The present disclosure relates to substrate processing systems, and more particularly to substrate processing systems including showerheads that deliver radicals and precursor gas to a downstream chamber.
The background description provided here is for the purpose of generally presenting the context of the disclosure. Work of the presently named inventors, to the extent it is described in this background section, as well as aspects of the description that may not otherwise qualify as prior art at the time of filing, are neither expressly nor impliedly admitted as prior art against the present disclosure.
Substrate processing systems may be used to deposit film on a substrate such as a semiconductor wafer. The substrate processing systems typically include a processing chamber and a substrate support. During film deposition, radicals and precursor gas maybe supplied to the processing chamber.
For example, the processing chamber may include an upper chamber, a lower chamber and a substrate support. A showerhead may be arranged between the upper chamber and the lower chamber. The substrate is arranged on the substrate support in the lower chamber. A plasma gas mixture is supplied to the upper chamber and plasma is struck in the upper chamber. Some of the radicals generated by the plasma flow through the showerhead to the lower chamber. The showerhead filters ions and shields UV light from reaching the lower chamber. A precursor gas mixture is supplied to the lower chamber through the showerhead and reacts with the radicals to deposit film on the substrate.
Typically, the showerhead does not have a thermal control system. However, in some processing systems, a basic thermal control system is used to control a temperature of an outer edge of the showerhead, which is accessible and not under vacuum. The basic thermal control system does not uniformly control temperature across the showerhead due to the heat from the plasma. In other words, the temperature at the center of the showerhead increases. Temperature changes also occur with process changes such as plasma on/off, pressure, flow rate, and/or pedestal temperature. Variations in the temperature of the showerhead adversely impact the uniformity of the deposition process and defect performance.
A substrate processing system includes a first chamber including a substrate support. A showerhead is arranged above the first chamber and is configured to filter ions and deliver radicals from a plasma source to the first chamber. The showerhead includes a heat transfer fluid plenum including an inlet to receive heat transfer fluid and a plurality of flow channels to direct the heat transfer fluid through a center portion of the showerhead to an outlet to control a temperature of the showerhead, a secondary gas plenum including an inlet to receive secondary gas and a plurality of secondary gas injectors to inject the secondary gas into the first chamber, and a plurality of through holes passing through the showerhead. The through holes are not in fluid communication with the heat transfer fluid plenum or the secondary gas plenum.
In other features, the heat transfer fluid plenum includes a first plenum in fluid communication with the inlet. The first ends of the flow channels are in communication with the first plenum. A second plenum is in fluid communication with opposite ends of the flow channels.
In other features, the heat transfer fluid plenum includes a first plenum in fluid communication with the inlet, a second plenum in fluid communication with first ends of the flow channels, a first plurality of restrictions arranged between the first plenum and the second plenum to restrict fluid flow therebetween, a third plenum in fluid communication with opposite ends of the flow channels, a fourth plenum in fluid communication with the outlet, and a second plurality of restrictions arranged between the third plenum and the fourth plenum to restrict fluid flow therebetween.
In other features, the plurality of flow channels flow in a radial direction from one side of the showerhead to an opposite side of the showerhead. The plurality of flow channels defines a straight path. The plurality of flow channels defines a curved path. The plurality of flow channels defines a sinusoidal-shaped path.
In other features, the secondary gas plenum includes a first plenum, a second plenum, and a flow restriction arranged between the first plenum and the second plenum.
In other features, the flow restriction comprises a first plurality of walls, and a plurality of slots defined between the first plurality of walls. The first plurality of walls is arcuate-shaped. A second plurality of walls is arranged around the through holes in the second plenum. The second plurality of walls is cylinder-shaped.
In other features, the secondary gas injectors are in fluid communication with the second plenum. A plurality of restrictions arranged between the second plenum and the secondary gas injectors.
In other features, the plurality of flow channels includes inlets and outlets. The inlets of the plurality of flow channels are arranged on one side of the showerhead, the outlets of the plurality of flow channels are arranged on the one side between the inlets, and the plurality of flow channels connect to the inlets, travel across the showerhead and return back across the showerhead to the outlets.
In other features, a second chamber is arranged above the first chamber. The showerhead is arranged between the first chamber and the second chamber. A coil is arranged around the second chamber. An RF generator is connected to the coil to generate plasma in the second chamber.
In other features, at least one of the flow channels includes a flow restriction. The heat transfer fluid comprises liquid. The heat transfer fluid comprises gas. The heat transfer fluid does not flow into the first chamber.
In other features, the secondary gas injectors extend a predetermined distance from a bottom surface of the showerhead, wherein the predetermined distance is in a range from 0.1″ to 1.5″. The through holes have a diameter in a range from 0.05″ to 0.3″.
In other features, the showerhead includes a cylindrical wall that extends from a bottom surface thereof and that is located radially outside of the plurality of through holes and the plurality of secondary gas injectors. The showerhead includes a cylindrical wall that extends upwardly from a top surface thereof and that is located radially outside of the plurality of through holes and the plurality of secondary gas injectors.
In other features, a first O-ring is arranged between a top surface of the showerhead and the upper chamber and a second O-ring is arranged between the bottom surface of the showerhead and the lower chamber.
Further areas of applicability of the present disclosure will become apparent from the detailed description, the claims and the drawings. The detailed description and specific examples are intended for purposes of illustration only and are not intended to limit the scope of the disclosure.
The present disclosure will become more fully understood from the detailed description and the accompanying drawings, wherein:
In the drawings, reference numbers may be reused to identify similar and/or identical elements.
The present disclosure relates to a substrate processing system including an integrated, flush-mount showerhead that delivers uniform radicals and filters ions from a remote plasma source. The showerhead provides uniform temperature control by supplying heat transfer fluid to channels through a center portion of the showerhead to maintain a uniform and controlled temperature. The showerhead also supplies uniform precursor gas flow delivery to a chamber including the substrate. In some examples, the substrate processing system can be used to deposit conformal carbide films, although other types of film can be deposited.
Referring now to
In some examples, the upper chamber 20 may include a dome shaped chamber, although other chamber shapes can be used. A substrate support 34 is arranged in the lower chamber 30. A substrate 36 is arranged on the substrate support 34 during substrate treatment. A showerhead 40 is arranged between the upper chamber 20 and the lower chamber 30. Inductive coils 42 may be arranged around the upper chamber 20.
A gas delivery system 50-1 may be used to supply a process gas mixture including plasma gas to the upper chamber 20. The gas delivery system 50-1 includes one or more gas sources 52-1, 52-2, . . . , and 52-N, valves 54-1, . . . , and 54-N, mass flow controllers (MFC) 56-1, . . . , and 56-N, and a manifold 58, although other types of gas delivery systems can be used (where N is an integer). A gas delivery system 50-2 delivers a process gas mixture including precursor gas to the showerhead 40.
An RF plasma generator 66 includes an RF source 70 and a matching network 72. The RF plasma generator 66 selectively supplies RF power to the inductive coil 42 (while plasma gas is supplied) to generate plasma 62 in the upper chamber 20.
A thermal control system 86 may be used to supply heat transfer fluid such as gas or a liquid coolant to the showerhead 40 to control a temperature of the showerhead 40. A valve 88 and a pump 90 may be used to evacuate reactants.
A controller 94 communicates with the gas delivery systems 50-1 and 50-2 to selectively supply process gases as needed to the upper chamber 20 and the showerhead 40. The controller 94 communicates with the RF plasma generator 66 to generate and extinguish plasma in the upper chamber 20.
The controller 94 communicates with the thermal control system 86 to control a flow rate and temperature of heat transfer fluid that is used to control the temperature of the showerhead 40. In some examples, the heat transfer fluid may include water, water mixed with ethylene glycol, perfluoropolyether fluorinated fluid or other fluid and/or one or more gases. In some examples, the thermal control system 86 controls the flow rate or temperature of the heat transfer fluid using closed loop control. In other examples, the thermal control system 86 controls the flow rate and temperature using proportional integral derivative (PID) control. The heat transfer fluid may be provided in an open loop system from a building water circulation system. In some examples, the heat transfer fluid is hermetically sealed from the vacuum chamber.
In some examples, the controller 94 may be connected to one or more temperature sensors (not shown) arranged in the showerhead 40 to sense one or more temperatures of the showerhead 40. In some examples, the controller 94 may be connected to one or more pressure sensors (not shown) arranged in the showerhead 40 to sense one or more pressures in the processing chamber. The controller 94 communicates with the valve 88 and the pump 90 to control pressure within the upper and lower chambers 20, 30 and to selectively evacuate reactants therefrom.
Referring now to
A plurality of secondary gas injectors 112 supply secondary gas such as precursor gas from the showerhead 40. In some examples, the secondary gas injectors 112 extend downwardly from the bottom surface 104 of the showerhead 40 in the center portion of the showerhead 40. In some examples, the secondary gas injectors 112 include a restriction (not shown) on the bottom surface 104 to prevent back-diffusion and to make gas flow uniform from one secondary gas injector to another. The restriction may induce choked flow conditions.
In
Referring now to
In some examples, the through holes 110 may include a plurality of smaller through holes that are clustered around each secondary gas injector 112 as shown in the examples in
Referring now to
The one or more heat transfer fluid plenums 140 are connected to thermal fluid ports 120, 122. The one or more secondary gas plenums 150 receive gas from the secondary gas inlet (
In some examples, the secondary gas injectors 112 extend a predetermined distance away from a bottom surface of the showerhead 40 to reduce deposition of film on the showerhead 40. In some examples, the predetermined distance is in a range from 0.1″ to 1.5″, although other distances can be used. In some examples, the secondary gas injectors 112 include a restriction to prevent back diffusion and ensure flow uniformity from one secondary gas injector to another. In some examples, the through holes 110 have a diameter in a range from 0.05″ to 0.3″.
In
In some examples, a top surface of the middle layer 165 defines the one or more heat transfer fluid plenums 140 and a bottom surface of the middle layer 165 defines the one or more secondary gas plenums 150. However, a bottom surface of the top layer 163 can be used to partially or fully define the one or more heat transfer fluid plenums 140 and the top surface of the bottom layer 167 can be used to fully or partially define the one or more secondary gas plenums.
In some examples, the thickness of the plenums and material above and below them is 0.05″ to 0.25″, although other thicknesses can be used. The thickness of the material in-between and above/below the plenums is determined by the strength needed to support the fluid pressure and material thickness required for manufacturing. A thickness of the heat transfer fluid plenum 140 may be sized to reduce a pressure drop of the fluid. A size of the secondary gas plenum 150 may be selected large enough to allow uniform distribution of gas to each injector 112. The thickness of each layer should be minimized to reduce the overall thickness to reduce loss of radicals in the through holes 110.
In some examples, the thickness of the top layer 163 and the bottom layer 167 is in a range from 0.075″ to 0.125″, although other thicknesses can be used. In some examples, the thickness of the top layer 163 and the bottom layer 167 is 0.1″, although other thicknesses can be used. In some examples, the thickness of the middle layer 165 is in a range from 0.4″ to 0.6″, although other thicknesses can be used. In some examples, the thickness of the middle layer 165 is 0.5″, although other thicknesses can be used. In some examples, the thickness of the showerhead is less than or equal to 1″. In some examples, the thickness of the showerhead is less than or equal to 0.7″.
In
In
In
Referring now to
The second plenum 156-2 opens into first ends of flow channels 160. In some examples, the flow channels 160 have a triangular, square-wave, curved or generally sinusoidal shape to increase surface area. Second ends of the flow channels 160 are connected to a third plenum 156-3 arranged at an opposite side of the showerhead 40. A plurality of restrictions 158-2 is arranged on one side of the third plenum 156-3. Each of the plurality of restrictions 158-2 is arranged to restrict flow into a fourth plenum 156-4. The fourth plenum 156-4 is connected to an outlet. If the flow channels 160 include the restriction 164, the plurality of restrictions 158-2 can be omitted and the third and fourth plenums 156-3 and 156-4 can be a single plenum.
In some examples, the thermal fluid flow channels 160 have a channel to channel non-uniformity of less than or equal to 10% flow rate. In some examples, the thermal fluid flow rate is 10 gallons per minute and controls the entire showerhead surface to +−1 degree Celsius. In some examples, the secondary gas injectors 112 have flow non-uniformity less than or equal to 1% mass flow rate. In some examples, the secondary gas injectors 112 have non-uniformity less than or equal to 0.1% mass flow rate.
In
A second plurality of walls 190 is arranged around the through holes 110. In some examples, the second plurality of walls 190 has a cylindrical shape, although other shapes can be used. In some examples, a top edge of the second plurality of walls 190 provides a bonding area to create a vacuum seal between the second plenum 176-2 and the through holes 110. In some examples, a plurality of restrictions 186 is provided at inlets of the secondary gas injectors 112 to control flow of the secondary gas from the second plenum 176-2 to the lower chamber 30.
In some examples, the slots 184 are sized relative to the restrictions 186 such that the pressure drop ΔPslots at the slots 184 is significantly greater than the pressure drop ΔPfirst plenum. In some examples, ΔPslots is 20 times greater than ΔPfirst plenum. In some examples, ΔPslots is 5 times greater than ΔPfirst plenum.
Referring now to
In
The outlets 334 pass through gas vias 338 in the middle portion 300 to an outlet plenum 350 located on a bottom side of the middle portion 300 in
The integrated showerheads described herein deliver sufficient and uniform radicals, filter ions from a remote plasma source, provide uniform temperature control, and supply uniform precursor. In some examples, thermal control provided by the showerheads including the heat transfer fluid channels described above control thermal non-uniformity across the substrate to less than 5° C. The heat transfer fluid channels are also capable of controlling the heat generated from the plasma contained in the volume of the upper chamber 20. The showerhead further includes an internal secondary gas plenum that provides uniform precursor delivery to the lower chamber. In some examples, gas outlets from the secondary gas plenum are offset by a predetermined distance from a bottom surface of the showerhead to minimize deposition on the showerhead and extend time between cleans.
The foregoing description is merely illustrative in nature and is in no way intended to limit the disclosure, its application, or uses. The broad teachings of the disclosure can be implemented in a variety of forms. Therefore, while this disclosure includes particular examples, the true scope of the disclosure should not be so limited since other modifications will become apparent upon a study of the drawings, the specification, and the following claims. It should be understood that one or more steps within a method may be executed in different order (or concurrently) without altering the principles of the present disclosure. Further, although each of the embodiments is described above as having certain features, any one or more of those features described with respect to any embodiment of the disclosure can be implemented in and/or combined with features of any of the other embodiments, even if that combination is not explicitly described. In other words, the described embodiments are not mutually exclusive, and permutations of one or more embodiments with one another remain within the scope of this disclosure.
Spatial and functional relationships between elements (for example, between modules, circuit elements, semiconductor layers, etc.) are described using various terms, including “connected,” “engaged,” “coupled,” “adjacent,” “next to,” “on top of,” “above,” “below,” and “disposed.” Unless explicitly described as being “direct,” when a relationship between first and second elements is described in the above disclosure, that relationship can be a direct relationship where no other intervening elements are present between the first and second elements, but can also be an indirect relationship where one or more intervening elements are present (either spatially or functionally) between the first and second elements. As used herein, the phrase at least one of A, B, and C should be construed to mean a logical (A OR B OR C), using a non-exclusive logical OR, and should not be construed to mean “at least one of A, at least one of B, and at least one of C.”
In some implementations, a controller is part of a system, which may be part of the above-described examples. Such systems can comprise semiconductor processing equipment, including a processing tool or tools, chamber or chambers, a platform or platforms for processing, and/or specific processing components (a substrate pedestal, a gas flow system, etc.). These systems may be integrated with electronics for controlling their operation before, during, and after processing of a semiconductor substrate or substrate. The electronics may be referred to as the “controller,” which may control various components or subparts of the system or systems. The controller, depending on the processing requirements and/or the type of system, may be programmed to control any of the processes disclosed herein, including the delivery of processing gases, temperature settings (e.g., heating and/or cooling), pressure settings, vacuum settings, power settings, radio frequency (RF) generator settings, RF matching circuit settings, frequency settings, flow rate settings, fluid delivery settings, positional and operation settings, substrate transfers into and out of a tool and other transfer tools and/or load locks connected to or interfaced with a specific system.
Broadly speaking, the controller may be defined as electronics having various integrated circuits, logic, memory, and/or software that receive instructions, issue instructions, control operation, enable cleaning operations, enable endpoint measurements, and the like. The integrated circuits may include chips in the form of firmware that store program instructions, digital signal processors (DSPs), chips defined as application specific integrated circuits (ASICs), and/or one or more microprocessors, or microcontrollers that execute program instructions (e.g., software). Program instructions may be instructions communicated to the controller in the form of various individual settings (or program files), defining operational parameters for carrying out a particular process on or for a semiconductor substrate or to a system. The operational parameters may, in some embodiments, be part of a recipe defined by process engineers to accomplish one or more processing steps during the fabrication of one or more layers, materials, metals, oxides, silicon, silicon dioxide, surfaces, circuits, and/or dies of a substrate.
The controller, in some implementations, may be a part of or coupled to a computer that is integrated with the system, coupled to the system, otherwise networked to the system, or a combination thereof. For example, the controller may be in the “cloud” or all or a part of a fab host computer system, which can allow for remote access of the substrate processing. The computer may enable remote access to the system to monitor current progress of fabrication operations, examine a history of past fabrication operations, examine trends or performance metrics from a plurality of fabrication operations, to change parameters of current processing, to set processing steps to follow a current processing, or to start a new process. In some examples, a remote computer (e.g. a server) can provide process recipes to a system over a network, which may include a local network or the Internet. The remote computer may include a user interface that enables entry or programming of parameters and/or settings, which are then communicated to the system from the remote computer. In some examples, the controller receives instructions in the form of data, which specify parameters for each of the processing steps to be performed during one or more operations. It should be understood that the parameters may be specific to the type of process to be performed and the type of tool that the controller is configured to interface with or control. Thus as described above, the controller may be distributed, such as by comprising one or more discrete controllers that are networked together and working towards a common purpose, such as the processes and controls described herein. An example of a distributed controller for such purposes would be one or more integrated circuits on a chamber in communication with one or more integrated circuits located remotely (such as at the platform level or as part of a remote computer) that combine to control a process on the chamber.
Without limitation, example systems may include a plasma etch chamber or module, a deposition chamber or module, a spin-rinse chamber or module, a metal plating chamber or module, a clean chamber or module, a bevel edge etch chamber or module, a physical vapor deposition (PVD) chamber or module, a chemical vapor deposition (CVD) chamber or module, an atomic layer deposition (ALD) chamber or module, an atomic layer etch (ALE) chamber or module, an ion implantation chamber or module, a track chamber or module, and any other semiconductor processing systems that may be associated or used in the fabrication and/or manufacturing of semiconductor substrates.
As noted above, depending on the process step or steps to be performed by the tool, the controller might communicate with one or more of other tool circuits or modules, other tool components, cluster tools, other tool interfaces, adjacent tools, neighboring tools, tools located throughout a factory, a main computer, another controller, or tools used in material transport that bring containers of substrates to and from tool locations and/or load ports in a semiconductor manufacturing factory.
The present disclosure is a continuation of U.S. patent application Ser. No. 16/820,003, filed on Mar. 16, 2020 which is a continuation of U.S. patent application Ser. No. 15/378,854, filed on Dec. 14, 2016 (now U.S. Pat. No. 10,604,841, issued Mar. 31, 2020). The entire disclosures of the applications referenced above are incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
5597439 | Salzman | Jan 1997 | A |
5614026 | Williams | Mar 1997 | A |
5871586 | Crawley et al. | Feb 1999 | A |
5919382 | Qian et al. | Jul 1999 | A |
5994662 | Murugesh | Nov 1999 | A |
6036878 | Collins | Mar 2000 | A |
6054013 | Collins et al. | Apr 2000 | A |
6059885 | Ohashi et al. | May 2000 | A |
6089472 | Carter | Jul 2000 | A |
6148761 | Majewski et al. | Nov 2000 | A |
6200412 | Kilgore et al. | Mar 2001 | B1 |
6205869 | Schadt et al. | Mar 2001 | B1 |
6251188 | Hashimoto et al. | Jun 2001 | B1 |
6291793 | Qian et al. | Sep 2001 | B1 |
6306247 | Lin | Oct 2001 | B1 |
6364949 | Or et al. | Apr 2002 | B1 |
6387182 | Horie et al. | May 2002 | B1 |
6387207 | Janakiraman et al. | May 2002 | B1 |
6444039 | Nguyen | Sep 2002 | B1 |
6537419 | Kinnard | Mar 2003 | B1 |
6565661 | Nguyen | May 2003 | B1 |
6616767 | Zhao et al. | Sep 2003 | B2 |
6635117 | Kinnard et al. | Oct 2003 | B1 |
6727654 | Ogawa et al. | Apr 2004 | B2 |
6782843 | Kinnard et al. | Aug 2004 | B2 |
6820570 | Kilpela et al. | Nov 2004 | B2 |
6921437 | DeDontney et al. | Jul 2005 | B1 |
7156921 | Byun | Jan 2007 | B2 |
7186395 | Walsdorff et al. | Mar 2007 | B2 |
7296534 | Fink | Nov 2007 | B2 |
7479303 | Byun | Jan 2009 | B2 |
7601242 | Fink | Oct 2009 | B2 |
7846291 | Otsuki | Dec 2010 | B2 |
7850779 | Ma et al. | Dec 2010 | B2 |
7931749 | Amikura et al. | Apr 2011 | B2 |
7976631 | Burrows et al. | Jul 2011 | B2 |
8057600 | Nishimoto et al. | Nov 2011 | B2 |
8083853 | Choi et al. | Dec 2011 | B2 |
8187679 | Dickey et al. | May 2012 | B2 |
8231799 | Bera et al. | Jul 2012 | B2 |
8298370 | Byun | Oct 2012 | B2 |
8308865 | Kim et al. | Nov 2012 | B2 |
8328939 | Choi et al. | Dec 2012 | B2 |
8361275 | Tahara et al. | Jan 2013 | B2 |
8361892 | Tam et al. | Jan 2013 | B2 |
8419959 | Bettencourt et al. | Apr 2013 | B2 |
8512509 | Bera et al. | Aug 2013 | B2 |
8562785 | Kang et al. | Oct 2013 | B2 |
8608852 | Mahadeswaraswamy et al. | Dec 2013 | B2 |
8679956 | Tam et al. | Mar 2014 | B2 |
8721791 | Tiner et al. | May 2014 | B2 |
8764902 | Suzuki et al. | Jul 2014 | B2 |
8869742 | Dhindsa et al. | Oct 2014 | B2 |
8882913 | Byun et al. | Nov 2014 | B2 |
9057128 | Olgado | Jun 2015 | B2 |
9315897 | Byun et al. | Apr 2016 | B2 |
9349619 | Kawamata et al. | May 2016 | B2 |
9441791 | Mizusawa et al. | Sep 2016 | B2 |
9447499 | Roy et al. | Sep 2016 | B2 |
9476121 | Byun et al. | Oct 2016 | B2 |
9677176 | Chandrasekharan et al. | Jun 2017 | B2 |
10023959 | Sung et al. | Jul 2018 | B2 |
10316409 | Van Schravendijk | Jun 2019 | B2 |
10494717 | Sung et al. | Dec 2019 | B2 |
11053587 | Van Schravendijk | Jul 2021 | B2 |
20020017243 | Pyo | Feb 2002 | A1 |
20020179012 | Takatsu et al. | Dec 2002 | A1 |
20030010451 | Tzu et al. | Jan 2003 | A1 |
20030019580 | Strang | Jan 2003 | A1 |
20030051665 | Zhao et al. | Mar 2003 | A1 |
20030054099 | Jurgensen et al. | Mar 2003 | A1 |
20030077388 | Byun | Apr 2003 | A1 |
20030151114 | Zyl | Aug 2003 | A1 |
20030205328 | Kinnard et al. | Nov 2003 | A1 |
20040031565 | Su et al. | Feb 2004 | A1 |
20040050326 | Thilderkvist et al. | Mar 2004 | A1 |
20040082251 | Bach et al. | Apr 2004 | A1 |
20040216844 | Janakiraman et al. | Nov 2004 | A1 |
20040226507 | Carpenter et al. | Nov 2004 | A1 |
20050000430 | Jang et al. | Jan 2005 | A1 |
20050092248 | Lee et al. | May 2005 | A1 |
20050241579 | Kidd | Nov 2005 | A1 |
20050241763 | Huang et al. | Nov 2005 | A1 |
20050241765 | Dhindsa et al. | Nov 2005 | A1 |
20050241767 | Ferris et al. | Nov 2005 | A1 |
20060021703 | Umotoy et al. | Feb 2006 | A1 |
20060169201 | Hwang et al. | Aug 2006 | A1 |
20060191637 | Zajac et al. | Aug 2006 | A1 |
20060228496 | Choi et al. | Oct 2006 | A1 |
20060263522 | Byun | Nov 2006 | A1 |
20070068798 | Honda et al. | Mar 2007 | A1 |
20070089817 | Ganguli et al. | Apr 2007 | A1 |
20070110918 | Yuda et al. | May 2007 | A1 |
20070163440 | Kim et al. | Jul 2007 | A1 |
20070193515 | Jeon et al. | Aug 2007 | A1 |
20070215048 | Suzuki et al. | Sep 2007 | A1 |
20070264427 | Shinriki et al. | Nov 2007 | A1 |
20070272154 | Amikura et al. | Nov 2007 | A1 |
20080017315 | Fukuchi | Jan 2008 | A1 |
20080020146 | Choi et al. | Jan 2008 | A1 |
20080081124 | Sano et al. | Apr 2008 | A1 |
20080124463 | Bour et al. | May 2008 | A1 |
20080156264 | Fair et al. | Jul 2008 | A1 |
20080156631 | Fair et al. | Jul 2008 | A1 |
20090008034 | Tahara et al. | Jan 2009 | A1 |
20090095222 | Tam et al. | Apr 2009 | A1 |
20090095621 | Kao et al. | Apr 2009 | A1 |
20090098276 | Burrows et al. | Apr 2009 | A1 |
20090169744 | Byun et al. | Jul 2009 | A1 |
20090178615 | Kim et al. | Jul 2009 | A1 |
20090178616 | Byun | Jul 2009 | A1 |
20090202721 | Nogami et al. | Aug 2009 | A1 |
20090223449 | Ishida | Sep 2009 | A1 |
20090236313 | Qiu et al. | Sep 2009 | A1 |
20090266911 | Kim et al. | Oct 2009 | A1 |
20090320756 | Tanaka | Dec 2009 | A1 |
20100003405 | Kappeler | Jan 2010 | A1 |
20100003406 | Lam et al. | Jan 2010 | A1 |
20100048028 | Rasheed et al. | Feb 2010 | A1 |
20100184298 | Dhindsa | Jul 2010 | A1 |
20100261340 | Nijhawan | Oct 2010 | A1 |
20100263588 | Zhiyin | Oct 2010 | A1 |
20100300359 | Armour et al. | Dec 2010 | A1 |
20110003087 | Soininen et al. | Jan 2011 | A1 |
20110023782 | Han | Feb 2011 | A1 |
20110039402 | Yamazaki et al. | Feb 2011 | A1 |
20110048325 | Choi et al. | Mar 2011 | A1 |
20110052833 | Hanawa et al. | Mar 2011 | A1 |
20110065276 | Ganguly et al. | Mar 2011 | A1 |
20110073038 | Chien et al. | Mar 2011 | A1 |
20110088847 | Law et al. | Apr 2011 | A1 |
20110097492 | Kerr et al. | Apr 2011 | A1 |
20110253044 | Tam et al. | Oct 2011 | A1 |
20110256315 | Tam et al. | Oct 2011 | A1 |
20110256692 | Tam et al. | Oct 2011 | A1 |
20110308551 | Chung et al. | Dec 2011 | A1 |
20120031559 | Dhindsa et al. | Feb 2012 | A1 |
20120052216 | Hanawa et al. | Mar 2012 | A1 |
20120067971 | Byun et al. | Mar 2012 | A1 |
20120135609 | Yudovsky et al. | May 2012 | A1 |
20120161405 | Mohn et al. | Jun 2012 | A1 |
20120225564 | Adachi et al. | Sep 2012 | A1 |
20120234945 | Olgado | Sep 2012 | A1 |
20120269968 | Rayner, Jr. | Oct 2012 | A1 |
20120321910 | Sneh | Dec 2012 | A1 |
20130052804 | Song | Feb 2013 | A1 |
20130093146 | Aihara et al. | Apr 2013 | A1 |
20130109159 | Carlson | May 2013 | A1 |
20130288485 | Liang et al. | Oct 2013 | A1 |
20130341433 | Roy et al. | Dec 2013 | A1 |
20140061324 | Mohn et al. | Mar 2014 | A1 |
20140103145 | White et al. | Apr 2014 | A1 |
20140127911 | Shih et al. | May 2014 | A1 |
20140179114 | van Schravendijk | Jun 2014 | A1 |
20140235069 | Breiling | Aug 2014 | A1 |
20140272185 | Na et al. | Sep 2014 | A1 |
20140299681 | Kashyap et al. | Oct 2014 | A1 |
20150004313 | Byun et al. | Jan 2015 | A1 |
20150007770 | Chandrasekharan et al. | Jan 2015 | A1 |
20150007771 | Silva et al. | Jan 2015 | A1 |
20150377481 | Smith et al. | Dec 2015 | A1 |
20150380221 | Liu et al. | Dec 2015 | A1 |
20160032453 | Qian et al. | Feb 2016 | A1 |
20160148789 | Chen et al. | May 2016 | A1 |
20160168705 | Lind | Jun 2016 | A1 |
20160340782 | Chandrasekharan et al. | Nov 2016 | A1 |
20160348242 | Sung et al. | Dec 2016 | A1 |
20180340256 | Sung et al. | Nov 2018 | A1 |
20190301013 | Van Schravendijk | Oct 2019 | A1 |
Number | Date | Country |
---|---|---|
1574229 | Feb 2005 | CN |
101003895 | Jul 2007 | CN |
101405433 | Apr 2009 | CN |
101423936 | May 2009 | CN |
101423937 | May 2009 | CN |
102424956 | Apr 2012 | CN |
102541102 | Jul 2012 | CN |
103403843 | Nov 2013 | CN |
103521956 | Jan 2014 | CN |
103890911 | Jun 2014 | CN |
103993293 | Aug 2014 | CN |
104278254 | Jan 2015 | CN |
104282530 | Jan 2015 | CN |
104342632 | Feb 2015 | CN |
106191814 | Oct 2018 | CN |
0709875 | May 1996 | EP |
0852392 | Jul 1998 | EP |
1496138 | Jan 2005 | EP |
1961837 | Aug 2008 | EP |
2187104 | May 2010 | EP |
H05186292 | Jul 1993 | JP |
H08239775 | Sep 1996 | JP |
2000144421 | May 2000 | JP |
2002030445 | Jan 2002 | JP |
2002033311 | Jan 2002 | JP |
2003533878 | Nov 2003 | JP |
2005303292 | Oct 2005 | JP |
2006261217 | Sep 2006 | JP |
2006322074 | Nov 2006 | JP |
2006324400 | Nov 2006 | JP |
2007142363 | Jun 2007 | JP |
2007191792 | Aug 2007 | JP |
2007227789 | Sep 2007 | JP |
2008066413 | Mar 2008 | JP |
2008211219 | Sep 2008 | JP |
2010062383 | Mar 2010 | JP |
201084190 | Apr 2010 | JP |
2010232402 | Oct 2010 | JP |
2012500471 | Jan 2012 | JP |
2012533890 | Dec 2012 | JP |
2014220231 | Nov 2014 | JP |
2016531436 | Oct 2016 | JP |
20040079559 | Sep 2004 | KR |
20040091218 | Oct 2004 | KR |
100687373 | Feb 2007 | KR |
20070118836 | Dec 2007 | KR |
20110036322 | Apr 2011 | KR |
20140000168 | Jan 2014 | KR |
20140103080 | Aug 2014 | KR |
20160133373 | Nov 2016 | KR |
490705 | Jun 2002 | TW |
492045 | Jun 2002 | TW |
200710928 | Mar 2007 | TW |
201229300 | Jul 2012 | TW |
201411761 | Mar 2014 | TW |
201502310 | Jan 2015 | TW |
201509537 | Mar 2015 | TW |
WO-0129282 | Apr 2001 | WO |
WO-0188962 | Nov 2001 | WO |
WO-2009055244 | Apr 2009 | WO |
WO-2011009002 | Jan 2011 | WO |
WO-2011011532 | Jan 2011 | WO |
WO-2011044451 | Apr 2011 | WO |
WO-2012122054 | Sep 2012 | WO |
WO-2012166362 | Dec 2012 | WO |
Entry |
---|
Chinese First Office Action dated Apr. 10, 2018 issued in Application No. CN 201610361563.2. |
Chinese First Office Action dated Dec. 9, 2015 issued in Application No. CN 20140052988.X. |
Chinese First Office Action dated Mary 2, 2016 issued in Application No. CN 201410312720.1. |
Chinese Fourth Office Action dated Sep. 13, 2017 issued in Application No. CN 201410052998.X. |
Chinese Second Office Action dated Jul. 27, 2016 issued in Application No. CN 20140052988.X. |
Chinese Third Office Action dated Mar. 2, 2017 issued in Application No. CN 201410052996.X. |
International Search Report and Written Opinion Corresponding to Application No. PCT/US2018/064524 dated Apr. 1, 2019, 10 pages. |
Japanese First Office Action dated Nov. 7, 2017 issued in Application No. JP 2014-021856. |
Singapore Final Examination Report dated Jan. 12, 2016 issued in Application No. SG 201401171-2. |
Singapore Search Report and Written Opinion dated Jul. 7, 2015 issued in Application No. SG 201401171-2. |
Taiwan Examination and Search Report dated Apr. 11, 2017 issued in Application No. TW 102147584. |
Taiwan Examination and Search Report dated May 12, 2017 issued in Application No. TW 103104956. |
Taiwan Examination and Search Report dated Oct. 13, 2016 issued in Application No. TW 102122169. |
U.S. Appl. No. 13/842,054, filed Mar. 15, 2013, entitled “Radical Source Design for Remote Plasma Atomic Layer Deposition.” |
U.S. Appl. No. 13/934,597, filed Jul. 3, 2013, entitled “Multi-Plenum, Dual-Temperature Showerhead.” |
U.S. Final Office Action dated May 18, 2016 issued in U.S. Appl. No. 13/842,054. |
U.S. Final Office Action dated Sep. 16, 2016 issued in U.S. Appl. No. 13/934,597. |
U.S. Notice of Allowance dated Apr. 14, 2017 issued in U.S. Appl. No. 13/934,597. |
U.S. Notice of Allowance dated Jan. 10, 2017 issued in U.S. Appl. No. 13/934,597. |
U.S. Notice of Allowance dated Jan. 15, 2016 issued in U.S. Appl. No. 13/531,254. |
U.S. Notice of Allowance dated Mar. 8, 2018 issued in U.S. Appl. No. 15/163,594. |
U.S. Notice of Allowance dated May 12, 2016 issued in U.S. Appl. No. 13/531,254. |
U.S. Office Action dated Apr. 12, 2017 issued in U.S. Appl. No. 13/842,054. |
U.S. Office Action dated Apr. 7, 2016 issued in U.S. Appl. No. 13/934,597. |
U.S. Office Action dated Dec. 3, 2015 issued in U.S. Appl. No. 13/842,054. |
U.S. Office Action dated Mar. 13, 2015 issued in U.S. Appl. No. 13/531,254. |
U.S. Office Action dated Oct. 20, 2017 issued in U.S. Appl. No. 13/842,054. |
U.S. Office Action dated Sep. 8, 2016 issued in U.S. Appl. No. 13/531,254. |
U.S. Office Action dated Sep. 17, 2015 issued in U.S. Appl. No. 13/531,254. |
Cao, et al., “Development of a scanning probe microscopy integrated atomic layer deposition system for in situ successive monitoring of thin film growth” Review of Scientific Instruments 89, 123702 (2018) pp. 1-8. https://doi.org/10.1063/1.5042463. |
Chen, et al., “Advances in Remote Plasma Sources For Cleaning 300 mm and Flat Panel CVD Systems” Semiconductor Magazine, , Aug. 2003, pp. 1-6. |
Chinese First Office Action dated Jun. 18, 2020 issued in Application No. CN 201811101686.8. |
Chinese Second Office Action dated Feb. 22, 2021 issued in Application No. CN 201811101686.8. |
Chinese Third Office Action dated Aug. 2, 2021 issued in Application No. CN 201811101686.8. |
International Search Report and Written Opinion dated Apr. 9, 2018 issued in Application No. PCT/US2017/066411. |
Japanese First Office Action dated Apr. 15, 2019 issued in Application No. JP 2018-087939. |
Japanese First Office Action dated Feb. 13, 2018 issued in Application No. JP 2014-130967. |
JP Office Action dated Dec. 21, 2021, in Application No. JP2019-531737 with English translation. |
Korean Decision for Grant of Patent dated Jul. 29, 2020 issued in Application No. KR 10-2013-016139. |
Korean First Office Action dated Aug. 28, 2019 issued in Application No. KR 10-2013-0071554. |
Korean First Office Action dated Mar. 10, 2020 issued in Application No. KR 10-2013-0161939. |
Korean First Office Action dated Nov. 18, 2020 issued in Application No. KR 10-2020-0142328. |
KR Office Action dated Feb. 15, 2022, in Application No. KR10-2019-7018989 with English Translation. |
Oviroh, Peter Ozaveshe, et al., “New development of atomic layer deposition: processes, methods and applications” Science and Technology of Advanced Materials (2019) vol. 20, No. 1, pp. 465-496. https://doi.org/10.1080/14686996.2019.1599694. |
Paul, et al., “Anti reflection Coating on PM MA Substrates by Atomic Layer Deposition” Coatings 2020, 10, 64; pp. 1-13. doi: 10.3390/coatings 10010064Cpatomgs. |
Taiwan First Office Action dated Jul. 3, 2018 issued in Application No. TW 107110096. |
Taiwanese First Decision of Refusal dated Nov. 20, 2017 issued in Application No. TW 102147584. |
Taiwanese First Office Action dated Aug. 7, 2019 issued in Application No. TW 105116200. |
U.S. Advisory Action dated Oct. 2, 2019 in U.S. Appl. No. 15/378,854. |
U.S. Advisory Action dated Dec. 6, 2018 issued in U.S. Appl. No. 13/934,620. |
U.S. Final office Action dated Jul. 15, 2019 in U.S. Appl. No. 15/378,854. |
U.S. Final Office Action dated Jun. 22, 2017 issued in U.S. Appl. No. 13/934,620. |
U.S. Final office Action dated Oct. 31, 2019 in U.S. Appl. No. 15/378,854. |
U.S. Final Office Action dated Sep. 13, 2018 issued in U.S. Appl. No. 13/934,620. |
U.S. Non-Final office Action dated Mar. 5, 2019 in U.S. Appl. No. 15/378,854. |
U.S. Notice of Allowance dated Nov. 20, 2019 in U.S. Appl. No. 15/378,854. |
U.S. Notice of Allowance dated Apr. 15, 2021, in U.S. Appl. No. 16/820,003. |
U.S. Notice of Allowance dated Feb. 11, 2019 issued in U.S. Appl. No. 13/842,054. |
U.S. Notice of Allowance dated Jul. 30, 2019 issued in U.S. Appl. No. 16/035,491. |
U.S. Notice of allowance dated Mar. 22, 2019 issued in U.S. Appl. No. 16/035,491. |
U.S. Notice of Allowance dated Mar. 3, 2021 issued in U.S. Appl. No. 16/434,043. |
U.S. Notice of Allowance dated Mar. 8, 2018 issued in U.S. Appl. No. 13/934,620. |
U.S. Notice of Allowance dated May 30, 2018 issued in U.S. Appl. No. 13/842,054. |
U.S. Office Action dated Nov. 20, 2017 issued in U.S. Appl. No. 13/934,620. |
U.S. Office Action dated Nov. 28, 2018, issued in U.S. Appl. No. 16/035,491. |
U.S. Office Action dated Oct. 12, 2016 issued in U.S. Appl. No. 13/934,620. |
U.S. Restriction Requirement dated Dec. 11, 2018 in U.S. Appl. No. 15/378,854. |
CN Office Action dated Nov. 25, 2022 in Application No. CN201780077684.7 with English translation. |
Number | Date | Country | |
---|---|---|---|
20210371982 A1 | Dec 2021 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 16820003 | Mar 2020 | US |
Child | 17401261 | US | |
Parent | 15378854 | Dec 2016 | US |
Child | 16820003 | US |