Embedding thin chips in polymer

Information

  • Patent Grant
  • 9583428
  • Patent Number
    9,583,428
  • Date Filed
    Friday, September 18, 2015
    9 years ago
  • Date Issued
    Tuesday, February 28, 2017
    7 years ago
Abstract
Systems and methods are provided for the embedding of thin chips. A well region is generated in a substrate that includes a conductive material disposed on a flexible polymer. The standoff well region can be generated by pattern the conductive material, where the thin chip is embedded in the standoff well region. A cavity can be generated in the polymer layer to form a polymer well region, where the thin chip is embedded in the polymer well region.
Description
BACKGROUND

Traditional integrated circuit (IC) chips are generally thick and rigid. In addition, they are mounted on printed circuit boards (PCBs) that are as thick, if not thicker, than the chips and similarly rigid. Such processing using thick printed circuit boards are generally incompatible with chips that are thinned or have stretchable interconnects.


SUMMARY

Many schemes have been proposed for embedding chips on PCBs in flexible polymers. Most of these schemes are based on an assumption that the chips are considerably thicker than the layers of the flexible polymer that makes up the PCBs. Such schemes are not compatible for thinner chips.


In view of the foregoing, various examples described herein are directed generally to methods for embedding thin device islands, including IC chips, and/or stretchable interconnects in a flexible polymer. Various examples described herein are also directed generally to apparatus and systems based on thin device islands, including IC chips, and/or stretchable interconnects embedded in flexible polymer.


According to the principles disclosed herein, an apparatus can include a substrate comprising a standoff well region. The substrate can include a layer of a first conductive material disposed on a layer of a flexible polymer, and a patterned portion of the first conductive material comprises a standoff bordering a portion of exposed flexible polymer, thereby forming the standoff well region. The apparatus can also include a thin chip disposed within the standoff well region on a portion of the exposed flexible polymer proximate to the standoff. The height of the standoff can be comparable to a height of the thin chip.


In an example, the apparatus can include an adhesive material disposed within the standoff well region at a portion of the exposed flexible polymer proximate to the standoff. The thin chip can be disposed on the adhesive material proximate to the standoff. The adhesive material can have a thickness of about 8 μm, about 10 μm, about 12 μm, about 15 μm, about 20 μm, about 25 μm, or about 30 μm. In some examples the adhesive material comprises a conductive adhesive or a non-conductive adhesive.


In an example, the patterned portion of the first conductive material can be formed using laser ablation or etching. The flexible polymer can be a polyimide or a liquid crystal polymer.


In an example, the first conductive material includes copper, gold, aluminum, or some combination thereof. The substrate can be a copper-clad polyimide.


In certain examples, the layer of flexible polymer can have a thickness of about 8 μm, about 10 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, about 75 μm, or about 85 μm, and the layer of first conductive material can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm. In an example, the thin chip can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm.


In an example, the thin chip can be a thinned chip. The thinned chip can be formed from a chip that can be thinned using an etching process or a grinding process. In an example, the thin chip can be disposed within the standoff well region such that the height of the standoff can be greater than or about equal to the height of the thin chip. In another example, the thin chip can be disposed within the standoff well region such that the height of the standoff can be less than the height of the thin chip.


In an example, the thin chip can have a layer of first conductive material can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm.


In one example, the apparatus can also include a polymer sheet disposed over the substrate. At least one via can be formed through the polymer sheet. The apparatus can also include a second conductive material disposed on a portion of the polymer sheet proximate to the at least one via, such that the second conductive material forms an electrical communication with an electrical contact of the thin chip.


In an example, the second conductive material can include titanium, tungsten, gold, nickel, chromium, or some combination thereof.


In an example, the standoff surrounds a portion of the thin chip. In another example, the standoff can completely surrounds the thin chip. In one example, a dielectric material can be disposed between the standoff and a portion of the thin chip.


In an example, at least one additional layer can be disposed on the first conductive material or on the flexible polymer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of the apparatus.


According to the principles disclosed herein, a method for embedding thin chips can include providing a substrate comprising a standoff well region, wherein the substrate includes a layer of a first conductive material disposed on a layer of a flexible polymer. The substrate can also include at least a portion of the first conductive material can be patterned to form a standoff bordering a portion of exposed flexible polymer, thereby forming the standoff well region. The method can also include disposing a thin chip on a portion of the exposed flexible polymer proximate to the standoff such that a height of the standoff can be comparable to a height of the thin chip.


In an example, the method can also include disposing an adhesive material on a portion of the exposed flexible polymer proximate to the standoff, and disposing the thin chip on the adhesive material disposed on the portion of the exposed flexible polymer proximate to the standoff.


In some examples, the height of the standoff can be greater than or about equal to a height of a thin chip.


In certain examples, the disposing step can also include disposing the thin chip on a portion of the flexible polymer proximate to the standoff such that the height of the standoff can be greater than or about equal to the height of the thin chip.


In an example, the thin chip can be a thinned chip, and the thinning a chip can be provided by an etching process or a grinding process. The thinned chip can be disposed on a portion of the exposed flexible polymer proximate to the standoff such that a height of the standoff can be comparable to a height of the thinned chip.


In an example, the method can also include disposing a polymer sheet over the substrate and forming at least one via through the polymer sheet. The method can further include disposing a conductive material on a portion of the second polymer sheet proximate to the at least one via, such that the conductive material forms an electrical communication with an electrical contact of the thin chip.


In an example, the method can further include disposing at least one additional layer on the first conductive material or on the flexible polymer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of the apparatus.


According to the principles disclosed herein, an apparatus can include a substrate with a polymer well region. The substrate can include a layer of a flexible polymer disposed on a layer of a first conductive material. The substrate can also include a cavity in at least a portion of the flexible polymer to form at least one polymer wall bordering a portion of exposed first conductive material, thereby forming the polymer well region. The apparatus can also include a thin chip disposed within the polymer well region on at least a portion of the exposed first conductive material proximate to the at least one polymer wall.


In an example, the apparatus can also include an adhesive material disposed within the polymer well region on at least a portion of the exposed first conductive material proximate to the at least one polymer wall, wherein the thin chip can be disposed on the adhesive material proximate to the at least one polymer wall.


In an example, the adhesive material can have a thickness of about 8 μm, about 10 μm, about 12 μm, about 15 μm, about 20 μm, about 25 μm, or about 30 μm. The adhesive material can include a conductive adhesive or a non-conductive adhesive.


In an example, the cavity can be formed using laser ablation or etching. The flexible polymer can be a polyimide or a liquid crystal polymer. The first conductive material can include copper, gold, aluminum, or some combination thereof. The substrate can include a copper-clad polyimide.


In an example, the layer of flexible polymer can have a thickness of about 8 μm, about 10 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, about 75 μm, or about 85 μm. The layer of first conductive material can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm. The thin chip can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm.


In an example, the thin chip can be a thinned chip. The thinned chip can be formed from a chip that can be thinned using an etching process or a grinding process. The thin chip can be disposed within the polymer well region such that the height of the at least one polymer wall can be greater than or about equal to the height of the thin chip. In an example, the thin chip can be disposed within the polymer well region such that the height of the at least one polymer wall can be less than the height of the thin chip.


In an example, the thin chip can have a layer of first conductive material can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm.


In an example, the apparatus can also include a polymer sheet disposed over the substrate. The apparatus can further include at least one via formed through the polymer sheet, and a second conductive material disposed on a portion of the polymer sheet proximate to the at least one via, such that the second conductive material forms an electrical communication with an electrical contact of the thin chip.


In an example, the second conductive material can include titanium, tungsten, gold, nickel, chromium, or some combination thereof.


In an example, the at least one polymer wall can surround a portion of the thin chip. The at least one polymer wall can completely surround the thin chip in another example.


In an example, a dielectric material can be disposed between the at least one polymer wall and a portion of the thin chip. The apparatus can further include at least one additional layer disposed on the first conductive material or on the flexible polymer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of the apparatus.


In an example, the thin chip can be a thinned chip, and the thin chip can be thinned using an etching process or a grinding process, and disposed within the polymer well region on at least a portion of the exposed first conductive material proximate to the at least one polymer wall such that a height of the least one wall can be comparable to a height of the thinned chip.


According to the principles described herein, a method for embedding thin chips can include providing a substrate comprising a polymer well region, the substrate comprising a layer of a flexible polymer and a layer of a first conductive material, the polymer well region comprising at least one polymer wall formed from a portion of the flexible polymer and a base region formed from at least a portion of the first conductive material, and disposing the thin chip within the polymer well region on a portion of the first conductive material proximate to the at least one polymer wall.


In an example, the method can also include disposing an adhesive material at the portion of the first conductive proximate to the at least one polymer wall, and disposing the thin chip on the adhesive material proximate to the at least one polymer wall.


In an example, the thin chip can be disposed within the polymer well region such that the height of the at least one polymer wall can be greater than or about equal to the height of the thin chip. In another example, the thin chip can be disposed within the polymer well region such that the height of the at least one polymer wall can be less than the height of the thin chip. In yet another example, thin chip can be disposed within the polymer well region such that the first conductive material can be in physical and electrical communication with the thin chip.


In an example, the method can further include disposing a polymer sheet over the substrate, forming at least one via through the polymer sheet, and disposing a second conductive material on a portion of the polymer sheet proximate to the at least one via, such that the second conductive material forms an electrical communication with an electrical contact of the thin chip.


In another example, the method can further include disposing at least one additional layer disposed on the first conductive material or on the flexible polymer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of the apparatus.


According to the principled disclosed herein, an apparatus can include a flexible substrate including a well region. The flexible substrate can include a polyimide or a liquid crystal polymer, and the flexible substrate can include a cavity forming a well region in the flexible substrate. The apparatus can also include a thin chip disposed within the well region, wherein the height of at least one polymer wall of the well region can be comparable to a height of the thin chip. The apparatus can further include a polymer adhesive material disposed in the well region in substantial contact with at least a portion of the thin chip.


In an example, the apparatus can also include a polymer sheet disposed over the flexible substrate and at least one via formed through the polymer sheet. The apparatus can also include a conductive material disposed on a portion of the polymer sheet proximate to the at least one via, such that the second conductive material forms an electrical communication with an electrical contact of the thin chip.


In an example, the apparatus can also include at least one via formed through the polymer adhesive material, and a conductive material disposed on a portion of the polymer adhesive material proximate to the at least one via, such that the conductive material forms an electrical communication with an electrical contact of the thin chip.


In an example, an adhesive material can be disposed within the well region, wherein the thin chip can be disposed on the adhesive material.


In another example, the thin chip can be disposed within the well region such that the height of the at least one polymer wall can be greater than or about equal to the height of the thin chip. The thin chip can be disposed within the well region such that the height of the at least one polymer wall can be less than the height of the thin chip. In an example, a dielectric material can be disposed between the at least one polymer wall and a portion of the thin chip.


The following publications, patents, and patent applications are hereby incorporated herein by reference in their entirety:


Kim et al., “Stretchable and Foldable Silicon Integrated Circuits,” Science Express, Mar. 27, 2008, 10.1126/science. 1154367;


Ko et al., “A Hemispherical Electronic Eye Camera Based on Compressible Silicon Optoelectronics.” Nature, Aug. 7, 2008, vol. 454, pp. 748-753;


Kim et al., “Complementary Metal Oxide Silicon Integrated Circuits Incorporating Monolithically Integrated Stretchable Wavy Interconnects,” Applied Physics Letters, Jul. 31, 2008, vol. 93, 044102;


Kim et al., “Materials and Noncoplanar Mesh Designs for Integrated Circuits with Linear Elastic Responses to Extreme Mechanical Deformations,” PNAS, Dec. 2, 2008. vol. 105, no. 48, pp. 18675-18680;


Meitl et al., “Transfer Printing by Kinetic Control of Adhesion to an Elastomeric Stamp,” Nature Materials, January, 2006, vol. 5, pp. 33-38;


U.S. Patent Application publication no. 2010 0002402-A1, published Jan. 7, 2010, filed Mar. 5, 2009, and entitled “STRETCHABLE AND FOLDABLE ELECTRONIC DEVICES;”


U.S. Patent Application publication no. 2010 0087782-A1, published Apr. 8, 2010, filed Oct. 7, 2009, and entitled “CATHETER BALLOON HAVING STRETCHABLE INTEGRATED CIRCUITRY AND SENSOR ARRAY;”


U.S. Patent Application publication no. 2010 0116526-A1, published May 13, 2010, filed Nov. 12, 2009, and entitled “EXTREMELY STRETCHABLE ELECTRONICS;”


U.S. Patent Application publication no. 2010 0178722-A1, published Jul. 15, 2010, filed Jan. 12, 2010, and entitled “METHODS AND APPLICATIONS OF NON-PLANAR IMAGING ARRAYS;” and


U.S. Patent Application publication no. 2010 027119-A1, published Oct. 28, 2010, filed Nov. 24, 2009, and entitled “SYSTEMS, DEVICES, AND METHODS UTILIZING STRETCHABLE ELECTRONICS TO MEASURE TIRE OR ROAD SURFACE CONDITIONS.”


Kim, D. H. et al. (2010). Dissolvable films of silk fibroin for ultrathin conformal bio-integrated electronics. Nature Materials, 9, 511-517.


Omenetto, F. G. and D. L. Kaplan. (2008). A new route for silk. Nature Photonics, 2, 641-643.


Omenetto, F. G., Kaplan, D. (2010). New opportunities for an ancient material. Science, 329, 528-531.


Halsed, W. S. (1913). Ligature and suture material. Journal of the American Medical Association, 60, 1119-1126.


Masuhiro, T., Yoko, G., Masaobu, N., et al. (1994). Structural changes of silk fibroin membranes induced by immersion in methanol aqueous solutions. Journal of Polymer Science, 5, 961-968.


Lawrence, B. D., Cronin-Golomb, M., Georgakoudi, I., et al. (2008). Bioactive silk protein biomaterial systems for optical devices. Biomacromolecules, 9, 1214-1220.


Demura, M., Asakura, T. (1989). Immobilization of glucose oxidase with Bombyx mori silk fibroin by only stretching treatment and its application to glucose sensor. Biotechnololgy and Bioengineering, 33, 598-603.


Wang, X., Zhang, X., Castellot, J. et al. (2008). Controlled release from multilayer silk biomaterial coatings to modulate vascular cell responses. Biomaterials, 29, 894-903.


U.S. patent application Ser. No. 12/723,475 entitled “SYSTEMS, METHODS, AND DEVICES FOR SENSING AND TREATMENT HAVING STRETCHABLE INTEGRATED CIRCUITRY,” filed Mar. 12, 2010.


U.S. patent application Ser. No. 12/686,076 entitled “Methods and Applications of Non-Planar Imaging Arrays,” filed Jan. 12, 2010.


U.S. patent application Ser. No. 12/636,071 entitled “Systems, Methods, and Devices Using Stretchable or Flexible Electronics for Medical Applications,” filed Dec. 11, 2009.


U.S. Patent Application publication no 2012-0065937-A1, published Mar. 15, 2012, and entitled “METHODS AND APPARATUS FOR MEASURING TECHNICAL PARAMETERS OF EQUIPMENT, TOOLS AND COMPONENTS VIA CONFORMAL ELECTRONICS.”


U.S. patent application Ser. No. 12/616,922 entitled “Extremely Stretchable Electronics.” filed Nov. 12, 2009.


U.S. patent application Ser. No. 12/575,008 entitled “Catheter Balloon Having Stretchable Integrated Circuitry and Sensor Array,” filed on Oct. 7, 2009.


U.S. patent application Ser. No. 13/336,518 entitled “Systems, Methods, and Devices Having Stretchable Integrated Circuitry for Sensing and Delivering Therapy,” filed Dec. 23, 2011.


It should be appreciated that all combinations of the foregoing concepts and additional concepts described in greater detail below (provided such concepts are not mutually inconsistent) are contemplated as being part of the inventive subject matter disclosed herein. It also should be appreciated that terminology explicitly employed herein that also may appear in any disclosure incorporated by reference should be accorded a meaning most consistent with the particular concepts disclosed herein.





BRIEF DESCRIPTION OF THE DRAWINGS

The skilled artisan will understand that the figures, described herein, are for illustration purposes only, and that the drawings are not intended to limit the scope of the disclosed teachings in any way. In some instances, various aspects or features may be shown exaggerated or enlarged to facilitate an understanding of the inventive concepts disclosed herein (the drawings are not necessarily to scale, emphasis instead being placed upon illustrating the principles of the teachings). In the drawings, like reference characters generally refer to like features, functionally similar and/or structurally similar elements throughout the various figures.



FIG. 1 shows a cross sectional view of an example apparatus that includes a thin chip disposed in a well region, according to the principles described herein.



FIGS. 2A-2E show example configurations of well regions, according to the principles described herein.



FIGS. 3A-3E illustrate an example manufacturing process for embedding a thin chip in standoff well region formed in an conductive layer, according to the principles described herein.]



FIG. 4 shows a cross sectional view of an example apparatus that includes a thin chip disposed in a well region, according to the principles described herein.



FIGS. 5A-5E show example configurations of well regions, according to the principles described herein.



FIGS. 6A-6G illustrate an example manufacturing process based on a thin chip embedded in a polymer well region, according to the principles described herein.



FIGS. 7A-7D show an example thinning of a chip to generate a thinned chip, according to the principles described herein.



FIGS. 8A-8H illustrate example manufacturing processes that can be performed on an embedded thin chip, according to the principles described herein.





DETAILED DESCRIPTION

Following below are more detailed descriptions of various concepts related to, and embodiments of, an apparatus and systems for embedding thinned chips in a flexible polymer. It should be appreciated that various concepts introduced above and described in greater detail below may be implemented in any of numerous ways, as the disclosed concepts are not limited to any particular manner of implementation. Examples of specific implementations and applications are provided primarily for illustrative purposes.


As used herein, the term “includes” means includes but is not limited to, the term “including” means including but not limited to. The term “based on” means based at least in part on. As used herein, the term “disposed on” or “disposed above” is defined to encompass “at least partially embedded in.”


With respect to substrates or other surfaces described herein in connection with various examples of the principles herein, any references to “top” surface and “bottom” surface are used primarily to indicate relative position, alignment and/or orientation of various elements/components with respect to the substrate and each other, and these terms do not necessarily indicate any particular frame of reference (e.g., a gravitational frame of reference). Thus, reference to a “bottom” of a substrate or a layer does not necessarily require that the indicated surface or layer be facing a ground surface. Similarly, terms such as “over,” “under,” “above,” “beneath” and the like do not necessarily indicate any particular frame of reference, such as a gravitational frame of reference, but rather are used primarily to indicate relative position, alignment and/or orientation of various elements/components with respect to the substrate (or other surface) and each other. The terms “disposed on” “disposed in” and “disposed over” encompass the meaning of “embedded in,” including “partially embedded in.” In addition, reference to feature A being “disposed on,” “disposed between,” or “disposed over” feature B encompasses examples where feature A is in contact with feature B, as well as examples where other layers and/or other components are positioned between feature A and feature B.


A system, apparatus and method described herein provides for embedding chips in well regions. The well region can be generated as a standoff well region or a polymer well region, as described herein.


Herein, a “thin chip” refers to chips or other device islands that are formed to have thicknesses of about 5 microns, about 8 microns, about 10 microns or more, or that have been thinned to thicknesses of about 5 microns, about 8 microns, about 10 microns or more. In various examples, the chips (or other device islands) can be fabricated as thin as (or be thinned to) about 5 microns, about 8 microns, about 15 microns, about 20 microns, about 25 microns, 30 microns, 37.5 microns, 42 microns, 50 microns or more.


An example standoff well region according to the principles described herein can be formed in a substrate that includes a layer of a conductive material disposed on a layer of a flexible polymer. Portion of the conductive material can be patterned to create standoffs bordering a portion of exposed flexible polymer, forming the standoff well region. According to the principles described herein, a thin chip can be disposed within the standoff well region on a portion of the exposed flexible polymer proximate to the standoff. Based on the thickness of the thin chips herein, the height of the standoff is comparable to the height of the thin chip.


In a non-limiting example, an adhesive can be disposed on the exposed portion of the flexible polymer prior to the thin chip being disposed in the standoff well region. The adhesive can be a non-conductive (dielectric) adhesive that is configured to withstand the temperatures of further processing.


In various examples, further processing can be performed on the apparatus including the thin chip disposed in the standoff well region. For example, an additional adhesive can be disposed over the thin chip to fill the void between the thin chip and the standoff of the standoff well region. As another example, at least one additional sheet of a flexible polymer can be disposed on the apparatus or vias can be generated to establish an electrical communication with the thin chip, as described in greater detail below.


The principles described herein can be applied to rigid or flexible printed circuit boards. The printed circuit boards are referred to herein as flex and/or PCB. As a non-limiting example, a PCB board or flex sheet that includes a metal clad polymer sheet can be patterned, including being etched, to generate at least one standoff well region in the metal layer that extends down to the polymer. A thin chip is disposed in the standoff well region on the exposed portions of the polymer sheet of the flex board. An adhesive can be placed above the nestled chip and a second flex sheet is placed above the polymer. The sandwiched structure can be subjected to further processing to cause the adhesive to flow around at least a portion of the chip. At least one via can be formed through the top flex board down to the chip, and filled with a conductive material, to provide electrical communication with the bond pads of the thin chip.


An example polymer well region according to the principles described herein can be formed in a layer of flexible polymer disposed on a layer of a conductive material. A cavity can be formed in at least a portion of the flexible polymer to form the at least one polymer wall bordering a portion of the exposed first conductive material to form the polymer well region. A thin chip can be disposed in the polymer well region on at least a portion of the exposed first conductive material proximate to the at least one polymer wall.


In various examples, based on the thickness of the flexible polymer of the substrate or the depth from the surface to which the cavity extends into the flexible polymer, the height of the polymer wall may be comparable to the height of the thin chip. In other examples, the thin chip can be mounted in the polymer well region such that the level of the top surface of the thin chip is comparable to the top surface of the thin chip.


In a non-limiting example, an adhesive can be disposed on the exposed portion of the conductive material prior to the thin chip being disposed in the polymer well region. The adhesive can be a conductive adhesive or a non-conductive (dielectric) adhesive that is configured to withstand the temperatures of further processing. The conductive adhesive can be used to establish electrical communication between the conductive material of the substrate and conductive contact pads on the bottom surface of the thin chip.


In various example, further processing can be performed on the apparatus including the thin chip disposed in the polymer well region. For example, an additional adhesive can be disposed over the thin chip to fill the void between the thin chip and the polymer wall of the polymer well region.


In another example, at least one additional sheet of a flexible polymer can be disposed on the apparatus including the thin chip disposed in the polymer well region. Vias can be generated to establish an electrical communication with the thin chip, as described in greater detail below. In this example, the additional sheet of a flexible polymer can include a layer of a conductive material, and can be disposed on the apparatus such that the side that includes the conductive material layer is directed away from the thin chip. In this example, the conductive layer of the substrate and the conductive layer of the additional sheet would be located on the outside of the “sandwich” with the thin chip embedded within the sandwich. Vias can be generated through the conductive material layers and the flexible polymer layers as described herein to facilitate the electrical communication to the thin chip.


In an example system, apparatus and method, an embedded device formed according to the principles herein can be encapsulated using an encapsulant, such as but not limited to a polymer, to form an encapsulated device. The encapsulated device can be placed on the skin to perform a measurement or other diagnostic or therapeutic procedure. In an example, the embedded device and the encapsulated device are is configured to withstand deformation in more than one direction (for example, in x, y and/or z-directions), torsion, compression, expansion, or other change in conformation.


In an example use, the encapsulated structure can be placed on a surface, such as but not limited to skin or other tissue. In an example use, the encapsulated structure can be configured such that it conforms to a contour of the surface.


In various examples, the flexible polymer and/or the encapsulant can be formed from the same polymer or polymeric material or different polymers or polymeric materials. Non-limiting examples of applicable polymers or polymeric materials include, but are not limited to, a polyimide, a polyethylene terephthalate (PET), or a polyurethane. Other non-limiting examples of applicable polymers or polymeric materials include plastics, elastomers, thermoplastic elastomers, elastoplastics, thermostats, thermoplastics, acrylates, acetal polymers, biodegradable polymers, cellulosic polymers, fluoropolymers, nylons, polyacrylonitrile polymers, polyamide-imide polymers, polyarylates, polybenzimidazole, polybutylene, polycarbonate, polyesters, polyetherimide, polyethylene, polyethylene copolymers and modified polyethylenes, polyketones, poly(methyl methacrylate, polymethylpentene, polyphenylene oxides and polyphenylene sulfides, polyphthalamide, polypropylene, polyurethanes, styrenic resins, sulphone based resins, vinyl-based resins, or any combinations of these materials. In an example, a polymer or polymeric material herein can be a DYMAX® polymer (Dymax Corporation, Torrington, Conn.), or other UV curable polymer.


In an example, a method of embedding chips inside rigid or flexible printed circuit boards (flex, PCB) is provided. The method can be used to embed chips and/or other components, including but not limited to light emitting diodes (LEDs) or interconnects, inside polymers or polymeric materials. The embedding process provides for protection of the embedded device against the environment and for connecting them to each other to form larger electronic circuits, including integrated electronic circuits.


The conductive material of any of the examples described herein can be but is not limited to a metal, a metal alloy, or other conductive material. In an example, the metal or metal alloy of the coating may include but is not limited to aluminum or a transition metal (including copper, silver, gold, platinum, zinc, nickel, titanium, chromium, or palladium, or any combination thereof) and any applicable metal alloy, including alloys with carbon. In other non-limiting example, suitable conductive materials may include a semiconductor-based conductive material, including a silicon-based conductive material, indium tin oxide or other transparent conductive oxide, or Group III-IV conductor (including GaAs).


In any example herein, the layer of flexible polymer can have a thickness of about 8 μm, about 10 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, about 75 μm, or about 85 μm.


In any example herein, the layer of conductive material can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm.


In any example herein, the thin chip can have a thickness of about 2 μm, about 5 μm, about 8 μm, about 12 μm, about 15 μm, about 25 μm, about 35 μm, about 50 μm, about 60 μm, or about 70 μm


In any example herein, the adhesive material can have a thickness of about 8 μm, about 10 μm, about 12 μm, about 15 μm, about 20 μm, about 25 μm, or about 30 μm.



FIG. 1 is a cross sectional view of an example apparatus 100 that is formed from a thin chip 101 embedded in a well region 102. In this and any other example herein, the thin chip 101 can be a thinned chip. The well region 102 is formed from standoffs 103 bordering exposed portions of a flexible polymer 104. The standoff 103 forms a wall of the well region 102, thereby providing a standoff well region. In this example, the thin chip 101 is disposed on the exposed portions of the flexible polymer 104 proximate to a standoff 103. The standoff 103 can have a height 105 that is comparable to the height of the thin chip 101.


In the example systems, apparatus and methods described herein, the thin chip 101 can be one or more passive electronic components and/or active electronic components. Non-limiting examples of components that can be embedded according to any of the principles described herein include a transistor, an amplifier, a photodetector, a photodiode array, a display, a light-emitting device, a photovoltaic device, a sensor, a LED, a semiconductor laser array, an optical imaging system, a large-area electronic device, a logic gate array, a microprocessor, an integrated circuit, an electronic device, an optical device, an opto-electronic device, a mechanical device, a microelectromechanical device, a nanoelectromechanical device, a microfluidic device, a thermal device, or other device structures.


In an example, embedded devices according to the principles described herein can be formed by embedding a plurality of chips (or other device islands) and/or a plurality of the interconnects in the flexible polymer according to the principles herein. In an example, the embedded device (e.g., thin chip 101) can be formed from an integrated device, or formed from a plurality of chips (or other device islands) interconnected by a plurality of interconnects, that is embedded according to the principles herein.


The thin chip 101 (including an integrated device or device island as described herein) can be made thinner than the thickness of the conductive coating on the flexible polymer layer 104 from which the standoffs 103 of the standoff well region 102 is created. The conductive material coating can include, but is not limited to, metal traces or other metal coatings. The standoff well region 102 can be formed in the conductive coating through, e.g., patterning the conductive material coating on a flexible polymer and etching through to the surface of the flexible polymer 104. The etch process might include to the removal of some surface portion of the flexible polymer 104 as well. In another examples, the patterning may be performed with laser ablation or similar patterning process. After the conductive material coating on the polymer layer has been patterned and the standoff well region formed, the chip (including any device island) can be disposed and fixed between walls of the conductive coating “well,” creating features above the polymer that are roughly the same height as the walls of the standoff well region. In other examples, the height of the standoff 105 can be greater than or less than the height of the thin chip 101.


In various examples, the standoff well 102 can be formed such that the positioned chip or other device island is shorter than or approximately equal to the well height 104. In other examples, the well 102 can be formed such that the positioned the thin chip 101 (including a device island and/or an interconnect) is taller than the height of the walls of the well. The standoffs 103 of the standoff well region 103 can be about 80%, about 90%, about, 100%, about 110%, about 120%, about 140%, or about 150% of the thickness of the thin chip 101 (including a device island and/or interconnect). In other examples, the standoffs 103 of the standoff well region 103 can be about twice the thickness of the thin chip 101 or other device island and/or interconnect.



FIGS. 2A-2E show non-limiting examples of different conformations of the standoff well region. As illustrated, the standoff well region 102 (including the standoffs 103) can have a square shape, a rectangular shape, a rounded or other donut shape, or any other polygonal shape, such that a chip or other device island and/or interconnect can be disposed therein.



FIG. 2D shows a non-limiting example standoff well region (including the standoffs) that is fabricated to not completely surround the thin chip (including a device island and/or the interconnect). In this example, the standoff well region 102 borders three sides of the thin chip 101. In the non-limiting example of FIG. 2E, the standoff well region (including the standoffs) is fabricated to border portions of the sides of the thin chip 101 (including a device island and/or the interconnect, with some gaps in portions of the standoffs of the standoff well regions.


In some examples, and as described further in connection with FIG. 3, an adhesive can be caused to flow around the thin chip 101 (including any other device island and/or interconnect). For example, the adhesive can be caused to flow using a heat-treatment process. In an example, the heat-treatment process can be carried out at temperatures that vary from about 60° C. to about 250° C. The stacked layers, including the device islands and/or interconnects and any adhesive layer between the flexible polymer sheets, can be positioned between two metal plates and brought up to temperature to cause the adhesive to flow around the device islands and/or interconnects.


In an example, the embedded device is configured such that an embedded serpentine interconnect retains substantial range of motion and stretchability within the plane of the embedded device. In an example, the embedded device is configured such that an embedded serpentine interconnect retains substantial range of motion such that portions of it can rotate out of the plane to provide increased stretchability.


In an example process, metal traces, and accordingly the well wall height 105, can be typically 35 μm (“1 oz. copper”), 17.5 μm (“½ oz. copper”), 9 μm (“¼ oz. copper”) or 5 μm. Printed circuit boards specify copper thickness in ounces. This represents the thickness of 1 ounce of copper rolled out to an area of 1 square foot. The thickness of 1 oz. of copper is 1.4 mils or 35.56 microns.


In an example, the thin chips 101 (including any other device islands and/or interconnects) can be thinned to about 25 μm to be more suitable for 1 oz. copper traces (which determines the height of the standoff s). In an example, the thin chips 101 (including any other device islands and/or interconnects) can be thinned to 10 μm to be suitable for ½ oz. copper traces (which determines the well wall or standoff height).


In an example, some margin can be left between the thin chip and the standoff for disposing an adhesion layer, which is either dispensed on the flexible polymer layer 104 prior to placement of the thin chip 101 (including any other device island and/or interconnects)), or which is pre-adhered to the thin chips (including any other device islands and/or interconnects) prior to being disposed in the standoff well region 102.


In an example, an additional layer of conductive material may be added to the metallization on the chip or other device island. Some amount of metallization is generally provided at selected portions of the thin chip 101 (including any other device island and/or interconnects) to facilitate creating an electrical contact to the functional capability of the thin chip (including any other device island and/or interconnects). This metallization can be about 1 μm to about 2 μm thick. In some examples, the metallization is made of aluminum. However, other materials can be used for the metallization, such as any other metal or metal alloy described hereinabove in connection with the conductive material. Laser drilling may be used to create channels through the flexible polymer and the adhesive material to create access to the metallization of the thin chip 101 or other device island within the embedded device structure. It can be difficult to control the laser drilling so that it stops at the metallization and does not remove the metallization or puncture the thin chip 101 or other device island. For example, about 5 μm thickness of copper may be needed to terminate the laser drilling without the risk of removing the metallization or puncture. Other techniques for creating the through channels, including etching, can present similar risks of damage to the thin chip 101 or other device island. The additional layer of conductive material added to the metallization on the thin chip 101 or other device island in this example provides extra thickness that can help to withstand the laser drilling. In an example, the additional layer of conductive material (such as but not limited to added metal or metal stacks) is selected to have properties such as but not limited to adherence to the metallization of the chip or other device island; possible to be added to a thickness of about 2 μm to about 7 μm; and/or the ability to support, and form an electrical communication with, the material that is electroplated into via, such as but not limited to a metal or metal alloy electroplating (including Cu electroplating). The additional layer of conductive material (such as but not limited to the added metal) can be patterned and etched to form the standoffs 103.


The additional layer of conductive material may be added to the metallization on the chip or other device island in a variety of ways. For example, an under-bump metallization (UBM) suitable for copper micro-pillars could be carried out, without following through with the usual bumps that would be added, to generate the additional layer of conductive material on the metallization. The UBM can be carried out based on, e.g., a multilayer chromium-copper system (Cr:Cr—Cu:Cu), titanium-nickel-vanadium system (Ti—Ni—V), titanium-copper system (Ti—Cu), titanium-tungsten-gold system (Ti—W—Au), or a nickel-gold system (Ni—Au). In another example, the additional layer of conductive material may be added using electroplating on to the chip (or other device island) pads, after deposition of one or more suitable seed layers. The electroplating can be caused to deposit only on the regions of the chip (or other device island) where the metallization exists. In another example, conductive material can be added to larger portions of the chip (or other device island) and can be patterned and selectively removed (e.g., by etching) to be present only in the regions of the thin chip 101 (or other device island) with the original metallization to provide the additional layer of conductive material.


In an example, an embedded device formed according to the principles herein can be patterned or sliced to remove a portion of the flexible polymer that does not enclose a portion of the chip (or other device island) and/or the interconnect. For example, the embedded device can be patterned along the outline and/or contour of the device structure that is embedded within the flexible polymer. According to any of these examples, the embedded device can be patterned along the outline and/or contour of a serpentine interconnect of the embedded device.


The example systems, apparatus and methods described herein exploit chips or other device islands that are thinner than the surrounding standoffs or well walls to embed the chips or other device islands between flex board layers. In a non-limiting example, the surrounding standoffs or well walls are formed from metal traces.


In an non-limiting example, the surrounding standoffs or well walls are formed from a process of writing an “ink” of conductive material, rather than from patterning and etching a coating layer. In an non-limiting example, the “ink” of conductive material can be written using an inkjet printer device or other device.


The example systems, apparatus and methods described herein provide for good adhesion of layers, conformability of embedding material around the chip or other device islands, elimination of air pockets, and prevention of ingress of liquids from the outside.


The example systems, apparatus and methods described herein provide for embedding thin chips or other device islands and/or stretchable interconnects to provide entire assemblies that are flexible. In an example, the embedded device formed in the flexible polymer can be cut or otherwise formed into serpentine traces that can cause the entire assembly circuit to become even become stretchable, and not merely just flexible.


The example embedded devices according to the systems, apparatus and methods described herein present little or no possibility that a device component will “pop off” or be otherwise detached, if the embedded structure is bent, or otherwise deformed.


In a non-limiting example, the chip or other device island and/or the interconnect is disposed close to the neutral mechanical plane of the overall embedded device. Through choice of suitable flexible polymer layers above and/or below the chips or other device islands and/or stretchable interconnects, the strain on the functional layer of the embedded device can be minimized. A functional layer herein can include the chips or other device islands and/or stretchable interconnects. In an example, the flexible polymer can be formed of a material having a Young's modulus of about 3 GPa. Non-limiting examples of such flexible polymers include a polyimide, such as but not limited to KAPTON® (available from DuPont, Del.).


In an example, any of the systems or apparatus according to the principles herein, the chips 101 or other device islands and/or stretchable interconnects can be positioned such that the functional layer of the embedded device lies at a neutral mechanical plane (NMP) or neutral mechanical surface (NMS) of the system or apparatus. The NMP or NMS lies at the position through the thickness of the device layers for the system or apparatus where any applied strains are minimized or substantially zero. In an example, the functional layer of a system or apparatus according to the principles described herein includes a plurality of chips or other device islands and/or stretchable interconnects.


The location of the NMP or NMS can be changed relative to the layer structure of the system or apparatus through introduction of materials that aid in strain isolation in various layers of the system or apparatus. In various examples, polymer materials described herein can be introduced to serve as strain isolation materials. For example, the encapsulating material described hereinabove also can be used to position the NMP or NMS, e.g., by varying the encapsulating material type and/or layer thickness. For example, the thickness of encapsulating material disposed over the functional layers described herein may be modified (i.e., decreased or increased) to depress the functional layer relative to the overall system or apparatus thickness, which can vary the position of the NMP or NMS relative to the functional layer. In another example, the type of encapsulating, including any differences in the elastic (Young's) modulus of the encapsulating material.


In another example, at least a partial intermediate layer of a material capable of providing strain isolation can be disposed between the functional layer and the flexible substrate to position the NMP or NMS relative to the functional layer. In an example, the intermediate layer can be formed from any of the polymer materials described herein, aerogel materials or any other material with applicable elastic mechanical properties.


Based on the principles described herein, the NMP or NMS can be positioned proximate to, coincident with or adjacent to a layer of the system or apparatus that includes the strain-sensitive component, such as but not limited to the functional layer. The layer can be considered “strain-sensitive” if it is prone to fractures or its performance can be otherwise impaired in response to a level of applied strain. In an example where the NMP or NMS is proximate to a strain-sensitive component rather than coincident with it, the position of the NMP or NMS may still provide a mechanical benefit to the strain-sensitive component, such as substantially lowering the strain that would otherwise be exerted on the strain-sensitive component in the absence of strain isolation layers. In various examples, the NMS or NMP layer is considered proximate to the strain-sensitive component that provides at least 10%, 20%, 50% or 75% reduction in strain in the strain-sensitive component for a given applied strain, e.g., where the embedded device is deformed.


In various examples, the encapsulating material and/or the intermediate layer material may be disposed at positions relative to the embedded device that are coincident with the strain-sensitive component. For example, portions of the encapsulating material and/or the intermediate layer material may be interspersed with portions of the strain-sensitive component, through the embedding layer, including at positions within the functional layer.



FIGS. 3A-3E show an example method for embedding a thinned chip in a standoff well region created in an conductive layer. FIG. 3A provides a top view and cross-sectional view of a thin chip 301 disposed on a flexible polymer 304 and within a standoff well region 302 defined by standoffs 303. As described above, the process can begin with a substrate formed as a metal coated flexible polymer sheet. The metal-coating can then be pattered to create the standoffs 303. In another example, alignment marks can be formed in the metal layer during the pattering process to create the standoffs. The alignment marks can assist in properly registering the thin chip 101 within the standoff well region 302.


As illustrated in FIG. 3B, additional processing can be performed on the apparatus including the standoffs 303 and the thin chip 301 disposed within the standoff well region 302. For example, as illustrated in FIG. 3B, an adhesive 310 can be disposed over the thin chip. As described above, the adhesive 310 can be caused to flow within the standoff well region and around the thin chip 301 as a result of a temperature treatment. As also illustrated in FIG. 3B, an additional polymer sheet 320 can be disposed over the apparatus including the thin chip 301. As described above, and as in this example, the second flexible polymer 320 can be coupled with a second conductive layer 322. In one examples, the layers 320 and 322 are the same as the respective polymer layer 304 and conductive material layer 303 used in forming the standoff well region 302. In another example, the polymer layer 320 and conductive material layer 303 can be different from polymer layer 304 and conductive material layer 303. For example, the respective layers can comprise different materials and/or have different thicknesses. In an example, the adhesive polymer layer 310 can be DuPont™ PYRALUX® Bond-Ply. In another example, the material of adhesive polymer layer 310 can be selected such that it is non-conductive (a dielectric) and capable of adhering flexible polymer layers.


As illustrated in FIG. 3C, the layered structure of FIG. 3B can be, heat treated and cured such that the adhesive layer 310 is caused to flow around the thin chip 301 and within the standoff well region 302. In some examples, standoffs 303 can be taller than the thin chip 301, and the second polymer layer 320 is not in contact with the thin chip 301 when the curing process is completed.


As illustrated in FIG. 3D, vias can be generated as channels through the top conductive layer 322, the top flexible polymer sheet 320, and the adhesive layer 310 to the thin chip 301. Once the vias have been created, the vias can be electroplated or filled through sputtering to create electrical vias 325 from the top conductive layer 322 to the electrical contact pad of the thin chip 301.


As illustrated in FIG. 3E, the conductive layer 322 can then be patterned. An overlay 330 can be applied to the top conductive layer 322. In some implementations, the overlay 330 is non-conductive. The overlay can be patterned to expose the underlying metal and, as in this example, an additional tarnish-resistant metallization 335 can be added to the exposed metal 322, to protect the exposed metal 322 from reacting with oxygen, water and other components of the environment. Such an example device can be between about 10 microns and about 100 microns in height. In another example, as described above, the embedded device also can be encapsulated to increase the overall thickness of the multilayer embedded device. For example, subsequent encapsulation steps can increase the multilayer embedded device thickness to about 70 microns, about 80 microns, or to about 100 microns. Encapsulation can increase the durability of the multilayer embedded device. Further, the encapsulation can be used to place the functional layer of the multilayer embedded device at the NMS of the structure.



FIG. 4 shows a cross sectional view of another example apparatus 400 that is formed from a thin chip 401 embedded in a polymer well region 402 according to the principles described herein. In this example, as with any other example herein, the thin chip 401 can be a thinned chip. The polymer well region 402 is formed from at least one polymer wall 403 bordering exposed portions of a layer of conductive material 404. The polymer wall 403 forms a wall of the polymer well region 402, thereby providing the polymer well region. In this example, the thin chip 401 is disposed on the exposed portions of the conductive material 404 proximate to a polymer wall 403. The polymer wall 403 can have a height 405 that is comparable to the height of the thin chip 401. In other examples, polymer wall 403 can have a height 405 that is greater than or less than the height of the thin chip 401.


In the example systems, apparatus and methods described herein, the thin chip 401 can be one or more passive electronic components and/or active electronic components. Non-limiting examples of components that can be embedded according to any of the principles described herein include a transistor, an amplifier, a photodetector, a photodiode array, a display, a light-emitting device, a photovoltaic device, a sensor, a LED, a semiconductor laser array, an optical imaging system, a large-area electronic device, a logic gate array, a microprocessor, an integrated circuit, an electronic device, an optical device, an opto-electronic device, a mechanical device, a microelectromechanical device, a nanoelectromechanical device, a microfluidic device, a thermal device, or other device structures.


In an example, embedded devices according to the principles described herein can be formed by embedding a plurality of chips (or other device islands) and/or a plurality of the interconnects in the polymer well region formed in the flexible polymer according to the principles herein. In an example, the embedded device (e.g., thin chip 401) can be formed from an integrated device, or formed from a plurality of chips (or other device islands) interconnected by a plurality of interconnects, that is embedded according to the principles herein.


The thin chip 401 (including an integrated device or device island as described herein) can be made thinner than the thickness of the flexible polymer layer 404 from which the polymer walls 403 of the polymer well region 402 is created. The conductive material coating can include, but is not limited to, metal traces or other metal coatings. The polymer well region 402 can be formed in the flexible polymer through, e.g., etching through to the surface of the conductive material 404, drilling, or laser ablation of the flexible polymer. After the conductive material coating on the polymer layer has been patterned and the polymer well region formed, the chip (including any device island) can be disposed and fixed between walls of the polymer “well,” creating features above the polymer that are roughly the same height as the walls of the polymer well region. In other examples, the height 405 of the polymer wall 403 can be greater than or less than the height of the thin chip 401.


In various examples, the polymer well region 402 can be formed such that the positioned chip or other device island is shorter than or approximately equal to the well height 405. In other examples, the polymer well region 402 can be formed such that the positioned thin chip 401 (including a device island and/or an interconnect) is taller than the height of the walls of the well. The polymer walls 403 of the polymer well region 403 can be about 80%, about 90%, about, 100%, about 110%, about 120%, about 140%, or about 150% of the thickness of the thin chip 401 (including a device island and/or interconnect). In other examples, the polymer walls 403 of the polymer well region 403 can be about twice the thickness of the thin chip 401 or other device island and/or interconnect.


Similarly to the example structures in FIGS. 5A-5E, the polymer well region can have different conformations. FIGS. 5A-5E show non-limiting examples of different conformations of the polymer well region. As illustrated, the polymer well region 402 (including the polymer walls 403) can have a square shape, a rectangular shape, a rounded or other donut shape, or any other polygonal shape, such that a chip or other device island and/or interconnect can be disposed therein.



FIG. 5D shows a non-limiting example polymer well region (including the polymer walls) that is fabricated to not completely surround the thin chip (including a device island and/or the interconnect). In this example, the polymer well region 402 borders three sides of the thin chip 401. In the non-limiting example of FIG. 5E, the polymer well region (including the polymer walls) is fabricated to border portions of the sides of the thin chip 401 (including a device island and/or the interconnect), with some gaps in portions of the polymers of the polymer well regions.


In some examples, and similarly to as described in connection with FIG. 3 above, an adhesive can be caused to flow around the thin chip 401 (including any other device island and/or interconnect). For example, the adhesive can be caused to flow using a heat-treatment process. In an example, the heat-treatment process can be carried out at temperatures that vary from about 60° C. to about 250° C. The stacked layers, including the device islands and/or interconnects and adhesive layer between the flexible polymer walls 103 can be positioned between two metal plates and brought up to temperature to cause the adhesive to flow around the device islands and/or interconnects.



FIGS. 6A-6G illustrates an example process to fabricate an apparatus having a thin chip embedded within a polymer well region. In the example of FIGS. 6A-6G, a cavity is generated in the flexible polymer layer down to a portion of the metal layer to create a polymer well region. The thin chip is disposed within the polymer well region on a portion of the exposed conductive material. In this example, an electrical communication can be established between the thin chip 401 and the conductive material of the substrate without use of vias if, for example, a conductive adhesive is disposed between the thin chip and the conductive material. In an example, several of the apparatus according to this example can be stacked to create a multilayered device.



FIG. 6A shows a substrate that includes a flexible polymer layer 505 disposed on a layer of conductive material 506. The polymer layer 505 can include, as non-limiting examples, a polyimide film such as but not limited to a DuPont™KAPTON® film), or a liquid crystal polymer, with a thickness of about 20 μm, about 30 μm, about 35 μm, about 45 μm, about 55 μm, about 66 μm, or about 75 μm. The conductive material layer 506 can be a copper layer, and can be about 5 μm, about 8 μm, about 15 μm, about 20 μm, or about 30 μm thick.


As illustrated in FIG. 5B, a cavity can be formed in the polymer layer 505 to generate a polymer well region. For example, the polymer layer 505 can be etched to expose the conductive material layer 506. The cavity forms a polymer well region 507 including at least one polymer wall 504. In another example, the polymer well region 507 can be generated by a cavity formed from laser ablation, drilling, patterning, and/or die cutting. As illustrated in FIG. 5C, an adhesive 508 can be placed in the polymer well region 507 on a portion of the conductive material 506 prior to placement of the thin chip. In some examples, the adhesive 508 has low stress properties after being cured, so as to avoid cracking the die during the curing step. In this example, the adhesive 508 can be a thermoset adhesive that can withstand the temperatures of later processing without re-flowing. The adhesive 508 can be thermally and/or electrically conductive, or non-conductive (dielectric). For example, an electrically conductive adhesive can be used to establish an electrical connection between the die chip and a portion of the conductive material layer 506. In one example, this electrically conductive adhesive material can be employed to establish a ground plane connection for the completed device between the underside of the thin chip and the conductive material layer 506.


In another example, the polymer layer 505 does not include a base conductive material layer 506. In this example, the cavity generated to create the polymer wall 503 and the polymer well region 507 does not extend completely through the polymer layer 505. Rather, the cavity is created through a portion of the thickness of the polymer layer 505, into which the die 504 is later embedded. This example can be used to provide embedded thin chips based on commercially-available polyimides or liquid crystal polymers, including the polymers of PCB boards, without need for the more expensive processing of a photo-definable spin-on polyimide.


As illustrated in FIG. 6D, the thin chip die 504 is placed into the polymer well region 507. In some implementations, at this step, the adhesive 507 can be cured, securing the thin chip die 504 into the polymer well region 507. As illustrated in FIG. 6E, an adhesive polymer layer 509 can be disposed over the thin chip die in the polymer well region 507 and caused to flow into the area around the thin chip die through thermal processing. In the example of FIG. 6E, the adhesive 509 can be disposed between a polymer sheet 511 that includes a polymer layer 510 and the polymer well region 507. In some examples, the conductive material-clad polymer layer can be a metal-clad polyimide layer. In one examples, the layers 511 and 510 are the same as the respective polymer 505 and conductive material layer 506 used in forming the polymer well region 507. In another example, the polymer layer 511 and conductive material layer 510 can be different from polymer layer 505 and conductive material layer 506. For example, the respective layers can comprise different materials and/or have different thicknesses. In an example, the adhesive polymer layer 509 can be DuPont™ PYRALUX® Bond-Ply. In another example, the material of adhesive polymer layer 509 can be selected such that it is non-conductive (a dielectric) and capable of adhering flexible polymer layers.


As illustrated in FIG. 6F, the adhesive polymer layer 509, polymer layer 511, and conductive material layer 510 can be pressed onto the polymer well region and die layer. In this example, the layers can be coupled using vacuum lamination while being heated to a processing temperature. The vacuum lamination process can cause the adhesive polymer 509 to flow around the thin chip die 504, filling the polymer well region 507.


As illustrated in FIG. 56, the top metal layer 510 and/or the bottom conductive material layer 506 can be patterned and additional circuitry applied. In some examples, such as the example of FIG. 5G, channels can be created through at least one of the polymer layers and conductive material layers. For example, channels can be created by laser ablation or reactive ion etching to form vias 512 from the top surface of the embedded system to the electrical contact pads of the thin chip die. The channels can then be metalized, e.g., by electroplating, evaporation, and/or sputtering, to create electrical communication to circuitry within the thin chips of the embedded device. For example, metalized vias 512 can facilitate electrical communication with the thin chip die's bond-pads or other such electrical contacts. In some implementations, the through channel can be created without previously adding additional conductive material to the die's bond-pads (a process referred to in the industry as bumping the die). As non-limiting examples, metals such as copper, titanium, titanium-tungsten alloy, gold, nickel, and chromium can be used to metalize the vias.



FIGS. 7A-7D show an example process that can be used to generate a thinned chip. In this example, a chip having a thicker substrate is thinned prior to being embedded according to any of the systems, methods and apparatus described herein. In this example, the chip dies can be thinned using a dicing before grinding (DBG) technique. In some examples, the DBG technique allows the thinning of chips to about 5 μm, about 8 μm, about 10 μm, about 15 μm, about 25 μm, about 35 μm or about 50 μm thickness. The DBG technique also can reduce the risk of wafer bowing that can be seen in other grinding techniques. As illustrated in FIG. 7A, the process can begin with the initial half die cut of the die with a dicing saw 705 or other dicing process. As illustrated in FIG. 7B, the channels 701 in the wafer 700 by the die cut are cut to a depth 702 that is used as a guide to the desired thickness of the thinned die. As illustrated in FIG. 7C, the wafer 700 can be turned over, and the dies are applied to a tape 703. The tape 703 can hold the wafer in place as the backside of the wafer is ground to the desired thickness. When the grinding process reaches the channels 701 used to indicate a stop, the thinned chip dies 704 are released from the wafer 700. In an example, a second layer of tape can be applied now-separate backs of the chips. The thin chips can then be released from the tape 703 by exposing tap 703 to ultraviolet light. The thinned chips 740 can be used in any of the processing described herein in connection with a thin chip, including thin chip 101 and thin chip 401.



FIGS. 8A-8H show non-limiting examples of manufacturing processes that may be applied to one or more of the methods, apparatus, or systems described herein. For example, the manufacturing processes described in FIGS. 8A-8H can be performed on an embedded thin chip generated according to any of the systems, methods and apparatus described herein, including in FIGS. 1-7D. As illustrated in FIG. 8A, the processing can be applied to a polymer sheet 801 that includes a conductive metal coating on either side. In this example the conductive material layers 802 and 803 are 17.5 μm copper layers on a 75 μm thick KAPTON® substrate.


As illustrated in FIG. 8B, through channels are created from one conductive material layer to the second conductive material layer. The through channels are electroplated to create electrical vias 804. As illustrated in FIG. 8C, one or both of the conductive material layers 802 and 803 can be patterned.


Next, as illustrated in FIG. 8D, an adhesive layer 806 is inserted between the patterned conductive material layers 802 and 803 and additional polymer sheets 806. In this example, each of the polymer sheets 806 are metal-coated to create conductive layers 807. In another example, one or both of the second polymer sheets 806 are not metal-coated.


As illustrated in FIG. 8E, the adhesive layers 805 are subjected to heat and pressure. The heat and pressure cause the adhesive layers 805 to melt and flow into the gaps created by in the vias and the patterned conductive layers 802 and 803. Next, as illustrated in FIG. 8F, additional through channels are created and electroplated to connect the various conductive layers. In this example, the vias one or more layers. For example, via 808 electrically connects the bottom conductive layer 807 to internal conductive layer 802 and via 809 electrically connects bottom conductive layer 807 to internal conducive layer 803.


As illustrated in FIG. 8G, the now external conductive layers 807 can be patterned. In this example, both external conductive layers 807 are patterned, but in another example, one or none of the external layers 807 can be patterned. As illustrated in FIG. 8H, an overlay 810 can be applied to the external conductive layers 807. In another example, the overlay 810 can also be patterned. A corrosion and solder resistant metallization can be electro-deposited on any exposed copper traces.


While various inventive embodiments have been described and illustrated herein, those of ordinary skill in the art will readily envision a variety of other means and/or structures for performing the function and/or obtaining the results and/or one or more of the advantages described herein, and each of such variations and/or modifications is deemed to be within the scope of the inventive embodiments described herein. More generally, those skilled in the art will readily appreciate that all parameters, dimensions, materials, and configurations described herein are meant to be examples and that the actual parameters, dimensions, materials, and/or configurations will depend upon the specific application or applications for which the inventive teachings is/are used. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the specific inventive embodiments described herein. It is, therefore, to be understood that the foregoing embodiments are presented by way of example only and that inventive embodiments may be practiced otherwise than as specifically described. Inventive embodiments of the present disclosure are directed to each individual feature, system, article, material, kit, and/or method described herein. In addition, any combination of two or more such features, systems, articles, materials, kits, and/or methods, if such features, systems, articles, materials, kits, and/or methods are not mutually inconsistent, is included within the inventive scope of the present disclosure.


The above-described embodiments of the invention may be implemented in any of numerous ways. For example, some embodiments may be implemented using hardware, software or a combination thereof. When any aspect of an embodiment is implemented at least in part in software, the software code may be executed on any suitable processor or collection of processors, whether provided in a single device or computer or distributed among multiple devices/computers.


Also, the technology described herein may be embodied as a method, of which at least one example has been provided. The acts performed as part of the method may be ordered in any suitable way. Accordingly, embodiments may be constructed in which acts are performed in an order different than illustrated, which may include performing some acts simultaneously, even though shown as sequential acts in illustrative embodiments.


All definitions, as defined and used herein, should be understood to control over dictionary definitions, definitions in documents incorporated by reference, and/or ordinary meanings of the defined terms.


The indefinite articles “a” and “an,” as used herein in the specification, unless clearly indicated to the contrary, should be understood to mean “at least one.”


The phrase “and/or,” as used herein in the specification, should be understood to mean “either or both” of the elements so conjoined, i.e., elements that are conjunctively present in some cases and disjunctively present in other cases. Multiple elements listed with “and/or” should be construed in the same fashion, i.e., “one or more” of the elements so conjoined. Other elements may optionally be present other than the elements specifically identified by the “and/or” clause, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, a reference to “A and/or B”, when used in conjunction with open-ended language such as “comprising” can refer, in one embodiment, to A only (optionally including elements other than B); in another embodiment, to B only (optionally including elements other than A); in yet another embodiment, to both A and B (optionally including other elements); etc.


As used herein in the specification, “or” should be understood to have the same meaning as “and/or” as defined above. For example, when separating items in a list, “or” or “and/or” shall be interpreted as being inclusive, i.e., the inclusion of at least one, but also including more than one, of a number or list of elements, and, optionally, additional unlisted items. Only terms clearly indicated to the contrary, such as “only one of” or “exactly one of,” or “consisting of” will refer to the inclusion of exactly one element of a number or list of elements. In general, the term “or” as used herein shall only be interpreted as indicating exclusive alternatives (i.e. “one or the other but not both”) when preceded by terms of exclusivity, such as “either,” “one of” “only one of,” or “exactly one of.”


As used herein in the specification, the phrase “at least one,” in reference to a list of one or more elements, should be understood to mean at least one element selected from any one or more of the elements in the list of elements, but not necessarily including at least one of each and every element specifically listed within the list of elements and not excluding any combinations of elements in the list of elements. This definition also allows that elements may optionally be present other than the elements specifically identified within the list of elements to which the phrase “at least one” refers, whether related or unrelated to those elements specifically identified. Thus, as a non-limiting example, “at least one of A and B” (or, equivalently, “at least one of A or B,” or, equivalently “at least one of A and/or B”) can refer, in one embodiment, to at least one, optionally including more than one, A, with no B present (and optionally including elements other than B); in another embodiment, to at least one, optionally including more than one, B, with no A present (and optionally including elements other than A); in yet another embodiment, to at least one, optionally including more than one, A, and at least one, optionally including more than one, B (and optionally including other elements); etc

Claims
  • 1. An apparatus comprising: A) a substrate comprising a standoff well region, wherein: the substrate comprises a layer of a first conductive material disposed on a layer of a flexible polymer that is further stretchable; anda patterned portion of the first conductive material comprises a standoff bordering a portion of exposed flexible polymer, thereby forming the standoff well region; andB) a thin chip disposed within the standoff well region on a portion of the exposed flexible polymer proximate to the standoff,wherein a height of the standoff is comparable to a height of the thin chip.
  • 2. The apparatus of claim 1, wherein the thin chip is a thinned chip.
  • 3. The apparatus of claim 1, wherein the thin chip is disposed within the standoff well region such that the height of the standoff is greater than or about equal to the height of the thin chip.
  • 4. The apparatus of claim 1, further comprising: a polymer sheet disposed over the substrate;at least one via formed through the polymer sheet; anda second conductive material disposed on a portion of the polymer sheet proximate to the at least one via, such that the second conductive material forms an electrical communication with an electrical contact of the thin chip.
  • 5. The apparatus of claim 1, wherein the standoff completely surrounds the thin chip.
  • 6. The apparatus of claim 1, wherein a dielectric material is disposed between the standoff and a portion of the thin chip.
  • 7. The apparatus of claim 1, further comprising at least one additional layer disposed on the first conductive material or on the flexible polymer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of the apparatus.
  • 8. The apparatus of claim 1, wherein the standoff includes a plurality of standoffs that define the standoff well region, the standoff configured to border at least three sides of the thin chip.
  • 9. The apparatus of claim 1, wherein the standoff includes at least one gap between the plurality of standoffs that define the standoff well region.
  • 10. The apparatus of claim 1, wherein the standoff includes a plurality of standoffs that define the standoff well region, the standoff being configured to border all sides of the thin chip, the standoff further including at least one gap between the plurality of standoffs that define the standoff well region.
  • 11. A method for embedding thin chips, the method comprising: A) providing a substrate comprising a standoff well region, wherein: the substrate comprises a first conductive material layer disposed on a flexible polymer layer, wherein the flexible polymer layer is further stretchable; andat least a portion of the first conductive material layer is patterned to form a standoff bordering a portion of exposed flexible polymer, thereby forming the standoff well region; andB) disposing a thin chip on a portion of the exposed flexible polymer proximate to the standoff such that a height of the standoff is comparable to a height of the thin chip.
  • 12. The method of claim 11, wherein the height of the standoff is greater than or about equal to a height of a thin chip.
  • 13. The method of claim 11, further comprising: disposing a polymer sheet over the substrate;forming at least one via through the polymer sheet; anddisposing a conductive material on a portion of the second polymer sheet proximate to the at least one via, such that the conductive material forms an electrical communication with an electrical contact of the thin chip.
  • 14. The method of claim 11, further comprising disposing at least one additional layer on the first conductive material layer or on the flexible polymer layer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of an apparatus including the embedded thin chips.
  • 15. An apparatus comprising: A) a substrate comprising a polymer well region, wherein: the substrate comprises a flexible polymer layer disposed on a first conductive material layer, wherein the flexible polymer is further stretchable;a cavity is formed in at least a portion of the flexible polymer layer to form at least one polymer wall bordering a portion of exposed first conductive material layer, thereby forming the polymer well region; andB) a thin chip disposed within the polymer well region on at least a portion of the exposed first conductive material layer proximate to the at least one polymer wall.
  • 16. The apparatus of claim 15, wherein the thin chip is a thinned chip.
  • 17. The apparatus of claim 15, wherein the thin chip is disposed within the polymer well region such that the height of the at least one polymer wall is less than the height of the thin chip.
  • 18. The apparatus of claim 15, further comprising: a polymer sheet disposed over the substrate;at least one via formed through the polymer sheet; anda second conductive material disposed on a portion of the polymer sheet proximate to the at least one via, such that the second conductive material forms an electrical communication with an electrical contact of the thin chip.
  • 19. The apparatus of claim 15, wherein the at least one polymer wall completely surrounds the thin chip.
  • 20. The apparatus of claim 15, wherein a dielectric material is disposed between the at least one polymer wall and a portion of the thin chip.
  • 21. The apparatus of claim 15, further comprising at least one additional layer disposed on the first conductive material layer or on the flexible polymer layer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of the apparatus.
  • 22. A method for embedding thin chips, the method comprising: A) providing a substrate comprising a polymer well region, the substrate comprising a first conductive material layer and a flexible polymer layer that is further stretchable, the polymer well region comprising at least one polymer wall formed from a portion of the flexible polymer layer and a base region formed from at least a portion of the first conductive material layer; andB) disposing a thin chip within the polymer well region on a portion of the first conductive material layer proximate to the at least one polymer wall.
  • 23. The method of claim 22, wherein the thin chip is disposed within the polymer well region such that the first conductive material layer is in physical and electrical communication with the thin chip.
  • 24. The method of claim 22, further comprising: a polymer sheet disposed over the substrate;at least one via formed through the polymer sheet; anda second conductive material disposed on a portion of the polymer sheet proximate to the at least one via, such that the second conductive material forms an electrical communication with an electrical contact of the thin chip.
  • 25. The method of claim 22, further comprising disposing at least one additional layer on the first conductive material layer or on the flexible polymer layer, wherein the at least one additional layer positions the thin chip at a neutral mechanical plane of an apparatus that include the embedded thin chips.
CROSS-REFERENCES TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No. 13/844,638, filed Mar. 15, 2013, now allowed, which claims priority to and the benefits of U.S. provisional application Ser. No. 61/711,629, filed Oct. 9, 2012, entitled “Embedding Thinned Chips and Interconnects in Flex Polymer,” each of which are hereby incorporated by reference herein in their entireties.

US Referenced Citations (275)
Number Name Date Kind
3716861 Root Feb 1973 A
3805427 Epstein Apr 1974 A
4304235 Kaufman Dec 1981 A
4416288 Freeman Nov 1983 A
4658153 Brosh Apr 1987 A
4918811 Eichelberger Apr 1990 A
5306917 Black Apr 1994 A
5326521 East Jul 1994 A
5331966 Bennett Jul 1994 A
5360987 Shibib Nov 1994 A
5454270 Brown Oct 1995 A
5491651 Janic Feb 1996 A
5567975 Walsh Oct 1996 A
5580794 Allen Dec 1996 A
5617870 Hastings Apr 1997 A
5811790 Endo Sep 1998 A
5817008 Rafert Oct 1998 A
5907477 Tuttle May 1999 A
6063046 Allum May 2000 A
6239980 Fillion May 2001 B1
6282960 Samuels Sep 2001 B1
6343514 Smith Feb 2002 B1
6387052 Quinn May 2002 B1
6421016 Phillips Jul 2002 B1
6567158 Falcial May 2003 B1
6641860 Kaiserman Nov 2003 B1
6665187 Alcoe Dec 2003 B1
6775906 Silverbrook Aug 2004 B1
6784844 Boakes Aug 2004 B1
6861757 Shimoto Mar 2005 B2
6938783 Chung Sep 2005 B2
6965160 Cobbley Nov 2005 B2
6987314 Yoshida Jan 2006 B1
7259030 Daniels Aug 2007 B2
7265298 Maghribi Sep 2007 B2
7302751 Hamburgen Dec 2007 B2
7337012 Maghribi Feb 2008 B2
7487587 Vanfleteren Feb 2009 B2
7491892 Wagner Feb 2009 B2
7521292 Rogers Apr 2009 B2
7557367 Rogers Jul 2009 B2
7618260 Daniel Nov 2009 B2
7622367 Nuzzo Nov 2009 B1
7651891 Nguyen Jan 2010 B1
7727228 Abboud Jun 2010 B2
7739791 Brandenburg Jun 2010 B2
7759167 Vanfleteren Jul 2010 B2
7936062 Humpston May 2011 B2
7960246 Flamand Jun 2011 B2
7982296 Nuzzo Jul 2011 B2
8097926 De Graff Jan 2012 B2
8198621 Rogers Jun 2012 B2
8207473 Axisa Jun 2012 B2
8217381 Rogers Jul 2012 B2
8337656 Nishio Dec 2012 B2
8372726 De Graff Feb 2013 B2
8389862 Arora Mar 2013 B2
8431828 Vanfleteren Apr 2013 B2
8440546 Nuzzo May 2013 B2
8520399 Daniel Aug 2013 B2
8536667 De Graff Sep 2013 B2
8552299 Rogers Oct 2013 B2
8664699 Nuzzo Mar 2014 B2
8679888 Rogers Mar 2014 B2
8729524 Rogers May 2014 B2
8754396 Rogers Jun 2014 B2
8865489 Rogers Oct 2014 B2
8886334 Ghaffari Nov 2014 B2
8905772 Rogers Dec 2014 B2
9012784 Arora Apr 2015 B2
9082025 Fastert Jul 2015 B2
9105555 Rogers Aug 2015 B2
9105782 Rogers Aug 2015 B2
9119533 Ghaffari Sep 2015 B2
9123614 Graff Sep 2015 B2
9159635 Elolampi Oct 2015 B2
9168094 Lee Oct 2015 B2
9171794 Rafferty Oct 2015 B2
9186060 De Graff Nov 2015 B2
20010012918 Swanson Aug 2001 A1
20010021867 Kordis Sep 2001 A1
20020026127 Balbierz Feb 2002 A1
20020082515 Campbell Jun 2002 A1
20020094701 Biegelsen Jul 2002 A1
20020113739 Howard Aug 2002 A1
20020119292 Venkatasanthanam Aug 2002 A1
20020128700 Cross, Jr. Sep 2002 A1
20020145467 Minch Oct 2002 A1
20020151934 Levine Oct 2002 A1
20020158330 Moon Oct 2002 A1
20030017848 Engstrom Jan 2003 A1
20030045025 Coyle Mar 2003 A1
20030097165 Krulevitch May 2003 A1
20030120271 Burnside Jun 2003 A1
20030162507 Vatt Aug 2003 A1
20030214408 Grajales Nov 2003 A1
20030236455 Swanson Dec 2003 A1
20040006264 Mojarradi Jan 2004 A1
20040085469 Johnson May 2004 A1
20040092806 Sagon May 2004 A1
20040106334 Suzuki Jun 2004 A1
20040135094 Niigaki Jul 2004 A1
20040138558 Dunki-Jacobs Jul 2004 A1
20040149921 Smyk Aug 2004 A1
20040178466 Merrill Sep 2004 A1
20040192082 Wagner Sep 2004 A1
20040201134 Kawai Oct 2004 A1
20040203486 Shepherd Oct 2004 A1
20040221370 Hannula Nov 2004 A1
20040243204 Maghribi Dec 2004 A1
20050021103 DiLorenzo Jan 2005 A1
20050067293 Naito Mar 2005 A1
20050070778 Lackey Mar 2005 A1
20050096513 Ozguz May 2005 A1
20050113744 Donoghue May 2005 A1
20050139683 Yi Jun 2005 A1
20050171524 Stern Aug 2005 A1
20050203366 Donoghue Sep 2005 A1
20060003709 Wood Jan 2006 A1
20060038182 Rogers Feb 2006 A1
20060071349 Tokushige Apr 2006 A1
20060084394 Engstrom Apr 2006 A1
20060106321 Lewinsky May 2006 A1
20060128346 Yasui Jun 2006 A1
20060154398 Qing Jul 2006 A1
20060160560 Josenhans Jul 2006 A1
20060248946 Howell Nov 2006 A1
20060257945 Masters Nov 2006 A1
20060264767 Shennib Nov 2006 A1
20060286785 Rogers Dec 2006 A1
20060292756 Primavera Dec 2006 A1
20070015357 Ashley Jan 2007 A1
20070027514 Gerber Feb 2007 A1
20070031283 Davis Feb 2007 A1
20070045819 Edwards Mar 2007 A1
20070103697 Degertekin May 2007 A1
20070108389 Makela May 2007 A1
20070113399 Kumar May 2007 A1
20070123756 Kitajima May 2007 A1
20070270672 Hayter Nov 2007 A1
20080046080 Vanden Bulcke Feb 2008 A1
20080074383 Dean Mar 2008 A1
20080075414 Van Ostrand Mar 2008 A1
20080096620 Lee Apr 2008 A1
20080139894 Szydlo-Moore Jun 2008 A1
20080157235 Rogers Jul 2008 A1
20080193749 Thompson Aug 2008 A1
20080204021 Leussler Aug 2008 A1
20080211087 Mueller-Hipper Sep 2008 A1
20080237840 Alcoe Oct 2008 A1
20080259576 Johnson Oct 2008 A1
20080287167 Caine Nov 2008 A1
20080313552 Buehler Dec 2008 A1
20090000377 Shipps Jan 2009 A1
20090001550 Li Jan 2009 A1
20090015560 Robinson Jan 2009 A1
20090017884 Rotschild Jan 2009 A1
20090048556 Durand Feb 2009 A1
20090088750 Hushka Apr 2009 A1
20090107704 Vanfleteren Apr 2009 A1
20090154736 Lee Jun 2009 A1
20090184254 Miura Jul 2009 A1
20090204168 Kallmeyer Aug 2009 A1
20090215385 Waters Aug 2009 A1
20090225751 Koenck Sep 2009 A1
20090261828 Nordmeyer-Massner Oct 2009 A1
20090273909 Shin Nov 2009 A1
20090291508 Babu Nov 2009 A1
20090294803 Nuzzo Dec 2009 A1
20090322480 Benedict Dec 2009 A1
20100002402 Rogers Jan 2010 A1
20100059863 Rogers Mar 2010 A1
20100072577 Nuzzo Mar 2010 A1
20100073669 Colvin Mar 2010 A1
20100087782 Ghaffari Apr 2010 A1
20100090781 Yamamoto Apr 2010 A1
20100090824 Rowell Apr 2010 A1
20100116526 Arora May 2010 A1
20100117660 Douglas May 2010 A1
20100178722 De Graff Jul 2010 A1
20100245011 Chatzopoulos Sep 2010 A1
20100271191 De Graff Oct 2010 A1
20100298895 Ghaffari Nov 2010 A1
20100317132 Rogers Dec 2010 A1
20100321161 Isabell Dec 2010 A1
20100327387 Kasai Dec 2010 A1
20110011179 Gustafsson Jan 2011 A1
20110034912 De Graff Feb 2011 A1
20110051384 Kriechbaum Mar 2011 A1
20110054583 Litt Mar 2011 A1
20110101789 Salter May 2011 A1
20110121822 Parsche May 2011 A1
20110140897 Purks Jun 2011 A1
20110175735 Forster Jul 2011 A1
20110184320 Shipps Jul 2011 A1
20110215931 Callsen Sep 2011 A1
20110218756 Callsen Sep 2011 A1
20110218757 Callsen Sep 2011 A1
20110220890 Nuzzo Sep 2011 A1
20110277813 Rogers Nov 2011 A1
20110306851 Wang Dec 2011 A1
20120016258 Webster Jan 2012 A1
20120051005 Vanfleteren Mar 2012 A1
20120052268 Axisa Mar 2012 A1
20120065937 De Graff Mar 2012 A1
20120074546 Chong Mar 2012 A1
20120087216 Keung Apr 2012 A1
20120091594 Landesberger Apr 2012 A1
20120092178 Callsen Apr 2012 A1
20120092222 Kato Apr 2012 A1
20120101413 Beetel Apr 2012 A1
20120101538 Ballakur Apr 2012 A1
20120108012 Yasuda May 2012 A1
20120157804 Rogers Jun 2012 A1
20120165759 Rogers Jun 2012 A1
20120172697 Urman Jul 2012 A1
20120226130 De Graff Sep 2012 A1
20120244848 Ghaffari Sep 2012 A1
20120256308 Helin Oct 2012 A1
20120316455 Rahman Dec 2012 A1
20120320581 Rogers Dec 2012 A1
20120327608 Rogers Dec 2012 A1
20130041235 Rogers Feb 2013 A1
20130062996 Udayakumar Mar 2013 A1
20130099358 Elolampi Apr 2013 A1
20130100618 Rogers Apr 2013 A1
20130118255 Callsen May 2013 A1
20130150693 D'Angelo Jun 2013 A1
20130185003 Carbeck Jul 2013 A1
20130192356 De Graff Aug 2013 A1
20130200268 Rafferty Aug 2013 A1
20130211761 Brandsma Aug 2013 A1
20130214300 Lerman Aug 2013 A1
20130215467 Fein Aug 2013 A1
20130225965 Ghaffari Aug 2013 A1
20130237150 Royston Sep 2013 A1
20130245388 Rafferty Sep 2013 A1
20130274562 Ghaffari Oct 2013 A1
20130313713 Arora Nov 2013 A1
20130316442 Meurville Nov 2013 A1
20130316487 De Graff Nov 2013 A1
20130320503 Nuzzo Dec 2013 A1
20130321373 Yoshizumi Dec 2013 A1
20140001058 Ghaffari Jan 2014 A1
20140012160 Ghaffari Jan 2014 A1
20140012242 Lee Jan 2014 A1
20140022746 Hsu Jan 2014 A1
20140039290 De Graff Feb 2014 A1
20140097944 Fastert Apr 2014 A1
20140110859 Rafferty Apr 2014 A1
20140140020 Rogers May 2014 A1
20140188426 Fastert Jul 2014 A1
20140191236 Nuzzo Jul 2014 A1
20140216524 Rogers Aug 2014 A1
20140240932 Hsu Aug 2014 A1
20140249520 Ghaffari Sep 2014 A1
20140303452 Ghaffari Oct 2014 A1
20140340857 Hsu Nov 2014 A1
20140374872 Rogers Dec 2014 A1
20140375465 Fenuccio Dec 2014 A1
20150001462 Rogers Jan 2015 A1
20150019135 Kacyvenski Jan 2015 A1
20150035680 Li Feb 2015 A1
20150069617 Arora Mar 2015 A1
20150099976 Ghaffari Apr 2015 A1
20150100135 Ives Apr 2015 A1
20150194817 Lee Jul 2015 A1
20150237711 Rogers Aug 2015 A1
20150241288 Keen Aug 2015 A1
20150260713 Ghaffari Sep 2015 A1
20150272652 Ghaffari Oct 2015 A1
20150286913 Fastert Oct 2015 A1
20150320472 Ghaffari Nov 2015 A1
20150335254 Fastert Nov 2015 A1
20150342036 Elolampi Nov 2015 A1
Foreign Referenced Citations (56)
Number Date Country
0585670 Mar 1994 EP
2259062 Dec 2010 EP
05-087511 Apr 1993 JP
2009-170173 Jul 2009 JP
WO 9938211 Jul 1999 WO
WO 03021679 Mar 2003 WO
WO 2005122285 Dec 2005 WO
WO 2007003019 Jan 2007 WO
WO 2007116344 Oct 2007 WO
WO 2007136726 Nov 2007 WO
WO 2008030960 Mar 2008 WO
WO 2009111641 Sep 2009 WO
WO 2009114689 Sep 2009 WO
WO 2010036807 Apr 2010 WO
WO 2010042653 Apr 2010 WO
WO 2010042957 Apr 2010 WO
WO 2010046883 Apr 2010 WO
WO 2010056857 May 2010 WO
WO 2010081137 Jul 2010 WO
WO 2010082993 Jul 2010 WO
WO 2010102310 Sep 2010 WO
WO 2010132552 Nov 2010 WO
WO 2011003181 Jan 2011 WO
WO 2011041727 Apr 2011 WO
WO 2011084450 Jul 2011 WO
WO 2011084709 Jul 2011 WO
WO 2011127331 Oct 2011 WO
WO 2012125494 Sep 2012 WO
WO 2012166686 Dec 2012 WO
WO 2013010171 Jan 2013 WO
WO 2013022853 Feb 2013 WO
WO 2013033724 Mar 2013 WO
WO 2013034987 Mar 2013 WO
WO 2013049716 Apr 2013 WO
WO 2013052919 Apr 2013 WO
WO 2013170032 Nov 2013 WO
WO 2014007871 Jan 2014 WO
WO 2014058473 Apr 2014 WO
WO 2014059032 Apr 2014 WO
WO 2014106041 Jul 2014 WO
WO 2014110176 Jul 2014 WO
WO 2014130928 Aug 2014 WO
WO 2014130931 Aug 2014 WO
WO 2014186467 Nov 2014 WO
WO 2014197443 Dec 2014 WO
WO 2014205434 Dec 2014 WO
WO 2015021039 Feb 2015 WO
WO 2015054312 Apr 2015 WO
WO 2015077559 May 2015 WO
WO 2015080991 Jun 2015 WO
WO 2015102951 Jul 2015 WO
WO 2015103483 Jul 2015 WO
WO 2015103580 Jul 2015 WO
WO 2015127458 Aug 2015 WO
WO 2015134588 Sep 2015 WO
WO 2015138712 Sep 2015 WO
Non-Patent Literature Citations (60)
Entry
U.S. Appl. No. 12/575,008, filed Oct. 7, 2009, R. Ghaffari et al., Catheter Balloon Having Stretchable Circuitry and Sensor Array.
U.S. Appl. No. 14/004,408, filed Mar. 9, 2012, R. Ghaffari et al., Integrated Devices to Facilitate Quantitative Assays and Diagnostics.
U.S. Appl. No. 13/481,843, filed May 27, 2012, B. Elolampi et al., Electronic, Optical and/or Mechanical Apparatus and Systems and Methods for Fabricating Same.
U.S. Appl. No. 13/499,626, filed Jun. 12, 2012, R. Ghaffari et al., Protective Cases With Integrated Electronics.
U.S. Appl. No. 13/568,022, filed Aug. 6, 2012, R. D'angelo et al., Catheter Balloon Methods and Apparatus Employing Sensing Elements.
U.S. Appl. No. 13/603,290, filed Sep. 4, 2012, C. Rafferty et al., Electronics for Detection of a Condition of Tissue.
U.S. Appl. No. 13/631,739, filed Sep. 28, 2012, C. Rafferty et al., Electronics for Detection of a Property of a Surface.
U.S. Appl. No. 13/646,613, filed Oct. 5, 2012, R. Ghaffari et al., Cardiac Catheter Employing Conformal Electronics for Mapping.
U.S. Appl. No. 13/843,873, filed Mar. 15, 2013, Y. Hsu, Strain Isolation Structures for Stretchable Electronics.
U.S. Appl. No. 13/843,880, filed Mar. 15, 2013, Y. Hsu, Strain Relief Structures for Stretchable Interconnects.
U.S. Appl. No. 13/844,399, filed Mar. 15, 2013, S. Fastert et al., Conformal Electronics Integrated With Apparel.
U.S. Appl. No. 13/844,508, filed Mar. 15, 2013, S. Fastert et al., Monitoring Hit Count for Impact Events.
U.S. Appl. No. 13/844,635, filed Mar. 15, 2013, R. Ghaffari et al., Catheter Balloon Having Stretchable Integrated Circuitry and Sensor Array.
U.S. Appl. No. 13/844,638, filed Mar. 15, 2013, C. Rafferty et al., Embedding Thin Chips in Polymer.
U.S. Appl. No. 13/844,677, filed Mar. 15, 2013, S. Lee et al., Catheter Device Including Flow Sensing.
U.S. Appl. No. 13/844,767, filed Mar. 15, 2013, R. Ghaffari et al., Catheter Balloon Employing Force Sensing Elements.
U.S. Appl. No. 14/147,347, filed Jan. 3, 2014, R. Ghaffari et al., Catheter or Guidewire Device Including Flow Sensing and Use Thereof.
U.S. Appl. No. 14/276,413, filed May 13, 2014, Y. Hsu et al., Conformal Electronics Including Nested Serpentine Interconnects.
U.S. Appl. No. 14/294,808, filed Jun. 3, 2014, I. Kacyvenski et al., Motion Sensor and Analysis.
U.S. Appl. No. 14/344,686, filed Jun. 23, 2014, J. Fenuccio et al., Band With Conformable Electronics.
U.S. Appl. No. 14/451,981, filed Aug. 5, 2014, X. Li et al., Flexible Temperature Sensor Including Conformable Electronics.
U.S. Appl. No. 14/488,544, filed Sep. 17, 2014, W. Arora et al., Extremely Stretchable Electronics.
U.S. Appl. No. 14/510,868, filed Oct. 9, 2014, B. Ives, Utility Gear Including Conformal Sensors.
U.S. Appl. No. 29/506,439, filed Oct. 15, 2014, X. Li et al., Electronics Device Having Antenna.
U.S. Appl. No. 14/518,856, filed Oct. 20, 2014, R. Ghaffari et al., Systems, Methods, and Devices Using Stretchable or Flexible Electronics for Medical Applications.
U.S. Appl. No. 14/524,817, filed Oct. 27, 2014, X. Li et al., Conformal Electronic Devices.
U.S. Appl. No. 14/588,765, filed Jan. 2, 2015, S. Lee et al., Integrated Devices for Low Power Quantitative Measurements.
U.S. Appl. No. 14/630,335, filed Feb. 24, 2015, B. Keen, Conformal Electronics with Deformation Indicators.
U.S. Appl. No. 14/656,046, filed Mar. 12, 2015, R. Ghaffari et al., Quantification of a Change in Assay.
U.S. Appl. No. 14/726,136, filed May 29, 2015, R. Gahffari et al., Catheter Balloon Methods an Apparatus Employing Sensing.
U.S. Appl. No. 14/726,142, filed May 29, 2015, R. Ghaffari et al., Cardiac Catheter Employing Conformal Electronics for Mapping.
U.S. Appl. No. 14/746,659, filed Jun. 22, 2015, S. Fastert et al., Conformal Electronics Integrated With Apparel.
U.S. Appl. No. 14/758,946, filed Jul. 1, 2015, S. Fastert et al., Application for Monitoring a Property of a Surface.
U.S. Appl. No. 14/812,197, filed Jul. 29, 2015, B. De Graff et al., Methods and Applications of Non-Planar Imaging Arrays.
U.S. Appl. No. 14/819,040, filed Aug. 5, 2015, B. Elolampi et al., A Method for Frabricating a Flexible Electronic Structure and a Flexible Electronic Structure.
U.S. Appl. No. 14/838,196, filed Aug. 27, 2015, G. Callsen et al., Methods and Apparatus for Conformal Sensing of Force and/or Acceleration at a Person's Head.
U.S. Appl. No. 14/859,112, filed Sep. 18, 2015, C. Rafferty et al., Embedded Thin Chips in Polymer.
U.S. Appl. No. 14/859,680, filed Sep. 21, 2015, D. Garlock, Methods and Apparatuses for Shaping and Looping Bonding Wires That Serve as Stretchable and Bendable Interconnects.
U.S. Appl. No. 14/870,719, filed Sep. 30, 2015, M. Dalal et al., Flexible Electronics Circuits With Embedded Integrated Circuit Die and Methods of Making and Using the Same.
U.S. Appl. No. 14/870,802, filed Sep. 30, 2015, M. Dalal et al., Flexible Interconnects for Modules of Integrated Circuits and Methods of Making and Using the same.
U.S. Appl. No. 14/874,148, filed Oct. 2, 2015, Stephen P. Lee, Catheter Device Including Flow Sensing.
U.S. Appl. No. 14/924,440, filed Oct. 27, 2015, Bassel De Graff, Systems, Methods, and Devices Having Stretchable Integrated Circuitry for Sensing and Delivering Therapy.
U.S. Appl. No. 14/947,558, filed Nov. 20, 2015, Yung-Yu Hsu, Strain Isolation Structures for Stretchable Electronics.
Camalhal et al., “Electrochemical Detection in a Paper-Based Separation Device”, Analytical Chemistry, vol. 82, No. 3, (1162-1165) (4 pages) (Jan. 7, 2010).
Demura et al., “Immobilization of Glucose Oxidase with Bombyx mori Silk Fibroin by Only Stretching Treatment and its Application to Glucose Sensor,” Biotechnology and Bioengineering, vol. 33, 598-603 (6 pages) (1989).
Ellerbee et al., “Quantifying Colorimetric Assays in Paper-Based Microfluidic Devices by Measuring the Transmission of Light through Paper,” Analytical Chemistry, vol. 81, No. 20 8447-8452, (6 pages) (Oct. 15, 2009).
Halsted, “Ligature and Suture Material,” Journal of the American Medical Association, vol. LX, No. 15, 1119-1126, (8 pages) (Apr. 12, 1913).
Kim et al., “Complementary Metal Oxide Silicon Integrated Circuits Incorporating Monolithically Integrated Stretchable Wavy Interconnects,” Applied Physics Letters, vol. 93, 044102-044102.3 (3 pages) (Jul. 31, 2008).
Kim et al., “Dissolvable Films of Silk Fibroin for Ultrathin Conformal Bio-Integrated Electronics,” Nature, 1-8 (8 pages) (Apr. 18, 2010).
Kim et al., “Materials and Noncoplanar Mesh Designs for Integrated Circuits with Linear Elastic Responses to Extreme Mechanical Deformations,” PNAS, vol. 105, No. 48, 18675-18680 (6 pages) (Dec. 2, 2008).
Kim et al., “Stretchable and Foldable Silicon Integrated Circuits,” Science, vol. 320, 507-511 (5 pages) (Apr. 25, 2008).
Kim et al., “Electrowetting on Paper for Electronic Paper Display,” ACS Applied Materials & Interfaces, vol. 2, No. 11, (3318-3323) (6 pages) (Nov. 24, 2010).
Ko et al., “A Hemispherical Electronic Eye Camera Based on Compressible Silicon Optoelectronics,” Nature, vol. 454, 748-753 (6 pages) (Aug. 7, 2008).
Lawrence et al., “Bioactive Silk Protein Biomaterial Systems for Optical Devices,” Biomacromolecules, vol. 9, 1214-1220 (7 pages) (Nov. 4, 2008).
Meitl et al., “Transfer Printing by Kinetic Control of Adhesion to an Elastomeric Stamp,” Nature, vol. 5, 33-38 (6 pages) (Jan. 2006).
Omenetto et al., “A New Route for Silk,” Nature Photonics, vol. 2, 641-643 (3 pages) (Nov. 2008).
Omenetto et al., “New Opportunities for an Ancient Material,” Science, vol. 329, 528-531 (5 pages) (Jul. 30, 2010).
Siegel et al., “Foldable Printed Circuit Boards on Paper Substrates,” Advanced Functional Materials, vol. 20, No. 1, 28-35, (8 pages) (Jan. 8, 2010).
Tsukada et al., “Structural Changes of Silk Fibroin Membranes Induced by Immersion in Methanol Aqueous Solutions,” Journal of Polymer Science, vol. 32, 961-968 (8 pages) (1994).
Wang et al., “Controlled Release From Multilayer Silk Biomaterial Coatings to Modulate Vascular Cell Responses” Biomaterials, 29, 894-903 (10 pages) (Nov. 28, 2008).
Related Publications (1)
Number Date Country
20160111353 A1 Apr 2016 US
Provisional Applications (1)
Number Date Country
61711629 Oct 2012 US
Continuations (1)
Number Date Country
Parent 13844638 Mar 2013 US
Child 14859112 US