Patent Application
20200243364
The present invention relates to a technique for polishing a substrate.
There is known a chemical mechanical polishing (CMP, Chemical Mechanical Polishing) apparatus that polishes a surface of a substrate when a semiconductor device is manufactured. The CMP apparatus includes a polishing pad attached on a top surface of a polishing table, thereby forming a polishing surface. In this CMP apparatus, a polishing target surface of the substrate held by a top ring is pressed against the polishing surface, and the polishing table and the top ring rotates while supplying slurry as polishing liquid to the polishing surface. As a result, the polishing surface and the polishing target surface are slidably moved relative to each other, by which the polishing target surface is polished.
In recent years, the planarization technique including the CMP has been facing expansion of a variety of possible polishing target materials, and also has been subject to requirements that has been becoming increasingly stricter with respect to a polishing capability thereof (for example, flatness, a damage incurred from the polishing, and further, productivity). Under such circumstances, new planarization methods also have been proposed, and one of them is catalyst referred etching (Catalyst Referred Etching: hereinafter referred to as CARE). According to the CARE method, reactive species are produced from processing liquid that reacts with the polishing target surface only around a catalyst material in the presence of the processing liquid. Then, bringing the catalyst material and the polishing target surface into proximity to or contact with each other allows an etching reaction to selectively occur on the polishing subject surface on a surface located in proximity to or in contact with the catalyst material. For example, for a rough polishing target surface, bringing protrusions and the catalyst material into proximity to or contact with each other allows the protrusions to be selectively etched, thereby succeeding in the planarization of the polishing subject surface. Originally, this CARE method has been proposed for the purpose of planarizing next-generation substrate materials that used to be difficult to be highly efficiently planarized by the CMP due to their chemical stability, such as Sic and GaN (for example, the following patent literatures, PTL 1 to PTL 4). However, in recent years, the CARE method has been confirmed to be also usable to process a silicon dioxide film and the like, and has opened a possibility of being able to be employed even for a currently prevailing silicon substrate material (for example, the following patent literature, PTL 5).
PTL 1: Japanese Patent Application Public Disclosure No. 2008-121099
PTL 2: Japanese Patent Application Public Disclosure No. 2008-136983
PTL 3: Japanese Patent Application Application Public Disclosure No. 2008-166709
PTL 4: Japanese Patent Application Application Public Disclosure No. 2009-117782
PTL 5: International Publication No. WO/2013/084934
However, this CARE method is required to satisfy a similar processing capability to the CMP (the chemical mechanical polishing), which has been a representative method for this process until now, to be permitted to be employed for the planarization of a semiconductor material on the silicon substrate. Especially, in terms of an etching rate and an etching amount, the CARE method is required to be able to maintain evenness on a wafer level and a chip level. Further, the same applies to the planarization capability, and these requirements are getting further stricter as the process generation advances. Further, the normally practiced process for planarizing the semiconductor material on the silicon substrate often involves simultaneous removal and planarization of a plurality of materials, and a substrate processing apparatus using the CARE method is required to support similar processing.
The present invention has been made to solve at least a part of the above-described problems, and can be embodied according to the following aspects.
A first aspect of the present invention provides a substrate processing apparatus for processing a processing target region (a semiconductor material) on a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. This substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst, and a driving unit configured to move the substrate holding unit and the catalyst holding unit relative to each other with the processing target region on the substrate and the catalyst kept in contact with each other. The catalyst holding unit includes an elastic member for holding the catalyst. According to this aspect, when the processing target region on the substrate and the catalyst are brought into contact with each other, the elastic member is deformed, which allows the catalyst to evenly contact the substrate in conformity with the shape of the substrate (warpage and the like of the substrate), thereby allowing a uniform etching rate within the contat area.
According to a second aspect of the present invention, in the first aspect, the elastic member includes a structure having a pressure chamber formed by an elastic film. A layer of the catalyst is formed on an outer surface of the elastic film. The pressure chamber is configured to control a contact pressure between the processing target region of the substrate and the catalyst by control of a pressure of fluid supplied into this pressure chamber. According to this aspect, the catalyst can evenly contact the substrate, thereby allowing uniform etching rate within the contact area.
According to a third aspect of the present invention, in the first aspect, the elastic member includes a spherical body held in such a manner that, when the substrate holding unit and the catalyst holding unit are moved relative to each other, the spherical body is rotatable according to this relative movement. A layer of the catalyst is formed on an outer surface of the spherical body. According to this aspect, when the processing target region on the substrate and the catalyst are brought into contact with each other, the elastic member is deformed, which allows the catalyst to evenly contact the substrate in conformity with the shape of the substrate (the warpage and the like of the substrate), thereby allowing uniform etching rate within the contact area.
According to a fourth aspect of the present invention, in the third aspect, the substrate processing apparatus further includes a pressure adjustment unit configured to adjust the contact pressure between the processing target region on the substrate and the catalyst by adjusting a force pressing the spherical body toward a substrate side where the substrate is located. According to this aspect, adjusting the pressure with which the processing target region on the substrate and the catalyst are in contact with each other allows the catalyst to evenly contact the substrate in conformity with the shape of the substrate (the warpage and the like of the substrate), thereby allowing uniform retching rate within the contact area.
According to a fifth aspect of the present invention, in the first aspect, the elastic member includes a sponge having a cavity. According to this aspect, the elastic member is deformed, which allows the catalyst to evenly contact the substrate in conformity with the shape of the substrate (the warpage and the like of the substrate), thereby allowing uniform etching rate within the contact area. Further, the sponge is flexible, which contributes to prevention or a reduction of damage that otherwise might be inflicted to the semiconductor material, which is the processing target surface, due to friction.
According to a sixth aspect of the present invention, in the fifth aspect, the substrate processing apparatus includes a processing liquid supply unit configured to supply the processing liquid into the sponge. A layer that is a layer of the catalyst and has a pore is formed on an outer surface of the sponge. According to this aspect, the processing liquid can be supplied from inside the sponge, where the processing liquid can easily flow, to the contact portion between the polishing target surface of the substrate and the catalyst. In other words, the processing liquid can be supplied directly to the contact portion only by a necessary amount, which can lead to a reduction in a use amount of the processing liquid.
According to a seventh aspect of the present invention, in any of the first to sixth aspects, a plurality of grooves is formed on the elastic member, and the catalyst is embedded in each of the plurality of grooves. According to this aspect, the catalysts can be arranged in a specific distribution on the contact surface between the elastic member and the processing target region on the substrate, which allows adjustment of etching amount at the portion in contact with the catalysts.
According to an eighth aspect of the present invention, in any of the first to seventh aspects, a plurality of grooves for transferring the processing liquid is formed on the elastic member. According to this aspect, these grooves facilitate introduction of the processing liquid onto the contact portion between the catalyst and the processing target region on the substrate, and substitution thereon, thereby allowing the substrate to be etched at a higher etching rate and with improved stability.
According to a ninth aspect of the present invention, in any of the first to eighth aspects, the elastic member includes a plurality of elastic members. Each of the plurality of elastic members individually holds the catalyst. According to this aspect, the catalyst can further easily follow the shape of the substrate. Further, when being combined with the second aspect, the ninth aspect allows an etching status to be controlled for each region, thereby allowing the contact portion to be etched with more uniform etching rate.
According to a tenth aspect of the present invention, in any of the first to ninth aspects, the catalyst includes two or more kinds of individual catalysts, or is a mixture or a compound containing two kinds of catalysts. According to this aspect, if the processing target surface is constituted by a plurality of materials, suitable catalysts for each materials are disposed in the form of the individual catalysts, the mixture, or the compound, which allows these materials to be etched at the same time with the aid of the individual catalysts.
According to an eleventh aspect of the present invention, in any of the first to tenth aspects, the catalyst holding unit includes a plurality of catalyst holding units, and the catalyst holding units individually holds the catalyst. According to this aspect, the plurality of catalyst holding units is used at the same time, which can improve a processing capability per unit time.
According to a twelfth aspect of the present invention, in the eleventh aspect, at least two of catalyst holding units, among the plurality of catalyst holding units, hold different kinds of catalysts from each other. According to this aspect, even if the processing target surface is constituted by the plurality of materials, the materials can be etched at the same time. And furthermore the simultaneous use of the plurality of catalyst holding units can improve the processing capability per unit time.
According to a thirteenth aspect of the present invention, in any of the first to twelfth aspects, the substrate processing apparatus includes a substrate temperature control unit configured to control a temperature of the substrate. According to this aspect, the etching rate can be changed by changing the temperature, and thus becomes adjustable.
According to a fourteenth aspect of the present invention, in any of the first to thirteenth aspects, the substrate holding unit includes a substrate position adjustment unit configured to rotate the substrate by an arbitrary predetermined angle so that a notch, an orientation flat, or a laser marker of the substrate is located at a predetermined position. According to this aspect, the catalyst can be brought into contact with a desired portion of the substrate.
According to a fifteenth aspect of the present invention, in any of the first to fourteenth aspects, the substrate processing apparatus further includes a processing liquid temperature adjustment unit configured to adjust a temperature of the processing liquid to a predetermined temperature within a range of 10 degrees to 60 degrees, inclusive. According to this aspect, the etching rate can be changed by changing the temperature, and thus becomes adjustable.
According to a sixteenth aspect of the present invention, in any of the first to fifteenth aspects, the substrate processing apparatus includes a processing liquid supply unit including a supply port for supplying the processing liquid onto the processing target region of the substrate. The processing liquid supply unit is configured in such a manner that the supply port is movable together with the catalyst holding unit. According to this aspect, fresh processing liquid can be always supplied to around the catalyst, resulting in a reduction in variation of the etching rate due to a change in concentration of the processing liquid. Further, the processing liquid can be efficiently supplied onto the processing target region on the substrate, resulting in a reduction in the use amount of the processing liquid.
According to a seventeenth aspect of the present invention, in any of the first to sixteenth aspects, the catalyst holding unit is disposed above the substrate holding unit. The substrate holding unit includes a wall extending vertically upwardly throughout an entire circumferential direction outside a region for holding the substrate. According to this aspect, the processing liquid can be held inside the wall portion, which can prevent or reduce an outward leak of the processing liquid. As a result, the use amount of the processing liquid can be reduced.
According to an eighteenth aspect of the present invention, in any of the first to seventeenth aspects, the substrate processing apparatus includes a processing liquid holding unit surrounding the catalyst holding unit and open on a substrate side that faces the substrate. The processing liquid holding unit is configured to hold the processing liquid in this processing liquid holding unit. The processing liquid is supplied into the processing liquid holding unit. According to this aspect, most of the supplied processing liquid is held inside the processing liquid holding unit, which contributes to the reduction in the use amount of the processing liquid.
According to a nineteenth aspect of the present invention, in any of the first to eighteenth aspects, the substrate processing apparatus includes a processing liquid suction unit in communication with the inside of the processing liquid holding unit. The processing liquid suction unit is configured to suck the processing liquid held in the processing liquid holding unit. According to this aspect, the processing liquid is circulated, so that fresh processing liquid can be always supplied to around the catalyst, resulting in a reduction in variation of the etching rate due to a change in concentration of the processing liquid.
According to a twentieth aspect of the present invention, in any of the first to nineteenth aspects, the substrate processing apparatus includes a conditioning unit configured to condition a surface of the catalyst. According to this aspect, an etching product adhered on the surface of the catalyst during the etching processing can be removed. As a result, the surface of the catalyst is recovered into an active status, which allows a plurality of substrates to be processed stably.
According to a twenty-first aspect of the present invention, in the twentieth aspect, the conditioning unit includes a scrub cleaning unit configured to scrub and clean the surface of the catalyst. According to this aspect, the etching product adhered on the surface of the catalyst during the etching processing can be removed. As a result, the surface of the catalyst is recovered into the active status, which allows a plurality of substrates to be processed stably.
According to a twenty-second aspect of the present invention, in the twentieth or twenty-first aspect, the conditioning unit includes a chemical supply unit configured to supply a chemical for removing the etching product adhered on the surface of the catalyst. According to this aspect, the etching product adhered on the surface of the catalyst during the etching processing can be removed. As a result, the surface of the catalyst is recovered into the active status, which allows a plurality of substrates to be processed stably.
According to a twenty-third aspect of the present invention, in any of the twentieth to twenty-second aspects, the conditioning unit includes an electrolytic regeneration unit configured to remove the etching product on the surface of the catalyst with use of an electrolytic action. The electrolytic regeneration unit includes an electrode configured to be electrically connectable to the catalyst, and is configured to remove the etching product adhered on the surface of the catalyst with use of the electrolytic action by applying a voltage to between the catalyst and the electrode. According to this aspect, the etching product adhered on the surface of the catalyst during the etching processing can be removed. As a result, the surface of the catalyst is recovered into the active status, which allows a plurality of substrates to be processed stably.
According to a twenty-fourth aspect of the present invention, in any of the twentieth to twenty-third aspects, the conditioning unit includes a plating regeneration unit configured to regenerate the catalyst by plating the catalyst with a regeneration catalyst prepared from the same kind of catalyst as the catalyst. The plating regeneration unit includes an electrode configured to be electrically connectable to the catalyst, and is configured to plate and regenerate the surface of the catalyst by applying a voltage to between the catalyst and the electrode with the catalyst immersed in liquid containing the regeneration catalyst. According to this aspect, a new catalyst layer can be formed on the catalyst. As a result, the surface of the catalyst is recovered into the active status, which allows a plurality of substrates to be processed stably.
According to a twenty-fifth aspect of the present invention, in any of the twentieth to twenty-fourth aspects, the substrate processing apparatus includes a monitoring unit configured to monitor a status of processing for etching the processing target region of the substrate. According to this aspect, the processing status of the processing target region on the substrate can be monitored in real time.
According to a twenty-sixth aspect of the present invention, in the twenty-fifth aspect, the substrate processing apparatus includes a control unit configured to control an operation of the substrate processing apparatus. The control unit is configured to control at least one parameter in a processing condition of the substrate in process based on the status of the processing for etching the substrate that is acquired by the monitoring unit. According to this aspect, the processing target region on the substrate can be processed so as to approach a predetermined target value.
According to a twenty-seventh aspect of the present invention, in the twenty-fifth aspect, the control unit is configured to determine an end point of the processing based on the status of the processing for etching the substrate that is acquired by the monitoring unit. According to this aspect, the processing target region on the substrate can be processed so as to approach a predetermined target value.
According to a twenty-eighth aspect of the present invention, in the twenty-fifth or twenty-seventh aspect, the monitoring unit includes a torque current monitoring unit configured to monitor the status of the processing for etching the substrate based on a torque current of the driving unit when the catalyst holding unit and the substrate holding unit are moved relative to each other. According to this aspect, a friction generated due to the contact between the processing target region of the substrate and the catalyst can be monitored via the torque current. For example, the status of the processing for etching the substrate can be fed back to a determination about the processing end point and a processing condition by monitoring a variation in the torque current due to, for example, a change in a roughness status of the processing target region or an exposure of another material on the processing target surface.
According to a twenty-ninth aspect of the present invention, in any of the twenty-fifth to twenty-seven aspects, the monitoring unit includes an optical monitoring unit configured to emit light toward the processing target region of the substrate to receive reflection light reflected on a surface of the processing target region of the substrate or reflected after being transmitted through the substrate, and monitor the status of the processing for etching the substrate based on the received light. According to this aspect, if the semiconductor material of the processing target region is a light transmissive material, the status of the processing for etching the substrate can be fed back to the determination about the processing end point and the processing condition by monitoring a variation in intensity of reflected light due to a change in a film thickness.
According to a thirtieth aspect of the present invention, in any of the twenty-fifth to twenty-seventh aspects, the monitoring unit includes an eddy current monitoring unit configured to apply a high-frequency current to a sensor coil disposed in proximity to the surface of the substrate to generate an eddy current on the substrate, and monitor the status of the processing for etching the substrate based on a change in the eddy current or a synthetic impedance according to a thickness of the processing target region of the substrate. According to this aspect, if the semiconductor material of the processing target region is a conductive material, the status of the processing for etching the substrate can be fed back to the determination about the processing end point and the processing condition by monitoring a variation in an eddy current value or synthetic impedance due to the change in the film thickness.
According to a thirty-first aspect of the present invention, in any of the first to thirtieth aspects, the substrate processing apparatus includes a potential adjustment unit including a reference electrode. The potential adjustment unit is configured to establish an electrochemical connection between the catalyst and the reference electrode to each other via the processing liquid to control a potential on the surface of the catalyst. According to this aspect, the substrate processing apparatus can prevent the surface of the catalyst during the etching processing from adhering of a material that would block an activity of catalyst. As a result, the surface of the catalyst can be kept in the active status.
According to a thirty-second aspect of the present invention, in any of the first to thirty-first aspects, the catalyst holding unit includes a spherical body or a cylindrical body with the layer of the catalyst formed on a spherical surface of the spherical body or a circumferential surface of the cylindrical body. The spherical body or the cylindrical body is configured in such a manner that, when the substrate holding unit and the catalyst holding unit are moved relative to each other, the spherical body or the cylindrical body is rotatable according to this relative movement. According to this aspect, the friction can be reduced between the surface of the processing target region on the substrate and the catalyst when the substrate holding unit and the catalyst holding unit are moved relative to each other, resulting in prevention or a reduction of the damage on the surface of the processing target region and wear of the catalyst due to the friction.
According to a thirty-third aspect of the present invention, in the thirty-second aspect, the spherical body or the cylindrical body includes an elastic member therein. According to this aspect, the elastic member is deformed, which allows the catalyst to evenly contact the substrate in conformity with the shape of the substrate (warpage and the like of the substrate), thereby allowing the contact portion to be etched with more uniform etching rate.
A thirty-fourth aspect of the present invention provides a substrate processing system. This substrate processing system includes the substrate processing apparatus according to any one of the first to thirty-third aspects, a substrate cleaning unit configured to clean the substrate, and a substrate transfer unit configured to transfer the substrate. According to this substrate processing system, the etching product can be removed from the surface of the substrate after the substrate is processed, as a result of which the surface of the substrate can be cleaned.
According to a thirty-fifth aspect of the present invention, in the thirty-fourth aspect according to the fourteenth aspect, the substrate processing system includes a detection unit configured to detect at least one of the notch, the orientation flat, and the laser marker of the substrate. According to this aspect, the effect of the fourteenth aspect can be preferably brought about.
According to a thirty-sixth aspect of the present invention, in the thirty-fourth or thirty-fifth aspect, the substrate processing system includes a thickness measurement unit configured to measure a thickness of the processing target region of the substrate after the substrate is processed by the substrate processing apparatus. According to this aspect, the substrate processing system can detect a thickness distribution of the processing target region of the substrate after the processing, and therefore can improve a quality of the processing performed on the substrate by changing a parameter in a processing condition based on a result of the measurement by the thickness measurement unit when processing a next substrate.
According to a thirty-seventh aspect of the present invention, in the thirty-sixth aspect, the substrate processing system includes a first parameter setting unit configured to set, based on the result of the measurement by the thickness measurement unit, a control parameter for use in substrate processing that will be performed by the substrate processing apparatus next time. According to this aspect, the substrate processing system can perform the processing after correcting an original processing condition based on the result of the measurement by the thickness measurement unit when processing a next substrate, and therefore can improve the quality of the processing performed on the substrate.
According to a thirty-eighth aspect of the present invention, in the thirty-seventh aspect, the first parameter setting unit corrects the control parameter based on a difference between a distribution of the thickness of the processing target region that is acquired based on the result of the measurement by the thickness measurement unit, and a predetermined target distribution of the thickness. According to this aspect, the substrate processing system can process the processing target region so as to achieve a thickness distribution closer to a target value when processing the next substrate, and therefore can improve the quality of the processing performed on the substrate.
According to a thirty-ninth aspect of the present invention, in any of the thirty-sixth to thirty-eighth aspects, the substrate processing system includes a reprocessing control unit configured to reprocess the substrate after the substrate is processed by the substrate processing apparatus if the result of the measurement by the thickness measurement unit does not satisfy a predetermined target value. According to this aspect, the substrate processing system can process the processing target region so as to achieve a thickness distribution closer to a target value when processing the next substrate, and therefore can improve the quality of the processing performed on the substrate.
According to a fortieth aspect of the present invention, in any of the twentieth to thirtieth aspects, the substrate processing system includes a second parameter change unit configured to change the control parameter to be used by the substrate processing apparatus in the next substrate processing based on the status of the processing for etching the substrate that is monitored by the monitoring unit. According to this aspect, a similar effect to the thirty-sixth aspect can be brought about.
According to a forty-first aspect of the present invention, in the fortieth aspect, the second parameter change unit changes the control parameter based on the result of the monitoring by the monitoring unit. According to this aspect, a similar effect to the thirty-eighth aspect can be brought about.
According to a forty-second aspect of the present invention, in any of the thirty-fourth to forty-first aspects, the substrate processing system includes a Chemical Mechanical Polishing apparatus configured to polish the substrate before or after the substrate is processed by the substrate processing apparatus. According to this aspect, more flexibly polishing processing can be performed by using the substrate processing system as prior processing or subsequent processing to the polishing by the Chemical Mechanical Polishing apparatus.
A forty-third aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst, and a conditioning unit configured to condition a surface of the catalyst. The substrate processing apparatus according to this aspect can condition the surface of the catalyst, for example, during exchanging the catalyst or replacing the substrate to be processed.
According to a forty-fourth aspect of the present invention, in the forty-third aspect, the conditioning unit includes a scrub cleaning unit configured to scrub and clean the surface of the catalyst. According to this aspect, the substrate processing apparatus can clean and condition the surface of the catalyst by applying a physical force to the surface of the catalyst, and can effectively remove a residue and the like adhered on the surface of the catalyst during deposition of the catalyst and the processing of the substrate.
According to a forty-fifth aspect of the present invention, in the forty-third or forty-fourth aspect, the conditioning unit includes a chemical supply unit configured to supply a chemical for removing an etching product adhered on the surface of the catalyst. According to this aspect, the etching product adhered on the surface of the catalyst and an altered layer on the surface of the catalyst can be removed with use of a chemical action.
According to a forty-sixth aspect of the present invention, in any one of the forty-third to forty-fifth aspects, the conditioning unit includes an electrolytic regeneration unit configured to remove the etching product on the surface of the catalyst with use of an electrolytic action. The electrolytic regeneration unit includes a regeneration electrode configured to be electrically connectable to the catalyst, and is configured to remove the etching product adhered on the surface of the catalyst with use of the electrolytic action by applying a voltage to between the catalyst and the regeneration electrode. According to this aspect, the etching product adhered on the surface of the catalyst and the altered layer on the surface of the catalyst can be removed with use of an electrolytic action.
According to a forty-seventh aspect of the present invention, in any of the forty-third to forty-sixth aspects, the conditioning unit includes a plating regeneration unit configured to regenerate the catalyst by plating the catalyst with a regeneration catalyst prepared from the same kind of catalyst as the catalyst. The plating regeneration unit includes a regeneration electrode configured to be electrically connectable to the catalyst, and is configured to regenerate the catalyst by plating the catalyst with the regeneration catalyst by applying a voltage to between the catalyst and the regeneration electrode with the catalyst immersed in liquid containing the regeneration catalyst. According to this aspect, a new surface of the catalyst can be created.
According to a forty-eighth aspect of the present invention, in the forty-third aspect, the conditioning unit includes a conditioning stage disposed so as to face the surface of the catalyst.
According to a forty-ninth aspect of the present invention, in the forty-eighth aspect, the substrate processing apparatus includes a catalyst cleaning nozzle configured to supply water and/or a chemical for cleaning the surface of the catalyst to the surface of the catalyst. According to this aspect, the etching product and the like adhered on the surface of the catalyst can be easily removed.
According to a fiftieth aspect of the present invention, in the forty-ninth aspect, the catalyst cleaning nozzle is disposed outside the conditioning stage. According to this aspect, the catalyst cleaning nozzle can be prepared as a different member from the other structure, which improves maintainability.
According to a fifty-first aspect of the present invention, in the forty-eighth aspect, the catalyst cleaning nozzle is disposed inside the conditioning stage. The conditioning stage includes a passage for passing the water and/or the chemical into the conditioning stage. The passage is in fluid communication with the catalyst cleaning nozzle. According to this aspect, the water and/or chemical can be evenly sprayed from below the catalyst. Further, a space where an external nozzle is disposed can be reduced.
According to a fifty-second aspect of the present invention, in any of the forty-eighth to fifty-first aspects, the conditioning unit includes a scrub member disposed on the conditioning stage for cleaning the surface of the catalyst.
According to a fifty-third aspect of the present invention, in any of the forty-eighth to fifty-second aspects, the substrate processing apparatus includes an electrode configured to be electrically connectable to the catalyst, a regeneration electrode disposed on the conditioning stage, and a power source configured to apply a voltage to between the electrode and the regeneration electrode. According to this aspect, the catalyst can be conditioned with use of the electrolytic action.
According to a fifty-fourth aspect of the present invention, in the fifty-third aspect, the substrate processing apparatus is configured to electrolytically etch the surface of the catalyst by applying the voltage in such a manner that the electrode on the catalyst side becomes a positive side and the regeneration electrode becomes a negative side in conditioning. According to this aspect, the surface of the catalyst can be conditioned by electrolytic etching. As a result, a foreign object and the like which cannot be removed by other action can be removed.
According to a fifty-fifth aspect of the present invention, in the fifty-fourth aspect, the substrate processing apparatus is configured to reduce an oxide on the surface of the catalyst by applying the voltage in such a manner that the electrode on the catalyst side becomes the negative side and the regeneration electrode becomes the positive side in conditioning. According to this aspect, the surface of the oxidized catalyst can be recovered into the active status by a reduction action.
According to a fifty-sixth aspect of the present invention, in the fifty-third aspect, the substrate processing apparatus includes an ion exchanger provided on the regeneration electrode. The substrate processing apparatus is configured to apply the voltage with the catalyst and the ion exchanger located in proximity to or in contact with each other. The ion exchanger has a catalytic function for enhancing ionization of the water under an electric field, and H+ ions and OH− ions generated therefrom act on the surface of the catalyst, by which a similar effect to the fifty-fourth or fifty-fifth aspect can be brought about. Further, liquid used in this case may be water or a dilute chemical, which can reduce a use amount of the chemical in conditioning.
According to a fifty-seventh aspect of the present invention, in any of the forty-eighth to fifty-sixth aspects, the conditioning stage includes a liquid reservoir portion configured to be able to keep liquid on the conditioning stage. According to this aspect, the surface of the catalyst can keep the liquid during the conditioning, so that the surface of the catalyst can be effectively conditioned. Further, the use amount of the liquid can be reduced.
According to a fifty-eighth aspect of the present invention, in the fifty-seventh aspect, the substrate processing apparatus includes an ultrasonic wave generator configured to emit an ultrasonic wave to the liquid kept in the liquid reservoir portion. According to this aspect, the use of the ultrasonic wave can effectively remove a foreign object and the like adhered on the catalyst.
According to a fifty-ninth aspect of the present invention, in any of the forty-eighth to fifty-eighth aspects, the conditioning stage is rotatably configured.
According to a sixtieth aspect of the present invention, in any of the forty-eighth to fifty-ninth aspects, the substrate processing apparatus includes a catalyst measurement sensor for measuring a status of the surface of the catalyst. The conditioning status is monitored by the catalyst sensor, which can prevent or reduce an excess or insufficient conditioning of the catalyst.
According to a sixty-first aspect of the present invention, in the sixtieth aspect, the catalyst measurement sensor includes at least one of (i) a resistance sensor configured to measure electric resistance of the catalyst, (ii) a thickness sensor configured to measure the thickness of the catalyst, and (iii) an optical sensor.
According to a sixty-second aspect of the present invention, in any of the forty-third to sixty-first aspects, the catalyst includes metal, and the substrate processing apparatus includes an electrode electrically connectable to the metal of the catalyst. The electrode includes metal having larger ionization tendency than the metal of the catalyst. According to this aspect, the reduction action can be caused on the surface of the catalyst with use of a cell reaction. As a result, the surface of the catalyst can be prevented from being oxidized and hydroxylated or kept less oxidized and hydroxylated, and therefore can be kept in the active status.
According to a sixty-third aspect of the present invention, in any of the forty-third to sixty-first aspects, the substrate processing apparatus includes a gas supply nozzle for supplying gas to the surface of the catalyst. According to this aspect, the surface of the catalyst can be prevented from being oxidized and hydroxylated or kept less oxidized and hydroxylated, which otherwise would be caused due to a reaction between the catalyst and the water, by being dried, and therefore can be kept in the active status when the etching processing of the substrate is not performed for a long time, for example, during an interval period in lot processing of the wafer W.
A sixty-fourth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst, and a control unit configured to control an operation of the substrate processing apparatus. The control unit performs control so as to move the catalyst holding unit in an in-plane direction of the processing target region of the substrate with the processing target region of the substrate and the catalyst kept in contact with each other, and performs control so as to change a speed at which the catalyst holding unit is moved according to a position of the catalyst holding unit on the processing target region of the substrate. According to this aspect, the substrate processing apparatus can move the catalyst holding unit with a variable speed according to a position of the substrate and can control a time for which the catalyst and the substrate are in contact with each other, i.e., an etching time within the substrate, and thus can control the uniformity of etching rate within the substrate.
A sixty-fifth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding stage including a substrate holding surface for holding the substrate, and a catalyst holding unit configured to hold the catalyst. The substrate holding surface of the substrate holding stage is larger in area than a surface of the catalyst on the catalyst holding unit. The substrate holding stage includes an extension portion located externally with respect to an outer periphery of the substrate when the substrate to be processed is set on the substrate holding stage. According to this aspect, the substrate processing apparatus can prevent the catalyst holding unit from tilting even when the catalyst holding unit overhangs beyond the substrate, and therefore can keep the catalyst and the substrate in a constant contact status (for example, a distribution of a contact pressure). Therefore, the substrate processing apparatus can improve the uniformity of etching rate within the substrate.
According to a sixty-sixth aspect of the present invention, in the sixty-fifth aspect, the substrate processing apparatus includes a conditioning unit at the extension portion of the substrate holding stage. The conditioning unit is configured to condition the surface of the catalyst. This configuration allows the catalyst to be conditioned during not only the interval period of the substrate processing but also the period of the substrate processing, thereby allowing the surface of the catalyst to be kept in the active status during the processing.
A sixty-seventh aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding stage including a substrate holding surface for holding the substrate, and a catalyst holding unit configured to hold the catalyst. The substrate holding surface of the substrate holding stage is larger in area than a surface of the catalyst on the catalyst holding unit. The catalyst holding unit further includes a tilt sensor for detecting a tilt of the surface of the catalyst with respect to the substrate holding surface of the substrate holding stage, and a tilt correction mechanism for correcting the tilt of the surface of the catalyst with respect to the substrate holding surface of the substrate holding stage. According to this aspect, the substrate processing apparatus can detect the tilt of the catalyst holding surface, and prevent or reduce concentration of a load due to the tilt of the catalyst holding surface by correcting the tilt according to a result of the detection, and thus can keep the catalyst and the substrate in the constant contact status (for example, the distribution of the contact pressure). Therefore, the substrate processing apparatus can improve the uniformity of etching rate within the substrate.
A sixty-eighth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst, and a processing liquid supply unit including a supply port for supplying the processing liquid passed through an inside of the catalyst holding unit onto the processing target region of the substrate. According to this aspect, the processing liquid can be supplied to the surface where the catalyst and the substrate are in contact with each other, which allows the processing liquid to be effectively supplied to the surface where the catalyst and the substrate are in contact with each other, improving the uniformity of etching rate within the substrate.
According to a sixty-ninth aspect of the present invention, in the sixty-eighth aspect, the catalyst holding unit includes a buffer portion configured to temporarily hold the processing liquid in the catalyst holding unit, and a processing liquid supply portion including a plurality of supply ports for supplying the processing liquid passed through the inside the catalyst holding portion onto the processing target region of the substrate. The plurality of supply ports is in fluid communication with the buffer portion. According to this aspect, the processing liquid can be evenly supplied to the surface where the catalyst and the substrate are in contact with each other, which can improve the uniformity of etching rate within the substrate.
A seventieth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, and a catalyst holding unit configured to hold the catalyst. The catalyst holding unit includes a plurality of grooves configured to allow the processing liquid to flow between the catalyst holding unit and the substrate with the catalyst holding unit and the substrate kept in contact with each other. According to this aspect, the processing liquid can be effectively supplied to the surface where the catalyst and the substrate are in contact with each other, which can improve the uniformity of etching rate within the substrate.
According to a seventy-first aspect of the present invention, in the seventieth aspect, the plurality of grooves each has such a trapezoidal shape in cross-section that a width of the groove is wider at an opening of the groove than a bottom of the groove. According to this aspect, the grooves can be maintained without being closed when the catalyst and the substrate are in contact with each other, thereby keeping the supply of the processing liquid to between the catalyst and the substrate, which can improve the uniformity of etching rate within the substrate.
According to a seventy-second aspect of the present invention, in the seventieth or the seventy-first aspect, the plurality of grooves includes at least one of (i) a pattern including a plurality of concentric circles, (ii) a pattern including a plurality of radial lines, (iii) a pattern including pluralities of parallel lines extending in intersecting different directions, and (iv) a spiral pattern.
A seventy-third aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, and a catalyst holding unit configured to hold the catalyst. The catalyst holding unit includes a counter electrode configured to be electrically connectable to the catalyst via the processing liquid. According to this aspect, the active status of the surface of the catalyst can be changed by application of a voltage optimum for the substrate processing to the catalyst, which can improve the etching rate within the substrate.
According to a seventy-fourth aspect of the present invention, in the seventy-third aspect, the catalyst holding unit includes a catalyst holding member for holding the catalyst. The counter electrode is disposed outside the catalyst holding member.
According to a seventy-fifth aspect of the present invention, in the seventy-third aspect, the counter electrode is disposed in such a manner that a plurality of counter electrodes is exposed to an inside of the catalyst holding member. According to this aspect, an uniform potential can be applied in the plane of the catalyst, resulting in achievement of evenness of the distribution of the active status of the surface of the catalyst, thereby improving the uniformity of etching rate on the surface where the catalyst and the substrate are in contact with each other.
According to a seventy-sixth aspect of the present invention, in any of the seventy-third to seventy-fifth aspects, the catalyst holding unit includes a processing liquid holding portion surrounding the catalyst and open on a surface thereof facing the substrate holding portion, and is configured in such a manner that the processing liquid is kept in the processing liquid holding portion with the catalyst brought into contact with the substrate.
According to a seventy-seventh aspect of the present invention, in the seventy-sixth aspect, the substrate processing apparatus includes a processing liquid supply unit including a supply port for supplying the processing liquid passed through the catalyst holding portion onto the processing target region of the substrate.
According to a seventy-eighth aspect of the present invention, in any of the seventy-third to seventy-seventh aspects, the substrate processing apparatus includes a voltage control device configured to apply a voltage to between the catalyst and the counter electrode. The voltage control device is configured to control the voltage in such a manner that a potential on the catalyst side decreases below a potential of the counter electrode so as to intermittently become a reduction side while the substrate is processed. According to this aspect, the reduction action can be caused on the catalyst while the substrate is processed, by which the catalyst can be prevented from being oxidized and hydroxylated or kept less oxidized and hydroxylated, and the surface of the catalyst can be kept in the active status.
According to a seventy-ninth aspect of the present invention, in any one of the seventy-third to seventy-eighth aspects, the catalyst is electrically divided into a plurality of regions, and is configured to allow a different voltage to be applied for each of the plurality of regions. According to this aspect, the active status of the surface of the catalyst can be changed by the application of the voltage varying for each region of the catalyst, which leads to an ability to change the etching rate of substrate for each region, thereby improving controllability of the etching of the substrate.
According to an eightieth aspect of the present invention, in the seventy-ninth aspect, the catalyst holding unit is rotatably configured. The substrate processing apparatus includes a rotational position sensor configured to detect a rotational position of the catalyst holding unit, and a position sensor configured to detect a position of the catalyst holding unit relative to the substrate holding unit.
According to an eighty-first aspect of the present invention, in the eightieth aspect, the substrate processing apparatus includes a voltage control device configured to apply a voltage to between each of the regions of the catalyst and the counter electrode. The voltage control device receives the rotational position of the catalyst holding unit that is detected by the rotational position sensor and the position of the catalyst holding unit relative to the substrate holding unit that is detected by the position sensor, and control the voltage to each of the regions of the catalyst according to the rotational position of the catalyst holding unit and the position of the catalyst holing unit relative to the substrate holding unit.
An eighty-second aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst and including a plurality of catalyst holding members for holding the catalyst, and a pressure control mechanism configured to control the each of catalyst holding members independently and control a contact pressure between the substrate and the catalyst when the substrate and the catalyst are in contact with each other.
According to an eighty-third aspect of the present invention, in the eighty-second aspect, the pressure control mechanism controls the contact pressure between the substrate and the catalyst by controlling a pressure or a flow amount of fluid supplied into the plurality of catalyst holding members.
According to an eighty-fourth aspect of the present invention, in the eighty-second aspect, the pressure control mechanism includes piezoelectric elements attached to the plurality of catalyst holding members, and controls the contact pressure between the catalyst and the substrate by controlling each of the piezoelectric elements independently.
According to an eighty-fifth aspect of the present invention, in any one of the eighty-second to eighty-fourth aspects, the catalyst holding unit is rotatably configured. The substrate processing apparatus includes a rotational position sensor configured to detect a rotational position of the catalyst holding unit, and a position sensor configured to detect a position of the catalyst holding unit relative to the substrate holding unit.
According to an eighty-sixth aspect of the present invention, in the eighty-fifth aspect, the pressure control mechanism receives a signal indicating the rotational position of the catalyst holding unit that is detected by the rotational position sensor and a signal indicating the position of the catalyst holding unit relative to the substrate holding unit that is detected by the position sensor, and controls contact pressures between the substrate and the catalyst at the plurality of catalyst holding members independently according to the rotational position of the catalyst holding unit and the position of the catalyst holing unit relative to the substrate holding unit.
According to an eighty-seventh aspect of the present invention, in any one of the eighty-second to eighty-sixth aspects, each of the plurality of catalyst holding members includes a pressure sensor configured to detect the contact pressure between the substrate and the catalyst.
According to an eighty-eighth aspect of the present invention, in the eighty-seventh aspect, the pressure control mechanism receives a signal indicating the pressure detected by each of the pressure sensors, and controls the contact pressures between the substrate and the catalyst at the plurality of catalyst holding members independently so that the substrate and the catalyst are in contact with each other with a pressure that achieves a predetermined contact pressure distribution.
An eighty-ninth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst and including a plurality of catalyst holding members for holding the catalyst, and a processing liquid supply unit including a plurality of processing liquid supply passages and a plurality of processing liquid supply ports for supplying the processing liquid passed through an inside of the catalyst holding unit onto the processing target region of the substrate. Each of the plurality of processing liquid supply passages is configured to allow a flow amount of the processing liquid to be adjusted independently.
According to a ninetieth aspect of the present invention, in the eighty-ninth aspect, each of the plurality of processing liquid supply passages is provided with a flowmeter for measuring the flow amount of the processing liquid and a valve for adjusting the flow amount of the processing liquid.
According to a ninety-first aspect of the present invention, in the eighty-ninth or ninetieth aspect, the substrate processing apparatus includes a pressure control mechanism configured to control the plurality of catalyst holding members independently to control a contact pressure between the substrate and the catalyst independently for each of the plurality of catalyst holding members when the substrate and the catalyst are in contact with each other.
According to a ninety-second aspect of the present invention, in the ninety-first aspect, the pressure control mechanism controls the contact pressure between the substrate and the catalyst by supplying fluid into each of the plurality of catalyst holding members.
According to a ninety-third aspect of the present invention, in the ninety-first aspect, the pressure control mechanism includes piezoelectric elements attached to the plurality of catalyst holding members, and controls a distribution of the contact pressure between the catalyst and the substrate by controlling each of the piezoelectric elements independently.
A ninety-fourth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the disk-shaped substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst, and a driving unit configured to move the substrate holding unit and the catalyst holding unit relative to each other with the processing target region of the substrate and the catalyst kept in contact with each other. The substrate holding unit has a circular region for holding the substrate. The catalyst holding unit includes a catalyst holding member for holding the catalyst. The catalyst holding member has a substantially fan-like shape or triangular shape overlapping the substrate from a central portion of the substrate to a part of an outer edge of the substrate with the disk-shaped substrate and the catalyst kept in contact with each other.
According to a ninety-fifth aspect of the present invention, in the ninety-fourth aspect, the driving unit is configured to be able to move the catalyst holding unit in a radial direction of the circler region for holding the substrate.
According to a ninety-sixth aspect of the present invention, in the ninety-fourth or ninety-fifth aspect, the catalyst holding member includes a groove configured to allow the processing liquid to pass through between the catalyst holding member and the substrate with the catalyst holding member and the substrate kept in contact with each other.
A ninety-seventh aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst, and a driving unit configured to move the substrate holding unit and the catalyst holding unit relative to each other with the processing target region of the substrate and the catalyst kept in contact with each other. The catalyst holding unit includes a catalyst holding member for holding the catalyst. The catalyst holding member includes a plurality of spherical bodies or a plurality of cylindrical bodies with a layer of the catalyst formed on special surfaces of the spherical bodies or circumferential surfaces of the cylindrical bodies. The plurality of spherical bodies or the plurality of cylindrical bodies is configured to be held in such a manner that, when the substrate holding unit and the catalyst holding unit are moved relative to each other, the plurality of spherical bodies or the plurality of cylindrical bodies is rotatable according to this relative movement.
A ninety-eighth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, and a catalyst holding unit configured to hold the catalyst. The catalyst holding unit is configured to be able to vibrate in a direction perpendicular to a surface of the substrate.
According to a ninety-ninth aspect of the present invention, in the ninety-eighth aspect, the catalyst holding unit includes a piezoelectric element. The substrate processing apparatus includes a power source configured to apply an alternating-current to the piezoelectric element.
A hundredth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate and including a plurality of substrate holding stages each configured to hold a single substrate, and a plurality of catalyst holding units each associated with corresponding one of the plurality of substrate holding stages and configured to hold the catalyst.
According to a hundred and first aspect of the present invention, in the hundredth aspect, at least some of the plurality of catalyst holding units hold different kinds of catalysts.
A hundred and second aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, and a plurality of catalyst holding units configured to hold the catalyst.
According to a hundred and third aspect of the present invention, in the hundred and second aspect, the substrate processing includes a conditioning unit configured to condition a surface of the catalyst.
According to a hundred and fourth aspect of the present invention, in the hundred and second or hundred and third aspect, at least some of the plurality of catalyst holding units are operable under different processing conditions.
According to a hundred and fifth aspect of the present invention, in any one of the hundred and second to hundred and fourth aspects, at least some of the plurality of catalyst holding units have regions for holding the catalyst that are different from each other or one another in area.
According to a hundred and sixth aspect of the present invention, in any one of the hundred and second to hundred and fifth aspects, at least some of the plurality of catalyst holding units hold different kinds of catalysts.
A hundred and seventh aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst for processing the substrate held on the substrate holding unit, and a substrate cleaning unit configured to clean the substrate held on the substrate holding unit.
A hundred and eighth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate, a catalyst holding unit configured to hold the catalyst, and a processing liquid supply unit including a supply port for supplying the processing liquid onto the processing target region of the substrate. A region of the substrate holding unit for holding the substrate tilts by a predetermined angle with respect to a horizontal plane. The supply port of the processing liquid supply unit is disposed on an upper side with respect to the catalyst holding unit in terms of the gravity with the substrate and the catalyst kept in contact with each other.
According to a hundred and ninth aspect of the present invention, in the hundred and eighth aspect, the processing liquid supply unit is configured in such a manner that the supply port is movable together with the supply port.
A hundred and tenth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst. The catalyst holding unit includes a catalyst temperature control mechanism for controlling a temperature of the catalyst.
According to a hundred and eleventh aspect of the present invention, in the hundred and tenth fourth aspect, the catalyst temperature control mechanism includes a Peltier element.
A hundred and twelfth aspect of the present invention provides a substrate processing system. The substrate processing system includes the substrate processing apparatus according to any one of the first to thirty-second aspects and the forty-third to the hundred and eleventh aspects, a substrate cleaning unit configured to clean the substrate, a substrate drying unit for drying the cleaned substrate, and a substrate transfer unit configured to transfer the substrate.
According to a hundred and thirteenth aspect of the present invention, in the hundred and twelfth aspect, the substrate transfer unit is configured to be able to transfer the substrate in a wet status and the substrate in a dry status separately.
A hundred and fourteenth aspect of the present invention provides a substrate processing system. The substrate processing system includes the substrate processing apparatus according to any one of the first to thirty-second aspects and the forty-third to the hundred and eleventh aspects, and a deposition apparatus configured to perform deposition processing on the substrate.
According to a hundred and fifteenth aspect of the present invention, in the hundred and fourteenth aspect, the deposition apparatus includes at least one of a chemical vapor deposition (CVD) apparatus, a sputtering apparatus, a plating apparatus, and a coater apparatus.
A hundred and sixteenth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst. The catalyst holding unit includes an elastic member, and a film attached to the elastic member to hold the catalyst.
According to a hundred and seventeenth aspect of the present invention, in the hundred and sixteenth aspect, the film is made from resin.
According to a hundred and eighteenth aspect of the present invention, in the hundred and sixteenth or hundred and seventeenth aspect, the film includes a groove configured in such a manner that the processing liquid can flow in a plane of the substrate between the catalyst and the substrate with the catalyst and the substrate kept in contact with each other.
According to a hundred and nineteenth aspect of the present invention, in the hundred and eighteenth aspect, a cross-sectional shape of the groove is such a trapezoidal shape that a width of the groove is wider at an opening of the groove than at a bottom of the groove.
According to a hundred and twentieth aspect of the present invention, in any one of the hundred and sixteenth to hundred nineteenth aspects, the catalyst holding unit includes a processing liquid supply unit provided with a plurality of processing liquid supply passages and a plurality of processing liquid supply ports for transmitting the processing liquid in the catalyst holding unit to supply the processing liquid to the processing target region of the substrate.
A hundred and twenty-first aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst. The catalyst holding unit includes an elastic member and a layer of a harder material than the elastic member that is disposed between the elastic member and the catalyst.
A hundred and twenty-second aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst. The catalyst holding unit includes an inlet passage for supplying the processing liquid to a surface of the catalyst, and an outlet passage for collecting the processing liquid from the surface of the catalyst.
A hundred and twenty-third aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a monitoring unit configured to monitor a status of processing for etching the processing target region of the substrate.
According to a hundred and twenty-fourth aspect of the present invention, in the hundred and twenty-third aspect, the substrate processing apparatus includes a control unit configured to control an operation of the substrate processing apparatus. The control unit is configured to control at least one parameter in a condition of the processing performed on the substrate in process based on the status of the processing for etching the substrate that is acquired by the monitoring unit.
According to a hundred and twenty-fifth aspect of the present invention, in the hundred and twenty-third aspect, the control unit is configured to determine an end point of the processing based on the status of the processing for etching the substrate that is acquired by the monitoring unit.
According to a hundred and twenty-sixth aspect of the present invention, in the hundred and twenty-third or hundred and twenty-fifth aspect, the substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst. The monitoring unit includes a torque current monitoring unit configured to monitor the status of the processing for etching the substrate based on a torque current of the driving unit when the catalyst holding unit and a substrate holding unit are moved relative to each other.
According to a hundred and twenty-seventh aspect of the present invention, in the hundred and twenty-third aspect, the substrate processing apparatus includes a substrate holding unit configured to hold the substrate, and a catalyst holding unit configured to hold the catalyst. The monitoring unit includes a torque current monitoring unit configured to monitor the status of the processing for etching the substrate based on at least one of a torque current when the catalyst holding unit is rotationally driven and a torque current when the substrate holding unit is rotationally driven.
According to a hundred and twenty-eighth aspect of the present invention, in the hundred and twenty-third aspect, the substrate processing apparatus includes a substrate holding unit configured to hold the substrate, and a catalyst holding unit configured to hold the catalyst. The monitoring unit includes a vibration sensor provided to the catalyst holding unit. The vibration sensor is configured to detect a vibration when the substrate holding unit and the catalyst holding unit are moved relative to each other. The monitoring unit is configured to monitor the status of the processing for etching the substrate by detecting a change in the vibration detected by the vibration sensor.
A hundred and twenty-ninth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configure to hold the catalyst. The catalyst holding unit includes a disk holder portion, and a catalyzer disk portion coupled detachably from the disk holder portion. The catalyzer disk portion includes a catalyst holding unit having a surface where the catalyst is held, a catalyst electrode electrically connected to the catalyst, and a counter electrode. The disk holder portion includes a catalyst electrode wiring electrically connected to the catalyst electrode, a counter electrode wiring electrically connected to the counter electrode, and a contact probe for electrically connecting the catalyst electrode to the catalyst electrode wiring and a contact probe for electrically connecting the counter electrode to the couther electrode wiring when the disk holder portion and the catalyzer disk portion are coupled with each other. The substrate processing apparatus includes power source for applying a voltage to between the catalyst electrode and the counter electrode.
A hundred and thirtieth aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a catalyst holding unit configured to hold the catalyst, and a swing arm configured to be able to move the catalyst holding unit in a direction perpendicular to a surface of the substrate. The swing arm is attached to the catalyst holding unit. The swing arm includes a load cell configured to measure a contact pressure when the catalyst of the catalyst holding unit is in contact with the substrate.
According to a hundred and thirty-first aspect of the present invention, in the hundred and thirtieth aspect, the substrate processing apparatus includes a PID controller configured to control a pressure with which the catalyst and the substrate are in contact with each other based on the contact pressure measured by the load cell.
According to a hundred and thirty-second aspect of the present invention, in the hundred and thirtieth aspect, the swing arm includes a cover surrounding the entire swing arm, and is configured to be able to supply air and/or nitrogen into the cover.
A hundred and thirty-third aspect of the present invention provides a substrate processing apparatus for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The substrate processing apparatus includes a substrate holding unit configured to hold the substrate. The substrate holding unit includes a substrate holding stage and a vacuum suction plate for holding the substrate onto the substrate holding stage with use of vacuum suction. The vacuum suction plate includes a suction bore. The substrate holding unit includes a vacuum line in fluid communication with the suction bore of the vacuum suction plate. The vacuum line is configured to be able to carry out vacuum suction of the substrate onto the vacuum suction plate by vacuuming, and release the vacuum suction by supplying water and/or air or nitrogen to the vacuum line.
A hundred and thirty-fourth aspect of the present invention provides a method for processing a processing target region of a substrate by bringing the substrate and a catalyst into contact with each other in the presence of processing liquid. The method includes supplying the processing liquid to the processing target region of the substrate, bringing the catalyst into contact with the processing target region of the substrate, moving the substrate and the catalyst relative to each other with the substrate and the catalyst kept in contact with each other, cleaning the substrate with a chemical, cleaning the substrate with water, and conditioning a surface of the catalyst while cleaning the substrate with the chemical or the water.
The present invention can also be realized by freely combining or omitting at least a part of the components of any of the above-described aspects or components of embodiments that will be described below, besides the above-described aspects. Several specific examples thereof will be described now. For example, an aspect of the present invention may be an arbitrary substrate processing apparatus including at least one of a substrate holding unit configured to hold a substrate, a catalyst holding unit configured to hold a catalyst, and a driving unit configured to move the substrate holding unit and the catalyst holding unit relative to each other with a processing target region of the substrate and the catalyst kept in contact with each other, and having a part of the features described in the present disclosure. Alternatively, an aspect of the present invention may be an arbitrary substrate processing apparatus including at least one of a substrate holding unit configured to hold a substrate, a catalyst holding unit configured to hold a catalyst, and a driving unit configured to move the substrate holding unit and the catalyst holding unit relative to each other with a processing target region of the substrate and the catalyst kept in contact with each other, in which the catalyst includes two or more kinds of individual catalysts, or is a mixture or a compound containing two kinds of catalysts. Alternatively, an aspect of the present invention may be an arbitrary substrate processing apparatus including at least one of a substrate holding unit configured to hold a substrate, a catalyst holding unit configured to hold a catalyst, and a driving unit configured to move the substrate holding unit and the catalyst holding unit relative to each other with a processing target region of the substrate and the catalyst kept in contact with each other, in which the catalyst holding unit includes a spherical body or a cylindrical body with a layer of the catalyst formed on a spherical surface of the spherical body or a circumferential surface of the cylindrical body, and the spherical body or the cylindrical body is configured in such a manner that, when the substrate holding unit and the catalyst holding unit are moved relative to each other, the spherical body or the cylindrical body is rotatable according to this relative movement. It should be noted that, in these aspects, the catalyst does not necessarily have to be smaller than the substrate, which is one of characteristic features of the first aspect.
Further, the specific features of the components in the above-described aspects or the components in the embodiments that will be described below can be treated separately from one another, and can be omitted as needed. For example, the processing liquid temperature adjustment unit in the fifteenth aspect can be modified into a component configured to adjust the temperature of the processing liquid to a predetermined temperature without the range from ten degrees to sixth degrees, inclusive. Having described several modifications other than the first to forty-second aspects, but they are merely one example. The present invention can also be realized by arbitrarily combining or omitting at least a part of the components describe in the present disclosure and the respective specific features of these components, as long as at least a part of the above-described problems can be solved or at least a part of the above-described effects can be brought about.
In the following description, embodiments of a substrate processing apparatus and a substrate processing system including the substrate processing apparatus according to the present invention will be described with reference to the drawings. The drawings and the following description cover only characteristic features of the embodiments as will be described below, and refrain from elaborating other components herein. The present invention can be embodied with use of features of other embodiments and known techniques in terms of the components undiscussed herein.
The substrate processing apparatus 10 includes a substrate holding unit 20, a catalyst holding unit 30, a processing liquid supply unit 40, a swing arm 50, a conditioning unit 60, and a control unit 90. The substrate holding unit 20 is configured to hold a wafer W, which is one kind of substrate. In the present embodiment, the substrate holding unit 20 holds the wafer W in such a manner that the wafer W is placed with a polishing target surface face up. Further, in the present embodiment, the substrate holding unit 20 includes a vacuum suction mechanism equipped with a vacuum suction plate that sucks a back surface of the wafer W (an opposite surface from the polishing target surface) with vacuum as a mechanism for holding the wafer W. The vacuum suction may be carried out by any method of a point suction method using a suction plate including a plurality of suction holes connected to a suction line on a suction surface thereof, and a surface suction method using a suction surface including grooves (for example, concentrically formed grooves) to suck the wafer via connection holes formed in the grooves that lead to a vacuum line. Further, a packing member may be attached on the surface of the suction plate and the wafer W may be sucked via this packing member so that the suction status can be stabilized. However, the mechanism for holding the wafer W can be any known mechanism, and for example, may be a clamp mechanism that clamps the front surface and the back surface of the wafer W on at least one portion along a circumferential edge of the wafer W or a roller chuck mechanism that holds a side surface of the wafer W on at least one portion along the circumferential edge of the wafer W. This substrate holding unit 20 is configured rotatably around an axis AL1 by a driving unit motor and an actuator (not illustrated). Further, in
The catalyst holding unit 30 according to the embodiment illustrated in
In the present embodiment, the pressure chamber 33 has a substantially cuboid shape or cylindrical shape as illustrated in
Exemplary candidates of the materials of the elastic members 32 and 32a illustrated in
In the embodiments illustrated in
As one embodiment, the groove formed on the surface of the catalyst 31 or the elastic member 32 is formed so as to extend in a direction in the plane of the catalyst 31, and is formed so as to allow the processing liquid PL to flow in the plane of the wafer W between the catalyst 31 and the wafer W with the catalyst 31 and the wafer W in contact with each other. As one embodiment of the groove form, the groove form has such a trapezoidal shape in cross-section that a width of the groove is greater at an opening of the groove than at a bottom of the groove (for example, refer to
Each of the catalyst holding units 30 according to the embodiments illustrated in
Each of the catalyst holding units 30 illustrated in
Each of the catalyst holding units 30 illustrated in
As one embodiment, the catalyst holding unit 30 disclosed in the present disclosure can be attached to the swing arm 50.
As one embodiment, the pressure with which the catalyst holding unit 30 and the wafer W are in contact with each other can be controlled by PID control.
Any of the catalyst holding units 30 disclosed in the present disclosure can include a catalyst temperature control mechanism for controlling a temperature of the catalyst 31. For example, a Peltier element can be used as the catalyst temperature control mechanism.
Next, the conditioning unit 60 is configured to condition the surface of the catalyst 31 at a predetermined timing. This conditioning unit 60 is disposed outside the wafer W held on the substrate holding unit 20. The catalyst 31 held on the catalyst holding unit 30 can be positioned above the conditioning unit 60 by the swing arm 50.
The control unit 90 controls an entire operation of the substrate processing apparatus 10. Further, the control unit 90 also controls a parameter regarding a condition of the etching processing to be performed on the wafer W. Examples of such a parameter include a condition of a motion such as a rotation and an angular rotation of the substrate holding unit, the pressure with which the catalyst 31 and the wafer W are in contact with each other, a condition of the swinging motion of the swing arm 50, a condition of the supply such as a flow amount and a temperature of the processing liquid to be supplied from the processing liquid supply unit 40, a condition of application of a voltage of a potential adjustment unit 580, which will be described below, and a condition of conditioning the surface of the catalyst by the conditioning unit 60.
A flow of the etching processing that is performed on the substrate by the present substrate processing apparatus 10 will be described. First, the wafer W is held onto the substrate holding unit 20 by the substrate transfer unit with the aid of the vacuum suction. Next, the processing liquid is supplied from the processing liquid supply unit 40. Next, after the catalyst 31 on the catalyst holding unit 30 is placed at a predetermined position on the wafer W by the swing arm 50, the vertical movement of the catalyst holding unit 30 brings the catalyst 31 into contact with the processing target region of the wafer W, and also adjusts the pressure therebetween to a predetermined contact pressure. Further, at the same time as this contact operation or after the contact, the relative movement between the substrate holding unit 20 and the catalyst holding unit 30 is started. In the present embodiment, this relative movement is realized by the rotation of the substrate holding unit 20, the rotation of the catalyst holding unit 30, and the swinging motion by the swing arm 50. The relative movement between the substrate holding unit 20 and the catalyst holding unit 30 can be realized by at least one of a rotational motion, a translation motion, a circular arc motion, a reciprocating motion, a scroll motion, and an angular rotational motion (a motion of rotating only by a predetermined angle smaller than 360 degrees) of at least one of the substrate holding unit 20 and the catalyst holding unit 30.
By this operation, an etchant generated from an action of the catalyst 31 acts on the surface of the wafer W at the portion where the wafer W and the catalyst 31 are in contact with each other with the aid of a catalytic action of the catalyst 31, by which the surface of the wafer W is etched and removed. The processing target region of the wafer W can be made of an arbitrary single material or a plurality of arbitrary materials, and examples of the material(s) include an insulating film represented by an SiO2 material and a Low-k material, wiring metal represented by Cu and W, barrier metal represented by Ta, Ti, TaN, TiN, Co, and the like, and a III-V series material represented by GaAs and the like. Further, the material of the catalyst 31 can be, for example, precious metal, transition metal, a ceramic solid catalyst, a basic solid catalyst, or an acid solid catalyst. Further, the processing liquid PL can be, for example, an oxygen solution, ozone water, acid, an alkali solution, H2O2 water, and a hydrofluoric acid solution. The catalyst 31 and the processing liquid PL can be arbitrary set according to the material of the processing target region of the wafer W. For example, if the material of the processing target region is Cu, an acid solid catalyst and ozone water may be used as the catalyst 31 and the processing liquid PL, respectively. Further, if the material of the processing target region is SiO2, platinum or nickel, and acid may be used as the catalyst 31 and the processing liquid PL, respectively. Further, if the material of the processing target region is the III-V series metal (for example, GaAs), iron and H2O2 water may be used as the catalyst 31 and the processing liquid PL, respectively.
Further, if a plurality of materials to be etched is mixed together in the processing target region of the wafer W, a plurality of catalysts and/or a plurality of kinds of processing liquid may be used for the individual materials. Specific examples of how to actually construct this configuration regarding the catalyst side include (1) constructing this configuration with use of a single catalyst holding unit with the plurality of catalysts mounted thereon, and (2) constructing this configuration with use of a plurality of catalyst holding units with the different catalysts mounted thereon, respectively. In the configuration (1), the plurality of catalysts may be a mixture or a compound including a plurality of catalyst materials. Further, regarding the processing liquid side, if the configuration (1) is employed on the catalyst side, a mixture of elements suitable for etching materials to be etched by the individual catalyst materials may be used as the processing liquid. Alternatively, if the configuration (2) is employed on the catalyst side, processing liquid suitable for etching a material that should be etched may be supplied to around each of the catalyst holding units. However, the processing liquid may be deteriorated due to the mixture depending on the kind of the processing liquid. In this case, this deterioration can be avoided with use of a processing liquid holding unit 270, which will be described below in a fourth embodiment, so that regions where the processing liquid exists are localized.
Further, in the present embodiment, because the catalyst 31 is smaller than the wafer W, the catalyst holding unit 30 swings on the entire surface of the wafer W when the entire surface of the wafer W should be processed by the etching processing. Then, the present CARE method etches the wafer W only at the portion in contact with the catalyst, whereby the distribution of the etching amount in the plane of the wafer W is largely affected by a distribution of the contact time between the wafer W and the catalyst 31 in the plane of the wafer. Regarding that, varying a speed at which the swing arm 50 swings in the plane of the wafer can even out the distribution of the contact time. More specifically, a range where the swing arm 50 swings in the plane of the wafer W is divided into a plurality of sectors, and the swing arm 50 is arranged to swing at a controlled speed in each section.
For example, if the catalyst holding unit 30 swings along such a track that the catalyst holding unit 30 passes through the center of the wafer W with the wafer W rotating at a constant rotational speed as illustrated in
The substrate processing apparatus that processes the wafer W while swinging, on the wafer W, the catalyst holding unit 30 having a smaller radius than the wafer W to be processed may require the catalyst holding unit 30 to overhang out of the wafer W. If the catalyst holding unit 30 is caused so as to overhang from the wafer W, the catalyst holding unit 30 may tilt with respect to the plane of the wafer W because of absence of a structure for supporting the catalyst holding unit 30 outside the wafer W.
In embodiments including the extension portion 20-4 of the wafer holding stage 20-2, like the embodiments illustrated in
The extension portion 20-4 of the wafer holding stage 20-2 can also be provided with the conditioning unit 60 having any feature described in the present disclosure. Configuring the extension portion 20-4 in this manner contributes to efficient utilization of the space occupied by the entire apparatus.
In the embodiment illustrated in
The catalyst holding unit 30 according to the embodiment illustrated in
In the embodiment illustrated in
According to the above-described substrate processing apparatus 10 using the CARE method, the wafer W is etched only at the portion in contact with the catalyst 31, and is not etched at other portions out of contact with the catalyst 31. Therefore, only protrusions of the wafer W having the rough surface are selectively chemically removed, so that the planarization processing can be performed. Further, the wafer W is chemically polished, so that the processed surface of the wafer W is less likely damaged. Theoretically, the wafer W and the catalyst 31 do not necessarily have to contact each other, and may be merely located in proximity to each other. In this case, “located in proximity to each other” can be defined to mean being located sufficiently close to each other to allow the etchant generated from the catalytic reaction to reach the processing target region of the wafer W. A distance between the wafer W and the catalyst 31 when they are separated from each other can be, for example, 50 nm or shorter.
After the etching processing according to the present CARE method, the wafer W is cleaned by the substrate cleaning unit, but may be cleaned within the present substrate processing apparatus 10. For example, the wafer W is cleaned by being rotated while wafer cleaning liquid or water is supplied from the processing liquid supply unit 40 thereto.
Further, because an etching product is adhered onto the surface of the catalyst 31, an etching capability of the substrate processing apparatus 10 should be gradually deteriorating. Therefore, the control unit 90 retracts the catalyst holding unit 30 to the conditioning unit 60 to condition the catalyst 31 at a predetermined timing. The predetermined timing can be set to a timing during an interval of the etching processing (a time period during which the processed wafer W is transferred out, and an unprocessed wafer W is mounted on the substrate holding unit 20), each time a predetermined operation time has elapsed, or the like. In the present embodiment, the conditioning unit 60 includes a scrub cleaning unit 61. The scrub cleaning unit 61 includes a scrub member, such as a sponge and a brush, and cleans the catalyst 31 by scrubbing it under existence of cleaning liquid supplied form a cleaning liquid supply unit 62. At this time, a contact between the catalyst holding unit 30 and the scrub member of the scrub cleaning unit 61 is established by a vertical movement of the catalyst holding unit 30 side or the scrub member. Further, when conditioning the catalyst 31, the conditioning unit 60 causes a relative motion such as a rotation of at least one of the catalyst holding unit 30 or the scrub member of the scrub cleaning unit 61. As a result, this embodiment can recover the surface of the catalyst 31 with the etching product adhered thereon to an active status, and can also prevent or reduce the damage that the processing target region of the wafer W might be incurred due to the etching product.
The conditioning unit 60 can be embodied with use of not only the above-described configuration but also various configurations. For example, basically, water may be used as the cleaning liquid in the present scrub cleaning unit 61, but it may be difficult to remove the etching product only by the scrub cleaning depending on a type of the etching product. In this case, a chemical capable of removing the etching product may be supplied as the cleaning liquid. For example, if the etching product is silicate salt (SiO2), hydrofluoric acid may be used as the chemical. Alternatively, the conditioning unit 60 may include an electrolytic regeneration unit configured to remove the etching product adhered on the surface of the catalyst 31 with the aid of an electrolytic action. More specifically, the electrolytic regeneration unit includes an electrode configured to be electrically connectable to the catalyst 31, and is configured to remove the etching product adhered on the surface of the catalyst 31 by applying a voltage to between the catalyst and the electrode.
Alternatively, the conditioning unit 60 may include plating regeneration unit configured to regenerate the catalyst 31 by newly plating the catalyst 31. This plating regeneration unit includes an electrode configured to be electrically connectable to the catalyst 31, and is configured to plate and regenerate the surface of the catalyst 31 by applying a voltage to between the catalyst 31 and the electrode with the catalyst 31 immersed in liquid containing a catalyst for regeneration.
Further, the conditioning unit 60 includes a catalyst cleaning nozzle 60-4 configured to supply the water and/or the chemical for cleaning the surface of the catalyst 31. The cleaning nozzle 60-4 is connected to a not-illustrated supply source of the water and/or the chemical, a required pipe and valve, and the like, and can supply desired fluid to the catalyst 31. The conditioning unit 60 may include a plurality of catalyst cleaning nozzles 60-4, and can be configured to supply the water and different kinds of chemicals from these nozzles, respectively. Alternatively, the conditioning unit 60 may be configured to be able to supply the water and the different kinds of chemicals from the catalyst cleaning nozzle 60-4 with use of the single catalyst cleaning nozzle 60-4 by operating a valve and the like. In the embodiment illustrated in
Providing the cleaning nozzle 60-4 to the conditioning unit 60, like the embodiment illustrated in
The conditioning unit 60 illustrated in each of
In the embodiment illustrated in
Further, conversely, the voltage can also be applied in such a manner that the electrode connected to the catalyst 31 becomes the negative side and the regeneration electrode 60-12 disposed on the conditioning stage 60-2 becomes as the positive side. As a result, a reduction action can be caused on the surface of the catalyst 31 via the water and/or the chemical. For example, if the surface of the catalyst 31 is oxidized by the etching processing performed on the substrate, oxides on the surface of the catalyst can be reduced with the aid of the reduction action, so that the surface of the catalyst 31 can be recovered to the active status.
Further, an ion exchanger may be used as a modification of the embodiment illustrated in
As one embodiment, the catalyst measurement sensor 60-10 can be a resistance sensor that measures electric resistance of the catalyst 31. If the catalyst 31 is metal, an electric resistance value varies due to a change in the film thickness of the catalyst 31, the adhesion of the etching residue on the surface of the catalyst 31, and the generation of the altered layer constituted by oxides. Use of this variation allows the catalyst measurement sensor 60-10 to measure the status of the surface of the catalyst 31.
As one embodiment, the catalyst measurement sensor 60-10 can be a thickness sensor that measures the thickness of the catalyst. For example, if the catalyst is metal, the thickness of the catalyst can be measured by measurement of an eddy current flowing on the surface of the catalyst 31. More specifically, a high-frequency current is applied to a sensor coil disposed in proximity to the surface of the catalyst 31 to generate the eddy current on the catalyst 31, thereby producing an induction magnetic field on the electrically-conductive metallic film formed on the catalyst 31. The eddy current generated there and a synthetic impedance calculated therefrom vary according to the thickness of the metallic film of the catalyst 31, the adhesion of the etching residue on the surface of the catalyst 31, and the altered layer constituted by the oxides, so that the thickness sensor 60-10 can measure the status of the catalyst 31 in a non-contact manner by using this variation.
As one embodiment, the catalyst measurement sensor 60-10 is an optical sensor. Use of the optical sensor allows the catalyst measurement sensor 60-10 to measure the status of the surface of the catalyst 31 in a non-contact manner by measuring a reflection intensity according to the change in the film thickness if the catalyst 31 is a light transmissive material.
Generally, the catalyst is conditioned for the purpose of keeping the surface of the catalyst in an optimal status. The insufficiently conditioned catalyst makes it impossible to acquire a desired capability of etching the substrate to be processed due to the deterioration of the active status of the catalyst surface. On the other hand, the excessively conditioned catalyst leads to a shortened lifetime of the catalyst. The use of the catalyst measurement sensor 60-10 to measure the status of the surface of the catalyst, like the above-described sensor, allows the conditioning unit 60 to acquire an appropriate catalytic status with a minimum conditioning amount. For example, the conditioning unit 60 can detect an end point of the conditioning while measuring the status of the catalyst with use of the catalyst measurement sensor 60-10 as needed in the process of the conditioning of the catalyst 31. More specifically, the adhesion of the etching residue on the catalyst 31 or the generation of the altered layer constituted by the oxides, if any, leads to an increase in the electric resistance of the surface of the catalyst 31. On the other hand, the electric resistance reduces as the catalyst 31 is being conditioned and the surface of the catalyst 31 is being cleaned. Therefore, the conditioning unit 60 can determine the end point of the conditioning by using the catalyst measurement sensor 60 of the type that measures the above-described electric resistance or the above-described impedance from the eddy current. Alternatively, the conditioning unit 60 can measure the status of the catalyst with use of the catalyst measurement sensor 60-10 before conditioning the catalyst 31, and predetermine a parameter of the conditioning, such as a setting of the conditioning (for example, a time to be taken for the conditioning, a setting about the application of the voltage, and a scrub setting such as a pressure with which the scrum member 61 should contact the catalyst 31 and the number of times that the scrub member 61 should rotate), based on the measured value. Alternatively, the conditioning unit 60 can also estimate the status of the catalyst 31 from a processing rate while the substrate is processed with use of a monitoring unit 480, which will be described below, without use of the catalyst measurement sensor 60-10 to determine the parameter of the conditioning. Further, the catalyst measurement sensor 60-10a also allows the conditioning unit 60 to acquire a signal corresponding to the film thickness of the catalyst 31, and determine a timing when the catalyst 31 should be replaced by monitoring a reduction in the catalyst 31 due to wear.
Having described the conditioning to correct the deterioration of the surface of the catalyst 31, the deterioration of the catalyst 31 can be eliminated or reduced even by another method than the above-described conditioning especially with respect to the generation of the altered layer, such as the oxidation of the surface of the catalyst 31. For example, in one embodiment, the substrate processing apparatus 10 uses platinum, nickel, iron, or chrome as the catalyst 31, and the catalyst holding unit 30 includes the counter electrode electrically connectable to this metallic catalyst via the processing liquid. Metal having larger ionization tendency than the metal of the catalyst 31 can be used for this counter electrode. In this case, an electromotive force is generated between the two kinds of metal in a direction in which electrons move from the metal with smaller ionization tendency to the metal with larger ionization tendency while the wafer W is processed. As a result, the electrode with larger ionization tendency is preferentially oxidized, which reduces or prevents oxidation and/or hydroxylation of the catalyst 31, which is the metal with smaller ionization tendency.
Further, in one embodiment, the conditioning unit 60 includes a gas supply nozzle for supplying gas to the surface of the catalyst 31. A nozzle configured similarly to the catalyst cleaning nozzle 60-4 illustrated in
The conditioning unit 60 may be configured to remove or reduce the oxidation and/or the hydroxylation of the catalyst 31 by applying the voltage in such a manner that the electrode on the catalyst side becomes the negative side and the regeneration electrode becomes the positive side as described with reference to
Further, the substrate processing apparatus 10 may be used in combination with the CMP apparatus. This combined use allows the substrate processing apparatus 10 to flexibly process the semiconductor material on the substrate, thereby improving the processing capability as a whole. The order of the processing performed by the substrate processing apparatus 10 and the processing performed by the CMP apparatus varies depending on the material to be processed, so that a transfer route by the substrate transfer unit can be selected appropriately according to a situation. For example, the substrate processing apparatus 10 can process the wafer W after the CMP apparatus processes the wafer W first, or the CMP apparatus processes can process the wafer W after the substrate processing apparatus 10 processes the wafer W first.
As an alternative configuration, the substrate processing apparatus 110 may include a processing liquid temperature adjustment unit that adjusts a temperature of the processing liquid PL to a predetermined temperature instead of or in addition to the substrate temperature control unit 121. Alternatively, the catalyst holding unit 30 may include a catalyst temperature control mechanism that adjusts a temperature of the catalyst 31 instead of or in addition to them. This configuration also allows the substrate processing apparatus 110 to adjust the etching rate by adjusting the temperature of the processing liquid. The temperature of the processing liquid PL may be adjusted to, for example, a predetermined temperature within a range of 10 degrees or higher and 60 degrees or lower.
Further, the etching capability can be stabilized by applying this temperature dependency, and for example, placing the substrate processing apparatus 110 in a constant-temperature bath to thereby control the temperature of the entire substrate processing apparatus 110.
In the embodiments illustrated in
The monitoring unit 480 can have not only the above-described configuration but also various configurations. For example, if a polishing target is a light transmissive material, such as an oxidized film, the monitoring unit 480 may emit light toward the processing target region of the wafer W and detect light reflected therefrom. More specifically, the monitoring unit 480 receives refection light reflected on the surface of the processing target region of the wafer W or reflected after being transmitted through the processing target layer of the wafer W. An intensity of this reflection light varies depending on the film thickness of the processing target layer, so that the monitoring unit 480 can monitor the status of the etching processing based on this variation.
Alternatively, if a processing target layer is a compound semiconductor (for example, GaN or SiC), the monitoring unit 480 may use at least one of a photocurrent method, a photoluminescence optical method, and a Raman optical method. According to the photocurrent method, the monitoring unit 480 measures a value of a current flowing through a conductive wire connecting the wafer W and a metallic wiring laid in the substrate holding unit 20 when the surface of the wafer W is irradiated with excitation light, thereby measuring the etching amount of the surface of the wafer W. According to the photoluminescence optical method, the monitoring unit 480 measures photoluminescence light discharged from the surface of the wafer W when this surface is irradiated with excitation light, thereby measuring the etching amount of the surface of the wafer W. According to the Raman optical method, the monitoring unit 480 irradiates the surface of the wafer W with visible monochromatic light to measure Raman light contained in light reflected from this surface, thereby measuring the etching amount of the surface of the wafer W.
Alternatively, the monitoring unit 480 may monitor the status of the etching processing based on a torque current of the driving unit when the substrate holding unit 220 and the catalyst holding unit 30 are moved relative to each other. This configuration allows the monitoring unit 480 to monitor a friction status generated due to the contact between the semiconductor material of the substrate and the catalyst via the torque current, thereby monitoring the etching status based on a variation in the torque current due to, for example, a change in the roughness status of the semiconductor material or an exposure of another material on the processing target surface.
Further, as one exemplary embodiment, the monitoring unit 480 may be configured as a vibration sensor included in the catalyst holding unit 3. The monitoring unit 480 detects a vibration when the substrate holding unit 220 and the catalyst holding unit 30 are moved relative to each other with use of the vibration sensor. The friction status between the wafer W and the catalyst 31 varies if the roughness status of the wafer W changes or another material is exposed while the wafer W is processed, and the vibration status varies due to this variation in the friction status. The monitoring unit 480 can detect the status of the processing performed on the wafer W by detecting this variation in the vibration with use of the vibration sensor.
The status of the etching processing monitored in this manner is reflected in the processing performed on the next wafer W in the substrate processing apparatus 410 by the parameter change unit 491. More specifically, the parameter change unit 491 changes a control parameter regarding the condition of the etching processing to be performed on the next wafer based on the status of the etching processing monitored by the monitoring unit 480. For example, the parameter change unit 491 changes the control parameter based on a difference between a distribution of the thickness of the processing target layer acquired based on the result of the monitoring by the monitoring unit 480 and a predetermined target distribution of the thickness in such a manner that this difference reduces. This configuration allows the substrate processing apparatus 410 to feed back the result of the monitoring by the monitoring unit 480, thereby succeeding in improving an etching performance of the processing performed on the next wafer.
The control unit 490 may feed back the result of the monitoring by the monitoring unit 480 for the processing performed on the wafer W currently in process. For example, the control unit 490 may change a parameter among conditions of the processing by the substrate processing apparatus 410 in the middle of the processing, in such a manner that the difference between the distribution of the thickness of the processing target region acquired based on the result of the monitoring by the monitoring unit 480 and the predetermined target distribution of the thickness falls within a predetermined range (ideally, zero). The result of the monitoring acquired by the monitoring unit 480 can be not only fed back for the above-described conditions of the processing but also used to function as an end point detection unit for detecting the end point of the polishing processing.
Further, the substrate processing apparatus 410 may include a thickness measurement unit that measures the thickness of the wafer W after the processing, instead of the above-described monitoring unit 480. The thickness measurement unit may be disposed outside the substrate holding unit 220. The processed wafer W is transferred to the thickness measurement unit, and is measured there in terms of the distribution of the thickness of the processing target layer thereof. A result of the measurement by this thickness measurement unit can also be fed back for the conditions of the processing to be performed on the next wafer W, similarly to the monitoring unit 480. More specifically, the control unit 490 calculates a value of a difference between the result of this measurement and a target film thickness, and changes the condition of the processing to be performed on the wafer W so as to eliminate this difference. Further, in this case, the control unit 490 may function as a reprocessing control unit. The reprocessing control unit causes the substrate processing apparatus 410 to reprocess the wafer W, if the result of the measurement by the thickness measurement unit does not satisfy a predetermined target value, i.e., if the difference between the distribution of the thickness of the processing target layer acquired by this thickness measurement unit and the predetermined target distribution of the thickness is larger than a reference value. If the distribution as the difference value that requires the reprocessing is kept even within the circumference of the wafer but is uneven in the radial direction, the substrate processing apparatus 410 can reprocess the wafer W by, for example, radially adjusting the speed at which the swing arm 50 swings while the wafer W is rotated. However, if the distribution as the difference value is largely uneven in the circumferential direction of the wafer, this method cannot be employed. In this case, the substrate processing apparatus 410 can reprocess the wafer W by, for example, specifying a position of a portion in the plane of the wafer W that should be reprocessed based on a notch, an oriental flat, or a laser marker of the wafer, and moving the substrate holding unit 20 and the catalyst holding unit 30 in such a manner that the catalyst 31 can contact this position. More specifically, the substrate processing system may include a detection unit that detects at least one of the notch, the oriental flat, and the laser maker of the substrate, and a substrate position adjustment unit configured to rotate the substrate only b an arbitrary predetermined angle so that the notch, the oriental flat, or the laser marker of the substrate is located at a predetermined position. The substrate processing apparatus 410 can reprocess the wafer W by setting the substrate by the substrate transfer unit in such a manner that the above-described mark or the like detected by the detection unit is located at the predetermined position of the substrate holding unit 20, and angularly rotating the substrate holding unit 20 based on this predetermined position in such a manner that the portion required to be reprocessed is located on the track along which the swing arm 50 of the catalyst holding unit 30 swings. This configuration allows the substrate processing apparatus 410 to reprocess a desired portion required to be reprocessed, resulting in succeeding in acquiring a satisfactory quality of the etching processing. Further, the substrate processing apparatus 410 may include a thickness measurement unit that measures the thickness of the wafer W before the processing. The thickness measurement unit may be disposed outside the substrate holding unit 220. Further, if the substrate processing apparatus 410 includes a CMP processing unit, the substrate processing apparatus 410 may use a film thickness measurement unit built in the CMP processing unit. The substrate processing apparatus 410 can acquire the target distribution of the thickness regardless of a variation in an initial status among wafers, by feeding back the result of measuring the distribution of the thickness of the processing target layer of the wafer before the processing for the condition of the processing to be performed on the wafer W.
In the CARE method, the etching rate can be adjusted by the application of the voltage to between the catalyst 31 and the counter electrode. Therefore, it is desirable to apply an electrode that maximizes the etching rate of the wafer W, to between the catalyst 31 and the counter electrode 30-50 regarding the voltage between the catalyst 31 and the counter electrode 30-50, from the point of view of the rate at which the wafer W is processed. On the other hand, the surface of the catalyst 31 may be oxidized and/or hydroxylated while the wafer W is processed, depending on the kind of the catalyst 31 and the kind of the processing liquid PL. In this case, the substrate processing apparatus can recover the active status of the surface of the catalyst by conditioning the surface of the catalyst as described above during the interval time period between the processing performed on the wafer W and the processing to be performed on the new wafer W. On the other hand, if the catalyst 31 is such a catalyst that the active status of the surface of the catalyst is recoverable by the reduction action, the substrate processing apparatus can reduce the surface of the catalyst by intermittently applying a potential on the reduction side to the catalyst 31 while the wafer W is processed. In other words, the surface of the catalyst can be conditioned to maintain the active status while the wafer W is processed.
In the substrate processing apparatus 10 as a seventh embodiment, the catalyst 31 includes two kinds or more of individual catalysts. As an alternative embodiment, the catalyst 31 may be a mixture (for example, an alloy) or a compound (for example, an intermetallic compound) containing two kinds of catalysts. According to this configuration, the substrate processing apparatus 10 can etch the wafer W evenly or at a desired selection ratio, if the surface to be polished is made of two or more different kinds of materials according to the region of the wafer W. For example, if a Cu layer and an SiO2 layer are formed on a first region and a second region of the wafer W, respectively, the catalyst 31 may include a region containing an acid solid catalyst for Cu and a region containing platinum for SiO2. In this case, ozone water for Cu and acid for SiO2 may be used as the processing liquid PL. Alternatively, if a III-V series metallic (for example, GaAs) layer and an SiO2 layer are formed on the first region and the second region of the wafer W, respectively, the catalyst 31 may include a region containing iron for the III-V series metal and a region containing platinum or nickel for SiO2. In this case, ozone water for the III-V series metal and acid for SiO2 may be used as the processing liquid PL.
In this case, the substrate processing apparatus 10 may include a plurality of catalyst holding units 30. Each of the plurality of catalyst holding units 30 may hold a different kind of catalyst from one another. For example, a first catalyst holding unit 30 may hold the catalyst 31 containing an acid solid catalyst, and a second catalyst holding unit 30 may hold the catalyst containing platinum. In this case, the two catalyst holding units 30 can be configured to scan only on the layer of the corresponding material on the wafer W. According to this configuration, the substrates processing apparatus 10 can further efficiently process the wafer W by sequentially using the first catalyst holding unit 30 and the second catalyst holding unit 30 and supplying the processing liquid PL according to the catalyst holding unit 30 in use. As a result, the substrates processing apparatus 10 can improve the processing capability per unit time.
As an alternative embodiment, in the fourth embodiment, different kinds of processing liquid PL may be sequentially supplied. According to this configuration, the substrate processing apparatus can etch the wafer W evenly or at a desired selection ratio, if the processing target surface is made of two or more different kinds of materials according to the region of the wafer W. For example, the catalyst holding unit 30 may hold a catalyst containing platinum. Then, the substrate processing apparatus 10 may first supply a neutral solution or a solution containing Ga ions as the processing liquid PL to etch the III-V series metallic layer of the wafer W, and then supply acid as the processing liquid PL to etch the SiO2 layer of the wafer W.
As an another alternative embodiment, the substrate processing apparatus 10 may include a plurality of catalyst holding units 30 holding the same kind of catalyst. In this case, the plurality of catalyst holding units 30 may be used simultaneously. According to this configuration, the substrate processing apparatus 10 can improve the processing capability per unit time.
The waver W held by the substrate holding head 604 can be located at a first position P1, where the wafer W is etched by the CARE method, and a second position P2, where the wafer W is polished by the CMP apparatus, with use of a swinging motion of the swing arm 602. The wafer W processed by the CMP processing at the second position P2 is placed on the first position P1 while being kept held by the substrate holding head 604. At this time, the surface of the wafer W to be polished remains face-down. In the present embodiment, the order of the processing procedures performed on the wafer W is set in such a manner that the wafer W is processed by CMP and CARE in this order, but is not limited thereto depending on the material of the processing target region. The wafer W may be processed by CARE and CMP in this order, or may be processed only by CARE or CMP.
The substrate processing unit 610 basically has a similar configuration to the above-described substrate processing apparatus 10, and performs similar processing to the above-described substrate processing apparatus 10. However, the surface of the wafer W to be polished is placed face down, so that the catalyst holding unit 630 mounted on the distal end of the swing arm 650 is moved vertically upwardly to carry the catalyst into contact with the surface to be polished. According thereto, the processing liquid supply unit 640 supplies the processing liquid PL to the bottom surface of the wafer W as the PL. In this case, the processing liquid supply unit 640 may be a spray device that sprays the processing liquid PL vertically upwardly. Alternatively, the processing liquid holding unit 270 illustrated in
In this manner, the substrate processing unit 610 may be realized as a unit integrated with the CMP processing unit 603. According to this configuration, the processing performed by the substrate processing apparatus 610 and the processing performed by the CMP processing unit 603 can share the operation of holding the wafer W, which contributes to a reduction in the processing time as a whole.
As another embodiment, the number of catalyst holding units 30 is not limited to two, but the substrate processing apparatus can include an arbitrary number of catalyst holding units 30. Further, the dimension may be changed for each of the catalyst holding units 30. For example, the substrate processing apparatus can use the catalyst holding unit 30 large in dimension and the catalyst holding unit 30 small in dimension. The catalyst holding unit 30 small in dimension can especially provide high controllability of the etching rate of the wafer W in the processing performed on the wafer W, so that the use of the catalyst holding units 30 having different dimensions can contribute to the further improvement of the uniformity in the plane of the wafer. As a specific example, the substrate processing apparatus can process the central portion of the wafer W with use of the catalyst holding unit 30 large in dimension, and can process the edge of the wafer W and the vicinity thereof with use of the catalyst holding unit 30 small in dimension.
Further, as another embodiment, a plurality of catalyst holding members 32 can also be mounted on the single swing arm 50. In this case, the respective sizes of the catalyst holding units 32 may be different from one another or may be the same as one another. For example, the substrate processing apparatus can also be configured in such a manner that the single swing arm 50 is provided with the catalyst holding unit 30 large in dimension, and the catalyst holding units 30 small in dimension disposed on both sides of the catalyst holding unit 30 large in dimension so as to sandwich the catalyst holding unit 30 large in dimension Further, the catalysts held on the different catalyst holding units 32 may be the same as one another or may be different from one another. As a modification of the embodiment illustrated in
Further, as a modification of the embodiment illustrated in
In this substrate processing apparatus 710, the catalyst holding unit 730 contacts the wafer W with a predetermined contact pressure after being horizontally moved to the predetermined position of the wafer W held on the substrate holding unit 730. At this time, the wafer W and the catalyst holding unit 730 may simultaneously start the rotational motions. The holing unit 730a and the second catalyst holding unit 730b rotate in the opposite directions from each other, and further rotate in directions for cancelling out relative speeds with respect to the direction in which the wafer W rotates. Further, the supply of the processing liquid may also be simultaneously started from the processing liquid supply units 740 and 741. According to this configuration, the substrate processing apparatus 710 can reduce a difference between the relative speed between the first catalyst holding unit 730a and the wafer W, and the relative speed between the second catalyst holding unit 730b and the wafer W, and as a result thereof, can reduce a damage that the surface of the wafer W would incur due to the friction.
In the embodiment illustrated in
Having described aspects of the present invention based on several embodiments, the above-described embodiments of the invention are intended only to facilitate the understanding of the present invention, and are not intended to limit the present invention thereto. It is apparent that the present invention can be modified and improved without departing from the gist of the present invention, and equivalents thereof are also included in the present invention. Further, the components described in the claims and the specification of the present application can be arbitrarily combined or omitted within a range that can solve at least a part of the above-described problems or achieve at least a part of the advantageous effects.
| Number | Date | Country | Kind |
|---|---|---|---|
| 086869-2014 | Apr 2014 | JP | national |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15305088 | Oct 2016 | US |
| Child | 16845914 | US |
