The present invention relates to the field of packaging and interconnection of integrated circuit assemblies and particularly to a method for providing near-hermetically coated integrated circuit assemblies.
Integrated circuit packages are produced for usage in a variety of products or for a variety of applications. For example, integrated circuit packages which are designed for use in military and avionics applications are often required to survive and/or operate under aggressive or rigorous operating conditions and environments. These integrated circuit packages (ex—hermetic packages) are often expected to have a long lifespan (i.e., remain functionally operable over a long period of time), such as for 20 years or more, and are typically very costly to produce.
Contrastingly, most currently available integrated circuit packages are designed for usage in products which present relatively benign/much less rigorous operating conditions, such as desktop PC's, electronic games and cell phones. Such integrated circuit packages are commonly referred to as Commercial off the Shelf (COTS) devices. These COTS devices tend to have a relatively short lifespan (ex—2 to 5 years) and are relatively inexpensive to produce compared to military electronics components.
In recent years the military electronics industry has sought a less expensive alternative to the high cost integrated circuit packages discussed above, which are currently implemented in environmentally severe military and avionics applications. One alternative has been to implement the currently available (and less expensive) COTS devices, in the more demanding military and avionics environments. However, when the currently available COTS devices have been subjected to these more rigorous conditions, they have been especially prone to failure due to higher operating temperatures, corrosion, or the like. Current methods of modifying or designing integrated circuit packages for improved corrosion resistance are typically very expensive and may exacerbate other failure mechanisms and thereby reduce reliability.
Thus, it would be desirable to have a method for providing near-hermetically coated integrated circuit assemblies which address the problems associated with current solutions.
Accordingly, an embodiment of the present invention is directed to a method for providing an integrated circuit assembly, the integrated circuit assembly including an integrated circuit and a substrate, the method including: mounting the integrated circuit to the substrate; during assembly of the integrated circuit assembly, applying a low processing temperature, at least near-hermetic, glass-based coating directly to the integrated circuit and a localized interconnect interface, the interface being configured for connecting the integrated circuit to at least one of the substrate and a second integrated circuit of the assembly; and curing the coating.
A further embodiment of the present invention is directed to a method for providing an electronic device, the electronic device including an integrated circuit assembly, the integrated circuit assembly including an integrated circuit and a substrate, the method including: mounting the integrated circuit to the substrate; during assembly of the integrated circuit assembly, applying a low processing temperature, at least near-hermetic, glass-based coating directly to the integrated circuit and a localized interconnect interface, the interface being configured for connecting the integrated circuit to at least one of the substrate and a second integrated circuit of the assembly; curing the coating; and at least substantially enclosing the integrated circuit assembly within a housing.
A still further embodiment of the present invention is directed to an integrated circuit assembly, including: a substrate; and an integrated circuit configured for being mounted to the substrate via a localized interconnect interface, the interface being configured for connecting the integrated circuit to at least one of the substrate and a second integrated circuit of the assembly, wherein the integrated circuit and the localized interconnect interface are at least partially coated with a low processing temperature, at least near-hermetic, glass-based coating for promoting reliability of the integrated circuit assembly in at least one of high temperature operating environments and corrosive operating environments.
The numerous advantages of the present invention may be better understood by those skilled in the art by reference to the accompanying figures in which:
Reference will now be made in detail to the presently preferred embodiments of the invention, examples of which are illustrated in the accompanying drawings.
In current embodiments, the integrated circuit assembly 100 includes the integrated circuit 104. For instance, the integrated circuit 104 (IC) may be a microcircuit, a chip, a microchip, a silicon chip, a computer chip, a monolithic integrated circuit, a hybrid integrated circuit, or the like.
The integrated circuit 104 of the present invention is configured for being mounted to the substrate 102 via a localized interconnect interface 106, the interface being configured for connecting (ex—electrically connecting) the integrated circuit to the substrate. For example, the integrated circuit 104 may be wire bonded (such as by ball bonding, wedge bonding, or the like) to the substrate 102, with the localized interconnect interface 106 being a bond wire-bond pad interface. Further, the bond wire-bond pad interface may include one or more bond wires 108 and/or bond pads 110. For instance, a bond wire included in the one or more bond wires 108 may be a gold, copper, or aluminum wire. Further, a first end of the bond wire 108 may be configured for attachment to an inner lead of the substrate 102, while a second end of the bond wire 108 may be configured for attachment to a bond pad 110 of the integrated circuit 104. For example, one or more of heat, pressure and ultrasonic energy may be utilized in attaching the ends of the wire 108 to the substrate 102 and integrated circuit 104 respectively for electrically connecting to and/or securing the integrated circuit 104 onto the substrate.
In an exemplary embodiment, the integrated circuit 104 and the localized interconnect interface 106 of the integrated circuit assembly 100 (shown prior to being coated/without coating in
In a current embodiment, the coating 112 may be a hermetic (ex—airtight) or near-hermetic coating for promoting reliability of the integrated circuit assembly 100 in high temperature operating environments and/or corrosive operating environments, such as military or avionics environments. In further embodiments, the coating 112 may be a low processing temperature coating. For instance, the coating 112 may be formulated for being applied and/or cured at a temperature less than or equal to 160 degrees Celsius. In additional embodiments, the coating 112 may be a glass-based Coating. For example, the coating may be an alkali silicate-based coating. Still further, the coating may be a variety of formulations, such as any one or more of the formulations described in U.S. patent application Ser. No. 11/508,782 entitled: Integrated Circuit Protection and Ruggedization Coatings and Methods filed Aug. 23, 2006, (pending) which is herein incorporated by reference in its entirety.
In a present embodiment, the integrated circuit 104 may be a device which is available for at least one of sale, lease and license to a general public. For instance, the integrated circuit 104 may be a Commercial off the Shelf (COTS) device.
In a present embodiment, the method 200 further includes, prior to applying the coating, adding nanoparticles/nano-sized particles (ex—particles having at least one dimension less than 100 nm) to the coating for promoting corrosion resistance of the assembly 208 and/or the coating itself. For example, nano-sized particles of calcium carbonate, zinc oxide, divalent metal cations, rare earth oxides and/or the like may be added to the coating for promoting corrosion resistance of the integrated circuit assembly.
In further embodiments, the method 300 further includes at least substantially enclosing the integrated circuit assembly within a housing 308. For example, as shown in
In present embodiments, the method 300 further includes, prior to applying the coating, adding nanoparticles/nano-sized particles (ex—particles having at least one dimension less than 100 nm) to the coating for promoting corrosion resistance of the assembly 310 and/or the coating itself. For example, nano-sized particles of calcium carbonate, zinc oxide, and/or the like may be added to the coating for promoting corrosion resistance of the integrated circuit assembly.
It is to be noted that the foregoing described embodiments according to the present invention may be conveniently implemented using conventional general purpose digital computers programmed according to the teachings of the present specification, as will be apparent to those skilled in the computer art. Appropriate software coding may readily be prepared by skilled programmers based on the teachings of the present disclosure, as will be apparent to those skilled in the software art.
It is to be understood that the present invention may be conveniently implemented in forms of a software package. Such a software package may be a computer program product which employs a computer-readable storage medium including stored computer code which is used to program a computer to perform the disclosed function and process of the present invention. The computer-readable medium may include, but is not limited to, any type of conventional floppy disk, optical disk, CD-ROM, magnetic disk, hard disk drive, magneto-optical disk, ROM, RAM, EPROM, EEPROM, magnetic or optical card, or any other suitable media for storing electronic instructions.
It is understood that the specific order or hierarchy of steps in the foregoing disclosed methods are examples of exemplary approaches. Based upon design preferences, it is understood that the specific order or hierarchy of steps in the method can be rearranged while remaining within the scope of the present invention. The accompanying method claims present elements of the various steps in a sample order, and are not meant to be limited to the specific order or hierarchy presented.
It is believed that the present invention and many of its attendant advantages will be understood by the foregoing description. It is also believed that it will be apparent that various changes may be made in the form, construction and arrangement of the components thereof without departing from the scope and spirit of the invention or without sacrificing all of its material advantages. The form herein before described being merely an explanatory embodiment thereof, it is the intention of the following claims to encompass and include such changes.
The present application is a continuation-in-part application and claims priority under 35 U.S.C. §120 to the U.S. patent application Ser. No. 11/508,782 entitled: Integrated Circuit Protection and Ruggedization Coatings and Methods filed Aug. 23, 2006 now U.S. Pat. No. 8,076,185, which is herein incorporated by reference in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
3508974 | Bressler | Apr 1970 | A |
3654528 | Barkan | Apr 1972 | A |
3723790 | Dumbaugh et al. | Mar 1973 | A |
3812404 | Barkan et al. | May 1974 | A |
4177015 | Davidson | Dec 1979 | A |
4294658 | Humphreys et al. | Oct 1981 | A |
4410874 | Scapple et al. | Oct 1983 | A |
4505644 | Meisner et al. | Mar 1985 | A |
4513029 | Sakai | Apr 1985 | A |
4560084 | Wolfson | Dec 1985 | A |
4572924 | Wakely et al. | Feb 1986 | A |
4622433 | Frampton | Nov 1986 | A |
4761518 | Butt et al. | Aug 1988 | A |
4765948 | Deluca et al. | Aug 1988 | A |
4773826 | Mole | Sep 1988 | A |
4802531 | Nathenson et al. | Feb 1989 | A |
4882212 | SinghDeo et al. | Nov 1989 | A |
4963503 | Aoki et al. | Oct 1990 | A |
5041342 | Umeda et al. | Aug 1991 | A |
5136365 | Pennisi et al. | Aug 1992 | A |
5140109 | Matsumoto et al. | Aug 1992 | A |
5184211 | Fox | Feb 1993 | A |
5195231 | Fanning et al. | Mar 1993 | A |
5232970 | Solc et al. | Aug 1993 | A |
5244726 | Laney et al. | Sep 1993 | A |
5265136 | Yamazaki et al. | Nov 1993 | A |
5288769 | Papageorge et al. | Feb 1994 | A |
5315155 | O'Donnelly et al. | May 1994 | A |
5405808 | Rostoker et al. | Apr 1995 | A |
5502889 | Casson et al. | Apr 1996 | A |
5581286 | Hayes et al. | Dec 1996 | A |
5686703 | Yamaguchi | Nov 1997 | A |
5690837 | Nakaso et al. | Nov 1997 | A |
5702963 | Vu et al. | Dec 1997 | A |
5863605 | Bak-Boychuk et al. | Jan 1999 | A |
5916944 | Camilletti et al. | Jun 1999 | A |
5958794 | Bruxvoort et al. | Sep 1999 | A |
5965947 | Nam et al. | Oct 1999 | A |
5991351 | Woolley | Nov 1999 | A |
6010956 | Takiguchi et al. | Jan 2000 | A |
6019165 | Batchelder | Feb 2000 | A |
6021844 | Batchelder | Feb 2000 | A |
6027791 | Higashi et al. | Feb 2000 | A |
6028619 | Saita et al. | Feb 2000 | A |
6039896 | Miyamoto et al. | Mar 2000 | A |
6048656 | Akram et al. | Apr 2000 | A |
6087018 | Uchiyama | Jul 2000 | A |
6110656 | Eichorst et al. | Aug 2000 | A |
6121175 | Drescher et al. | Sep 2000 | A |
6124224 | Sridharan et al. | Sep 2000 | A |
6159910 | Shimizu et al. | Dec 2000 | A |
6356334 | Mathew et al. | Mar 2002 | B1 |
6370015 | Noda et al. | Apr 2002 | B2 |
6423415 | Greene et al. | Jul 2002 | B1 |
6451283 | Kuznicki et al. | Sep 2002 | B1 |
6452090 | Takato et al. | Sep 2002 | B2 |
6486087 | Saling et al. | Nov 2002 | B1 |
6496359 | Clark et al. | Dec 2002 | B2 |
6541083 | Landa et al. | Apr 2003 | B1 |
6586087 | Young | Jul 2003 | B2 |
6599643 | Heimann et al. | Jul 2003 | B2 |
6658861 | Ghoshal et al. | Dec 2003 | B1 |
6665186 | Calmidi et al. | Dec 2003 | B1 |
6708501 | Ghoshal et al. | Mar 2004 | B1 |
6798072 | Kajiwara et al. | Sep 2004 | B2 |
6800326 | Uchiyama | Oct 2004 | B1 |
6918984 | Murray et al. | Jul 2005 | B2 |
7045905 | Nakashima | May 2006 | B2 |
7078263 | Dean | Jul 2006 | B2 |
7131286 | Ghoshal et al. | Nov 2006 | B2 |
7176564 | Kim | Feb 2007 | B2 |
7202598 | Juestel et al. | Apr 2007 | B2 |
7293416 | Ghoshal | Nov 2007 | B2 |
7296417 | Ghoshal | Nov 2007 | B2 |
7297206 | Naruse et al. | Nov 2007 | B2 |
7340904 | Sauciuc et al. | Mar 2008 | B2 |
7342787 | Bhatia | Mar 2008 | B1 |
7348665 | Sauciuc et al. | Mar 2008 | B2 |
7391060 | Oshio | Jun 2008 | B2 |
7476981 | Bergmann et al. | Jan 2009 | B2 |
7491431 | Chiruvolu et al. | Feb 2009 | B2 |
7692259 | Suehiro | Apr 2010 | B2 |
7737356 | Goldstein | Jun 2010 | B2 |
7915527 | Lower et al. | Mar 2011 | B1 |
7998601 | Mack et al. | Aug 2011 | B2 |
8017872 | Cripe et al. | Sep 2011 | B2 |
8075185 | Hecht et al. | Dec 2011 | B2 |
8119040 | Lower et al. | Feb 2012 | B2 |
20010015443 | Komoto | Aug 2001 | A1 |
20010046933 | Parkhill et al. | Nov 2001 | A1 |
20020000630 | Coyle | Jan 2002 | A1 |
20020054976 | Nakamura et al. | May 2002 | A1 |
20020076192 | Bartholomew et al. | Jun 2002 | A1 |
20020078856 | Hahn et al. | Jun 2002 | A1 |
20020086115 | Lamers et al. | Jul 2002 | A1 |
20020170173 | Mashino | Nov 2002 | A1 |
20020189495 | Hayashi et al. | Dec 2002 | A1 |
20020189894 | Davis et al. | Dec 2002 | A1 |
20030047735 | Kyoda et al. | Mar 2003 | A1 |
20030080341 | Sakano et al. | May 2003 | A1 |
20030218258 | Charles et al. | Nov 2003 | A1 |
20030228424 | Dove et al. | Dec 2003 | A1 |
20040106037 | Cho et al. | Jun 2004 | A1 |
20040116577 | Naruse et al. | Jun 2004 | A1 |
20040156995 | Komiyama et al. | Aug 2004 | A1 |
20040194667 | Reuscher | Oct 2004 | A1 |
20050003947 | Mazany et al. | Jan 2005 | A1 |
20050082691 | Ito et al. | Apr 2005 | A1 |
20050099775 | Pokharna et al. | May 2005 | A1 |
20050116237 | Voutsas | Jun 2005 | A1 |
20050123684 | Makowski et al. | Jun 2005 | A1 |
20050179742 | Keenan et al. | Aug 2005 | A1 |
20060045755 | McDonald et al. | Mar 2006 | A1 |
20060068218 | Hooghan et al. | Mar 2006 | A1 |
20060095677 | Hakura et al. | May 2006 | A1 |
20060113066 | Mongia et al. | Jun 2006 | A1 |
20060135342 | Anderson et al. | Jun 2006 | A1 |
20060158849 | Martin et al. | Jul 2006 | A1 |
20060250731 | Parkhurst et al. | Nov 2006 | A1 |
20060268525 | Jeong | Nov 2006 | A1 |
20060283546 | Tremel et al. | Dec 2006 | A1 |
20070075323 | Kanazawa et al. | Apr 2007 | A1 |
20070102833 | Hack et al. | May 2007 | A1 |
20070108586 | Uematsu et al. | May 2007 | A1 |
20070224400 | Meguro et al. | Sep 2007 | A1 |
20080006204 | Rusinko et al. | Jan 2008 | A1 |
20080050512 | Lower et al. | Feb 2008 | A1 |
20080063875 | Robinson et al. | Mar 2008 | A1 |
20080142966 | Hirano et al. | Jun 2008 | A1 |
20080299300 | Wilcoxon et al. | Dec 2008 | A1 |
20090183774 | Atanackovic | Jul 2009 | A1 |
20090246355 | Lower et al. | Oct 2009 | A9 |
20100064518 | Lower et al. | Mar 2010 | A1 |
20100064695 | Wilcoxon et al. | Mar 2010 | A1 |
20100065256 | Wilcoxon et al. | Mar 2010 | A1 |
20100066178 | Lower et al. | Mar 2010 | A1 |
20120118623 | Lower et al. | May 2012 | A1 |
Number | Date | Country |
---|---|---|
55-120083 | Sep 1980 | JP |
57-027942 | Feb 1982 | JP |
57027942 | Feb 1982 | JP |
60-013875 | Jan 1985 | JP |
02-064071 | Mar 1990 | JP |
11-095246 | Apr 1999 | JP |
2003-332505 | Nov 2003 | JP |
2006-045420 | Feb 2006 | JP |
WO 2006095677 | Sep 2006 | WO |
WO 2006095677 | Sep 2006 | WO |
PCTUS2008074224 | Aug 2008 | WO |
PCTUS2008075591 | Sep 2008 | WO |
PCTUS2009031699 | Jan 2009 | WO |
Entry |
---|
U.S. Appl. No. 12/286,207, filed Sep. 29, 2008, Lower et al. |
U.S. Appl. No. 12/240,775, filed Sep. 29, 2008, Lower et al. |
U.S. Appl. No. 11/959,225, filed Dec. 18, 2007, Lower et al. |
U.S. Appl. No. 11/784,932, filed Apr. 10, 2007, Lower et al. |
U.S. Appl. No. 11/732,981, filed Apr. 5, 2007, Wilcoxon et al. |
U.S. Appl. No. 11/784,158, filed Apr. 5, 2007, Lower et al. |
Click, et al., “Schott Low Temperature Bonding for Precision Optics,” can be found at website: http://optics.nasa.gov/tech—days/tech—days—2004/docs/18%20Aug%202004/23%20Schott%20Low%20Temperature%20Bonding.pdf, p. 20. |
Lewis, J. A., et al., Materialstoday: Jul./Aug. 2004, Direct Writing in three dimension, ISSN: 1369 7021 © Elsevier Ltd 2004, pp. 32-39. |
Optomec® Systems M3D® Breakthrough Technology for Printable Electronics, pp. 1-2. |
International Search Report and Written Opinion for Application No. PCT/US2009/036355, mail date Jun. 30, 2009, 11 pages. |
International Search Report and Written Opinion for Application No. PCT/US2009/031699, mail date Aug. 18, 2009, 16 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Dec. 2, 2009, 15 pages. |
International Search Report and Written Opinion for International Application No. PCT/US2008/075591, mail date Apr. 8, 2009, 7 pages. |
Non-Final Office Action for U.S. Appl. No. 11/784,932, dated Apr. 3, 2009, 8 pages. |
Non-Final Office Action for U.S. Appl. No. 11/784,158, dated Apr. 21, 2009, 10 pages. |
Office Action for U.S. Appl. No. 12/116,126, mail date Apr. 22, 2010, 7 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date May 26, 2010, 17 pages. |
Office Action for U.S. Appl. No. 11/784,158, mail date Jun. 17, 2010, 7 pages. |
Office Action for U.S. Appl. No. 12/116,126, mail date Nov. 20, 2009, 7 pages. |
Office Action for U.S. Appl. No. 11/784,932, mail date Feb. 16, 2010, 11 pages. |
Office Action for U.S. Appl. No. 11/508,782, mail date Feb. 24, 2010, 12 pages. |
Office Action for U.S. Appl. No. 11/784,158, mail date Oct. 8, 2009, 7 pages. |
Office Action for U.S. Appl. No. 11/784,158, mail date Mar. 26, 2010, 7 pages. |
Final Office Action for U.S. Appl. No. 11/508,782, dated Jun. 16, 2009, 13 pages. |
U.S. Appl. No. 11/508,782, Nathan P. Lower, et al. |
U.S. Appl. No. 12/116,126, Nathan P. Lower, et al. |
Golubev, K.S., et al., Modeling of Acid-Base Properties of Binary Alkali-Silicate Melts, Rev. Adv. Mater. Sci. 6, (2004), pp. 33-40, website: http://www.ipme.ru/e-journals/RAMS/no—1604/golubev/golubev.pdf. |
Kennedy, C. R., Strength and Fracture Toughness of Binary Alkali Silicate Glasses (Abstract only), Feb. 14, 1974, website: http://oai.dtic.mil/oai/oai?verb=getRecord&metadataPrefix=html&identifier=ADA016820, 1 page. |
Amendment and Reply for U.S. Appl. No. 11/959,225, mail date Jan. 27, 2011, 9 pages. |
Amendment and Reply for U.S. Appl. No. 11/959,225, mail date Jun. 13, 2011, 12 pages. |
Advisory Action for U.S. Appl. No. 11/959,225, mail date Jul. 5, 2011, 3 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Nov. 18, 2011, 16 pages. |
Amendment and Reply for U.S. Appl. No. 11/508,782, mail date Sep. 2, 2008, 7 pages. |
Amendment and Reply for U.S. Appl. No. 11/508,782, mail date Mar. 24, 2009, 10 pages. |
Amendment and Reply for U.S. Appl. No. 11/508,782, mail date Aug. 14, 2009, 12 pages. |
Amendment and Reply for U.S. Appl. No. 11/508,782, mail date Jun. 24, 2010, 10 pages. |
Amendment and Reply for U.S. Appl. 11/508,782, mail date Nov. 2, 2010, 12 pages. |
Supplemental Amendment and Reply for U.S. Appl. No. 11/508,782, mail date Nov. 3, 2010, 3 pages. |
Request for Continued Examination for U.S. Appl. No. 11/508,782, mail date Dec. 2, 2010, 10 pages. |
Amendment and Reply for U.S. Appl. No. 11/508,782, mail date Apr. 5, 2011, 9 pages. |
Request for Continued Examination for U.S. Appl. No. 11/508,782, mail date Aug. 30, 2011, 6 pages. |
Notice of Allowance for U.S. Appl. No. 11/508,782, mail date Sep. 20, 2011, 7 pages. |
Amendment and Reply for U.S. Appl. No. 12/116,126, mail date Aug. 10, 2011, 11 pages. |
Office Action for U.S. Appl. No. 12/116,126, mail date Sep. 12, 2011, 11 pages. |
Amendment and Reply for U.S. Appl. No. 12/116,126, mail date Dec. 12, 2011, 10 pages. |
Notice of Allowance for U.S. Appl. No. 12/116,126, mail date Jan. 5, 2012, 10 pages. |
Amendment and Reply for U.S. Appl. No. 12/240,775, mail date Sep. 26, 2011, 11 pages. |
Request for Continued Examination for U.S. Appl. No. 11/732,981, mail date May 16, 2011, 12 pages. |
Terminal Disclaimer for U.S. Appl. No. 11/732,981, mail date May 16, 2011, 1 page. |
Notice of Allowance for U.S. Appl. No. 11/732,981, mail date Dec. 29, 2011, 7 pages. |
Request for Continued Examination for U.S. Appl. No. 11/784,932, mail date Aug. 10, 2011, 6 pages. |
Notice of Allowance for U.S. Appl. No. 11/784,932, mail date Aug. 23, 2011, 8 pages. |
Notice of Allowance for U.S. Appl. No. 12/286,207, mail date Oct. 6, 2011, 8 pages. |
Terminal Disclaimer for U.S. Appl. No. 11/784,158, mail date May 26, 2010, 1 page. |
International Search Report and Written Opinion for International Application No. PCT/US2008/074224, mail date Jan. 30, 2009, 10 pages. |
Office Action for U.S. Appl. No. 12/284,670, mail date Sep. 28, 2010, 11 pages. |
Office Action for U.S. Appl. No. 12/116,126, mail date Oct. 25, 2010, 9 pages. |
Office Action for U.S. Appl. No. 12/286,207, mail date Dec. 27, 2010, 15 pages. |
Office Action for U.S. Appl. No. 11/508,782, mail date Jan. 19, 2011, 10 pages. |
Office Action for U.S. Appl. No. 12/284,670, mail date Feb. 17, 2011, 13 pages. |
Office Action for U.S. Appl. No. 12/116,126, mail date Feb. 25, 2011, 9 pages. |
Office Action for U.S. Appl. No. 11/732,981, mail date Mar. 16, 2011, 7 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Apr. 13, 2011, 17 pages. |
Response for U.S. Appl. No. 11/784,158, mail date Jan. 8, 2010, 10 pages. |
Amendment and Reply for U.S. Appl. No. 11/784,158, mail date May 26, 2010, 12 pages. |
Response for U.S. Appl. No. 11/784,932, mail date Jul. 2, 2009, 8 pages. |
Notice of Allowance for U.S. Appl. No. 11/784,932, mail date May 12, 2011, 11 pages. |
Office Action for U.S. Appl. No. 11/508,782, mail date Dec. 24, 2008, 9 pages. |
Response for U.S. Appl. No. 11/508,782, mail date Nov. 13, 2009, 14 pages. |
Notice of Allowance for U.S. Appl. No. 11/508,782, mail date May 31, 2011, 9 pages. |
Supplemental Notice of Allowability for U.S. Appl. No. 11/508,782, mail date Jul. 26, 2011, 4 pages. |
Notice of Allowance for U.S. Appl. No. 11/732,981, mail date Jul. 26, 2011, 7 pages. |
Notice of Allowance for U.S. Appl. No. 12/284,670, mail date May 11, 2011, 7 pages. |
Notice of Allowance for U.S. Appl. No. 12/286,207, mail date Jun. 27, 2011, 12 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Jul. 22, 2009, 10 pages. |
Response for U.S. Appl. No. 11/959,225, mail date Mar. 2, 2010, 9 pages. |
Response for U.S. Appl. No. 12/116,126, mail date Feb. 22, 2010, 10 pages. |
Office Action for U.S. Appl. No. 12/116,126, mail date May 10, 2011, 8 pages. |
Office Action for U.S. Appl. No. 12/240,775, mail date May 26, 2011, 9 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Apr. 23, 2013, 6 pages. |
Advisory Action for U.S. Appl. No. 11/508,782, mail date Aug. 31, 2009, 3 pages. |
Advisory Action for U.S. Appl. No. 11/959,225, mail date Jul. 31, 2012, 3 pages. |
Advisory Action for U.S. Appl. No. 12/116,126, mail date Jun. 29, 2010, 4 pages. |
Advisory Action for U.S. Appl. No. 12/240,775, mail date Nov. 14, 2012, 2 pages. |
Amendment and Reply for U.S. Appl. No. 12/116,126, mail date Jul. 22, 2010, 9 pages. |
Amendment and Reply for U.S. Appl. No. 11/732,981, mail date Jan. 6, 2011, 9 pages. |
Amendment and Reply for U.S. Appl. No. 11/732,982, mail date Sep. 28, 2012, 7 pages. |
Amendment and Reply for U.S. Appl. No. 11/784,158, mail date Jul. 21, 2009, 10 pages. |
Amendment and Reply for U.S. Appl. No. 11/784,932, mail date Jun. 14, 2010, 9 pages. |
Amendment and Reply for U.S. Appl. No. 11/959,225, mail date Aug. 24, 2009, 2 pages. |
Amendment and Reply for U.S. Appl. No. 11/959,225, mail date Aug. 26, 2010, 11 pages. |
Amendment and Reply for U.S. Appl. No. 11/959,225, mail date Feb. 15, 2012, 15 pages. |
Amendment and Reply for U.S. Appl. No. 11/959,225, mail date Jul. 5, 2011, 6 pages. |
Amendment and Reply for U.S. Appl. No. 11/959,225, mail date Jun. 25, 2012, 14 pages. |
Amendment and Reply for U.S. Appl. No. 12/116,126, mail date Apr. 29, 2011, 9 pages. |
Amendment and Reply for U.S. Appl. No. 12/116,126, mail date Jan. 25, 2011, 8 pages. |
Amendment and Reply for U.S. Appl. No. 12/116,126, mail date Jun. 22, 2010, 7 pages. |
Amendment and Reply for U.S. Appl. No. 12/240,775, mail date Jul. 2, 2012, 12 pages. |
Amendment and Reply for U.S. Appl. No. 12/240,775, mail date Nov. 6, 2012, 8 pages. |
Amendment and Reply for U.S. Appl. No. 12/284,670, mail date Apr. 18, 2011, 9 pages. |
Amendment and Reply for U.S. Appl. No. 12/286,207, mail date Mar. 28, 2011, 12 pages. |
Amendment and Reply for U.S. Appl. No. 12/493,022, mail date Aug. 28, 2012, 7 pages. |
Amendment and Reply for U.S. Appl. No. 12/493,022, mail date Mar. 23, 2012, 3 pages. |
Amendment and Reply for U.S. Appl. No. 13/359,105, mail date Aug. 8, 2012, 10 pages. |
Examiner Interview Summary for U.S. Appl. No. 11/508,782, mail date Jan. 5, 2011, 2 pages. |
Notice of Allowance for U.S. Appl. No. 12/493,022, mail date Sep. 20, 2012, 5 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Apr. 25, 2012, 17 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Sep. 25, 2012, 16 pages. |
Office Action for U.S. Appl. No. 12/240,775, mail date Apr. 2, 2012, 8 pages. |
Office Action for U.S. Appl. No. 12/240,775, mail date Sep. 6, 2012, 9 pages. |
Office Action for U.S. Appl. No. 12/493,022, mail date May 30, 2012, 13 pages. |
Office Action for U.S. Appl. No. 13/359,105, mail date Jan. 17, 2013, 7 pages. |
Office Action for U.S. Appl. No. 13/359,105, mail date May 8, 2012, 12 pages. |
Office Action for U.S. Appl. No. 13/359,105, mail date Oct. 19, 2012, 7 pages. |
Request for Continued Examination for U.S. Appl. No. 11/784,932, mail date Jun. 14, 2010, 4 pages. |
Request for Continued Examination for U.S. Appl. No. 11/959,225, mail date Aug. 27, 2012, 19 pages. |
Request for Continued Examination for U.S. Appl. No. 12/116,126, mail date Apr. 29, 2011, 4 pages. |
Request for Continued Examination for U.S. Appl. No. 12/116,126, mail date Jul. 22, 2010, 4 pages. |
Request for Continued Examination for U.S. Appl. No. 12/286,207, mail date Sep. 26, 2011, 4 pages. |
Restriction Requirement for U.S. Appl. No. 12/493,022, mail date Feb. 22, 2012, 6 pages. |
Restriction Requirement for U.S. Appl. No. 13/329,068, mail date Jan. 15, 2013, 5 pages. |
Technical Standard Order, TSO-C115b, Airborne Area Navigation Equipment Using Multi-Sensor Inputs, Department of Transportation, Federal Aviation Administration, Sep. 30, 1994, 11 pages. |
Techpowerup, “NanoCoolers puts liquid metal in your PC,” website: http://www.techpowerup.com/?3105, May 4, 2005, 19 pages. |
Click, et al., “Schott Low Temperature Bonding for Precision Optics,” can be found at website: http://optics.nasa.gov/tech—days/tech—days—2004/docs/18%20Aug%202004/23%20Schott%20Low%20Temperature%20Bonding.pdf, p. 20. |
Lewis, J. A., et al., Materialstoday: Jul./Aug. 2004, Direct Writing in three dimension, ISSN: 1369 7021© Elsevier Ltd 2004, pp. 32-39. |
PQ Corporation, “Bonding and Coating Applications of PQ® Soluble Silicates,” Bulletin 12-31, (2003) p. 7. |
PQ Corporation, PQ® Soluble Silicates in Refractory and Chemical-Resistant Cements, Bulletin 24-1, (2003), p. 6. |
Thresh, John C., “The Action of Natural Waters on Lead,” The Analyst, vol. XLVII, No. 560, (Nov. 1922) pp. 459-468. |
Nascimento, M. L. F., et al. Universal curve of ionic conductivities in binary alkali silicate glasses, Journal of Materials Science (2005), Springer Science + Business Media, Inc., website: http://www.springerlink.com/content/p7535075x1872016/, 3 pgs. |
Pedone, A., et al. Insight into Elastic Properties of Binary Alkali Silicate Glasses; Prediction and Interpretation through Atomistic Simulation Techniques, Chemistry of Materials, 2007, vol. 19, No. 13, pp. 3144-3154, American Chemical Society (Abstract only) website: http://pubs.acs.org/doi/abs/10.1021/cm062619r, 2 pgs. |
Shermer, H. F., Thermal expansion of binary alkali silicate glasses, Journal of Research of the National Bureau of Standards, vol. 57, No. 2, Aug. 1956, Research Paper No. 2698, website: http://nvl.nist.gov/pub/nistpubs/jres/057/2/V57.N02.A05.pdf, 5 pgs. |
The Mixed—Alkali Effect for the Viscosity of Glasses, printed on Dec. 3, 2010 from website: http://glassproperties.com/viscosity/mixed-alkali-effect-viscosity/, 7 pages. |
The Structure of Glasses. Alkali silicate glasses, printed on Dec. 3, 2010 from website: http://www.ptc.tugraz.at/specmag/struct/ss.htm, 1 page. |
Office Action for U.S. Application No. 11/508,782 (F&L Ref.: 047141-0580), mail date Sep. 2, 2010, 14 pp. |
Office Action for U.S. Appl. No. 11/732,981, mail date Oct. 6, 2010, 10 pages. |
Office Action for U.S. Appl. No. 11/959,225, mail date Oct. 27, 2010, 12 pages. |
Office Action for U.S. Appl. No. 11/784,932, mail date Nov. 10, 2010, 10 pages. |
Notice of Allowance for U.S. Appl. No. 11/784,158, mail date Nov. 29, 2010, 8 pages. |
Office Action for U.S. Appl. No. 13/287,734, mail date Apr. 11, 2013, 18 pages. |
Number | Date | Country | |
---|---|---|---|
Parent | 11508782 | Aug 2006 | US |
Child | 11732982 | US |