The present invention relates to a method for embedding a component in a printed circuit board, or in a printed circuit board intermediate product, wherein the printed circuit board, or the printed circuit board intermediate product, comprises at least one insulating layer made of a prepreg material, and the component is fixed by the resin of the prepreg material, and to a printed circuit board or a printed circuit board intermediate product.
Printed circuit boards are used to fix and electrically connect electronic components and to connect these, in the form of a module, in electronic devices. Printed circuit boards are generally composed of a plurality of alternating layers made of insulating material and conducting material, wherein the layers made of electrically conducting material, such as copper, are structured to form conductor tracks, which are connected to the contact pads of the electronic components and route these accordingly. In addition to fixing and connecting the electronic components to each other, printed circuit boards can additionally assume a static function in an electronic device given the relatively high mechanical stability of the same.
In keeping with the steadily progressing miniaturization of electronic devices, such as mobile telephones, tablet computers and the like, the increasingly smaller electronic components are not only mounted and soldered to the surface of printed circuit boards, but also integrated into the interior, the cross-section of the printed circuit boards, to an ever greater extent. A conventional method for embedding electronic components in printed circuit boards provides for the creation of clearances or holes in the printed circuit board having the size and shape of the component to be embedded so that, in a subsequent step, the components can be inserted in the respective holes and glued in place there. The disadvantage of gluing the components in the printed circuit board, however, is that the adhesive necessarily represents a different material than the material of the insulating layer in the printed circuit board. While the insulating layers in the printed circuit board are made of prepreg materials, such as FR4, which is to say resin system, adhesives for inserting the components are usually solvent-based. The bonding of components therefore automatically results in inhomogeneities, wherein the relatively strong heating of the components in the printed circuit board during operation results in the formation of cracks over time due to differing coefficients of thermal expansion of the materials that are used, which adversely affects the durability of the printed circuit board, and thus of the corresponding electronic devices.
A method was therefore provided in WO 2012/100274 A1 in which the components are not fixed in the printed circuit board by way of adhesive, but fixation is achieved by way of the resin of the insulating layers of the printed circuit board. In the production of printed circuit boards, the insulating layers, which are made of a prepreg material, are joined to the conducting layers by lamination and compression at elevated temperatures. Prior to the lamination and compression at the elevated temperature, the resin of the prepreg materials is in a non-cured state, which is referred to as the B-stage. B-stage prepregs are stored on rollers while being cooled so as to prevent premature curing of the resin. The method according to WO 2012/100274 A1 now provides for clearances for the components to be created in a combination that comprises curable prepreg material, which is to say B-stage prepreg material, for the components to be mounted in the clearances, and the clearances or openings comprising the components to be covered with further B-stage prepreg layers, and optionally with further contact layers or electrically conducting layers. This combination is subsequently compressed to yield the finished printed circuit board, in which the prepreg material is present in the cured state, the cured state being referred to as the C-stage in professional circles.
The disadvantage with this method is the circumstance that covering the clearances comprising the components with further layers is necessarily required, so that the printed circuit boards produced by way of the method according to WO 2012/100274 A1 were relatively thick, which is contrary to the idea of miniaturization.
It is the aim of the invention to improve a method of the type mentioned above to the effect that the prepreg layers covering clearances and components can be avoided, whereby preferably thin printed circuit boards can be implemented.
According to the present invention, a printed circuit board or a printed circuit board intermediate product, comprises a first main surface and a second main surface; a combination of layers including a plurality of insulating layers and at least one first metal layer, wherein the at least one first metal layer extends along a first horizontal plane in parallel to at least one of the first and second main surfaces; at least one cavity in the printed circuit board or the printed circuit board intermediate product, said cavity extending through at least one of the plurality of insulating layers; a component inserted in the at least one cavity, said component being embedded in said at least one cavity by a material from the at least one insulating layer through which the cavity extends.
According to an embodiment, the cavity is laterally delimited by at least one side wall, the material from the at least one insulating layer through which the cavity extends fills the space between the component and the at least one side wall of the cavity.
According to an embodiment, the printed circuit board or printed circuit board intermediate product comprises at least one of the following features: wherein the material from the at least one insulating layer embedding the component is provided in the cavity only; wherein the cavity exposes at the first main surface and the second main surface, said first main surface and second main surface being free of the material from the at least one insulating layer embedding the component; wherein said component is embedded in the cavity by a material from the at least one insulating layer through which the cavity extends; wherein a component main surface of the component is vertically misaligned from a layer main surface of a layer of the combination of layers, in particular from each layer of the combination of layers; wherein a component main surface of the component is vertically aligned with a layer main surface of a layer of the combination of layers, in particular with a first metal layer main surface of the at least one first metal layer; wherein at least one insulating layer of the plurality of insulating layers is made of a curable prepreg material.
According to an embodiment, the component comprises at least one first contact pad, in particular wherein a first further metal layer directly connects the at least one first contact pad and/or one component main surface of the component to the at least one first metal layer without any insulating layer being interposed between the at least one first metal layer and the first further metal layer, and/or a first further metal layer directly connects the at least one first contact pad to a first contact portion of the at least one first metal layer without any insulating layer being interposed between the at least one first metal layer and the first further metal layer within a horizontal area between the first contact pad and the first contact portion.
According to an embodiment, the first further metal layer and the at least one first metal layer define a step shape.
According to an embodiment, the one component main surface of the component is in contact with the first further metal layer, in particular defining a stepped connection area.
According to an embodiment, one component main surface of the component is vertically aligned with an external main surface of the at least one first metal layer and/or the component comprises at least one first contact pad which is vertically aligned with the external main surface of the at least one first metal layer.
According to an embodiment, one component main surface of the component is vertically aligned with a layer main surface of one layer of the combination of layers and/or the component comprises at least one first contact pad which is vertically aligned with the layer main surface of one layer of the combination of layers; and an opposed component main surface of the component is vertically misaligned from a further layer main surface of one layer of the combination of layers.
According to an embodiment, the component comprises a first component main surface and a second component main surface being opposed to the first component main surface, wherein at least one first contact pad of the component is arranged at the first component main surface and a second contact pad of the component is arranged at the second component main surface.
According to an embodiment, the combination of layers includes at least one second metal layer extending along a second horizontal plane in parallel to at least one of the first and second main surfaces; the component has at least one second contact pad intersecting the second horizontal plane; and the printed circuit board or printed circuit board intermediate product comprises a second further metal layer which directly connects the at least one second contact pad to the at least one second metal layer without any insulating layer being interposed between the at least one second metal layer and the second further metal layer.
According to an embodiment, the second further metal layer directly connects the at least one second contact pad and/or one component main surface of the component to a second contact portion of the at least one second metal layer without any insulating layer being interposed between the at least one second metal layer and the second further metal layer within a horizontal area between the second contact pad and the second contact portion.
According to an embodiment, the second further metal layer and the at least one second metal layer define a step shape.
According to an embodiment, one component main surface of the component is in contact with the second further metal layer, in particular defining a stepped connection area.
According to an embodiment, a plurality of the components is embedded in the combination of layers.
According to an embodiment, at least two of the plurality of the components have different thicknesses to one another.
According to an embodiment, a component main surface of one component of the plurality of components is vertically aligned with a layer main surface of a layer of the combination of layers, in particular with the at least one first metal layer, and a further component main surface of a further component of the plurality of components is vertically aligned with a further layer main surface of a further layer of the combination of layers.
According to an embodiment, at least one first contact pad of a component of the plurality of components is vertically aligned with a layer main surface of a layer of the combination of layers, in particular with the at least one first metal layer, and at least a second first contact pad of a further component of the plurality of components is vertically aligned with a further layer main surface of a further layer of the combination of layers.
According to an embodiment, the component main surface and/or at least one first contact pad of the component of the plurality of components faces away from the further component main surface and/or at least one second contact pad of the further component of the plurality of components.
According to an embodiment, the combination of layers includes at least one second metal layer extending along a second horizontal plane in parallel to at least one of the first and second main surfaces; and the printed circuit board or printed circuit board intermediate product comprises a second further metal layer which directly connects the at least one first contact pad and/or the at least one second contact pad to the at least one second metal layer without any insulating layer being interposed between the at least one second metal layer and the second further metal layer, in particular wherein the second further metal layer and the at least one second metal layer define a step shape and/or wherein one main surface of the component is in contact with the second further metal layer, more in particular defining a stepped connection area.
According to an embodiment, the combination of layers comprises a core having a first core main surface and a second core main surface, wherein at least one insulating layer of the plurality of insulating layers is a first insulating layer arranged at the first core main surface, wherein the core and the first insulating layer form a stack; and the component is embedded in the stack.
According to an embodiment, the printed circuit board or printed circuit board intermediate product further comprises a second insulating layer arranged at the second core main surface and being part of the stack.
According to an embodiment, a method of manufacturing a printed circuit board or a printed circuit board intermediate product is provided. The printed circuit board or printed circuit board intermediate product comprises a first main surface and a second main surface. The method comprising steps of providing a combination of layers including a plurality of insulating layers and at least one first metal layer, the at least one first metal layer extending along a first horizontal plane in parallel to at least one of the first and second main surfaces; providing a cavity in the printed circuit board or a printed circuit board intermediate product, said cavity extending through at least one of the plurality of insulating layers; embedding a component in the cavity by a material from the at least one insulating layer through which the cavity extends.
According to the invention a method of the type mentioned above can be characterized by the following steps:
The method according to the invention can thus provide a combination of all the layers of the printed circuit board, or of the printed circuit board intermediate product, wherein this combination includes B-stage prepreg material, which is to say prepreg material that still must be cured, in contrast to already cured prepreg material. After the clearance for the component has been created, at least the region of the clearance according to step c) is covered with a first temporary carrier layer, so that the component to be embedded can be mounted on the first temporary carrier layer. Thereafter, the region of the clearance comprising the component positioned therein is covered on the second side of the combination with a second temporary carrier layer. A separating film may be used for this purpose, which may have any arbitrary design, as long as it can be removed after the prepreg material has cured and reached the C-stage. Curing of the prepreg material takes place in step f) and is carried out according to methods that are well-known in the prior art. The combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, comprising the mounted component and the two temporary carrier layers is generally subjected to mechanical pressure and simultaneous heating, whereby cross-linking of the resin of the prepreg material of the insulating layer or of the insulating layers takes place. During compressing according to step f), the resin of the prepreg material flows around the component, meets with a spatial delimitation at the temporary carrier layers, and thus also cures in the region of the components, resulting in a continuous resin phase through the prepreg layers forming the insulating layers of the printed circuit board, or of the printed circuit board intermediate product. In this way, only minor stresses develop during operation of the printed circuit board, as the components heat, which in the absence of an interface, as it occurs in the case of gluing between the adhesive and the resin, can be dissipated directly to the surrounding regions. Since the region of the embedded component did not have to be covered by additional prepreg layers so as to enable compressing, an extremely thin product is yielded after the temporary carrier layers have been removed in accordance with step g), which excellently meets today's requirements in regard to miniaturization.
The method according to the invention can be defined with respect to one component that is being embedded. However, it is clear to a person skilled in the art that it is also possible in industrial production to embed a plurality of components in one and the same combination; however, the invention shall be understood such that only one component is inserted in each case in one clearance. The present description may therefore refer to the component in the singular form, or to a plurality of components, which does not change the meaning and the essence of the present invention.
The invention can be based on different types of a combination of the layers of the printed circuit board, or of the printed circuit board intermediate product. According to a preferred variant of the method according to the invention, it can be provided that the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, is composed of a plurality of layers made of a prepreg material. The use of such a combination in step a) of the method according to the invention results in a particularly homogeneous printed circuit board, or in a particularly homogeneous printed circuit board intermediate product, since no conducting layers are present between the layers made of a prepreg material, and the resin of the prepreg material can thus flow unimpaired prior to curing, and can consequently flow around the component to be embedded, or the components to be embedded. After compression and after removal of the temporary carrier layers, this preferred embodiment of the present invention generally requires for the wiring or the routing of the embedded component or components to take place in a subsequent processing step, in which conductor tracks can be formed on the outsides according to known methods.
So as to simplify the formation of conductor tracks, the invention can be refined according to one preferred embodiment to the effect that the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, can be composed of a plurality of layers made of prepreg material and copper layers located on the outside on both sides. In this case, copper layers can be provided on the outside of the printed circuit board, or of the printed circuit board intermediate product, on both sides after compression and after removal of the temporary carrier layers, from which suitable conductor tracks can be formed, for example using photolithography methods.
If the printed circuit board, or the printed circuit board intermediate product, which can be to be produced by way of the method according to the invention, is to meet particular requirements in terms the mechanical stability, according to a preferred embodiment of the present invention the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, can be composed of a plurality of layers made of prepreg material and a central core. In professional circles, a core is understood to mean a layer of a cured prepreg material, such as FR4, having copper layers laminated thereon on both sides. Such cores can be procured industrially as a standard part and offer a certain stability in the method according to the invention already before compressing the curable prepreg material in the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, which results in improved handling during processing and increased strength of the finished product. The central core may optionally be appropriately structured for the formation of conductor tracks.
According to a further preferred embodiment of the present invention, the combination can be composed of a plurality of layers made of prepreg material and a central core, as well as copper layers located on the outside on both sides, which corresponds to a combination of the two preceding variants, whereby a combination of the above-described advantages is achieved.
Moreover, it is conceivable according to a preferred embodiment of the present invention that the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, can be composed of an inside layer made of a prepreg material and cores located on the outside on both sides.
The method according to the invention allows printed circuit boards, or printed circuit board intermediate products, comprising embedded components to be produced in a particularly thin manner. According to a preferred embodiment of the present invention, the method according to the invention can be refined to the effect that the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, essentially has the thickness of the components to be embedded. Insufficient thickness would cause the components to protrude beyond the cross-section of the printed circuit board and consequently prevent these from being entirely encased by the resin of the prepreg material. However, a thickness of the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, that considerably exceeds the thickness of the components is likewise not necessary to ensure sufficient embedding into the resin of the prepreg material.
As was already mentioned above, the method according to the invention can be applied to a plurality of components, so that a plurality of components can be embedded into the printed circuit board. It can be essential, however, that the method, as it is defined in the main claim, can be carried out for each individual component, so that in each case one clearance is created for a respective component to be embedded.
According to a preferred embodiment of the present invention, it can be provided that components having differing thicknesses can be mounted in the respective clearances, and the second temporary carrier layer can be oriented with a non-adhering surface to the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product. In this case, the thickness of the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, can be selected based on the thickest component, or based on the thickest components, so that thinner components do not extend completely through the cross-section of the combination. For this reason, the second temporary carrier layer must be oriented with a non-adhering surface to the combination of the layers of the printed circuit board, or of the printed circuit board intermediate product, so as to prevent the component from being lifted off the first temporary carrier layer when an adhesive layer can be compressed with the second temporary carrier layer.
The first side of the combination is preferably a contact side of the printed circuit board, or of the printed circuit board intermediate product, and the component to be embedded can be fixed in the clearance face up with respect to this contact side.
According to a preferred refinement of the present invention, both the first side and the second side of the combination can be a contact side of the printed circuit board. In this case, both sides of the printed circuit board can comprise conductor tracks, whereby a highly integrated and thus space-saving printed circuit board is obtained.
This is particularly advantageous when a component having contacts on two opposing sides of the component is being embedded, as is the subject matter of a preferred embodiment of the present invention. This configuration allows current to flow vertically, which is to say current to flow through the cross-section of the printed circuit board, wherein the electronic component serves as a current bridge.
The component can be preferably selected from the group consisting an integrated circuit, an LED, a heat sink, a battery, and a printed circuit board, and in particular a multilayer printed circuit board. In particular, the aforementioned component can be any active or passive electronic part. In this connection, the electronic component can also be a fully or partially populated printed circuit board (module) or a MEMS- or MOEMS structure. However, the component may also be a non-electronic component, for example a cooling element, which in particular can be made of a metallic material. It is obvious to a person skilled in the art that the method according to the invention can be used to embed any type of electronic component, so that this enumeration shall not be considered to be exhaustive.
According to a particularly preferred embodiment of the present invention, the component can be an IMS component. The abbreviation IMS denotes “insulated metal substrate” and refers to a component in which a thin insulator layer, for example epoxy resin-based, can be disposed between a thick, metallic base layer, for example made of aluminum or copper, and a relatively thin conducting layer, for example made of aluminum or copper. IMS components can be used for contacting and the simultaneous cooling of power components, since the conducting layer, on the one hand, can be structured to obtain contact areas and conductor tracks and, on the other hand, can be electrically insulated with respect to the base layer by the insulator layer, wherein the insulator layer ensures good heat transfer to the base layer where the heat developed by the power component can be dissipated.
The first temporary carrier layer is preferably designed in the form of an adhesive tape. The adhesive action of the adhesive tape positions or temporarily fastens the components, wherein however the second temporary carrier layer does not necessarily have to be an adhesive tape.
The invention will be described hereafter in greater detail based on one exemplary embodiment shown schematically in the drawings. In the drawings:
To carry out the method according to the invention, it is essentially only necessary to cover at least the region of the clearance, or the regions of the clearances, with a first temporary carrier layer 5. In industrial production, however, it is usually easier to cover not only the region or the regions of the clearances with a first temporary carrier layer, but the entire surface area of the combination 100 with a continuous first temporary carrier layer 5.
It is now apparent in
It is apparent from
According to a preferred embodiment of the present invention, in
The use of IMS parts is particularly suited for dissipating heat, and in the case shown in
In one aspect of a method for embedding a component in a printed circuit board or a printed circuit board intermediate product, the printed circuit board or the printed circuit board intermediate product comprises at least one insulating layer made of a prepreg material, and the component is fixed by the resin of the prepreg material, characterized by a sequence of the following steps:
In one aspect of the method, the combination of the layers of the printed circuit board or of the printed circuit board intermediate product is composed of a plurality of layers made of a prepreg material.
In one aspect of the method, the combination of the layers of the printed circuit board or of the printed circuit board intermediate product is composed of a plurality of layers made of a prepreg material and copper layers located on the outside on both sides.
In one aspect of the method, the combination of the layers of the printed circuit board or of the printed circuit board intermediate product is composed of a plurality of layers made of prepreg material and a central core.
In one aspect of the method, the combination is composed of a plurality of layers made of prepreg material and a central core, as well as copper layers located on the outside on both sides.
In one aspect of the method, the combination of the layers of the printed circuit board or of the printed circuit board intermediate product is composed of an inside layer made of a prepreg material and cores located on the outside on both sides.
In one aspect of the method, the combination of the layers of the printed circuit board or of the printed circuit board intermediate product essentially has the thickness of the component to be embedded.
In one aspect of the method, a plurality of components are embedded into the printed circuit board, or into the printed circuit board intermediate product.
In one aspect of the method, components having differing thicknesses are mounted in the respective clearances, and the second temporary carrier layer is oriented with a non-adhering surface to the combination of the layers of the printed circuit board or of the printed circuit board intermediate product.
In one aspect of the method, the first side of the combination is a contact side of the printed circuit board or of the printed circuit board intermediate product and the component to be embedded is fixed in the clearance face up with respect to this contact side.
In one aspect of the method, both the first side and the second side of the combination are contact sides of the printed circuit board, or of the printed circuit board intermediate product.
In one aspect of the method, a component having contacts on two opposing sides of the component is being embedded.
In one aspect of the method, the component is selected from the group consisting an integrated circuit, an LED, a heat sink, a battery, and a printed circuit board, and in particular a multilayer printed circuit board.
In one aspect of the method, the component is an IMS part.
In one aspect of the method, the first temporary carrier layer is designed in the form of an adhesive tape.
In one aspect of the method, a printed circuit board, or a printed circuit board intermediate product is produced according to the method.
One aspect of a printed circuit board or a printed circuit board intermediate product, comprises:
In one aspect of the printed circuit board or printed circuit board intermediate product the first further metal layer directly connects the at least one first contact pad to a first contact portion of the at least one first metal layer without any insulating layer being interposed between the at least one first metal layer and the first further metal layer within a horizontal area between the first contact pad and the first contact portion.
In one aspect of the printed circuit board or printed circuit board intermediate product the at least one insulating layer is made of a curable prepreg material.
In one aspect of the printed circuit board or printed circuit board intermediate product the component comprises a first component main surface and a second component main surface, wherein the at least one first contact pad is arranged at the first component main surface and a second contact pad is arranged at the second component main surface.
In one aspect of the printed circuit board or printed circuit board intermediate product according the combination of layers includes at least one second metal layer extending along a second horizontal plane in parallel to at least one of the first and second main surfaces; the component has at least one second contact pad intersecting the second horizontal plane; and the printed circuit board or printed circuit board intermediate product comprises a second further metal layer which directly connects the at least one second con-tact pad to the at least one second metal layer without any insulating layer being interposed between the at least one second metal layer and the second further met-al layer.
In one aspect of the printed circuit board or printed circuit board intermediate product the second further metal layer directly connects the at least one second con-tact pad to a second contact portion of the at least one second metal layer without any insulating layer being interposed between the at least one second metal layer and the second further metal layer within a horizontal area between the second contact pad and the second contact portion.
In one aspect of the printed circuit board or printed circuit board intermediate product a plurality of the components is embedded in the combination of layers.
In one aspect of the printed circuit board or printed circuit board intermediate product another component embedded in the combination of layers, wherein the component and the other component have different thicknesses.
In one aspect of the printed circuit board or printed circuit board intermediate product the component is selected from the group consisting an IMS part, a copper inlay, an integrated circuit, an LED, a heat sink, a battery, and a printed circuit board, and in particular a multilayer printed circuit board.
In one aspect of the printed circuit board or printed circuit board intermediate product the combination comprises a core having a first core main surface and a second core main surface, wherein the at least one insulating layer is a first insulating layer arranged at the first core main surface, wherein the core and the first insulating layer form a stack; and the component is embedded in the stack.
In one aspect of the printed circuit board or printed circuit board intermediate product a second insulating layer arranged at the second core main surface and being part of the stack.
One aspect of a method of manufacturing a printed circuit board or a printed circuit board intermediate product, the printed circuit board or printed circuit board intermediate product comprising a first main surface and a second main surface, the method includes the steps of:
In one aspect of the method the first further metal layer is arranged to directly connect the at least one first contact pad to a first contact portion of the at least one first metal layer without inter-posing any insulating layer between the at least one first metal layer and the first further metal layer within a horizontal area between the first contact pad and the first contact portion.
In one aspect of the method the at least one insulating layer is made of a curable prepreg material.
In one aspect of the method the component comprises a first component main surface and a second component main surface, the at least one first contact pad being arranged at the first component main surface and a second contact pad being arranged at the second component main surface.
In one aspect of the method the combination of layers includes at least one second metal layer extending along a second horizontal plane in parallel to at least one of the first and second main surfaces; the component has at least one second contact pad, wherein the component is embedded in the combination of layers such that the at least one second contact pad intersects the second horizontal plane; and arranging a second further metal layer which directly connects the at least one second contact pad to the at least one second metal layer without interposing any insulating layer between the at least one second metal layer and the second further metal layer.
In one aspect of the method the second further metal layer is arranged to directly connect the at least one second contact pad to a second contact portion of the at least one second metal layer without interposing any insulating layer between the at least one second metal layer and the second further metal layer within a horizontal area between the second contact pad and the second contact portion.
In one aspect of the method a plurality of the components is embedded in the combination of layers.
In one aspect of the method another component is embedded in the combination of layers, wherein the component and the other component have different thicknesses.
In one aspect of the method the component is selected from the group consisting an IMS part, a copper inlay, an integrated circuit, an LED, a heat sink, a battery, and a printed circuit board, and in particular a multilayer printed circuit board.
In one aspect of the method the combination comprises a core having a first core main surface and a second core main surface, the at least one insulating layer being a first insulating layer arranged at the first core main surface, wherein the core and the first insulating layer form a stack; and the component is embedded in the stack.
In one aspect of the method a second insulating layer is arranged at the second core main surface, the second insulating layer being part of the stack
| Number | Date | Country | Kind |
|---|---|---|---|
| A 50821/2013 | Dec 2013 | AT | national |
This application is a continuation application of U.S. application Ser. No. 16/908,500, filed Jun. 22, 2020, which is a continuation application of U.S. application Ser. No. 15/103,826, filed Jun. 10, 2016, which application is a national stage of Application No. PCT/AT2014/050300, filed Dec. 12, 2014, which application claims priority to Austrian Application No. A 50821/2013, filed on Dec. 12, 2013, the disclosures of which are hereby incorporated by reference in their entireties
| Number | Date | Country | |
|---|---|---|---|
| Parent | 16908500 | Jun 2020 | US |
| Child | 19093674 | US | |
| Parent | 15103826 | Jun 2016 | US |
| Child | 16908500 | US |