Methods of fluxless micro-piercing of solder balls, and resulting devices

Information

  • Patent Grant
  • 10515918
  • Patent Number
    10,515,918
  • Date Filed
    Friday, September 21, 2018
    6 years ago
  • Date Issued
    Tuesday, December 24, 2019
    5 years ago
Abstract
A method of establishing conductive connections is disclosed. The method includes providing an integrated circuit die having a plurality of solder balls each of which has an oxide layer on an outer surface of the solder ball. The method also includes performing a heating process to heat at least the solder balls and applying a force causing each of a plurality of piercing bond structures on a substrate to pierce one of the solder balls and its associated oxide layer to thereby establish a conductive connection between the solder ball and the piercing bond structure.
Description
TECHNICAL FIELD

The present subject matter is generally directed to the field of microelectronic devices and, more particularly, to methods of fluxless micro-piercing of solder balls, and the resulting devices.


DESCRIPTION OF THE RELATED ART

Chip-on-board and board-on-chip (BOC) techniques are used to attach semiconductor dies to an interposer or other carrier substrate such as a printed circuit board (PCB). Attachment can be achieved through flip chip attachment, wirebonding, or tape automated bonding (“TAB”). Flip chip attachment typically utilizes ball grid array (BGA) technology. The BGA component (die) includes conductive external contacts, typically in the form of solder balls or bumps, arranged in a grid pattern on the active surface of the die, which permit the die to be flip chip mounted to an interposer or other carrier substrate (e.g., PCB).


In a flip chip attachment, the balls of the BGA component are aligned with terminals on the carrier substrate, and connected by reflowing the solder balls. The solder balls can be replaced with a conductive polymer that is cured. A dielectric underfill is then interjected between the flip chip die and the surface of the carrier substance to embed the solder balls and mechanically couple the BGA component to the carrier substrate.


Wirebonding and TAB attachment generally involve attaching a die by its backside to the surface of a carrier substrate with an appropriate adhesive (e.g., epoxy) or tape. With wirebonding, bond wires are attached to each bond pad on the die and bonded to a corresponding terminal pad on the carrier substrate (e.g., interposer). With TAB, ends of metal leads carried on a flexible insulating tape, such as a polyimide, are attached to the bond pads on the die and to the terminal pads on the carrier substrate. A dielectric (e.g., silicon or epoxy) is generally used to cover the bond wires or metal tape leads to prevent damage.


Flip chip attachment has provided improved electrical performance and allowed greater packaging density. However, developments in ball grid array technology have produced arrays in which the balls are made smaller and with tighter pitches. As the balls become smaller and are set closer together, it poses problems for the mutual alignment of the conductive bumps on the flip chip die with the bond pads on the substrate or interposer. Flip chip attachment can also lead to high costs and process difficulties. For example, a flip chip mounter is required to accurately align the die to the interposer or substrate.


In flip chip packaging, solid-state welding, adhesive bonding and soldering are often used for joining the interconnect system. These bonding techniques face numerous assembly challenges. Soldering is the preferred bonding technique, thanks to its high assembly yield, ability to eliminate the probe mark through reflow, allowance for rework after assembly, electrical stability and high tolerance in placement accuracy because of self-alignment effects. However, some challenges still remain for soldering assembly, such as a long processing time and the need for a flux-based removal of oxides and hydrocarbons for solderability. For example, solder balls typically have an oxide layer formed on the outer surface of the ball due to the manufacturing processes employed to manufacture the solder balls in an ambient environment.


In making conductive connections to such solder balls, a flux is employed due to the presence of the oxide layer, i.e., flux is employed to remove such oxides. Processing time is lengthened by flux application, the vision time required for precise alignment and the need for a reflow process to provide sufficient wetting time for soldering. Flux removal of oxides leaves behind undesirable residues that are deleterious to package reliability. Entrapped residues also cause gross solder voids that can result in premature joint failure. Although chlorofluorocarbons (CFCs) are effective in removing flux residues, they are environmentally hazardous and do not present a long-term solution. Thus, the use of flux and its cleaning processes erects a barrier to flip chip deployment in the packaging and integration of microelectronic, optoelectronic and microelectromechanical systems. Fluxless soldering processes, on the other hand, rely on a controlled atmosphere for the reduction of oxides for soldering, but this is cumbersome in high-volume implementation. Obviously, a method of instantaneous fluxless soldering in ambient atmosphere for flip chip assembly is highly desirable.


The present subject matter is directed to various methods and devices that may solve, or at least reduce, some or all of the aforementioned problems.





BRIEF DESCRIPTION OF THE DRAWINGS

The subject matter disclosed herein may be understood by reference to the following description taken in conjunction with the accompanying drawings, in which like reference numerals identify like elements, and in which:



FIGS. 1A-1D are various views of an illustrative device described herein;



FIGS. 2A-2B depict a reduced pitch that may be achieved using the piercing bond structures disclosed herein;



FIG. 3 depicts the piercing bond structures disclosed herein as engaged with different size solder balls;



FIG. 4 depicts a variety of illustrative end configurations for the piercing bond structures disclosed herein; and



FIGS. 5A-5D depict one illustrative process flow for forming the piercing bond structures disclosed herein.





While the subject matter described herein is susceptible to various modifications and alternative forms, specific embodiments thereof have been shown by way of example in the drawings and are herein described in detail. It should be understood, however, that the description herein of specific embodiments is not intended to limit the invention to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.


DETAILED DESCRIPTION

Illustrative embodiments of the present subject matter are described below. In the interest of clarity, not all features of an actual implementation are described in this specification. It will of course be appreciated that in the development of any such actual embodiment, numerous implementation-specific decisions must be made to achieve the developers' specific goals, such as compliance with system-related and business-related constraints, which will vary from one implementation to another. Moreover, it will be appreciated that such a development effort might be complex and time-consuming, but would nevertheless be a routine undertaking for those of ordinary skill in the art having the benefit of this disclosure.


Although various regions and structures shown in the drawings are depicted as having very precise, sharp configurations and profiles, those skilled in the art recognize that, in reality, these regions and structures are not as precise as indicated in the drawings. Additionally, the relative sizes of the various features and doped regions depicted in the drawings may be exaggerated or reduced as compared to the size of those features or regions on fabricated devices. Nevertheless, the attached drawings are included to describe and explain illustrative examples of the subject matter disclosed herein.



FIGS. 1A-1B depict an illustrative embodiment of a device 10 in accordance with one aspect of the present subject matter. The device 10 comprises a die 12 that is attached to an interposer or substrate 14, e.g., a printed circuit board. The terms “substrate” and “interposer” will be used interchangeably herein and they shall be understood to refer to any type of structure to which an integrated circuit die may be mounted. The die 12 comprises a plurality of schematically depicted solder balls 16 that are conductively coupled to conductive pads 17. The solder balls 16 have an illustrative oxide layer 20, e.g., tin oxide, formed on the outer surface thereof due to the manufacturing processes performed to form the solder balls 16. A plurality of piercing bond structures 22 are formed on the substrate 14. The piercing bond structures 22 are conductively coupled to illustrative wire traces or lines 24 that extend through vias 26 formed in the substrate 14. The wiring traces 24 are conductively coupled to illustrative contact pads 28 formed on the substrate 14. A layer of dielectric material 30 is also provided to electrically isolate various electrical components on the substrate 14. At least one anti-oxidation film 23 (see FIG. 1C) is provided on the piercing bond structures 22.



FIG. 1A depicts the situation wherein the die 12 is positioned proximate the substrate 14 prior to attachment. The die 12 may be coupled to the substrate 14 using a variety of known techniques, e.g., adhesives, epoxies, etc. In the depicted example, an amount of non-conductive paste 32 is positioned on the substrate 14. A non-conductive film may, in some applications, be applied in lieu of the non-conductive paste 32.



FIG. 1B depicts the device 10 at the point of fabrication wherein the die 12 has been conductively coupled to the substrate 14 by virtue of the conductive engagement between the piercing bond structures 22 and the solder balls 16. The piercing bond structures 22 pierce the oxide layer 20 and the solder ball 16 to thereby establish this conductive connection. Also note that FIG. 1B depicts an illustrative standoff structure 34 that may be employed if desired or needed to ensure that the die 12 is positioned a fixed distance from the substrate 14.


In attaching the die 12 to the substrate 14, the device 10 is heated and an illustrative downforce 40 is applied. The magnitude of the downforce 40 may vary depending upon the particular application. In one illustrative embodiment, the downforce 40 may range from approximately 2-12 kg. In some specific applications, a downforce 40 of approximately 8 kg may be employed. The device 10 is heated to a temperature above the melting point of the material of the solder ball 16, e.g., to a temperature ranging from approximately 190-210° C. The downforce 40 may be applied for a duration of 0.5-2 seconds, depending on the particular application. The article entitled “Instantaneous Fluxless Bonding of Au with Pb—Sn Solder in Ambient Atmosphere,” Journal of Applied Physics, Vol. 98, 034904 (2005) is hereby incorporated by reference in its entirety.



FIGS. 1C-1D are enlarged views of an illustrative solder ball 16 and piercing bond structure 22 prior to engagement (FIG. 1C) and after engagement (FIG. 1D). As mentioned previously, the piercing bond structure 22 has one or more anti-oxidation layers 23 formed on the structure 22 to prevent an oxide film from forming on the piercing bond structure 22. In the illustrative example depicted in FIGS. 1C-1D, the anti-oxidation layer 23 comprises a layer of gold 23A and a layer of nickel 23B. Of course, other materials may be employed. The layer of gold 23A may have a thickness of approximately 2.5 μm, while the layer of nickel 23B may have a thickness of approximately 0.3 μm.



FIGS. 2A-2B schematically depict the reduced pitch between adjacent conductive structures that may result by use of the piercing bond structures 22 disclosed herein. FIG. 2A schematically depicts an illustrative conductive bond structures 90 that are commonly formed using known techniques. The conventional bond structures 90 have a substantially planar upper or contact surface 92. In FIG. 2A, the width of the contact surface 92 is designated “A,” the width of the sloped sidewalls 94, due to the isotropic nature of the etching process used to form the structures 90, is designated as “B” and the spacing between the structures 90 is designated as “C.” Thus, the pitch “P” for the conductive structure 90 would be A+2B+C. In contrast, the pitch (“P1”) between the piercing bond structures 22 shown in FIG. 2B would be equal to 2B+C. In short, using the techniques and piercing bond structures 22 disclosed herein, the pitch between conductive bonding structures (like the piercing bond structures 22 disclosed herein) may be substantially less as compared to prior art devices that employ bonding structures having a substantially planar or non-piercing upper surface 92, as shown in FIG. 2A. For example, using the piercing bond structures 22 described herein, the pitch “P1” may be approximately 60 μm minimum.


As shown in FIG. 3, the methodologies and piercing bond structures 22 disclosed herein may be employed with solder balls 16A, 16B, 16C of differing sizes. Thus, the piercing bond structures 22 described herein may be employed with a vast variety of different connection technologies and techniques.


The present subject matter may also be employed to control the offset between the die 12 and the printed circuit board 14. In general, all other things being equal, the greater the downforce 40, the less the distance between the die 12 and the printed circuit board 14. The temperature during the engagement process can also be employed to control the spacing between the die 12 and the printed circuit board 14. In general, the greater the temperature, the less the spacing between the die 12 and the printed circuit board 14.


As shown in FIG. 4, the piercing bond structures 22 may have a variety of configurations for the piercing end 22A of the structure 22. For example, the piercing end 22A may be pointed, rounded or comprise multiple peaks as depicted on the piercing bond structures 22 in FIG. 4 (from left to right).



FIGS. 5A-5D depict one illustrative process flow for forming the piercing bond structures 22 described herein. Initially, as shown in FIG. 5A, a masking layer 80 is formed above a layer of conductive material 82. The masking layer 80 may be comprised of a variety of materials, e.g., a photoresist material, and it may be formed using traditional photolithography techniques. The layer of conductive material 82 may be comprised of a variety of different materials, e.g., gold, and it may be formed by a variety of known techniques, e.g., plating.


As shown in FIG. 5B, an anisotropic etching process 84 is performed to partially define conductive structures 86 having sloped sidewalls 87. The etching process 84 may be stopped at a point in time such that a portion 88 of the layer of conductive material 82 is not etched completely away. In some applications, stopping the etch process 84 so as to leave a remaining portion 88 of the layer of conductive material 82 may not be required. As shown in FIG. 5C, the masking layer 80 is removed, and an isotropic etching process 89 is performed until such time as the piercing bond structures 22 depicted in FIG. 5D are formed. Note that, in the illustrative embodiment depicted herein, the piercing bond structures 22 have a substantially triangular cross-sectional configuration and a substantially pointed end 22A. The end 22A of the piercing bond structure 22 is generally non-planar or non-flat, but it may take on other configurations. For example, FIG. 4 depicts various illustrative configurations for the end 22A of the piercing bond structures 22.


The particular embodiments disclosed above are illustrative only, as the invention may be modified and practiced in different but equivalent manners apparent to those skilled in the art having the benefit of the teachings herein. For example, the process steps set forth above may be performed in a different order. Furthermore, no limitations are intended to the details of construction or design herein shown, other than as described in the claims below. It is therefore evident that the particular embodiments disclosed above may be altered or modified and all such variations are considered within the scope and spirit of the invention. Accordingly, the protection sought herein is as set forth in the claims below.

Claims
  • 1. A device comprising: a substrate having a first side and a second side facing away from the first side;a plurality of piercing bond structures at the first side of the substrate, each of the piercing bond structures having an outer surface that surrounds a solid core of conductive material, wherein the outer surface includes an anti-oxidation material;a plurality of contact pads at the second side of the substrate; anda plurality of wiring traces electrically coupling the piercing bond structures with the contact pads,wherein the anti-oxidation material is a first anti-oxidation material, the device further including a second anti-oxidation material over the first anti-oxidation material,wherein the first anti-oxidation material is gold and the second anti-oxidation material is nickel, andwherein individual piercing bond structures have a first end facing the first side of the substrate and a second end facing away from the first end, and wherein the second ends are non-flat.
  • 2. The device of claim 1, further comprising a standoff structure at the first side of the substrate, wherein the standoff structure extends away from the first side of the substrate for a distance.
  • 3. The device of claim 1, further comprising a non-conductive paste at the first side of the substrate.
  • 4. The device of claim 1, wherein the substrate includes a via extending from the first side of the substrate to the second side of the substrate, wherein at least one wiring trace lines the via.
  • 5. A device comprising: a substrate having a first side and a second side facing away from the first side;a plurality of piercing bond structures at the first side of the substrate, each of the piercing bond structures having an outer surface that surrounds a solid core of conductive material, wherein the outer surface includes an anti-oxidation material;a plurality of contact pads at the second side of the substrate; anda plurality of wiring traces electrically coupling the piercing bond structures with the contact pads,wherein the anti-oxidation material is a first anti-oxidation material, the device further including a second anti-oxidation material over the first anti-oxidation material,wherein the first anti-oxidation material is gold and the second anti-oxidation material is nickel, andwherein the piercing bond structures have substantially triangular cross-sections.
  • 6. The device of claim 5, further comprising a standoff structure at the first side of the substrate, wherein the standoff structure extends away from the first side of the substrate for a distance.
  • 7. The device of claim 5, further comprising a non-conductive paste at the first side of the substrate.
  • 8. The device of claim 5, wherein the substrate includes a via extending from the first side of the substrate to the second side of the substrate, wherein at least one wiring trace lines the via.
  • 9. A device comprising: a substrate having a first side and a second side facing away from the first side;a plurality of piercing bond structures at the first side of the substrate, each of the piercing bond structures having an outer surface that surrounds a solid core of conductive material, wherein the outer surface includes an anti-oxidation material;a plurality of contact pads at the second side of the substrate; anda plurality of wiring traces electrically coupling the piercing bond structures with the contact pads,wherein the anti-oxidation material is a first anti-oxidation material, the device further including a second anti-oxidation material over the first anti-oxidation material,wherein the first anti-oxidation material is gold and the second anti-oxidation material is nickel, andwherein individual piercing bond structures have a first end facing the first side of the substrate and a second end facing away from the first end, and wherein the individual second ends have cross-sections selected from a group consisting of a pointed cross-section, a rounded cross-section, and a multiple-peak cross section.
  • 10. The device of claim 9, further comprising a standoff structure at the first side of the substrate, wherein the standoff structure extends away from the first side of the substrate for a distance.
  • 11. The device of claim 9, further comprising a non-conductive paste at the first side of the substrate.
  • 12. The device of claim 9 wherein the substrate includes a via extending from the first side of the substrate to the second side of the substrate, wherein at least one wiring trace lines the via.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No. 14/201,031, filed Mar. 7, 2014; which is a continuation of U.S. application Ser. No. 13/873,509, filed Apr. 30, 2013, now U.S. Pat. No. 8,669,173; which is a divisional of U.S. application Ser. No. 12/827,476, filed Jun. 30, 2010, now U.S. Pat. No. 8,436,478; which is a divisional of U.S. application Ser. No. 11/958,842, filed Dec. 18, 2007, now U.S. Pat. No. 7,749,887; each of which is incorporated herein by reference in its entirety.

US Referenced Citations (110)
Number Name Date Kind
4483720 Bartlett et al. Nov 1984 A
4865245 Schulte et al. Sep 1989 A
4912545 Go Mar 1990 A
4930001 Williams May 1990 A
5071787 Mori et al. Dec 1991 A
5134460 Brady et al. Jul 1992 A
5207585 Byrnes et al. May 1993 A
5326428 Farnworth et al. Jul 1994 A
5341980 Nishikawa et al. Aug 1994 A
5592736 Akram et al. Jan 1997 A
5634267 Farnworth et al. Jun 1997 A
5793117 Shimada et al. Aug 1998 A
5796163 Glenn Aug 1998 A
5869903 Nakatani Feb 1999 A
5877079 Karasawa et al. Mar 1999 A
5878943 Nishikawa et al. Mar 1999 A
5889326 Tanaka Mar 1999 A
5906312 Zakel et al. May 1999 A
5929521 Wark et al. Jul 1999 A
5952840 Farnworth et al. Sep 1999 A
6077723 Farnworth et al. Jun 2000 A
6083773 Lake Jul 2000 A
6137184 Ikegami Oct 2000 A
6179198 Eifuku et al. Jan 2001 B1
6214642 Chen et al. Apr 2001 B1
6291897 Wark et al. Sep 2001 B1
6333555 Farnworth et al. Dec 2001 B1
6335571 Capote et al. Jan 2002 B1
6337445 Abbott et al. Jan 2002 B1
6426636 Das et al. Jul 2002 B1
6497943 Jimarez Dec 2002 B1
6537482 Farnworth Mar 2003 B1
6537854 Chang et al. Mar 2003 B1
6538335 Shimada et al. Mar 2003 B2
6562545 Hembree et al. May 2003 B1
6583517 Jimarez Jun 2003 B1
6634100 Akram et al. Oct 2003 B2
6641406 Yatskov et al. Nov 2003 B1
6667556 Moden Dec 2003 B2
6669173 Dunn Dec 2003 B1
6813662 Park Nov 2004 B2
6849944 Murtuza et al. Feb 2005 B2
7015132 Lahiri et al. Mar 2006 B2
7115495 Wark et al. Oct 2006 B2
7122907 Lee Oct 2006 B2
7129584 Lee Oct 2006 B2
7161237 Lee Jan 2007 B2
7190065 Saimen Mar 2007 B2
7205661 Wark et al. Apr 2007 B2
7271497 Joshi et al. Sep 2007 B2
7691675 Garcia et al. Apr 2010 B2
7749887 Lee Jul 2010 B2
7838954 Buchwalter et al. Nov 2010 B2
7969004 Ohnishi Jun 2011 B2
8288871 Shieh Oct 2012 B1
8294279 Chen et al. Oct 2012 B2
8299368 Endo Oct 2012 B2
8586409 Davoine et al. Nov 2013 B2
9070586 Dang Jun 2015 B1
9929230 Liu Mar 2018 B2
10001508 Liu Jun 2018 B2
10132836 Dang Nov 2018 B2
10163840 Lee Dec 2018 B2
20010003296 Morimoto et al. Jun 2001 A1
20010048153 Wark Dec 2001 A1
20010054771 Wark et al. Dec 2001 A1
20020158655 Wark Oct 2002 A1
20020185301 Wark Dec 2002 A1
20020196041 Wark Dec 2002 A1
20030160325 Yoneda et al. Aug 2003 A1
20030168739 Huang Sep 2003 A1
20030216023 Wark et al. Nov 2003 A1
20040155357 Ho et al. Aug 2004 A1
20040164389 Lee Aug 2004 A1
20040166661 Lei et al. Aug 2004 A1
20040173902 Kim Sep 2004 A1
20050110163 Koo et al. May 2005 A1
20050120553 Brown et al. Jun 2005 A1
20050124181 Brown et al. Jun 2005 A1
20050174134 Wark Aug 2005 A1
20060019481 Liu et al. Jan 2006 A1
20060055034 Wark et al. Mar 2006 A1
20060060968 Wark et al. Mar 2006 A1
20060177965 Senda Aug 2006 A1
20070063722 Wark Mar 2007 A1
20070090855 Wark Apr 2007 A1
20070123020 Jungnickel et al. May 2007 A1
20070132097 Wark et al. Jun 2007 A1
20070148819 Haba et al. Jun 2007 A1
20070218591 Chou Sep 2007 A1
20080146071 Davoine et al. Jun 2008 A1
20080150135 Oyama et al. Jun 2008 A1
20080185705 Osborn et al. Aug 2008 A1
20090152719 Lee Jun 2009 A1
20090188706 Endo et al. Jul 2009 A1
20090236130 Mok Sep 2009 A1
20100163090 Liu Jul 2010 A1
20100264541 Lee Oct 2010 A1
20100330797 Douriet Dec 2010 A1
20120068335 Song Mar 2012 A1
20120279287 Andry Nov 2012 A1
20130234328 Lee Sep 2013 A1
20130313704 Souriau Nov 2013 A1
20150008577 Lee Jan 2015 A1
20150111342 Lin et al. Apr 2015 A1
20150214162 Lai et al. Jul 2015 A1
20150241476 Dang Aug 2015 A1
20150382463 Kim Dec 2015 A1
20160084882 Dang Mar 2016 A1
20180348259 Dang Dec 2018 A1
Foreign Referenced Citations (5)
Number Date Country
1622304 Jun 2005 CN
1723551 Jan 2006 CN
1797749 Jun 2007 EP
2002344126 Nov 2002 JP
2006107854 Apr 2006 JP
Non-Patent Literature Citations (14)
Entry
EP Patent Application No. 08862313.7—European Office Action, dated Aug. 3, 2017, 8 pages.
“Examination Report dated Mar. 19, 2016 in Singapore Application No. 201208986-8, 7 pages.”
“International Search Report and Written Opinion of the International Search Authority dated Mar. 13, 2009 in International Application No. PCT/US2008/085433.”
“Lee, T.K. et al., “Instantaneous fluxless bonding of Au with Pb—Sn solder in ambient atmosphere,” Journal of Applied Physics, 98, 034904, 2005.”
“Office Action dated Apr. 8, 2013 in P.R.C. Application No. 200880121032.X, 21 pages.”
“Office Action dated Aug. 29, 2014 in European Application No. 08862313.7, 6 pages.”
“Office Action dated Dec. 12, 2012 in Taiwan Application No. 097148258, 5 pages.”
“Office Action dated Jun. 25, 2011 in Republic of Korea Application No. 10-2010-7012500, 6 pages.”
“Office Action dated May 7, 2012 in Taiwan Application No. 097148258, 7 pages.”
“Office Action dated Nov. 24, 2011 in P.R.C. Application No. 200880121032.X, 11 pages.”
“Search Report dated Aug. 14, 2014 in Singapore Application No. 201208986-8, 4 pages.”
“Written Opinion dated Aug. 31, 2015 in Singapore Application No. 201208986-8, 9 pages.”
“Written Opinion dated Dec. 22, 2014 in Singapore Application No. 201208986-8, 9 pages.”
EP Patent Application No. 18183518.2—Extended European Search Report, dated Sep. 3, 2018, 7 pages.
Related Publications (1)
Number Date Country
20190019774 A1 Jan 2019 US
Divisions (2)
Number Date Country
Parent 12827476 Jun 2010 US
Child 13873509 US
Parent 11958842 Dec 2007 US
Child 12827476 US
Continuations (2)
Number Date Country
Parent 14201031 Mar 2014 US
Child 16138074 US
Parent 13873509 Apr 2013 US
Child 14201031 US