be more specific, since the surfaces of the pad 18A and the like are covered with the plated film 20 made of nickel, the pad 18A made of copper does not come into direct contact with the solder 19. Therefore, a fragile intermetallic compound, which is made of tin contained in the solder and copper that is a material of the pad 18A, is never generated. Moreover, even if the circuit element such as a transistor 14A generates heat and the pad 18A and the solder 19 are heated, it is less problematic that the intermetallic compound described above further grows. By covering the surface of the pad 18A with the plated film 20, an alloy layer 13 made of nickel and tin is formed on the boundary between the plated film 20 and the solder 19. The alloy layer 13 has mechanical strength better than that of the intermetallic compound made of tin and copper. Therefore, even if, in use, the transistor 14A and the like are operated to heat up the solder 19 and the alloy layer 13 grows, the connection part between the solder 19 and the plated film 20 is never easily destroyed.
In this embodiment, with reference to FIGS. 3 to 8, description will be given of a method of manufacturing the hybrid integrated circuit device 10 described above.
First Step: See
In this step, a conductive pattern 18 is formed on a surface of a substrate 16.
As shown in
Moreover, surfaces of the pads 18A to 18C are covered with a plated film 20 made of nickel. Furthermore, a surface of a bonding pad 18E is also covered with a plated film made of nickel. Thus, bonding properties are improved. By forming the plated film 20 on the surfaces of the pad 18A and the like, sink of a solder formed on the pad 18A can be suppressed. This matter will be described in detail below.
Second Step: See
In this step, a solder 19A is formed on upper surfaces of the pads 18A and 18C.
First, as shown in
It is preferable that the solder paste 21A used in this step be a mixture of flux containing sulfur and solder powder. Sulfur is mixed in a proportion of 20 to 80 PPM into the flux. By mixing sulfur into the flux within such a concentration range, surface tension of the flux is reduced. Thus, wettability of the solder paste 21A can be improved. If the amount of sulfur is 20 PPM or less, the effect of improving the wettability is not sufficient. Consequently, there is a risk of occurrence of sink. Furthermore, if the amount of sulfur is 80 PPM or more, a nucleus of mixed sulfur remains in the solder. Thus, there is a risk that a local depression might be formed in the surface of the solder.
As a method of manufacturing the solder paste 21A, first, granular sulfur (S) is dissolved in a solvent. Next, after the solvent containing sulfur and flux are mixed, the flux and solder powder are mixed. A proportion of the flux contained in the solder paste 21A is, for example, about 5 to 15 wt %.
As the solder powder mixed in the solder paste 21A, both of solder containing lead and lead-free solder can be adopted. As a specific composition of the solder powder, for example, Sn63/Pb37, Sn/Ag3.5, Sn/Ag3.5/Cu0.5, Sn/Ag2.9/Cu0.5, Sn/Ag3.0/Cu0.5, Sn/Bi58, Sn/Cu0.7, Sn/Zn9, Sn/Zn8/Bi3 and the like are conceivable. The numbers described above indicate wt % relative to the entire solder. Considering that lead has a load significantly affecting on the environment, it is preferable to use the lead-free solder. The solder paste 21A containing the lead-free solder tends to have poor solder wettability. However, the surface tension of the flux is reduced by action of the added sulfur. Thus, occurrence of sink is suppressed.
As the flux, rosin-based flux and water-soluble flux are both applicable. However, the water-soluble flux is preferable. This is because the water-soluble flux has strong soldering properties and is suitable for attaching the solder 19A to the entire surface of the pad 18A. When the water-soluble flux is used, by melting of the solder paste 21A, a highly corrosive flux residue is generated. Therefore, in this embodiment, after a reflow step is finished, the residue is cleaned and removed.
The flux used in this embodiment is a RA type having a very strong active force. By using the flux of the RA type, even if an oxide film is formed on the surface of the plated film 20, the oxide film can be removed by the flux. Therefore, in this embodiment, it is not required to cover the surface of the plated film 20 with gold plating or the like in order to prevent formation of the oxide film. Generally, the flux is classified broadly into a R type (Rosin base), a RMA type (Mildly Activated Rosin base) and a RA type (Activated Rosin base) in the order from a weaker active force. In this embodiment, the flux of the RA type having the strongest active force is used.
In this embodiment, before the circuit elements are mounted, the melted solder 19A is previously formed on the large pad 18A. This is because, in this embodiment, mounting of the circuit elements is sequentially performed from a relatively small circuit element such as a small signal transistor. After the circuit element such as the small signal transistor is fixed, it is difficult to print the solder paste on the upper surface of the large pad 18A. Thus, by preparing the solder 19A melted on the pad 18A, the problem described above can be avoided.
As shown in
The heating and melting of the solder paste 21A is performed by heating a rear surface of the substrate 16 by use of a heater block and performing infrared irradiation from above. If the solder paste 21A contains tin-lead eutectic solder, a reflow temperature is about 220° C. Moreover, if the solder paste 21A is the lead-free solder (for example, Sn/Ag3.5/Cu0.5), the reflow temperature is about 250° C.
In this embodiment, by allowing the solder paste 21A to contain sulfur in a predetermined proportion, the solder 19A can be formed by heating and melting the solder paste 21A while suppressing sink of the solder. Therefore, as shown in
Furthermore, in this embodiment, formation of the plated film 20 made of nickel on the surface of the pad 18A also contributes to prevention of occurrence of the sink. To be more specific, the plated film 20 is formed on the surface of the pad 18A made of copper, and the solder 19A is formed on the surface of the plated film 20. Thus, the solder 19A and the pad 18A can be prevented from coming into direct contact with each other. Therefore, an intermetallic compound made of tin that is a major component of the solder and copper that is a material of the pad is never generated. According to the configuration of this embodiment, an intermetallic compound made of tin that is a major component of the solder and nickel that is a material of the plated film 20 is generated. Specifically, a Ni/Sn alloy layer 13 is formed on an interface between the plated film 20 and the solder 19A. The Ni/Sn alloy layer 13 has solder wettability better than that of a Cu/Sn alloy layer. Therefore, in this embodiment, occurrence of sink caused by poor solder wettability of the intermetallic compound is suppressed.
It is considered that by heating and melting the solder paste 21A, most of sulfur flows out to the outside of the solder 19A together with the flux component. However, there is also a possibility that a very small amount of sulfur remains in the solder 19A and reduces the surface tension of the melted solder 19A in a subsequent step of remelting the solder 19A.
Third Step: See
In this step, a small signal transistor and the like are fixed to the substrate 16.
As shown in
As shown in
When the solder 19A attached to the large pad 18A is remelted, there is a high risk that sink occurs. This is because the solder 19A to be remelted contains no flux that improves soldering properties. Furthermore, when a large amount of the solder 19A attached to the large pad 18A is melted, there is action of large surface tension. This large surface tension also causes occurrence of sink.
Accordingly, in this embodiment, the plated film 20 made of nickel is formed on the surface of the pad 18A so that the solder 19A does not come into direct contact with the pad 18A. Thus, occurrence of the sink is suppressed. To be more specific, by forming the plated film 20, tin contained in the solder and copper that is the material of the pad do not come into direct contact with each other. Thus, the Cu/Sn alloy layer formed of the intermetallic compound made of tin and copper is never formed. According to the configuration of this embodiment, the Ni/Sn alloy layer formed on the surface of the plated film has soldering properties better than those of the Cu/Sn alloy layer. Thus, in this step, sink of the solder 19A is suppressed.
After the step described above is finished, the small signal transistor 14C is electrically connected to the conductive pattern 18 through a thin wire 15B. Moreover, the small signal transistor 14C may be fixed by use of conductive paste such as Ag paste.
With reference to
As shown in
Moreover, nickel becomes a barrier film of Cu formed therebelow and can suppress deposition of Cu on a surface of Ni. Thus, a reaction of Cu and Sn is suppressed as much as possible, and occurrence of sink is suppressed. Furthermore, a surface of the alloy layer 13 is set to be a rough surface compared with that described in the background. Thus, the surface of the alloy layer 13 is an environment where it is difficult for the liquefied solder 19A to move. This also contributes to prevention of the sink.
Fourth Step: See
In this step, a heat sink 14D is mounted on the pad 18A.
As shown in
In this embodiment, since the sink of the solder 19A is suppressed, an entire rear surface of the heat sink 14D is fixed to the pad 18A with the solder 19A interposed therebetween. Therefore, heat release properties of the power transistor 14A mounted on the heat sink 14D are ensured.
As shown in
In this embodiment, after the small signal transistor 14C is fixed and the thin wire 15B is formed, the heat sink 14D is fixed. This is because it is difficult to dispose the transistor 14C and form the thin wire 15B in the vicinity of the heat sink 14D after the heat sink 14D is fixed. By disposing the heat sink 14D that is a large circuit element after a small circuit element is fixed, the small circuit element can be disposed near the heat sink 14D.
Fifth Step: See
In this step, the lead 11 is fixed and a sealing resin 12 is formed.
As shown in
As shown in
In this embodiment, description will be given of another method of manufacturing a hybrid integrated circuit device. Here, solder paste is collectively melted to fix circuit elements.
As shown in
In this embodiment, a plated film 20 made of nickel is formed on a surface of the large pad 18A in which sink is likely to occur. Therefore, even if the solder paste 21 is melted, a Cu/Sn alloy layer having poor soldering properties is not formed. In this embodiment, a Ni/Sn alloy layer having soldering properties better than those of the Cu/Sn alloy layer is formed on a surface of the plated film 20.
Furthermore, as the solder paste 21 used in this step, flux having sulfur mixed therein can be used as in the case of the second embodiment. Sulfur is mixed in a proportion of 20 to 80 PPM into the flux. By adding sulfur, surface tension of the melted solder paste 21 is reduced.
As shown in
As described above, in this embodiment, the upper surfaces of the pad 18A and the like are covered with the plated film 20. Therefore, when the solder paste 21 applied to the pad 18A is melted, the Ni/Sn alloy layer having excellent soldering properties is formed on the surface of the plated film 20. Thus, the sink of the solder 19 is suppressed.
As shown in
As shown in
In this embodiment, the circuit elements fixed by use of the solder paste are collectively reflowed. Thus, it is possible to provide a manufacturing method including reduced steps.
According to the circuit device of the embodiments of the present invention and the manufacturing method thereof, it is possible to suppress occurrence of sink in the solder attached to the surface of the pad by forming the plated film on the surface of the pad on which the circuit element is mounted. To be more specific, the solder is attached to the surface of the plated film formed so as to cover the pad, and the circuit element such as a heat sink is fixed by use of the solder. Therefore, since the solder does not come into direct contact with the pad, an ally layer formed of an intermetallic compound made of tin contained in the solder and copper that is a material of the pad is not formed. Since the intermetallic compound made of copper and tin has poor soldering properties, solder wettability for the pad can be improved by preventing generation of the intermetallic compound.
In the conventional case, particularly, when the lead-free solder is used, there occurs a problem of sink of solder due to the intermetallic compound made of copper and tin. According to the configuration of the embodiments of the present invention, the compound itself is not formed. Therefore, even if the lead-free solder having poor wettability is attached to a relatively large pad, occurrence of sink in the solder can be suppressed.
Number | Date | Country | Kind |
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2005-346916 | Nov 2005 | JP | national |
2005-023328 | Jan 2005 | JP | national |