The present invention relates to a method of manufacturing a multi-layered substrate and, in particular, to a method of manufacturing a multi-layered substrate by an inkjet process.
A method of manufacturing a wiring substrate or a circuit substrate by a printing method is used because the process can be performed at low cost compared to a method of manufacturing a wiring substrate or a circuit substrate by repeating a process of coating a thin film and a process of photolithography.
Although forming a conductive pattern by an inkjet method is known as a technique that uses an additive process (see for example, JP-A-2004-6578), a method of manufacturing a multi-layered substrate having an electronic component embedded therein by an inkjet process is not known in the related art.
An advantage of some aspects of the present teachings is that it provides a multi-layered substrate having an electronic component embedded therein by an inkjet process.
According to an aspect of the present teachings, there is provided a method of manufacturing a multi-layered substrate. The method includes steps of providing an electronic component on a surface so that a terminal of the electronic component faces upward, and providing a first insulation pattern on the surface so as to fill a step generated due to a thickness of the electronic component.
It is preferable that the method further includes steps of providing a second insulation pattern on the first insulation pattern to form a via hole on an edge of the terminal, and providing a conductive post in the via hole.
It is preferable that the method further includes steps of providing a conductive post on the terminal, and providing a second insulation pattern on the first insulation pattern so as to surround the sides of the conductive post.
It is preferable that the method further includes steps of providing a conductive pattern on the second insulation pattern to be connected to the conductive post, and providing a third insulation pattern on the second insulation pattern to eliminate a step generated due to a thickness of the conductive pattern.
It is preferable that the method further includes steps of providing a second insulation pattern on the first insulation pattern to form a via hole on an edge of the terminal, and forming a conductive pattern on the terminal and the second insulation pattern.
It is preferable that the method further includes providing a third insulation pattern on the second insulation pattern to fill a step generated due to a thickness of the conductive pattern.
According to another aspect of the present teachings, there is provided a method of manufacturing a multi-layered substrate, including steps of providing an electronic component on a surface so that a bump of the electronic component faces upward, providing a first insulation pattern on the surface to cover the electronic component except for the bump, providing a second insulation pattern on the first insulation pattern to surround the sides of the bump, and providing a conductive pattern on the second insulation pattern to be connected to the bump.
According to another aspect of the present teachings, there is provided a method of manufacturing a multi-layered substrate, including steps of providing an electronic component on a conductive pattern so that a terminal of the electronic component comes in contact with a surface of the conductive pattern, and providing an insulation pattern to fill at least a step generated due to a thickness of the electronic component.
According to another aspect of the present teachings, there is provided a method of manufacturing a multi-layered substrate including steps of providing a conductive pattern on a surface so that the conductive pattern contacts a terminal of an electronic component provided on the surface, and providing an insulation pattern on the surface to fill at least a step generated due to the thickness of the electronic component.
According to the present teachings, a step generated due to a thickness of the electronic component is filled. Accordingly, it is possible to form a layer covering, the electronic component by an inkjet process. Furthermore, it is possible to manufacture a multi-layered substrate having an electronic component embedded therein by an inkjet process.
The invention will be described with reference to the accompanying drawings, wherein like numbers reference like elements.
An embodiment describes a method of manufacturing a multi-layered substrate 1 as shown in
As shown in
In the present embodiment, the electronic components 40 and 41 have the same thickness. The electronic component 40 is a surface-mounted resistor. The electronic component 41 is a chip inductor. In another embodiment, the electronic components 40 and 41 may be rectangular chip resistors, rectangular chip thermistors, diodes, varistors, LSI bare chips, or LSI packages.
As shown in
An ‘inkjet sub-process’ includes a process of forming a layer, film, or pattern on a surface of an object by using, for example, a liquid droplet ejection apparatus 100, which is described in
The ‘inkjet sub-process’ may also include a process of making a surface lyophilic with respect to the insulation material 111A or conductive material 111B. In addition, the ‘inkjet sub-process’ may include a process of making a surface lyophobic with respect to the insulation material 111A or conductive material 111B.
In addition, the ‘inkjet sub-process’ may include a process of activating a layer, film, or pattern formed on a surface of an object. In a case using the insulation material 111A, the activation process includes a process of curing a resin material contained in the insulation material 111A and/or a process of vaporizing a solvent from the insulation material 111A. In a case using the conductive material 111B, the activation process is a process of welding or sintering conductive particles contained in the conductive material 111B. The activation process will be described in more detail below.
It should be understood that one or more ‘inkjet sub-processes’ may be collectively referred to as an ‘inkjet process’.
Returning to
As a result, the upper surface of the insulation sub-pattern 10 is substantially flat. In the present embodiment, the upper surface of the insulation sub-pattern 10 is substantially flat with respect to a surface of the base layer 5. However, when the upper surface of the insulation sub-pattern 10 is substantially flat, the upper surface of the insulation sub-pattern 10 may be inclined with respect to the surface of the base layer 5. The expression of a ‘substantially flat’ surface implies a surface on which a pattern can be formed by the inkjet sub-process, or a surface on which an electronic component can be provided.
Next, as shown in
Next, as shown in
In addition, in the present embodiment, the sum of thicknesses of the insulation sub-patterns 10 and 11 is equal to a thickness of each of the electronic components 40 and 41. Accordingly, the stacked insulation sub-patterns 10 and 11 are used to fill a step generated due to the thickness of the electronic components 40 and 41. In addition, in the present embodiment, the upper surface of the insulation sub-pattern 11 is formed to be at the same level as the upper surface of each of the electronic components 40 and 41. In the present embodiment, the two insulation sub-patterns 10 and 11 are also referred to as an ‘insulation pattern P1’.
Next, as shown in
As shown in
As shown in
Next, as shown in
As shown in
As shown in
Next, as shown in
As shown in
The thickness of the insulation sub-pattern 14 may be thinner than the thickness (i.e., height) of the conductive posts 24A, 24B, 24C, 24D, and 24E. When the insulation sub-pattern 14 is smaller in thickness than the conductive posts 24A, 24B, 24C, 24D, and 24E, edges of the conductive posts 24A, 24B, 24C, 24D, and 24E are projected from the surface of the insulation sub-pattern 14. In this case, the conductive posts 24A, 24B, 24C, 24D, and 24E are securely connected to a conductive pattern which will be subsequently provided on the insulation sub-pattern 14.
Subsequently, the above-mentioned process is performed repeatedly and the multi-layered substrate 1 shown in
In the multi-layered substrate 1 of
The insulation sub-patterns 10, 11, 12, 13, 14, 15, 16, 17, 18, and 19 and the resist layer RE individually or in combination with other insulation sub-patterns are used to fill a step formed due to the conductive pattern, conductive post, or electronic component.
Thus, a plurality of layers provided on the multi-layered substrate 1 can be formed one-by-one by the inkjet process. Accordingly, if there is a defect in the pattern, it can be corrected by the inkjet sub-process before the following layers are stacked, thus improving the yield of the multi-layered substrate 1.
Hereinafter, a method of manufacturing the multi-layered substrate 1 will be described in detail by placing priority to each of the three sections 1A, 1B, and 1C. Section 1A is a part in which the electronic components 40 and 41 are formed. Section 1B is a part in which a capacitor 42 serving as an electronic component is formed. Section 1C is a part in which an LSI bare chip 44 serving as an electronic component is formed.
1. Process of Making a Lyophilic Surface
As shown in
Next, as shown in
When the electronic components 40 and 41 are provided on the base layer 5, a step is formed on the base layer 5 due to the thickness of the electronic components 40 and 41. As shown in
As described above, the insulation pattern P1 consists of two insulation sub-patterns 10 and 11 which are stacked. The inkjet sub-process of forming each of the insulation sub-patterns 10 and 11 will be described in detail.
2. Insulation Sub-Pattern 10
As shown in
In specific detail, as shown in
Next, as described in
Here, in addition to the process of irradiating light, the activation process of
3. Insulation Sub-Pattern 11
Next, as shown in
The thickness of the insulation sub-pattern 11 is set such that the sum of the thickness of the insulation sub-pattern 10 and the thickness of the insulation sub-pattern 11 is substantially equal to the thickness of the electronic components 40 and 41. As a result, the insulation sub-patterns 10 and 11 serve to eliminate a step formed between the surface of the base layer-5 and the electronic components 40 and 41.
As described above, the two stacked insulation sub-patterns 10 and 11 constitute the insulation pattern P1. When the electronic component 40 (41) has a relatively small thickness, the insulation pattern P1 may be formed of a layer of insulation sub-pattern. When the electronic component 40 (41), has a relatively large thickness, the insulation pattern P1 may be formed of three or more layers of insulation sub-pattern.
The surface of the insulation pattern P1 is formed to be at the same level as the surface of the electronic components 40 and 41, thereby obtaining almost a continuous or flat surface S1. When the surface S1 is substantially flat, the surface S1 may be inclined with respect to the base layer 5.
4. Via Hole V1
Next, a via hole V1 is provided on each of the terminals 40A, 40B, 41A, and 41B. The outer shape of the via hole V1 is formed on the edge by the insulation sub-pattern 12 provided on the surface S. As described below, in the embodiment, the insulation sub-pattern 12 is formed on the surface S1 by the inkjet sub-process.
As shown in
In the embodiment, post-forming regions 37A and 37B are formed on the terminals 40A and 40B, respectively. Similarly, post-forming regions 38A and 38B are formed on the terminals 41A and 41B, respectively. The post-forming regions 37A, 37B, 38A, and 38B are positions where conductive posts are provided. A region surrounding each of the post-forming regions 37A, 37B, 38A, and 38B is hereinafter referred to as a ‘base region 39’.
Next, an edge 12A is formed on the four base regions 39 by the inkjet sub-process.
As shown in
Since the four base regions 39 are part of the lyophobic surface S1, the base region 39 becomes lyophobic with respect to the insulation material 111A. That is, the liquid droplets D1 of the insulation material 111A placed on the base region 39 are less diffused. Thus, the four base regions 39 are suitable for taking the via holes V1 by the inkjet sub-process. In addition, in the present embodiment, the lyophobic surface S1 implies a surface of the FAS film covering the surface S1.
Next, as shown in
Next, an inner part 12B surrounding the four edges 12A is formed by the inkjet sub-process.
As shown in
The liquid droplet D1 of the insulation material 111A is ejected on the surface S1 to form a material pattern of the insulation material 111A. As described above, the surface S1 is lyophilic with respect to the insulation material 111A due to the above-mentioned process of making the surface S1 lyophilic. As a result, insulation material 111A on the surface S1 may be wet and diffused in a wide range.
Even though not shown, an inner part 12B is formed from the cured material pattern. In specific detail, light having a wavelength in an ultraviolet range is irradiated on the material pattern for about 60 seconds to obtain the inner part 12B. In the embodiment, the wavelength of the light to be irradiated on the material pattern is 365 nm.
From the above-mentioned processes, as shown in
5. Conductive Posts 21A, 21B, 21C, and 21D
After forming the four via holes V1, the conductive posts 21A, 21B, 21C, and 21D are provided in the four via holes V1 by the inkjet sub-process.
As shown in
As shown in
6. Conductive Patterns 23A and 23B
Next, as shown in
The conductive pattern 23A is conductively connected to the conductive post 21A exposed on the insulation sub-pattern 12. Since the conductive post 21A and the terminal 40A are conductively connected to each other, the conductive pattern 23A is conductively connected to the electronic component 40 through the conductive post 21A. Similarly, the conductive pattern 23B is conductively connected to two conductive posts 21B and 21C exposed on the insulation sub-pattern 12. The conductive post 21B and the terminal 40B are conductively connected to each other, and the conductive post 21C and the terminal 41A are conductively connected to each other. Accordingly, the conductive pattern 23B is used to connect in series the electronic component 40 and the electronic component 41. The conductive post 23C is conductively connected to the conductive post 21D exposed in the insulation sub-pattern 12. Since the conductive post 21D and the terminal 41B are conductively connected to each other, the conductive post 23C is conductively connected to the electronic component 41 through the conductive post 21D.
7. Insulation Pattern 13
Next, as shown in
From the above-mentioned processes, the section 1A shown in
The exemplary example is basically equal to the first exemplary example except for the inkjet sub-process of forming the conductive posts 21A, 21B, 21C, and 21D and the inkjet sub-process of forming the insulation sub-pattern 12.
As described in the first exemplary example, two electronic components 40 and 41 are provided on a predetermined position of the base layer 5. Next, an insulation pattern P1 is formed by the inkjet process. As described above, the insulation pattern P1 consists of stacked insulation sub-patterns 10 and 11, and is used to fill a step generated due to the thickness of the base layer 5. In addition, the surface of the insulation pattern P1 and the surfaces of the electronic components 40 and 41 form a single ‘surface S1’.
1. Conductive Posts 21A, 21B, 21C, and 21D
In the embodiment, the conductive posts 21A, 21B, 21C, and 21D are formed by the inkjet sub-process prior to forming the insulation sub-pattern 12. A detailed description thereof will be given below.
The liquid droplets D2 of the conductive material 111B are ejected on the terminals 40A, 40B, 41A, and 41B and a material pattern is provided. The material pattern is temporarily dried, and a sub post is formed on each of the terminals 40A, 40B, 41A, and 41B. The temporary drying process is performed such that at least the surface of the material pattern is dried. More specifically, dry air may be sprayed or infrared light may be irradiated for the temporary drying process.
The ejection of the liquid droplets D2 and the temporary drying process are repeatedly performed, and four sub posts are stacked on each of the terminals 40A, 40B, 41A, and 41B.
Next, the four sub posts stacked on the terminals 40A, 40B, 41A, and 41B are activated. In the embodiment, the base layer 5 is heated on a hot plate at a temperature of 150° C. for 30 minutes. In this case, a solvent remaining in each of the sub posts is vaporized and, at the same time, conductive particles in each of the sub posts are sintered or melted to be fixed. As a result, as shown in
2. Insulation Pattern 12
Next, the insulation pattern 12 is provided on the surface S1 by the inkjet sub-process. A detailed description thereof will be given below.
As shown in
Next, even though not shown, the liquid droplets D1 of the insulation material 111A are ejected, and a material pattern of the insulation material 111A is provided on the surface S1. The material pattern is preferably provided such that the material pattern of the insulation material 111A and a side of the conductive posts 21A, 21B, 21C, and 21D do not contact each other. At this time, preferably, there is a gap between the material pattern of the insulation material 111A and the conductive posts 21A, 21B, 21C, and 21D.
Next, although not shown, the surface S1 exposed at a gap between the material pattern of the insulation material 111A and the conductive posts 21A, 21B, 21C, and 21D is made to be lyophilic one more time. In specific detail, light having a wavelength of 172 nm is irradiated on the surface S1. As a result, the lyophilicity of the surface S1 with respect to the insulation material 111A is increased. Further, the material pattern of the insulation material 111A is wet and diffused until it contacts the sides of the conductive posts 21A, 21B, 21C, and 21D. That is, the gaps between the material pattern of the insulation material 11A and the conductive posts 21A, 21B, 21C, and 21D are filled with the material pattern by performing the process of making the surface lyophilic again.
In the embodiment, by the second process of making the surface lyophilic, the material pattern of the insulation material 111A is further wet and diffused. By doing so, it is possible to securely come in contact with the material pattern of the insulation material 111A and the sides of the conductive posts 21A, 21B, 21C, and 21D with each other and, at the same time, to securely expose the upper sides of the conductive posts 21A, 21B, 21C, and 21D from the material pattern of the insulation material 111A. As a result, the conductive posts 21A, 21B, 21C, and 21D pass through the insulation sub-pattern 12 reliably.
The material pattern of the insulation material 111A is then activated. In specific detail, light having a wavelength in an ultraviolet range is irradiated on the insulation material pattern to cure the insulation material pattern. Then, as a polymerization process of a monomer in the material pattern of the insulation material 111A is performed, the insulation sub-pattern 12 can be obtained from the insulation pattern of the insulation material 111A as shown in
3. Conductive Patterns 23A and 23B
Next, as described in the first exemplary example, the conductive patterns 23A and 23B are formed on the insulation sub-pattern 12 by the inkjet sub-process. The conductive post 23C is formed on the conductive post 21D by the inkjet sub-process. As described in the first exemplary example, the insulation pattern 13 is formed on the insulation sub-pattern 12 by the inkjet sub-process.
When the above-mentioned process is performed, as described in
(1) In the first and second exemplary examples, the conductive post 21A and conductive pattern 23A that join with each other are individually formed by the inkjet sub-process. However, when the depth of the via hole V1 is relatively small, the conductive pattern 23A may be directly connected to the terminal 40A without forming the conductive post 21A. In this case, as described in the first exemplary example, the insulation sub-pattern 12, in which the via hole is formed on an edge of the terminal 40A, is formed on the insulation sub-pattern 11 by the inkjet sub-process. Subsequently, the conductive pattern 23A is formed on the terminal 40A and the insulation sub-pattern 12 by the inkjet sub-process.
(2) In the first and second exemplary examples, the conductive posts 21A, 21B, 21C, and 21D are formed on the terminals 40A, 40B, 41A, and 41B by the inkjet sub-process. When each of the terminals 40A, 40B, 41A, and 41B is formed in a bump-shape, the conductive posts 21A, 21B, 21C, and 21D may not be formed. In this case, the electronic components 40 and 41 are provided on the base layer 5 so that bumps of the electronic components 40 and 41 can face upward. The insulation pattern P1 is formed on the base layer 5 by the inkjet process. The insulation pattern P1 is formed to cover the electronic components 40 and 41 except for the bumps. The insulation sub-pattern 12 is formed on the insulation pattern P1 by the inkjet sub-process. The insulation sub-pattern 12 is formed to surround the sides of the bump. Subsequently, if necessary, the conductive pattern 23A connected to the bump may be formed on the insulation sub-pattern 12 by the inkjet sub-process.
A process of forming the section 1B of
As shown in
Next, as shown in
In the exemplary example, the sum of the thickness of the insulation sub-pattern 11, the thickness of the insulation sub-pattern 12, and the insulation sub-pattern 13 is equal to the thickness of the capacitor 42. Accordingly, the three stacked insulation sub-patterns 11, 12, and 13 are used to fill a step generated due to the thickness of the capacitor 42. In addition, the upper surface of the insulation sub-pattern 13 located at the uppermost part and the upper surface of the capacitor 42 form almost a single, flat surface. In the embodiment, the three insulation sub-patterns 11, 12, and 13 are collectively referred to as an ‘insulation pattern P2.’
As shown in
The section 1B of
A process of forming the section 1C of
As shown in
As shown in
As shown in
As, described with reference to the insulation sub-patterns 10 and 11 of the first exemplary example, the inkjet sub-process of forming the insulation sub-pattern 18 may include the inkjet sub-process of forming each of the insulation sub-patterns. In addition, as shown in
A method of embedding the electronic component 40 in the section 1A of
As shown in
As shown in
As shown in
When the thickness of the electronic component 40 is relatively small, the insulation pattern P1′ may be formed of a layer of insulation sub-pattern. In addition, when the thickness of the electronic component 40 is relatively larger than, the insulation pattern P1′ may be formed of three or more insulation sub-patterns.
As shown in
Next, the conductive pattern 27 is formed on the insulation sub-pattern 11 by the inkjet sub-process. The conductive pattern 27 is formed to be connected to the conductive post 21A. Subsequently, the insulation sub-pattern 13 is formed on the insulation sub-pattern 12 by the inkjet sub-process. The insulation sub-pattern 13 is formed to surround the sides of the conductive pattern 27. The insulation sub-pattern 13 and the conductive pattern 27 are substantially equal in thickness to each other. Accordingly, the insulation sub-pattern 13 serves to eliminate a step generated due to the thickness of the conductive pattern 27.
In addition, the insulation sub-pattern 14 is formed on the insulation sub-pattern 13 and the conductive pattern 27 by the inkjet sub-process. As described above, the electronic component 40 can be embedded in the multi-layered substrate 1 in the above-mentioned process.
A. Structure of Liquid Droplet Ejection Apparatus
The methods of manufacturing the multi-layered substrate in the first to fifth exemplary examples are implemented in a plurality of liquid droplet ejection apparatuses. The number of liquid droplet ejection apparatuses may be equal to the number of the above-mentioned inkjet sub-processes or the number of kinds of the following aqueous materials 111. The structures of the liquid droplet ejection apparatuses are basically the same. Thus, the structure and function of the liquid droplet ejection apparatus 100 shown in
The liquid droplet ejection apparatus 100 shown in
The ejection head unit 103 holds a head 114 (see
The stage 106 serves to fix the base layer 5. The stage 106 also serves to fix a position of the base layer 5 by using, absorption force. As described above, the base layer 5 is a flexible substrate made of polyimide and is shaped like a tape. Both end portions of the base layer 5 are fixed to a pair of reels (not shown).
The first position control unit 104 is fixed at a predetermined position from the ground stage GS by the support unit 104a. The first position control unit 104 serves to move the ejection head unit 103 in X-axis direction and Z-axis direction orthogonal to the X-axis direction according to a signal from the controller 112. In addition, the first position control unit 104 serves to rotate the ejection head unit 103 around an axis parallel to the Z-axis. In the exemplary example, the Z-axis direction is a direction parallel to a vertical direction (i.e., in a direction of acceleration of gravity).
The second position control unit 108 moves the stage 106 on the ground stage GS in Y-axis direction according to a signal from the controller 112. The Y-axis direction is a direction orthogonal to both the X-axis and Z-axis directions.
The structure of the first position control unit 104 and second position control unit 108 can be achieved by a well-known X-Y robot using a linear motor or servo motor a detailed description thereof, however, will be omitted. In the present description, the first position control unit 104 and the second position control unit 108 are also referred to as a ‘robot’ or a ‘scanning unit’.
As described above, the ejection head unit 103 is moved in the X-axis direction by the first position control unit 104. The base layer 5 is moved in the Y-axis direction along with the stage 106 by the second position control unit 108. As a result, a position of the head 114 relative to the base layer 5 is changed. In specific detail, the ejection head unit 103, the head 114, or the nozzle 118 (see
The controller 112 is configured to receive, from an external information processing apparatus, the ejection data indicating a relative position on which the liquid droplet D of the aqueous material 111 is ejected. The controller 112 stores the ejection data in a storage unit, and controls the first position control unit 104, the second position control unit 108, and the head 114 according to the stored ejection data. The ejection data implies data used for providing the aqueous material 111 on the base layer 5 in a predetermined pattern. In the embodiment, the ejection data is recorded in bitmap form.
The liquid droplet ejection apparatus 100 relatively structured in this manner moves the nozzle 118 (see
In the present specification, a part on which the liquid droplet of the aqueous material 111 is placed is also denoted as an ‘ejected part.’ A part on which the liquid droplet is diffused is also denoted as a ‘coated part.’ The ‘ejected part’ and the ‘coated part’ may be formed by performing a surface modification process on a surface of an object such that the aqueous materials 111 indicate a desired contact angle. However, when the surface of the object represents a desired lyophobicity or lyophilicity with respect to the aqueous material 111 without performing the surface modification process (i.e., when the placed aqueous material 111 indicates a desired contact angle on the surface of the object), the surface of the object may be the ‘ejected part’ or the ‘coated part.’
Returning to
B. Head
As shown in
The liquid collection part 129 is positioned between the vibrating plate 126 and the nozzle plate 128. The aqueous material 111 supplied from an external tank (not shown) through a hole 131 is filled in the liquid collection part 129. In addition, the plurality of partitions 122 is positioned between the vibrating plate 126 and the nozzle plate 128.
The cavity 120 is surrounded by the vibrating plate 126, nozzle plate 128, and a pair of partitions 122. Since the cavity 120 is provided corresponding to the nozzle 118, the number of cavities 120 is equal to the number of nozzles 118. The aqueous material 111 is supplied from the liquid collection part 129 to the cavity 120 through a supply hole 130 positioned between a pair of partitions 122. In the present embodiment, the nozzle has a diameter of about 27 μm.
A plurality of vibrators 124 are located on the vibrating plate 126 that correspond to each of the cavities 120. Each of the vibrators 124 includes a piezo actuator 124C, and a pair of electrodes 124A and 124B having the piezo actuator 124C interposed therebetween. The controller 112 applies a driving voltage between the electrodes 124A and 124B to eject the liquid droplet D of the aqueous material 111 from a corresponding nozzle 118. The material ejected from the nozzle 118 has a volume ranging from 0 pl to 42 pl (picoliter). In addition, the nozzle 118 is adjusted such that the liquid droplet D of the aqueous material 111 is ejected from the nozzle 118 in the Z-axis direction.
In the present specification, a part that includes one nozzle 118, a cavity 120 corresponding to the nozzle 118, and a vibrator 124 corresponding to the cavity 120 is also denoted as an ‘ejection part’ 127. One head 114 has as many of the ejection parts 127 as the number of nozzles 118. The ejection part 127 may have an electricity-heat conversion element instead of the piezo actuator. That is, the ejection part 127 may have a configuration of ejecting a material by the use of thermal expansion of the material due to the electricity-heat conversion element.
C. Controller
Next, the configuration of the controller 112 will be described. As shown in
The light source driver 205 is connected to a light irradiating unit 140 so that they can communicate with each other. In addition, the scan driver 206 is connected to a first position control unit 104 and a second position control unit 108 so that they can communicate with one another. Similarly, the head driver 208 is connected to a head 114 so that they can communicate with each other.
The input buffer memory 200 receives ejection data for ejecting the liquid droplet D of the aqueous material 111 from an external information processing unit (not shown) located at the outside of the liquid droplet ejection apparatus 100. The input buffer memory 200 supplies the ejection data to the processing unit 204, and the processing unit 204 stores the ejection data in the memory unit 202. In
The processing unit 204 applies data indicating a position of the nozzle 118 relative to a placed part to the scan driver 206 based on the ejection data in the memory unit 202. The scan driver 206 applies the data and a stage driving signal depending on a predetermined ejection cycle to the first and second position control units 104 and 108. As a result, a position of the ejection head unit 103 relative to the ejected subject is changed. On the other hand, the processing unit 204 applies an ejection signal required for ejecting the aqueous material 111 to the head 114 based on the ejection data stored in the memory unit 202. As a result, the liquid droplet b of the aqueous material 111 is ejected from the nozzle 118 corresponding to the head 114.
In addition, the processing unit 204 turns on or off the light irradiating unit 140 based on the ejection data in the memory unit 202. In specific detail, the processing unit 204 supplies a turn-on or turn-off signal to the light source driver 205 so that the light source driver 205 can set the condition of the light irradiating unit 140.
The controller 112 is a computer including CPU, ROM, RAM, and bus. Accordingly, the controller 112 implements the above-mentioned functions by executing software programs stored in the ROM by using the CPU. The controller 112 may be realized with a dedicated circuit (hardware).
D. Aqueous Material
The ‘aqueous material 111’ implies a material having the highest viscosity until it can be ejected as a liquid droplet D from the nozzle 118 of the head 114. The aqueous material 111 may have an aqueous or oily nature. The aqueous material 111 may include a solid substance as long as it is a fluid. Here, the aqueous material 111 preferably has a viscosity in the range of 1 mPa·s to 50 mPa·s. In case of a viscosity having more than 1 mPa·s, the area around the nozzle 118 is seldom contaminated by the aqueous material 111 when the liquid droplet D of the aqueous material 111 is ejected. On the other hand, in the case of when the viscosity is less than 50 mPa·s, the nozzle 118 seldom becomes clogged, such that the liquid droplet D can be smoothly ejected.
The conductive material 111B is a kind of aqueous material 111. The conductive material 111B of the embodiment includes a silver particle having an average diameter of about 10 nm and a dispersion medium. In the conductive material 111B, the silver particles are consistently dispersed in the dispersion medium. The silver particle may be coated with a coating material. The coating material is a compound which is coordinated with a silver atom.
In addition, a particle having an average diameter of about 1 nm to several hundred nm is denoted as a ‘nano particle.’ The conductive material 111B includes a silver nano particle.
The dispersion medium (or solvent) is not particularly restricted as long as it can disperse conductive particles such as silver particles and does not cause aggregation. Examples of the dispersion medium include water; an alcohol such as methanol, ethanol, propanol, or butanol; a hydrocarbon compound such as n-heptane, n-octane, decane, dodecan, tetradecan, toluene, xylene, cymene, durene, indene, dipentene, tetrahydronaphthalene, decahydronaphthalene, or cyclohexylbenzene; an ether compound such as ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol methylethyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol methylethyl ether, 1,2-dimetohxyethane, bis(2-methoxyethyl)ether, or p-dioxane; and a polar compound such as propylene carbonate, 7-butyrolacton, N-methyl-2-pyrrolidone, dimethylformamide, dimethylsulfoxide, or cyclohexanone. In terms of dispersibility of the conductive particles, a stability of the dispersion, and easy application the of liquid droplet ejection method, water, alcohol, hydrocarbon compounds, and ether compounds are preferable. Water and hydrocarbon compounds are more preferable.
The above-mentioned insulation material 111A is also a kind of aqueous material 111. The insulation material 111A of the embodiment includes a photosensitive resin material. In specific detail, the insulation material 111A includes photopolymerization initiator, acrylic acid monomer, and/or oligomer.
The conductive material 111B of the above-mentioned embodiment includes silver nanoparticles. However, nanoparticles of other metals may be used instead of silver nanoparticles. Examples of other metals include gold, platinum, copper, palladium, rhodium, osmium, ruthenium, iridium, iron, tin, zinc, cobalt, nickel, chromium, titanium, tantalum, tungsten, indium, or an alloy formed by combining two or more of the metals. However, since silver is reduced at relatively low temperatures, it is easy to handle. Accordingly, when a liquid droplet ejection apparatus is used, the conductive material 111B including silver nanoparticles is preferably used.
In addition, the conductive material 111B may include an organometallic compound instead of metal nanoparticles. The organometallic compound as used herein is a compound from which a metal is extracted by decomposition under heating. Examples of the organometallic compound include chlorotriethylphosphine gold(I), chlorotrimethylphosphine gold(I), chlorotriphenylphosphine gold(I), silver(I) 2,4-pentanedionate complex, trimethylphosphin(hexafluoroacetylacetonato) silver(I) complex, copper(I) hexafluoropentandionatocyclooctadiene complex, and the like.
Accordingly, the metal contained in the aqueous conductive material 111B may have a particle form, such as nanoparticles, or a compound, such as organometallic compound.
In addition, the conductive material 111B may include a highly polymerized soluble material, such as polyaniline, polythiophene, or polyphenylvinylene.
As described in the sixth exemplary example, the silver nanoparticles as the conductive material 111B may be coated by a coating material such as organic material. Examples of the coating material include an amine, an alcohol, and a thiol. In specific detail, examples of the coating material include an amine compound such as 2-methylaminoethanol, diethanolamine, diethylmethylamine, 2-dimethylamino ethanol, or methyldiethanolamine, alkylamines, ethylenediamine, alkyl alcohols, ethylene glycol, propylene glycol, alkyl thiol, and ethane dithiol. As a result, the silver nanoparticles coated with the coating material can be dispersed in the dispersion medium consistently.
According to the above-mentioned embodiment, the surface of the base layer 5 and the surfaces of the insulation sub-patterns 10 and 11 are made lyophilic by irradiating light having a wavelength in an ultraviolet range. However, the surfaces can be made lyophilic when they are subjected to an O2 plasma process in which oxygen is used in an air atmosphere. The O2 plasma process is a process in which oxygen in a plasma state is radiated onto a surface of an object from a plasma discharge electrode (not shown). The O2 plasma process is performed under the following conditions: a plasma power in the range of 50 to 1000 W, the volume of flowing oxygen gas in the range of 50 to 100 mL/min, a moving speed of a surface of an object relative to a plasma discharge electrode in the range of 0.5 to 10 nm/sec, and a temperature of the surface of the object in the range; of 70 to 90° C.
In the above-mentioned embodiment, the method of manufacturing a multi-layered substrate is implemented by a plurality of liquid droplet ejection apparatuses. However, the number of liquid droplet ejection apparatuses used in the method of manufacturing the multi-layered substrate may be only one. When the number of the liquid droplet ejection apparatuses is one, different aqueous materials 111 may be ejected from different heads 114 in the one liquid droplet ejection apparatus.
In the above-mentioned exemplary example, the insulation material 111A includes a photopolymerization initiator, an acrylic acid monomer, and/or an oligomer. However, instead of the acrylic acid monomer and/or oligomer, the insulation material 111A may include a photopolymerization initiator, and a monomer and/or oligomer having a polymerizable functional group such as vinyl or epoxy.
In addition, the insulation material 111A may be an organic solution in which a monomer having a photo functional group is dissolved. A photo-curable imide monomer may be used as a monomer having the photo functional group.
When the monomer, as a material of a resin, has fluidity that is suitable to be ejected from the nozzle 118, the monomer (i.e., monomer solution) may be used as the insulation material 111A instead of an organic solution having the monomer dissolved therein. When the insulation material 111A is used, it is possible to form an insulation pattern or insulation sub-pattern according to the invention.
In addition, the insulation material 111A may be an organic solution in which a polymer as a resin is dissolved. In this case, a toluene may be used as a solvent in the insulation material 111A.
Number | Date | Country | Kind |
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2005-105765 | Apr 2005 | JP | national |