This invention relates in general to electronic assemblies and testing thereof. In particular, the invention relates to a method of manufacture of protruding, controlled aspect ratio and shape contacts for uses in interconnections of assemblies and testing thereof.
Interconnections which involve protruding electrical contacts are used extensively in packaging of electronics. Pin grid array packages, both plastic and ceramic, housing a variety of semiconductors, use area arrays of pins as interconnect contacts for connection to circuit boards. Pins can be attached to their receiving package conductors by use of a variety of methods. For ceramic packages, pins are inserted into non-reacting brazing fixtures and are then gang-brazed to corresponding conductive terminals on the package. This approach is characterized by significant non-recurring engineering costs and lead times involved in production of the brazing fixture. Plastic pin grid array packages most commonly use pins which are inserted into metallized through holes in a circuit board, while the dimensions of pins and the holes normally chosen to facilitate good contact between the walls of the pins and the coating of the holes. This approach has a disadvantage in that the coated holes and the pins block some circuit routing channels within the circuit board, thus forcing either use of narrow circuit traces, or increase in circuit board area, either of which results in increased costs.
Permanent connection of the pin grid array packages to circuit boards often is accomplished by inserting pins through corresponding holes in a circuit board, the pins protruding to a predetermined length beyond the circuit board. A resulting assembly then is passed through a wave soldering machine, and the pin grid array thus is soldered to the circuit board. Alternatively, a pin grid array can be inserted into a low insertion force or zero insertion force socket for a demountable assembly. Such a socket, in its turn, normally is connected permanently to a board.
A current trend in interconnections is toward face-to-face surface mounting of components to boards and semiconductor chips to substrates. This approach is best accomplished with protruding contact structures on top of (or otherwise protruding from) contact carrying conductive terminals or traces. Conductive terminal arrangements on facing components and substrates are increasingly being made of the area array type, as this allows for larger contact-to-contact separation as compared with components characterized by peripheral arrangement of interconnection contacts.
Pins attached to either ceramic or plastic packages according to the traditional methods are, in general, not appropriate for mounting to patterns of surface contacts on circuit boards, due to pin length variation. For surface mounting, the pins would have to be planarized, which represents an additional expensive step subsequent to pin assembly. In addition, there is a significant cost penalty associated with production of pin-carrying packages with pin-to-pin separations of 50 mils, or lower.
There is currently an increasing need for a low cost method of attaching protruding contacts from conductive terminals, arising from proliferation of surface mountable area array contact packages. Stand-off height of protruding contacts is particularly important when coefficients of thermal expansion of components and of circuit board materials differ significantly. The same is true for attachment of un-packaged semiconductor chips to interconnection substrates. These expansive concerns call for a low cost, high volume method of manufacturing protruding, controlled aspect ratio or shape electrical contacts on top of (or otherwise protruding from) contact carrying conductive terminals, on top of any device or circuit bearing substrate, board material or component, and its applications to surface mount interconnections of devices, components and substrates.
U.S. Pat. Nos. 5,189,507, 5,095,187 and 4,955,523 disclose a method of manufacturing of controlled height protruding contacts in a shape of wires for direct soldering to a mating substrate. The wires-are bonded to terminals without use of any material other than that of wire and the terminals, using ultrasonic wirebonding methods and equipment, which comprises a standard industry technique for interconnecting semiconductor chips to packages. The patents also describe a bonding head which incorporates a wire weakening means for controlling length of free standing severed wires. Vertically free standing wires present a handling problem during assembly, which is addressed in the patents by providing for polymer encapsulation of bonds between the wires and terminals. The polymer coating, which is optional, also compensates for another disadvantage of the approach, namely weak points along the wire, typically the point of contact between the wire and terminal metallization, and in case of ball bonding, in a heat effected zone of the wire just above impression of a bonding capillary. While these patents provide for controlled height contacts, and discuss 2d to 20 d aspect ratios, in practice they do not assume controlled aspect ratios for all kinds of protruding contacts which are required in various applications. For instance, standard, high speed wirebonding equipment could not handle a 30 mil diameter wire. Therefore, according to these inventions, a 30 mil diameter, 100 mil high contact could only be produced on lower throughput specialized equipment, at higher cost. In addition, a gold wire as described in a preferred embodiment, would have a problem of dissolving in solder during a soldering cycle, which causes long term reliability problems with solder joints similarly, direct soldering of copper contacts would in many cases result in undesirable reaction between copper and solder at elevated temperatures. While nickel metal-is the material of choice for solder joint reliability, nickel wire can not be used for ultrasonic wirebonding to metal terminals due to its high mechanical strength and passivating, oxide forming properties. Chemical, physical and mechanical properties, as well as permissible dimensions and shapes of the protuberant contacts produced according to this invention are limited to the capabilities and materials choices compatible with known wire bonding techniques.
U.S. Pat. No. 3,373,481 describes a method of interconnecting semiconductor components on substrates by means of dissolving protruding gold projections on the components in solder masses formed on the substrate terminals. The gold projections are formed by compression and extrusion of gold balls against the terminals. This approach is incapable of producing high aspect ratio protruding contacts because of limitations of the extrusion method. In addition, dissolution of gold in solder, as taught by this approach creates a problem due to reliability concerns. The method also limits selection of contact material to easily extrudable metals, like gold.
There are several methods in the prior art for controlled elongation of solder masses between a component and a substrate. The goal is to create a column-like solder shape, preferably an hourglass shape, in order to achieve increased resistance to thermal cycling. To that end, U.S. Pat. No. 5,148,968 discloses a web-like device which upon heating during solder reflow stretches the solder connections, forming such hourglass shaped solder columns. Aspect ratios of the columns are determined by the mass of solder in the joint, dimensions of the solder wettable terminals on the substrate and the component, and by the characteristics of the stretch device. This method is only limited to contact materials which are reflowed during the assembly, and requires external hardware for forming the contact shape, which adds cost of the hardware and increases the process complexity.
U.S. Pat. No. 4,878,611 teaches formation of controlled geometry solder joints by applying controlled volumes of solder to a semiconductor package and a substrate, bringing solder masses in contact, and reflowing the solder masses while maintaining controlled separation between the component and the substrate through mechanical means. This approach also requires hardware means for maintaining longitudinal dimension of the contacts, and does not lend itself to standard practices of surface mount soldering, in which industry already has made substantial time and capital investments.
In the same spirit, U.S. Pat. No. 4,545,610 discloses a process for forming elongated solder joints between a plurality of solder wettable terminals on a semiconductor component and a substrate by means of solder extenders, which transform the shape of the solder joints into uniform hourglass shapes during a solder reflow step. This approach requires additional, non-standard processing of either a silicon device, or on a substrate, which includes attachment of reflowable solder extenders, and non-reflowable means of maintaining vertical spacing between the silicon device and the substrate.
U.S. Pat. No. 5,154,341 discloses the use of a spacer bump which is composed of a solder alloy which does not melt at the temperature of component soldering. A eutectic solder microball is placed on a contact, and upon the reflow the reflowable solder encases the non-reflowable spacer, and produces an hourglass shaped joint. The aspect ratios of the joint contacts are controlled by dimensions of the spacer.
U.S. Pat. No. 4,332,341 teaches solid state-bonding of solder preforms to components, substrates or both, for further joining. Resulting protruding solder contacts either collapse during soldering if they consist of eutectic solder, or do not reflow at all, when they consist of higher melting temperature solder. In the latter case, a component would not have the benefit of a self-alignment effect as the pool of solder is confined to the vicinity of the terminals, and a main portion of the joint which controls aspect ratio, does not melt.
U.S. Pat. No. 4,914,814 discloses a process for fabricating solder columns through use of a mold with an array of pin holes, which are filled with solder, brought into contact with terminals on a component, and bonded by melting the solder which wets the terminals. The component with columns is then bonded to a substrate through reflow in a solder with lower melting temperature than the solder of the columns. This approach requires generating a mold for each solder column array pattern, commonly involving undesirable non-recurring engineering expenses and associated increase in delivery times.
U.S. Pat. No. 3,509,270 discloses a printed circuit assembly which is interconnected with a dielectric carrier that has a plurality of spring elements positioned in its apertures, the springs are optionally encased in a solder material to facilitate permanent electrical contact between circuit elements. This approach requires a custom interposer pattern manufactured for each application, while solder coated springs would have to be placed individually inside the apertures. Additionally, soldering usually requires flux, while the interposer material makes it difficult to clean flux after the reflow process.
U.S. Pat. Nos. 4,664,309 and 4,705,205 disclose a device and a method for interconnection with reinforced solder preforms which use a retaining member provided with apertures. The retaining member is optionally dissolved to leave resilient interconnect structures. The solder columns maintain their shape in the molten state, supported by particles, filaments, spiral metallic wire or tape. 20 to 80% by weight of filler material is specified. This approach, as several of the above described approaches, requires a custom made retaining member for every interconnect application, and therefore requires an additional non-recurring engineering expense and increased delivery time for every production order.
U.S. Pat. No. 4,642,889 teaches use of an interposer with a plurality of interconnect areas, interconnect areas comprise wire means surrounded with solder, and incorporate a soldering flux material. Upon heating the solder reflows and connects to the terminals of the mating components and boards, while the wires in the middle of each solder joint insure a column-like joint shape. The interposer preferably is dissolved away. While providing means for controlled aspect ratio interconnect joints, this approach also requires use of a custom manufactured interposer and inevitable non-recurring engineering expenses and increased delivery times. In addition, when improved alignment of the interconnect to the terminals is required, as terminal-to-terminal distances decrease, this approach suffers from heat and environmental effects on interposer material, causing it to distort or change dimension during processing steps, which makes the alignment difficult, and limits this approach to relatively coarse terminal-to-terminal pitch applications.
An elongated protruding solder contact is taught according to U.S. Pat. No. 5,130,779, by sequentially encapsulating solder deposits with a barrier metal. This approach insures that a staged solder deposit does not collapse upon reflow, and a controlled aspect ratio solder contact is thus formed. In order for the barrier metal to be effective, the walls of sequentially deposited solder masses must have a slope. Deposition of such a structure of solder is a lengthy and expensive process.
A method of attaching highly compliant leads to an array matrix of contacts on a semiconductor package is disclosed in U.S. Pat. No. 4,751,199. An array of leads is manufactured according to the required pattern with temporary tab structures tying the leads together. Compliant leads are gang bonded to terminals on the semiconductor package, and tabs are removed leaving compliant protruding contact leads, ready for attachment to a substrate. This approach, like the interposer techniques described above, requires specific tooling for every new package with a distinct pattern of the array of contacts.
One object of the present invention is to provide a high volume, low cost manufacturing process for production of precise shape and geometry protuberant conductive contacts on a wide variety of electronic components, the contacts having a controlled set of physical, metallurgical and mechanical properties, bulk and surface. Such protuberant contacts can be employed to satisfy electrical, thermal or geometrical requirements in various aspects of electronic interconnection applications. An inventive, multiple stage process is provided, according to which, first, wire stems are bonded to contact carrying terminals, the stems being shaped in three dimensional space, to define skeletons of the resulting contacts. The conductive contacts are then completed through at least one deposition step of a coating which envelopes or jackets the wire skeletons and the terminals. The common coating not only helps to “anchor” protruding contacts to the terminals, but also provides for characteristics of the protuberant contacts with respect to long term stability of their engagement contact with mating electronic component, including but not limited to interconnection substrates, semiconductor devices, interconnect or test sockets. The coating also determines soldering assembly characteristics, as well as long term effects from contact with solder. The coating, along with the wire material properties, determines the mechanical characteristics of the resulting protuberant, contact. The wire serves as a “skeleton” of a resulting protruding contact, and the coating serves as its. “muscle”.
The wire skeleton can be bonded employing high productivity, highly automated ultrasonic, thermosonic and thermocompression wirebonding equipment (hereinafter referred to as ultrasonic wirebonding equipment). The wirebonding equipment can be organized for ball bonding type ultrasonic wirebonding process, typically used for gold or copper wirebonding, but modifiable for use with other types of single phase or noble metal coated wires. Wire skeletons consisting of free standing single or multiple wire stems can be produced. As required by the shape and dimensions of the resulting conductive contacts, the stems can be standing normal to a terminal or at an angle thereto, or can be formed in three dimensional space. Alternatively, wire skeletons produced using an ultrasonic ball bonder can be produced by forming a traditional wire-bonding loop, which originates and terminates on a contact carrying terminal, or which originates on the contact carrying terminal and terminates on a sacrificial conductor outside the terminal area. Then the sacrificial conductor is selectively dissolved away after completion of the contact processing. Optionally, a wedge bonding type ultrasonic wirebonder can be employed, in which case controlled shape loops of wire are formed with both ends of a loop on the same terminal, or they are formed by originating the loops within the area of the terminal and terminating or severing the loops outside the terminals. Both types of wirebonders are available commercially from a variety of suppliers, and are highly automated, with the bonding speeds exceeding 10 wires per second.
An additional object of the present invention is to produce array patterns of contacts for unique component designs, without incurring costs and delays associated with production of unique tooling. This object is achieved through use of a sequential wirebonding process for attaching of the wire skeletons to the terminals, and then overcoating them in a single, non-pattern-specific step. Location targeting and geometric characteristics are entered into an electronic control system of the wirebonding equipment with a specific set of commands. A program controls all aspects of wire forming and shaping process, as well as bond characteristics. Production of the multiple protruding contacts does not require time-limiting and costly production of molds, masks or the like, which otherwise would be specific to every incoming order. This object is exemplified by application of the present invention to production of integrated pin-shaped contacts for ceramic pin grid array packages. This is achieved by bonding straight vertical, single stem skeletons, perpendicular to the surface of terminals, and overcoating them with a conductive structural metal or alloy, consisting substantially of nickel, copper, cobalt, iron or alloys thereof, with the thickness of the deposit determined by the required pin diameter value. This can also be accomplished with equal ease on plastic pin carrying substrates.
Yet another object of the present invention is to create protruding, tower-like solder contacts which substantially maintain a well controlled aspect ratio even when the solder is molten. This object is achieved through first bonding a wire skeleton which will define the final shape and aspect ratio of a solder contact, then optionally overcoating it with a barrier layer which prevents long term reaction between the solder and the wire, and finally depositing a mass of solder which wets the skeleton with a barrier, and clings onto the skeleton even after multiple reflows.
Yet another object of the present invention is to create controlled shape resilient contacts on top of (or otherwise protruding from) contact carrying terminals arranged in various patterns, including arrays. This object is achieved by overcoating the wire skeleton with at least one coating having a predetermined combination of thickness, yield strength and elastic modulus to insure predetermined force-to-deflection characteristics of resulting spring contacts.
Yet another object of the present invention is to produce protruding contacts on top of (or otherwise protruding from) a multitude of contact-carrying terminals, where the terminals have varying vertical coordinates, corresponding to an origin point of the protruding contacts, while uppermost points of the protruding contacts extend to a vertical coordinate which is substantially identical, within a permissible tolerance level for the component or substrate which is to be subsequently connected to the contacts. In a different embodiment related to this object, the terminals can originate on various electronic components, while the protuberant contacts extend to a substantially identical vertical coordinate. This object is achieved by controlling a wire severing step, by always severing the wire at a predetermined vertical coordinate. Overcoatings then follow the skeleton wire shape and geometry, yielding a contact having a controlled vertical coordinate level, regardless of the Z-axis point of origination of the contact, e.g. plane of the terminal. Some of the terminals having varying Z-coordinates and overlying the component, can optionally and additionally overlie single or multiple electronic devices, placed on the electronic component. In another embodiment related to this object of the present invention, the vertical coordinate of the tips of the protuberant contacts can be controlled by the software algorithm of the appropriately arranged automated wirebonding equipment.
The foregoing and other objects and advantages will appear more fully from a Summary of the Invention which follows viewed in conjunction with drawings which accompany and form part of this Application. In the drawings:
a and 1b are schematic representations of a known ball-and-wedge technique to form a loop-like wire skeleton of a protruding electrical contact.
a, 6b and 6c depict a sequence of bonding one end of a loop-like stem to a sacrificial pad, overcoating the skeleton, and a following step of removal of a sacrificial pad, resulting in protuberant contact with a floating end.
a, 7b and 7c represent schematically a sequence of bonding single stem, perpendicular skeletons to contact-carrying terminals.
The method of the present invention relies on wirebonding equipment to produce controlled aspect ratio and shape wire skeletons, which are subsequently overcoated with a desired material in order to produce a required set of properties for protuberant electrical contacts.
In the embodiment of the present invention represented in
Referring now to
The coating method also optionally includes so-called physical and chemical vapor methods of conductor material deposition. These optional techniques are detailed in a book by M. Ohring, The Materials Science of Thin Films, Academic Press, 1992. Coating methods also include and contemplate deposition of conductors through various decomposition processes of gaseous, liquid or solid precursors.
Nickel has a strong tendency to form an oxide and is, therefore, not the best choice as a contact metal. It requires large contact forces to break through the oxide. For low contact force applications, it requires a second noble or semi-noble coating layer on top. Gold, silver, elements of the platinum group and their alloys are preferred choices as a noble or semi-noble overcoating layer. Similarly, in other instances, multiple layers, comprising conductive overcoating 40, can be selected to tailor the set of properties of the protuberant contact to a given application.
Within the method of the present invention, a plurality of wire stems can be employed to create a wire skeleton. Referring now to
In a growing number of applications there is a requirement for controlled aspect ratio columns of solder on top of an area array of terminals on ceramic and plastic semiconductor packages. Most often, an area array of balls made of a solder alloy, commonly a eutectic alloy of lead and tin, is used in surface mounting of components with an array of terminals to a matching array of contacts on a circuit board. Long term resistance of such solder contacts is determined by the height, shape and the material characteristics of the solder joints. The method of the present invention provides for controlled shape solder contacts formed around a wire skeleton. Referring now to
Deposition of solder overcoating can be accomplished, for example, by sending a package or a substrate through a solder wave process cycle in a solder wave equipment. The solder wets the barrier layer 41, and bridges among adjacent wire portions forming the loop-shaped stems, to assume a shape depicted in
A preferred embodiment for a solder column contact, depicted in
Both types of protuberant contacts, solder contacts 52 shown in
Further increase of the overall proportion of solder material in protuberant solder contacts can be achieved by using multiple wire stem skeletons. Referring now to
Protuberant solder contacts 52 and 53 in
In the spirit of the present invention, but in yet an alternate embodiment, either the ball or a wedge bond of the wire stem can be formed outside the area of a contact carrying terminal. As shown in
Referring now to
After vertical wire stems 62 are formed on contact carrying terminals 90, and after the severing step which defines single stem skeletons 33, as shown in
The protuberant vertical contacts 55 shown in
Thickness and material composition of conductive layer 44 shown in
Referring again to
Wire skeletons consisting of multiple vertical wire stems are especially useful for protuberant solder contact applications.
In another embodiment of the present invention, the solder overcoat 42, which completes a protuberant solder contact 57, is a continuous coating deposited over a wire skeleton without a barrier layer between the solder and the wire and terminals. Gold wire without a barrier is not an appropriate choice for this embodiment, because a continuous reaction between the solder and the gold embrittles the solder or solder joint to a substrate or to a component. However, a copper wire is useful to form the wire skeleton, and then a solder coating is applied using, for example, a solder wave approach referred to above.
An alternative approach to forming solder columns on top of wire skeletons is to plate electrolytically the solder. The electrolytically deposited solder is appropriate for standard surface mount assembly. Alternatively, the solder can be reflowed after electrolytic deposition, and prior to the assembly.
The method of forming wire skeletons described by means of ball bonding, shown in
One preferred embodiment for a resilient overcoating is a nickel or a nickel alloy layer. For example, Ni electroplated out of standard nickel sulfamate solution could be used. Such nickel deposit can be produced with compressive internal stress which would improve the spring characteristics, as well as varying strengthand ductility levels. A plated nickel-cobalt alloy has greater strength and improved resilient properties. Rhodium, ruthenium or other elements of the platinum group and their alloys with gold, silver and copper constitute another group of preferred embodiment overcoat materials. Tungsten or nickel can also be deposited by chemical vapor deposition techniques, and represent another preferred embodiment materials.
Gold is the most commonly used wire material for ultrasonic wire bonding applications, but it is soft and it may not be an appropriate skeleton material for a spring contact if it constitutes a significant portion of the spring cross-sectional area. One embodiment of the present invention provides for a common high speed bonding of gold skeleton wires. An alloying layer is then deposited, which when reacted with gold, forms a gold alloy, the alloy having higher strength then pure gold. One preferred embodiment provides for deposition of tin on top of gold wire, with subsequent reaction of gold and tin at a temperature below the melting temperature of gold-tin eutectic. A gold-tin alloy results, which is significantly stronger than gold.
The contact properties of the springs in
Resilient protuberant contact produced by the method of the present invention rely on the shape of a skeleton and the properties of the conductive material for its spring properties. In another embodiment of the present invention, wire stems or wire skeletons can be additionally shaped by a tool external to a wirebonding equipment, prior or before the deposition step.
Protuberant contacts, as manufactured according to the present invention, are mounted on terminals on top of various interconnection substrates; such as laminate printed circuit boards, Teflon based circuit boards, multi-layer ceramic substrates, silicon based substrates, varieties of hybrid substrates, and other substrates for integration of electronic systems known to those skilled in the art. The contacts can also be put on top of terminals directly on semiconductor devices, such as silicon and gallium arsenide devices, for subsequent demountable or permanent attachment to interconnection substrates. The contacts could also be put on terminals on one or both sides of electronic components or devices, such as ceramic and plastic packages housing semiconductor components, and other devices. The contacts could be put directly on top of passive devices, such as resistors and capacitors.
One arrangement is shown in
Due to the fact that columns 57 can be manufactured with any solder, including eutectic tin-lead solder, the most of the volume of the contact 57 melts during the reflow, and the solder redistributes itself according to the surface area of its reinforcing wire skeleton and the surface area of its mating terminals. This feature allows one to achieve in some cases a self-alignment effect, e.g. the component is pulled into registration with the terminal array on a substrate due to surface forces of solder wetting. This feature is in contrast to other techniques for solder column utilization, which typically use higher melting temperature solder, and only the portions of solder deposited onto terminals on a substrate melt, which reduces the absolute value of solder-surface wetting forces.
The contacts of the present invention can be put on both sides of an electronic package or a substrate for multiple interconnection to various devices. Alternatively, the contacts can be put on one side of an electronic package for interconnection to a semiconductor device, and on the other side of the semiconductor package for subsequent interconnection to a circuit board or any other substrate.
Spring contacts produced by the present invention are used as a standard means of interconnect between substrates and components which have matching patterns of terminals in many cases it is desirable not to manufacture the contacts on either substrates or components, or devices, as the process yield associated with contact manufacturing would cause loss of costly devices, substrates or components. One embodiment of the present invention, illustrated in
It will be apparent to those skilled in the art that wide deviations may be made from the foregoing preferred embodiments of the invention without departing from a main theme of invention set forth in claims which follow herein.
This application is a continuation of U.S. patent application Ser. No. 10/290,639, filed Nov. 7, 2002 now U.S. Pat. No. 6,818,840, which is a continuation of U.S. patent application Ser. No. 09/245,499, filed Feb. 5, 1999 (abandoned), which is continuation of U.S. patent application Ser. No. 08/457,479, filed Jun. 1, 1995 (now U.S. Pat. No. 6,049,976), which is a divisional of U.S. patent application Ser. No. 08/152,812, filed Nov. 16, 1993 (now U.S. Pat. No. 5,476,211).
Number | Name | Date | Kind |
---|---|---|---|
2429222 | Ehrhardt et al. | Oct 1947 | A |
2820932 | Looney | Jan 1958 | A |
2869040 | Pifer | Jan 1959 | A |
3087239 | Clagett | Apr 1963 | A |
3119172 | Mazenro et al. | Jan 1964 | A |
3188535 | Walraven et al. | Jun 1965 | A |
3189799 | Moroney | Jun 1965 | A |
3241011 | De Mille et al. | Mar 1966 | A |
3271851 | Hayes | Sep 1966 | A |
3373481 | Lins | Mar 1968 | A |
3389457 | Goldman et al. | Jun 1968 | A |
3445770 | Harmon | May 1969 | A |
3460238 | Christy et al. | Aug 1969 | A |
3509270 | Dube et al. | Apr 1970 | A |
3519890 | Ashby | Jul 1970 | A |
3569789 | Jenik | Mar 1971 | A |
3616532 | Beck | Nov 1971 | A |
3623127 | Glenn | Nov 1971 | A |
3662454 | Miller | May 1972 | A |
3672047 | Sakamot et al. | Jun 1972 | A |
3734386 | Hazel | May 1973 | A |
3747198 | Benson et al. | Jul 1973 | A |
3753665 | McCary et al. | Aug 1973 | A |
3779804 | Urban | Dec 1973 | A |
3787966 | Klessika | Jan 1974 | A |
3795037 | Luttmer | Mar 1974 | A |
3842189 | Southgate | Oct 1974 | A |
3844909 | McCary et al. | Oct 1974 | A |
3849728 | Evans | Nov 1974 | A |
3849872 | Hubacher | Nov 1974 | A |
3924918 | Friend | Dec 1975 | A |
3982811 | Siu et al. | Sep 1976 | A |
4038599 | Bove | Jul 1977 | A |
4067104 | Tracy | Jan 1978 | A |
4085502 | Ostman et al. | Apr 1978 | A |
4295700 | Sado | Oct 1981 | A |
4303291 | Dines | Dec 1981 | A |
4330165 | Sado | May 1982 | A |
4332341 | Minetti | Jun 1982 | A |
4385341 | Main | May 1983 | A |
4418857 | Ainslie et al. | Dec 1983 | A |
4522893 | Bohlen et al. | Jun 1985 | A |
4523144 | Okubo et al. | Jun 1985 | A |
4532152 | Elarde | Jul 1985 | A |
4545610 | Lakritz et al. | Oct 1985 | A |
4548451 | Benarr et al. | Oct 1985 | A |
4553192 | Babuka et al. | Nov 1985 | A |
4567433 | Ohkubo et al. | Jan 1986 | A |
4615573 | White et al. | Oct 1986 | A |
4618879 | Mizukoshi et al. | Oct 1986 | A |
4634199 | Anhalt et al. | Jan 1987 | A |
4642889 | Grabbe | Feb 1987 | A |
4664309 | Allen et al. | May 1987 | A |
4667219 | Lee et al. | May 1987 | A |
4697143 | Lockwood | Sep 1987 | A |
4705205 | Allen et al. | Nov 1987 | A |
4707657 | Boegh-Petersen | Nov 1987 | A |
4724383 | Hart | Feb 1988 | A |
4727319 | Shahriary | Feb 1988 | A |
4728751 | Canestate | Mar 1988 | A |
4732313 | Kobayashi et al. | Mar 1988 | A |
4746857 | Sakai | May 1988 | A |
4751199 | Phy | Jun 1988 | A |
4757256 | Whann et al. | Jul 1988 | A |
4764122 | Sorel et al. | Aug 1988 | A |
4764723 | Strid | Aug 1988 | A |
4764848 | Simpson | Aug 1988 | A |
4777564 | Derfiny et al. | Oct 1988 | A |
4780836 | Miyazaki | Oct 1988 | A |
4784872 | Moeller et al. | Nov 1988 | A |
4793814 | Zifcak et al. | Dec 1988 | A |
4821148 | Kobayashi et al. | Apr 1989 | A |
4860433 | Miura | Aug 1989 | A |
4870356 | Tingley | Sep 1989 | A |
4878611 | LoVasco et al. | Nov 1989 | A |
4893172 | Matsumoto et al. | Jan 1990 | A |
4899099 | Mendenhall | Feb 1990 | A |
4899107 | Corbett | Feb 1990 | A |
4914814 | Behun et al. | Apr 1990 | A |
4918032 | Jain et al. | Apr 1990 | A |
4955523 | Carlomagno et al. | Sep 1990 | A |
4961052 | Tada | Oct 1990 | A |
4983907 | Crowley | Jan 1991 | A |
4985676 | Karasawa | Jan 1991 | A |
4989069 | Hawkins | Jan 1991 | A |
4996629 | Christiansen et al. | Feb 1991 | A |
4998062 | Ikeda | Mar 1991 | A |
4998885 | Beaman | Mar 1991 | A |
5007576 | Congleton et al. | Apr 1991 | A |
5007872 | Tang | Apr 1991 | A |
5010388 | Sasame et al. | Apr 1991 | A |
5045410 | Hiesbock et al. | Sep 1991 | A |
5045975 | Cray et al. | Sep 1991 | A |
5047711 | Smith | Sep 1991 | A |
5055778 | Kanji et al. | Oct 1991 | A |
5055780 | Takagi et al. | Oct 1991 | A |
5059143 | Grabbe | Oct 1991 | A |
5066907 | Tarzwell et al. | Nov 1991 | A |
5067007 | Kanji et al. | Nov 1991 | A |
5070297 | Kwon | Dec 1991 | A |
5071359 | Arnio et al. | Dec 1991 | A |
5073117 | Malhi | Dec 1991 | A |
5086337 | Noro et al. | Feb 1992 | A |
5090119 | Tsuda et al. | Feb 1992 | A |
5091772 | Kohara et al. | Feb 1992 | A |
5095187 | Gliga | Mar 1992 | A |
5097100 | Jackson | Mar 1992 | A |
5109596 | Driller et al. | May 1992 | A |
5110032 | Akiyama et al. | May 1992 | A |
5123850 | Elder et al. | Jun 1992 | A |
5130644 | Ott | Jul 1992 | A |
5130779 | Agarwala et al. | Jul 1992 | A |
5136367 | Chiu | Aug 1992 | A |
5139427 | Boyd et al. | Aug 1992 | A |
5140405 | King | Aug 1992 | A |
5148968 | Schmidt et al. | Sep 1992 | A |
5154341 | Melton et al. | Oct 1992 | A |
5157325 | Murphy | Oct 1992 | A |
5163834 | Chapin et al. | Nov 1992 | A |
5166774 | Banerji et al. | Nov 1992 | A |
5173055 | Grabbe | Dec 1992 | A |
5187020 | Kwon et al. | Feb 1993 | A |
5189507 | Carlomagno et al. | Feb 1993 | A |
5195237 | Cray et al. | Mar 1993 | A |
5198752 | Miyata | Mar 1993 | A |
5199889 | McDevitt, Jr. | Apr 1993 | A |
5214375 | Ikeuchi | May 1993 | A |
5218292 | Goto | Jun 1993 | A |
5220277 | Reitinger | Jun 1993 | A |
5228861 | Grabbe | Jul 1993 | A |
5230632 | Baumberger et al. | Jul 1993 | A |
5239126 | Oshiba | Aug 1993 | A |
5240588 | Uchida | Aug 1993 | A |
5247250 | Rios | Sep 1993 | A |
5266889 | Harwood | Nov 1993 | A |
5294039 | Pai et al. | Mar 1994 | A |
5296744 | Lang et al. | Mar 1994 | A |
5297967 | Baumberger et al. | Mar 1994 | A |
5298464 | Schlesinger et al. | Mar 1994 | A |
5299939 | Walker et al. | Apr 1994 | A |
5303938 | Miller | Apr 1994 | A |
5317479 | Pai et al. | May 1994 | A |
5325052 | Yamashita | Jun 1994 | A |
5329228 | Comeau | Jul 1994 | A |
5336992 | Saito | Aug 1994 | A |
5338223 | Melatti | Aug 1994 | A |
5349495 | Visel et al. | Sep 1994 | A |
5350947 | Takekawa t al. | Sep 1994 | A |
5355081 | Nakata | Oct 1994 | A |
5359227 | Liang et al. | Oct 1994 | A |
5363038 | Love | Nov 1994 | A |
5366380 | Reymond | Nov 1994 | A |
5386344 | Beaman et al. | Jan 1995 | A |
5389743 | Simila et al. | Feb 1995 | A |
5389873 | Ishii | Feb 1995 | A |
5391984 | Worley | Feb 1995 | A |
5396104 | Kimura | Mar 1995 | A |
5397997 | Tuckerman | Mar 1995 | A |
5399982 | Driller et al. | Mar 1995 | A |
5410162 | Tigelaar | Apr 1995 | A |
5414298 | Grube et al. | May 1995 | A |
5422516 | Hosokawa et al. | Jun 1995 | A |
5424651 | Green | Jun 1995 | A |
5434513 | Fujii | Jul 1995 | A |
5436571 | Karasawa | Jul 1995 | A |
5440241 | King | Aug 1995 | A |
5442282 | Rostoker et al. | Aug 1995 | A |
5444366 | Chiu | Aug 1995 | A |
5444386 | Mizumura | Aug 1995 | A |
5446395 | Goto | Aug 1995 | A |
5455390 | Distefano et al. | Oct 1995 | A |
5457398 | Schwindt | Oct 1995 | A |
5457400 | Ahmad | Oct 1995 | A |
5461328 | Devereaux | Oct 1995 | A |
5476211 | Khandros | Dec 1995 | A |
5479108 | Cheng | Dec 1995 | A |
5479109 | Lau | Dec 1995 | A |
5483175 | Ahmad | Jan 1996 | A |
5488292 | Tsuta | Jan 1996 | A |
5495395 | Yoneda et al. | Feb 1996 | A |
5495667 | Farnworth et al. | Mar 1996 | A |
5497079 | Yamada et al. | Mar 1996 | A |
5506498 | Anderson | Apr 1996 | A |
5510724 | Itoyama | Apr 1996 | A |
5517126 | Yamaguchi | May 1996 | A |
5518964 | DiStefano et al. | May 1996 | A |
5525545 | Grube et al. | Jun 1996 | A |
5532609 | Harwood | Jul 1996 | A |
5532610 | Tsujide | Jul 1996 | A |
5532614 | Chiu | Jul 1996 | A |
5534784 | Lum | Jul 1996 | A |
5534786 | Kaneko | Jul 1996 | A |
5536973 | Yamaji | Jul 1996 | A |
5550482 | Sano | Aug 1996 | A |
5555422 | Nakano | Sep 1996 | A |
5557501 | DiStefano et al. | Sep 1996 | A |
5559444 | Farnworth | Sep 1996 | A |
5559446 | Sano | Sep 1996 | A |
5568056 | Ishimoto | Oct 1996 | A |
5570032 | Atkins | Oct 1996 | A |
5585737 | Shibata | Dec 1996 | A |
5598627 | Saka et al. | Feb 1997 | A |
5599446 | Junker et al. | Feb 1997 | A |
5601740 | Eldridge et al. | Feb 1997 | A |
5606196 | Lee et al. | Feb 1997 | A |
5613861 | Smith | Mar 1997 | A |
5621263 | Kaida | Apr 1997 | A |
5626953 | Fujimoto et al. | May 1997 | A |
5627406 | Pace | May 1997 | A |
5639558 | Tatsumi et al. | Jun 1997 | A |
5656830 | Zechman | Aug 1997 | A |
5708297 | Clayton | Jan 1998 | A |
5773889 | Love et al. | Jun 1998 | A |
5829128 | Eldridge et al. | Nov 1998 | A |
5832601 | Eldridge et al. | Nov 1998 | A |
5852871 | Khandros | Dec 1998 | A |
5864946 | Eldridge et al. | Feb 1999 | A |
5900738 | Khandros et al. | May 1999 | A |
5917707 | Khandros et al. | Jun 1999 | A |
5926951 | Khandros et al. | Jul 1999 | A |
5983493 | Eldridge et al. | Nov 1999 | A |
5998228 | Eldridge et al. | Dec 1999 | A |
6023103 | Chang et al. | Feb 2000 | A |
6032356 | Eldridge et al. | Mar 2000 | A |
6049976 | Khandros | Apr 2000 | A |
6110823 | Eldridge et al. | Aug 2000 | A |
6168974 | Chang et al. | Jan 2001 | B1 |
6184587 | Khandros et al. | Feb 2001 | B1 |
6215670 | Khandros | Apr 2001 | B1 |
6242803 | Khandros et al. | Jun 2001 | B1 |
6246247 | Eldridge et al. | Jun 2001 | B1 |
6252175 | Khandros | Jun 2001 | B1 |
6274823 | Khandros et al. | Aug 2001 | B1 |
6279227 | Khandros et al. | Aug 2001 | B1 |
6336269 | Eldridge et al. | Jan 2002 | B1 |
6476333 | Khandros et al. | Nov 2002 | B1 |
6538214 | Khandros | Mar 2003 | B1 |
6615485 | Eldridge et al. | Sep 2003 | B1 |
6624648 | Eldridge et al. | Sep 2003 | B1 |
6655023 | Eldridge et al. | Dec 2003 | B1 |
6727579 | Eldridge et al. | Apr 2004 | B1 |
6778406 | Eldridge et al. | Aug 2004 | B1 |
6818840 | Khandros | Nov 2004 | B1 |
6835898 | Eldridge et al. | Dec 2004 | B1 |
20010002624 | Khandros et al. | Jun 2001 | A1 |
20020117330 | Eldridge et al. | Aug 2002 | A1 |
Number | Date | Country |
---|---|---|
1026876 | Mar 1958 | DE |
3129568 | Apr 1982 | DE |
2166 | May 1979 | EP |
396248 | Nov 1990 | EP |
402756 | Dec 1990 | EP |
500074 | Aug 1992 | EP |
528367 | Feb 1993 | EP |
593966 | Apr 1994 | EP |
614089 | Sep 1994 | EP |
708338 | Apr 1996 | EP |
2643753 | Aug 1990 | FR |
2680284 | Feb 1993 | FR |
54-146581 | Nov 1979 | JP |
56-26446 | Mar 1981 | JP |
60-150657 | Aug 1985 | JP |
61-170054 | Jul 1986 | JP |
61-244057 | Oct 1986 | JP |
61-287254 | Dec 1986 | JP |
62-165994 | Jul 1987 | JP |
63-56924 | Mar 1988 | JP |
01-313969 | Dec 1989 | JP |
03-068163 | Mar 1991 | JP |
03-142847 | Jun 1991 | JP |
04-65840 | Mar 1992 | JP |
04-240570 | Aug 1992 | JP |
05-129357 | May 1993 | JP |
1003396 | Mar 1983 | SU |
WO 9112706 | Aug 1991 | WO |
WO 9403036 | Feb 1994 | WO |
9514314 | May 1995 | WO |
WO 9602959 | Feb 1996 | WO |
Number | Date | Country | |
---|---|---|---|
20050028363 A1 | Feb 2005 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 08152812 | Nov 1993 | US |
Child | 08457479 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 10290639 | Nov 2002 | US |
Child | 10938267 | US | |
Parent | 09245499 | Feb 1999 | US |
Child | 10290639 | US | |
Parent | 08457479 | Jun 1995 | US |
Child | 09245499 | US |